Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Issue date: 1/25/2019 Revision date: 1/26/2022 Supersedes: 1/25/2019 Version: 1.3 1/26/2022 (Revision date) USA - en 1/12 SECTION 1: Identification 1.1. Identification Product form : Mixture Trade name : Iso-HEET? Gas Line Antifreeze Synonym : 584403 Part numbers : 28204; 28202; 28206; 28214 1.2. Recommended use and restrictions on use No additional information available 1.3. Supplier Gold Eagle Co 4400 S Kildare Ave Chicago, IL, 60632-4372 T 773-376-4400 https://www.goldeagle.com/ 1.4. Emergency telephone number Emergency number : INFOTrac: 1-800-535-5053 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS US classification Flammable liquids Category 2 H225 Highly flammable liquid and vapor Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation Carcinogenicity Category 2 H351 Suspected of causing cancer Specific target organ toxicity ? Single exposure, Category 3, Narcosis H336 May cause drowsiness or dizziness Full text of H statements : see section 16 2.2. GHS Label elements, including precautionary statements GHS US labeling Hazard pictograms (GHS US) : Signal word (GHS US) : Danger Hazard statements (GHS US) : H225 - Highly flammable liquid and vapor H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness H351 - Suspected of causing cancer Precautionary statements (GHS US) : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting equipment. P242 - Use only non-sparking tools. Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 2/12 P243 - Take precautionary measures against static discharge. P261 - Avoid breathing dust/fume/gas/mist/vapors/spray. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - If exposed or concerned: Get medical advice/attention. P312 - Call a poison center or doctor if you feel unwell. P337+P313 - If eye irritation persists: Get medical advice/attention. P370+P378 - In case of fire: Use media other than water to extinguish. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. 2.3. Other hazards which do not result in classification No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS US classification Isopropyl alcohol CAS-No.: 67-63-0 ? 75 Flam. Liq. 1, H224 Eye Irrit. 2, H319 STOT SE 3, H336 Ethylbenzene CAS-No.: 100-41-4 0.07498473 ? 0.15012173 Flam. Liq. 2, H225 Acute Tox. 4 (Inhalation), H332 Carc. 2, H351 STOT RE 2, H373 Asp. Tox. 1, H304 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : IF exposed or concerned: Get medical advice/attention. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Call a poison center/doctor/physician if you feel unwell. Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 3/12 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects : May cause drowsiness or dizziness. Symptoms/effects after eye contact : Eye irritation. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Specific hazards arising from the chemical Fire hazard : Highly flammable liquid and vapor. Hazardous decomposition products in case of fire : Toxic fumes may be released. 5.3. Special protective equipment and precautions for fire-fighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 4/12 SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapors may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well-ventilated area. Avoid breathing dust/fume/gas/mist/vapors/spray. Avoid contact with skin and eyes. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Iso-HEET? Gas Line Antifreeze No additional information available Ethylbenzene (100-41-4) USA - OSHA - Occupational Exposure Limits Local name Ethyl benzene OSHA PEL (TWA) [1] 435 mg/m? OSHA PEL (TWA) [2] 100 ppm Regulatory reference (US-OSHA) OSHA Annotated Table Z-1 Isopropyl alcohol (67-63-0) USA - ACGIH - Occupational Exposure Limits Local name 2-Propanol ACGIH OEL TWA [ppm] 200 ppm ACGIH OEL STEL [ppm] 400 ppm Remark (ACGIH) TLV? Basis: Eye & URT irr; CNS impair. Notations: A4 (Not classifiable as a Human Carcinogen); BEI Regulatory reference ACGIH 2019 USA - OSHA - Occupational Exposure Limits Local name Isopropyl alcohol OSHA PEL (TWA) [1] 980 mg/m? OSHA PEL (TWA) [2] 400 ppm Regulatory reference (US-OSHA) OSHA Annotated Table Z-1 Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 5/12 8.2. Appropriate engineering controls Appropriate engineering controls : Ensure good ventilation of the work station. Environmental exposure controls : Avoid release to the environment. 8.3. Individual protection measures/Personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Personal protective equipment symbol(s): SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Mixture contains one or more component(s) which have the following colour(s): Colourless Colourless to light yellow Odor : There may be no odour warning properties, odour is subjective and inadequate to warn of overexposure. Mixture contains one or more component(s) which have the following odour: Petroleum-like odour Sweet odour Aromatic odour Alcohol odour Stuffy odour Mild odour Characteristic odour Pleasant odour Commercial/unpurified substance: irritating/pungent odour Odor threshold : No data available pH : No data available Melting point : Not applicable Freezing point : No data available Boiling point : > 180 ?F Flash point : 54 ?F Relative evaporation rate (butyl acetate=1) : No data available Relative evaporation rate (ether=1) : 2.2 Flammability (solid, gas) : Not applicable. Vapor pressure : 32.25 mm Hg Relative vapor density at 20 ?C : > 1 Relative density : 0.79 Solubility : Water: 100 g/l Partition coefficient n-octanol/water (Log Pow) : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : 3 mm?/s (25 ?C) Viscosity, dynamic : No data available Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 6/12 Explosion limits : Lower explosion limit: 2 Upper explosion limit: 12.7 Explosive properties : No data available Oxidizing properties : No data available 9.2. Other information VOC content : 100 SECTION 10: Stability and reactivity 10.1. Reactivity Highly flammable liquid and vapor. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition. 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Not classified Ethylbenzene (100-41-4) LD50 oral rat 3500 mg/kg (Rat, Male / female, Experimental value, Oral) LD50 dermal rabbit 15432 mg/kg body weight (24 h, Rabbit, Male, Experimental value, Dermal) LC50 Inhalation - Rat 17.8 mg/l (4 h, Rat, Male, Experimental value, Inhalation (vapours)) Isopropyl alcohol (67-63-0) LD50 oral rat 5840 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Experimental value, Oral, 14 day(s)) LD50 dermal rabbit 16400 ml/kg (Equivalent or similar to OECD 402, 24 h, Rabbit, Experimental value, Dermal, 14 day(s)) LC50 Inhalation - Rat [ppm] > 10000 ppm (Equivalent or similar to OECD 403, 6 h, Rat, Male/female, Experimental value, Inhalation (vapours), 14 day(s)) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Causes serious eye irritation. Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 7/12 Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Suspected of causing cancer. Ethylbenzene (100-41-4) IARC group 2B - Possibly carcinogenic to humans Isopropyl alcohol (67-63-0) IARC group 3 - Not classifiable Reproductive toxicity : Not classified STOT-single exposure : May cause drowsiness or dizziness. Isopropyl alcohol (67-63-0) STOT-single exposure May cause drowsiness or dizziness. STOT-repeated exposure : Not classified Ethylbenzene (100-41-4) STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : Not classified Viscosity, kinematic : 3 mm?/s (25 ?C) Symptoms/effects : May cause drowsiness or dizziness. Symptoms/effects after eye contact : Eye irritation. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. Ethylbenzene (100-41-4) LC50 - Fish [1] 4.2 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Salmo gairdneri, Semi-static system, Fresh water, Experimental value) EC50 - Crustacea [1] 1.8 ? 2.4 mg/l (US EPA, 48 h, Daphnia magna, Static system, Fresh water, Experimental value) Isopropyl alcohol (67-63-0) LC50 - Fish [1] 9640 ? 10000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Flow- through system, Fresh water, Experimental value, Lethal) 12.2. Persistence and degradability Ethylbenzene (100-41-4) Persistence and degradability Biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD) 1.44 g O?/g substance Chemical oxygen demand (COD) 2.1 g O?/g substance ThOD 3.17 g O?/g substance Isopropyl alcohol (67-63-0) Persistence and degradability Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. Readily biodegradable in water. Biochemical oxygen demand (BOD) 1.19 g O?/g substance Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 8/12 Isopropyl alcohol (67-63-0) Chemical oxygen demand (COD) 2.23 g O?/g substance ThOD 2.4 g O?/g substance 12.3. Bioaccumulative potential Ethylbenzene (100-41-4) BCF - Fish [1] 1 ? 2.4 (Other, 6 week(s), Oncorhynchus kisutch, Flow-through system, Salt water, Experimental value) Partition coefficient n-octanol/water (Log Pow) 3.6 (Experimental value, EU Method A.8: Partition Coefficient, 20 ?C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Isopropyl alcohol (67-63-0) Partition coefficient n-octanol/water (Log Pow) 0.05 (Weight of evidence approach, 25 ?C) Partition coefficient n-octanol/water (Log Kow) 0.05 Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil Ethylbenzene (100-41-4) Surface tension 0.071 N/m (23 ?C, 0.0582 g/l, EU Method A.5: Surface tension) Organic Carbon Normalized Adsorption Coefficient (Log Koc) 2.71 (log Koc, PCKOCWIN v1.66, QSAR) Ecology - soil Low potential for adsorption in soil. Toxic to soil organisms. Isopropyl alcohol (67-63-0) Surface tension 0.021 N/m (25 ?C) Organic Carbon Normalized Adsorption Coefficient (Log Koc) 0.185 ? 0.541 (log Koc, SRC PCKOCWIN v2.0, Calculated value) Ecology - soil Highly mobile in soil. 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector?s sorting instructions. Additional information : Flammable vapors may accumulate in the container. SECTION 14: Transport information In accordance with DOT / TDG / IMDG / IATA 14.1. UN number DOT NA No : UN1219 UN-No. (TDG) : Not applicable Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 9/12 UN-No. (IMDG) : 1219 UN-No. (IATA) : 1219 14.2. UN proper shipping name Proper Shipping Name (DOT) : Isopropanol Proper Shipping Name (TDG) : Not applicable Proper Shipping Name (IMDG) : ISOPROPANOL (ISOPROPYL ALCOHOL) Proper Shipping Name (IATA) : Isopropanol 14.3. Transport hazard class(es) DOT Transport hazard class(es) (DOT) : LTD QTY Hazard labels (DOT) : LTD QTY TDG Transport hazard class(es) (TDG) : Not applicable IMDG Transport hazard class(es) (IMDG) : 3 Hazard labels (IMDG) : 3 IATA Transport hazard class(es) (IATA) : 3 Hazard labels (IATA) : 3 14.4. Packing group Packing group (DOT) : II Packing group (TDG) : Not applicable Packing group (IMDG) : II Packing group (IATA) : II 14.5. Environmental hazards Other information : No supplementary information available. 14.6. Special precautions for user DOT UN-No.(DOT) : UN1219 Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 10/12 DOT Special Provisions (49 CFR 172.102) : IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. DOT Packaging Exceptions (49 CFR 173.xxx) : 4b, 150 DOT Packaging Non Bulk (49 CFR 173.xxx) : 202 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 5 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 60 L DOT Vessel Stowage Location : B - (i) The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ??On deck only?? on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. TDG Emergency Response Guide (ERG) Number : 129 IMDG Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T4 Tank special provisions (IMDG) : TP1 EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS EmS-No. (Spillage) : S-D - SPILLAGE SCHEDULE Delta - FLAMMABLE LIQUIDS Stowage category (IMDG) : B Flash point (IMDG) : 12?C c.c. Properties and observations (IMDG) : Colourless, mobile liquid. Flashpoint: 12?C c.c. Explosive limits: 2% to 12% Miscible with water. IATA PCA Excepted quantities (IATA) : E2 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 353 PCA max net quantity (IATA) : 5L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L Special provision (IATA) : A180 ERG code (IATA) : 3L 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. US Federal regulations Commercial status of components according to the United States Environmental Protection Agency?s Toxic Substances Control Act (TSCA): Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 11/12 Name CAS-No. Listing Commercial status Flags Ethylbenzene 100-41-4 Present Active Isopropyl alcohol 67-63-0 Present Active Ethylbenzene (100-41-4) Subject to reporting requirements of United States SARA Section 313 Listed on EPA Hazardous Air Pollutant (HAPS) CERCLA RQ 1000 lb Isopropyl alcohol (67-63-0) Subject to reporting requirements of United States SARA Section 313 15.2. International regulations CANADA Ethylbenzene (100-41-4) Listed on the Canadian DSL (Domestic Substances List) Isopropyl alcohol (67-63-0) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available National regulations Ethylbenzene (100-41-4) Listed on IARC (International Agency for Research on Cancer) 15.3. US State regulations Ethylbenzene (100-41-4) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) Maximum allowable dose level (MADL) Yes No No No 54 ?g/day (inhalation); 41 ?g/day (oral) SECTION 16: Other information according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date : 01/26/2022 Full text of H-phrases H224 Extremely flammable liquid and vapor H225 Highly flammable liquid and vapor Iso-HEET? Gas Line Antifreeze Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/26/2022 (Revision date) USA - en 12/12 Full text of H-phrases H304 May be fatal if swallowed and enters airways H319 Causes serious eye irritation H332 Harmful if inhaled H336 May cause drowsiness or dizziness H351 Suspected of causing cancer H373 May cause damage to organs through prolonged or repeated exposure Indication of changes: Section Changed item Change Comments Transport hazard class(es) (DOT) Added 14 Transport hazard class(es) (DOT) Safety Data Sheet (SDS), USA This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.