HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Issue date: 1/25/2019 Revision date: 1/25/2022 Supersedes: 1/11/2019 Version: 1.3 1/25/2022 (Revision date) USA - en 1/10 SECTION 1: Identification 1.1. Identification Product form : Mixture Trade name : HEET? Gas Line Antifreeze Line Synonym : 584402 Part numbers : 28201; 28203; 28205; 28213; 28219 1.2. Recommended use and restrictions on use No additional information available 1.3. Supplier Gold Eagle Co 4400 S Kildare Ave Chicago, IL, 60632-4372 T 773-376-4400 https://www.goldeagle.com/ 1.4. Emergency telephone number Emergency number : INFOTrac: 1-800-535-5053 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS US classification Flammable liquids Category 2 H225 Highly flammable liquid and vapor Acute toxicity (oral) Category 4 H302 Harmful if swallowed Acute toxicity (inhalation:dust,mist) Category 2 H330 Fatal if inhaled Specific target organ toxicity (single exposure) Category 1 H370 Causes damage to organs Full text of H statements : see section 16 2.2. GHS Label elements, including precautionary statements GHS US labeling Hazard pictograms (GHS US) : Signal word (GHS US) : Danger Hazard statements (GHS US) : H225 - Highly flammable liquid and vapor H302 - Harmful if swallowed H330 - Fatal if inhaled H370 - Causes damage to organs Precautionary statements (GHS US) : P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 - Keep container tightly closed. P240 - Ground/Bond container and receiving equipment. P241 - Use explosion-proof electrical/ventilating/lighting equipment. P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P260 - Do not breathe dust/fume/gas/mist/vapors/spray. HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/25/2022 (Revision date) USA - en 2/10 P264 - Wash hands, forearms and face thoroughly after handling. P270 - Do not eat, drink or smoke when using this product. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P284 - [In case of inadequate ventilation] wear respiratory protection. P301+P312 - If swallowed: Call a poison center or doctor if you feel unwell. P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P307+P311 - If exposed: Call a poison center/doctor. P310 - Immediately call a poison center or doctor. P320 - Specific treatment is urgent (see supplemental first aid instruction on this label). P321 - Specific treatment (see supplemental first aid instruction on this label). P330 - Rinse mouth. P370+P378 - In case of fire: Use media other than water to extinguish. P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. 2.3. Other hazards which do not result in classification No additional information available 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS US classification Methanol CAS-No.: 67-56-1 ? 100 Flam. Liq. 2, H225 Acute Tox. 4 (Oral), H302 Acute Tox. 3 (Inhalation), H331 STOT SE 1, H370 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Call a physician immediately. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a physician immediately. Call a doctor. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. First-aid measures after eye contact : Rinse eyes with water as a precaution. First-aid measures after ingestion : Rinse mouth. Call a poison center/doctor/physician if you feel unwell. 4.2. Most important symptoms and effects (acute and delayed) No additional information available HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/25/2022 (Revision date) USA - en 3/10 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Specific hazards arising from the chemical Fire hazard : Highly flammable liquid and vapor. Hazardous decomposition products in case of fire : Toxic fumes may be released. 5.3. Special protective equipment and precautions for fire-fighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : No open flames, no sparks, and no smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Only qualified personnel equipped with suitable protective equipment may intervene. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Flammable vapors may accumulate in the container. Use explosion-proof equipment. Wear personal protective equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the product. HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/25/2022 (Revision date) USA - en 4/10 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Ground/bond container and receiving equipment. Storage conditions : Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store locked up. SECTION 8: Exposure controls/personal protection 8.1. Control parameters HEET? Gas Line Antifreeze Line No additional information available Methanol (67-56-1) USA - ACGIH - Occupational Exposure Limits Local name Methanol ACGIH OEL TWA [ppm] 200 ppm ACGIH OEL STEL [ppm] 250 ppm Remark (ACGIH) TLV? Basis: Headache; eye dam; dizziness; nausea. Notations: Skin; BEI Regulatory reference ACGIH 2019 USA - OSHA - Occupational Exposure Limits Local name Methyl alcohol OSHA PEL (TWA) [1] 260 mg/m? OSHA PEL (TWA) [2] 200 ppm Regulatory reference (US-OSHA) OSHA Annotated Table Z-1 8.2. Appropriate engineering controls Appropriate engineering controls : Ensure good ventilation of the work station. Environmental exposure controls : Avoid release to the environment. 8.3. Individual protection measures/Personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: Wear respiratory protection. Personal protective equipment symbol(s): HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/25/2022 (Revision date) USA - en 5/10 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Mixture contains one or more component(s) which have the following colour(s): Colourless Colourless to light yellow Odor : There may be no odour warning properties, odour is subjective and inadequate to warn of overexposure. Mixture contains one or more component(s) which have the following odour: Petroleum-like odour Sweet odour Aromatic odour Characteristic odour Mild odour Pleasant odour Alcohol odour Commercial/unpurified substance: irritating/pungent odour Odor threshold : No data available pH : No data available Melting point : Not applicable Freezing point : No data available Boiling point : 147 ?F Flash point : 56 ?F Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : Not applicable. Vapor pressure : 96 Relative vapor density at 20 ?C : No data available Relative density : 0.791 Solubility : Water: 100 Partition coefficient n-octanol/water (Log Pow) : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : 3 ? 5 (40 ?C) Viscosity, dynamic : No data available Explosion limits : Lower explosion limit: 2 Upper explosion limit: 12.7 Explosive properties : No data available Oxidizing properties : No data available 9.2. Other information VOC content : 100 SECTION 10: Stability and reactivity 10.1. Reactivity Highly flammable liquid and vapor. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition. 10.5. Incompatible materials No additional information available HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/25/2022 (Revision date) USA - en 6/10 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) : Harmful if swallowed. Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Fatal if inhaled. HEET? Gas Line Antifreeze Line ATE US (oral) 1187 mg/kg body weight ATE US (dust, mist) 0.5 mg/l/4h Methanol (67-56-1) LD50 oral rat 1187 ? 2769 mg/kg body weight (BASF test, Rat, Male/female, Weight of evidence, Aqueous solution, Oral, 7 day(s)) LD50 dermal rabbit 17100 mg/kg (Rabbit, Inconclusive, insufficient data, Dermal) LC50 Inhalation - Rat 128.2 mg/l air (BASF test, 4 h, Rat, Male/female, Experimental value, Inhalation (vapours)) Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified STOT-single exposure : Causes damage to organs. Methanol (67-56-1) STOT-single exposure Causes damage to organs. STOT-repeated exposure : Not classified Aspiration hazard : Not classified Viscosity, kinematic : 3 ? 5 (40 ?C) SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. Methanol (67-56-1) LC50 - Fish [1] 15400 mg/l (EPA 660/3 - 75/009, 96 h, Lepomis macrochirus, Flow-through system, Fresh water, Experimental value, Lethal) EC50 - Crustacea [1] 18260 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 96 h, Daphnia magna, Semi- static system, Fresh water, Experimental value, Locomotor effect) ErC50 algae 22000 mg/l (OECD 201: Alga, Growth Inhibition Test, 96 h, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value) HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/25/2022 (Revision date) USA - en 7/10 12.2. Persistence and degradability Methanol (67-56-1) Persistence and degradability Readily biodegradable in the soil. Readily biodegradable in water. Biochemical oxygen demand (BOD) 0.6 ? 1.12 g O?/g substance Chemical oxygen demand (COD) 1.42 g O?/g substance ThOD 1.5 g O?/g substance 12.3. Bioaccumulative potential Methanol (67-56-1) BCF - Fish [1] 1 ? 4.5 (72 h, Cyprinus carpio, Static system, Fresh water, Experimental value) Partition coefficient n-octanol/water (Log Pow) -0.77 (Experimental value) Partition coefficient n-octanol/water (Log Kow) -0.77 Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). 12.4. Mobility in soil Methanol (67-56-1) Surface tension 0.023 N/m (20 ?C) Organic Carbon Normalized Adsorption Coefficient (Log Koc) 0.088 (log Koc, SRC PCKOCWIN v2.0, Calculated value) Ecology - soil Highly mobile in soil. 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector?s sorting instructions. Additional information : Flammable vapors may accumulate in the container. SECTION 14: Transport information In accordance with DOT / TDG / IMDG / IATA 14.1. UN number DOT NA No : Not applicable UN-No. (TDG) : Not applicable UN-No. (IMDG) : 1230 UN-No. (IATA) : 1230 14.2. UN proper shipping name Proper Shipping Name (DOT) : Consumer commodity Proper Shipping Name (TDG) : Not applicable Proper Shipping Name (IMDG) : METHANOL Proper Shipping Name (IATA) : Methanol HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/25/2022 (Revision date) USA - en 8/10 14.3. Transport hazard class(es) DOT Transport hazard class(es) (DOT) : LTD QTY Hazard labels (DOT) : LTD QTY TDG Transport hazard class(es) (TDG) : Not applicable IMDG Transport hazard class(es) (IMDG) : 3 (6.1) Hazard labels (IMDG) : 3, 6.1 IATA Transport hazard class(es) (IATA) : 3 (6.1) Hazard labels (IATA) : 3, 6.1 14.4. Packing group Packing group (DOT) : II Packing group (TDG) : Not applicable Packing group (IMDG) : II Packing group (IATA) : II 14.5. Environmental hazards Other information : No supplementary information available. 14.6. Special precautions for user DOT DOT Special Provisions (49 CFR 172.102) : 222 - Shipments offered for transportation by aircraft may not be reclassed as ORM-D. DOT Packaging Exceptions (49 CFR 173.xxx) : 156;306 DOT Packaging Non Bulk (49 CFR 173.xxx) : 156;306 DOT Packaging Bulk (49 CFR 173.xxx) : None DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 30 kg gross DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 60 L DOT Vessel Stowage Location : A - The material may be stowed ??on deck?? or ??under deck?? on a cargo vessel and on a passenger vessel. DOT Vessel Stowage Other : 25 - Protected from sources of heat,11 - Keep away from heat and open flame HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/25/2022 (Revision date) USA - en 9/10 TDG No data available IMDG Special provision (IMDG) : 279 Limited quantities (IMDG) : 1 L Excepted quantities (IMDG) : E2 Packing instructions (IMDG) : P001 IBC packing instructions (IMDG) : IBC02 Tank instructions (IMDG) : T7 Tank special provisions (IMDG) : TP2 EmS-No. (Fire) : F-E - FIRE SCHEDULE Echo - NON-WATER-REACTIVE FLAMMABLE LIQUIDS EmS-No. (Spillage) : S-D - SPILLAGE SCHEDULE Delta - FLAMMABLE LIQUIDS Stowage category (IMDG) : B Flash point (IMDG) : 12?C c.c. Properties and observations (IMDG) : Colourless, volatile liquid. Flashpoint: 12?C c.c. Explosive limits: 6% to 36.5% Miscible with water.Toxic if swallowed; may cause blindness. Avoid skin contact. IATA Transport regulations (IATA) : Not subject PCA Excepted quantities (IATA) : E1 PCA Limited quantities (IATA) : Y341 PCA limited quantity max net quantity (IATA) : 1L PCA packing instructions (IATA) : 352 PCA max net quantity (IATA) : 1L CAO packing instructions (IATA) : 364 CAO max net quantity (IATA) : 60L Special provision (IATA) : A113 ERG code (IATA) : 3L 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. US Federal regulations Commercial status of components according to the United States Environmental Protection Agency?s Toxic Substances Control Act (TSCA): Name CAS-No. Listing Commercial status Flags Methanol 67-56-1 Present Active Methanol (67-56-1) Subject to reporting requirements of United States SARA Section 313 Listed on EPA Hazardous Air Pollutant (HAPS) CERCLA RQ 5000 lb 15.2. International regulations CANADA Methanol (67-56-1) Listed on the Canadian DSL (Domestic Substances List) HEET? Gas Line Antifreeze Line Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/25/2022 (Revision date) USA - en 10/10 EU-Regulations No additional information available National regulations No additional information available 15.3. US State regulations Methanol (67-56-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) Maximum allowable dose level (MADL) No Yes No No 47000 ?g/day (inhalation); 23,000 ?g/day (oral) SECTION 16: Other information according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date : 01/25/2022 Full text of H-phrases H225 Highly flammable liquid and vapor H302 Harmful if swallowed H330 Fatal if inhaled H331 Toxic if inhaled H370 Causes damage to organs Safety Data Sheet (SDS), USA This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.