Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 1 of 15 Safety Data Sheet Copyright,2022, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 29-3109-5 Version Number: 5.02 Issue Date: 03/18/22 Supercedes Date: 04/14/21 SECTION 1: Identification 1.1. Product identifier Super 77 Aerosol Spray Low 25% VOC Product Identification Numbers ID Number UPC ID Number UPC 62-4876-4920-4 62-4876-4930-3 62-4876-4935-2 7100014109, 7010329910, 7100248653 1.2. Recommended use and restrictions on use Recommended use Adhesive, Industrial use This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(5)) or processed (as defined in TSCA section 3(13)) for consumer paint or coating removal. 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Industrial Adhesives and Tapes Division ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Dissolved gas. Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1B. Reproductive Toxicity: Category 1B. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (single exposure): Category 3. Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 2 of 15 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Health Hazard | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. May cause an allergic skin reaction. May cause drowsiness or dizziness. May damage fertility or the unborn child. May displace oxygen and cause rapid suffocation. Causes damage to organs: cardiovascular system | Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed or concerned: Get medical advice/attention. Specific treatment (see Notes to Physician on this label). Storage: Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 3 of 15 Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. 2.3. Hazards not otherwise classified Repeated exposure may cause skin dryness or cracking. Supplemental Information: Intentional concentration and inhalation may be harmful or fatal. 4% of the mixture consists of ingredients of unknown acute dermal toxicity. 4% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Acetone 67-64-1 35 - 45 Trade Secret * Non-hazardous components (NJTS Reg. No. 04499600- 6849) Trade Secret* 10 - 25 Trade Secret * 1,1-Difluoroethane 75-37-6 10 - 20 Trade Secret * Propane 74-98-6 10 - 15 Trade Secret * Cyclohexane 110-82-7 < 10 Trade Secret * Rosin, Fumarated, Polymer with Glycerol 65997-10-6 5 - 10 Trade Secret * Glycerol esters of Rosin acids 8050-31-5 1 - 5 Trade Secret * Resin acids and Rosin acids, esters with diethylene glycol 68153-38-8 1 - 5 Trade Secret * Toluene 108-88-3 < 1 Trade Secret * Benzene 71-43-2 < 0.05 Trade Secret * NJTS or NJTSRN: New Jersey Trade Secret Registry Number. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 4 of 15 Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Allergic skin reaction (redness, swelling, blistering, and itching). Central nervous system depression (headache, dizziness, drowsiness, incoordination, nausea, slurred speech, giddiness, and unconsciousness). Target organ effects. See Section 11 for additional details. 4.3. Indication of any immediate medical attention and special treatment required Exposure may increase myocardial irritability. Do not administer sympathomimetic drugs unless absolutely necessary. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Exposure to extreme heat can give rise to thermal decomposition. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Fluoride During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. Collect the resulting residue containing solution per section 6.3. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 5 of 15 SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not breathe thermal decomposition products. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Use personal protective equipment (gloves, respirators, etc.) as required. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Toluene 108-88-3 ACGIH TWA:20 ppm A4: Not class. as human carcin, Ototoxicant Toluene 108-88-3 OSHA TWA:200 ppm;CEIL:300 ppm Cyclohexane 110-82-7 ACGIH TWA:100 ppm Cyclohexane 110-82-7 OSHA TWA:1050 mg/m3(300 ppm) Acetone 67-64-1 ACGIH TWA:250 ppm;STEL:500 ppm A4: Not class. as human carcin Acetone 67-64-1 OSHA TWA:2400 mg/m3(1000 ppm) Benzene 71-43-2 ACGIH TWA:0.5 ppm;STEL:2.5 ppm A1: Confirmed human carcin., SKIN Benzene 71-43-2 OSHA TWA:1 ppm;TWA:10 ppm;STEL:5 ppm;CEIL:25 ppm 29 CFR 1910.1028 Propane 74-98-6 ACGIH Limit value not established: simple asphyxiant Propane 74-98-6 OSHA TWA:1800 mg/m3(1000 ppm) 1,1-Difluoroethane 75-37-6 AIHA TWA:2700 mg/m3(1000 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls For those situations where the material might be exposed to extreme overheating due to misuse or equipment failure, use with appropriate local exhaust ventilation sufficient to maintain levels of thermal decomposition products below their exposure guidelines. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 6 of 15 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: For those situations where the material might be exposed to extreme overheating due to misuse or equipment failure, use a positive pressure supplied-air respirator. Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates Half facepiece or full facepiece supplied-air respirator Organic vapor respirators may have short service life. For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Multicolor Specific Physical Form: Aerosol Odor Solvent Odor threshold No Data Available pH Not Applicable Melting point Not Applicable Boiling Point -44 ?F [Details:Acetone] Flash Point -156 ?F [Test Method:Closed Cup] Evaporation rate > 1 [Ref Std:BUOAC=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 1.3 % volume Flammable Limits(UEL) 12.8 % volume Vapor Pressure <=4137 mmHg [@ 68 ?F] Vapor Density > 1 [Ref Std:AIR=1] Density 0.80 g/ml Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 7 of 15 Specific Gravity 0.80 [Ref Std:WATER=1] Solubility in Water Nil Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity <=100 centipoise [@ 73.4 ?F ] Molecular weight No Data Available Percent volatile <=80.6 % weight VOC Less H2O & Exempt Solvents <=25 % [Test Method:calculated per CARB title 2] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat Sparks and/or flames 10.5. Incompatible materials Not determined 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 8 of 15 incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Prolonged or repeated exposure may cause: Dermal Defatting: Signs/symptoms may include localized redness, itching, drying and cracking of skin. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Single exposure, above recommended guidelines, may cause: Cardiac Sensitization: Signs/symptoms may include irregular heartbeat (arrhythmia), faintness, chest pain, and may be fatal. Reproductive/Developmental Toxicity: Contains a chemical or chemicals which can cause birth defects or other reproductive harm. Carcinogenicity: Ingredient CAS No. Class Description Regulation BENZENE 71-43-2 Known To Be Human Carcinogen. National Toxicology Program Carcinogens BENZENE 71-43-2 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer BENZENE 71-43-2 Cancer hazard OSHA Carcinogens Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Acetone Dermal Rabbit LD50 > 15,688 mg/kg Acetone Inhalation- Vapor (4 hours) Rat LC50 76 mg/l Acetone Ingestion Rat LD50 5,800 mg/kg Propane Inhalation- Gas (4 hours) Rat LC50 > 200,000 ppm Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 9 of 15 1,1-Difluoroethane Inhalation- Gas (4 hours) Rat LC50 > 437,000 ppm 1,1-Difluoroethane Ingestion Rat LD50 > 1,500 mg/kg Cyclohexane Dermal Rat LD50 > 2,000 mg/kg Cyclohexane Inhalation- Vapor (4 hours) Rat LC50 > 32.9 mg/l Cyclohexane Ingestion Rat LD50 6,200 mg/kg Rosin, Fumarated, Polymer with Glycerol Dermal Rat LD50 > 2,000 mg/kg Rosin, Fumarated, Polymer with Glycerol Ingestion Rat LD50 > 2,000 mg/kg Glycerol esters of Rosin acids Ingestion Rat LD50 >300, <2000 mg/kg Toluene Dermal Rat LD50 12,000 mg/kg Toluene Inhalation- Vapor (4 hours) Rat LC50 30 mg/l Toluene Ingestion Rat LD50 5,550 mg/kg Resin acids and Rosin acids, esters with diethylene glycol Ingestion Rat LD50 >300, <2000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Acetone Mouse Minimal irritation Propane Rabbit Minimal irritation Cyclohexane Rabbit Mild irritant Rosin, Fumarated, Polymer with Glycerol Rabbit No significant irritation Glycerol esters of Rosin acids In vitro data No significant irritation Toluene Rabbit Irritant Resin acids and Rosin acids, esters with diethylene glycol In vitro data No significant irritation Serious Eye Damage/Irritation Name Species Value Acetone Rabbit Severe irritant Propane Rabbit Mild irritant Cyclohexane Rabbit Mild irritant Rosin, Fumarated, Polymer with Glycerol Rabbit Moderate irritant Glycerol esters of Rosin acids In vitro data No significant irritation Toluene Rabbit Moderate irritant Resin acids and Rosin acids, esters with diethylene glycol In vitro data No significant irritation Skin Sensitization Name Species Value Rosin, Fumarated, Polymer with Glycerol Mouse Sensitizing Glycerol esters of Rosin acids In vitro data Not classified Toluene Guinea pig Not classified Resin acids and Rosin acids, esters with diethylene glycol In vitro data Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 10 of 15 Acetone In vivo Not mutagenic Acetone In Vitro Some positive data exist, but the data are not sufficient for classification Propane In Vitro Not mutagenic 1,1-Difluoroethane In Vitro Some positive data exist, but the data are not sufficient for classification 1,1-Difluoroethane In vivo Some positive data exist, but the data are not sufficient for classification Cyclohexane In Vitro Not mutagenic Cyclohexane In vivo Some positive data exist, but the data are not sufficient for classification Rosin, Fumarated, Polymer with Glycerol In Vitro Not mutagenic Toluene In Vitro Not mutagenic Toluene In vivo Not mutagenic Carcinogenicity Name Route Species Value Acetone Not Specified Multiple animal species Not carcinogenic 1,1-Difluoroethane Inhalation Rat Some positive data exist, but the data are not sufficient for classification Toluene Dermal Mouse Some positive data exist, but the data are not sufficient for classification Toluene Ingestion Rat Some positive data exist, but the data are not sufficient for classification Toluene Inhalation Mouse Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Acetone Ingestion Not classified for male reproduction Rat NOAEL 1,700 mg/kg/day 13 weeks Acetone Inhalation Not classified for development Rat NOAEL 5.2 mg/l during organogenesi s 1,1-Difluoroethane Inhalation Not classified for development Rat NOAEL 50,000 ppm during organogenesi s Cyclohexane Inhalation Not classified for female reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for male reproduction Rat NOAEL 24 mg/l 2 generation Cyclohexane Inhalation Not classified for development Rat NOAEL 6.9 mg/l 2 generation Rosin, Fumarated, Polymer with Glycerol Ingestion Not classified for female reproduction Rat NOAEL 15,000 ppm in the diet premating into lactation Rosin, Fumarated, Polymer with Glycerol Ingestion Not classified for male reproduction Rat NOAEL 3,000 ppm in the diet 42 days Rosin, Fumarated, Polymer with Glycerol Ingestion Not classified for development Rat NOAEL 622 mg/kg/day during gestation Toluene Inhalation Not classified for female reproduction Human NOAEL Not available occupational exposure Toluene Inhalation Not classified for male reproduction Rat NOAEL 2.3 mg/l 1 generation Toluene Ingestion Toxic to development Rat LOAEL 520 mg/kg/day during gestation Toluene Inhalation Toxic to development Human NOAEL Not available poisoning and/or abuse Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 11 of 15 Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Acetone Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Acetone Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Acetone Inhalation immune system Not classified Human NOAEL 1.19 mg/l 6 hours Acetone Inhalation liver Not classified Guinea pig NOAEL Not available Acetone Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Propane Inhalation cardiac sensitization Causes damage to organs Human NOAEL Not available Propane Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Propane Inhalation respiratory irritation Not classified Human NOAEL Not available 1,1-Difluoroethane Inhalation cardiac sensitization Causes damage to organs Human and animal NOAEL Not available poisoning and/or abuse 1,1-Difluoroethane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL 100,000 ppm 1,1-Difluoroethane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not available not available Cyclohexane Inhalation central nervous system depression May cause drowsiness or dizziness Human and animal NOAEL Not available Cyclohexane Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human and animal NOAEL Not available Cyclohexane Ingestion central nervous system depression May cause drowsiness or dizziness Professio nal judgeme nt NOAEL Not available Rosin, Fumarated, Polymer with Glycerol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification similar health hazards NOAEL not available Toluene Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available Toluene Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available Toluene Inhalation immune system Not classified Mouse NOAEL 0.004 mg/l 3 hours Toluene Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Acetone Dermal eyes Not classified Guinea pig NOAEL Not available 3 weeks Acetone Inhalation hematopoietic system Not classified Human NOAEL 3 mg/l 6 weeks Acetone Inhalation immune system Not classified Human NOAEL 1.19 mg/l 6 days Acetone Inhalation kidney and/or bladder Not classified Guinea pig NOAEL 119 mg/l not available Acetone Inhalation heart | liver Not classified Rat NOAEL 45 8 weeks Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 12 of 15 mg/l Acetone Ingestion kidney and/or bladder Not classified Rat NOAEL 900 mg/kg/day 13 weeks Acetone Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion hematopoietic system Not classified Rat NOAEL 200 mg/kg/day 13 weeks Acetone Ingestion liver Not classified Mouse NOAEL 3,896 mg/kg/day 14 days Acetone Ingestion eyes Not classified Rat NOAEL 3,400 mg/kg/day 13 weeks Acetone Ingestion respiratory system Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Acetone Ingestion muscles Not classified Rat NOAEL 2,500 mg/kg 13 weeks Acetone Ingestion skin | bone, teeth, nails, and/or hair Not classified Mouse NOAEL 11,298 mg/kg/day 13 weeks 1,1-Difluoroethane Inhalation hematopoietic system | kidney and/or bladder | respiratory system Not classified Rat NOAEL 25,000 ppm 2 years Cyclohexane Inhalation liver Not classified Rat NOAEL 24 mg/l 90 days Cyclohexane Inhalation auditory system Not classified Rat NOAEL 1.7 mg/l 90 days Cyclohexane Inhalation kidney and/or bladder Not classified Rabbit NOAEL 2.7 mg/l 10 weeks Cyclohexane Inhalation hematopoietic system Not classified Mouse NOAEL 24 mg/l 14 weeks Cyclohexane Inhalation peripheral nervous system Not classified Rat NOAEL 8.6 mg/l 30 weeks Rosin, Fumarated, Polymer with Glycerol Ingestion heart | hematopoietic system | liver | nervous system | eyes | kidney and/or bladder | respiratory system Not classified Rat NOAEL 1,296 mg/kg/day 90 days Toluene Inhalation auditory system | eyes | olfactory system Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation nervous system May cause damage to organs though prolonged or repeated exposure Human NOAEL Not available poisoning and/or abuse Toluene Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 2.3 mg/l 15 months Toluene Inhalation heart | liver | kidney and/or bladder Not classified Rat NOAEL 11.3 mg/l 15 weeks Toluene Inhalation endocrine system Not classified Rat NOAEL 1.1 mg/l 4 weeks Toluene Inhalation immune system Not classified Mouse NOAEL Not available 20 days Toluene Inhalation bone, teeth, nails, and/or hair Not classified Mouse NOAEL 1.1 mg/l 8 weeks Toluene Inhalation hematopoietic system | vascular system Not classified Human NOAEL Not available occupational exposure Toluene Inhalation gastrointestinal tract Not classified Multiple animal species NOAEL 11.3 mg/l 15 weeks Toluene Ingestion nervous system Some positive data exist, but the Rat NOAEL 625 13 weeks Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 13 of 15 data are not sufficient for classification mg/kg/day Toluene Ingestion heart Not classified Rat NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion liver | kidney and/or bladder Not classified Multiple animal species NOAEL 2,500 mg/kg/day 13 weeks Toluene Ingestion hematopoietic system Not classified Mouse NOAEL 600 mg/kg/day 14 days Toluene Ingestion endocrine system Not classified Mouse NOAEL 105 mg/kg/day 28 days Toluene Ingestion immune system Not classified Mouse NOAEL 105 mg/kg/day 4 weeks Aspiration Hazard Name Value Cyclohexane Aspiration hazard Toluene Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Combustion products will include HF. Facility must be capable of handling halogenated materials. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. EPA Hazardous Waste Number (RCRA): D001 (Ignitable), D018 (Benzene) SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 14 of 15 EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Hazard Not Otherwise Classified (HNOC) Reproductive toxicity Respiratory or Skin Sensitization Serious eye damage or eye irritation Simple Asphyxiant Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Cyclohexane 110-82-7 Trade Secret < 10 Additional TSCA Information This chemical/product is not and cannot be distributed in commerce (as defined in TSCA section 3(5)) or processed (as defined in TSCA section 3(13)) for consumer paint or coating removal. 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 4 Instability: 0 Special Hazards: None Aerosol Storage Code: 3 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. The NFPA Health code of 3 is due to emergency situations where the material may thermally decompose and release Hydrogen Fluoride. During normal use conditions, please reference Section 2 and Section 11 of the SDS for additional health hazard information. Document Group: 29-3109-5 Version Number: 5.02 Super 77 Aerosol Spray Low 25% VOC 03/18/22 __________________________________________________________________________________________ Page 15 of 15 Issue Date: 03/18/22 Supercedes Date: 04/14/21 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com