Safety Data Sheet Issue Date: 13-Feb-2023 Revision Date: 14-Feb-2023 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product identifier Product Name Heavy-Duty Green Coolant Concentrate Other means of identification SDS/Part number # GREEN55GAL-SP Recommended use of the chemical and restrictions on use Recommended Use Coolant. Details of the supplier of the safety data sheet Manufacturer Address FMP 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 Phone: 888-784-0802 Emergency telephone number Emergency Telephone INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Green liquid Physical state Liquid Classification Acute toxicity - Oral Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Signal Word Warning Hazard statements Harmful if swallowed Harmful if inhaled Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area GREEN ANTIFREEZE / COOLANT CONCENTRATE SPLASH-042 - Heavy-Duty Green Coolant Concentrate Revision Date: 14-Feb-2023 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Response IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a poison center or doctor/physician if you feel unwell IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other hazards Toxic to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight-% Ethylene glycol 107-21-1 >95 Sodium Nitrite 7632-00-0 0.1-1 Sodium benzoate 532-32-1 0.1-1 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST AID MEASURES Description of first aid measures Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes, lifting lower and upper eyelids. Consult a physician. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center or doctor/physician if you feel unwell. Ingestion Call a poison center or doctor/physician if you feel unwell. Rinse mouth. Most important symptoms and effects, both acute and delayed Symptoms Harmful if swallowed. Harmful if inhaled. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Not determined. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. SPLASH-042 - Heavy-Duty Green Coolant Concentrate Revision Date: 14-Feb-2023 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Keep in suitable, closed containers for disposal. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Wash face, hands and any exposed skin thoroughly after handling. Do not eat, drink or smoke when using this product. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible Materials None known based on information supplied. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Ethylene glycol 107-21-1 STEL: 50 ppm vapor fraction STEL: 10 mg/m3 inhalable particulate matter, aerosol only TWA: 25 ppm vapor fraction - - Sodium benzoate 532-32-1 TWA: 2.5 mg/m3 benzoate inhalable particulate matter S* - - Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. SPLASH-042 - Heavy-Duty Green Coolant Concentrate Revision Date: 14-Feb-2023 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Green liquid Odor Not determined Color Green Odor Threshold Not determined Property Values Remarks ? Method pH No data available Melting point / freezing point No data available Initial boiling point and boiling range No data available Flash point No data available Evaporation Rate Not determined Flammability (Solid, Gas) Liquid-Not applicable Flammability Limit in Air Upper flammability or explosive limits No data available Lower flammability or explosive limits No data available Vapor Pressure Not determined Vapor Density No data available Relative Density 1.1200 Water Solubility Not determined Solubility in other solvents Not determined Partition Coefficient Not determined Autoignition temperature No data available Hyphen Not determined Kinematic viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Conditions to Avoid Keep out of reach of children. Incompatible materials None known based on information supplied. Hazardous decomposition products None known based on information supplied. SPLASH-042 - Heavy-Duty Green Coolant Concentrate Revision Date: 14-Feb-2023 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Inhalation Do not inhale. Ingestion Do not ingest. Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Ethylene glycol 107-21-1 = 4700 mg/kg ( Rat ) = 10600 mg/kg ( Rat ) > 2.5 mg/L ( Rat ) 6 h Sodium Nitrite 7632-00-0 = 85 mg/kg ( Rat ) - = 5.5 mg/L ( Rat ) 4 h Sodium tolyltriazole 64665-57-2 = 1980 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) - Sodium benzoate 532-32-1 = 4070 mg/kg ( Rat ) - - 2,2'-oxydiethanol 111-46-6 = 12565 mg/kg ( Rat ) = 11890 mg/kg ( Rabbit ) > 4600 mg/m3 ( Rat ) 4 h Symptoms related to the physical, chemical and toxicological characteristics Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Nitrate or nitrite ingested under conditions that result in endogenous nitrosation are considered carcinogens. Chemical name ACGIH IARC NTP OSHA Sodium Nitrite 7632-00-0 Group 2A X Legend IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity The following values are calculated based on chapter 3.1 of the GHS document Oral LD50 496.10 mg/kg Dermal LD50 10,976.00 mg/kg ATEmix (inhalation-dust/mist) 1.55 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic life with long lasting effects. SPLASH-042 - Heavy-Duty Green Coolant Concentrate Revision Date: 14-Feb-2023 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 Component Information Chemical name Algae/aquatic plants Fish Crustacea Ethylene glycol 107-21-1 EC50: 6500 - 13000mg/L (96h, Pseudokirchneriella subcapitata) LC50: =41000mg/L (96h, Oncorhynchus mykiss) LC50: 14 - 18mL/L (96h, Oncorhynchus mykiss) LC50: =27540mg/L (96h, Lepomis macrochirus) LC50: =40761mg/L (96h, Oncorhynchus mykiss) LC50: 40000 - 60000mg/L (96h, Pimephales promelas) LC50: =16000mg/L (96h, Poecilia reticulata) EC50: =46300mg/L (48h, Daphnia magna) Sodium Nitrite 7632-00-0 LC50: =0.19mg/L (96h, Oncorhynchus mykiss) LC50: 0.092 - 0.13mg/L (96h, Oncorhynchus mykiss) LC50: 0.4 - 0.6mg/L (96h, Oncorhynchus mykiss) LC50: 0.65 - 1mg/L (96h, Oncorhynchus mykiss) LC50: =2.3mg/L (96h, Pimephales promelas) LC50: =20mg/L (96h, Pimephales promelas) Sodium benzoate 532-32-1 LC50: 420 - 558mg/L (96h, Pimephales promelas) LC50: >100mg/L (96h, Pimephales promelas) EC50: <650mg/L (48h, Daphnia magna) 2,2'-oxydiethanol 111-46-6 LC50: =75200mg/L (96h, Pimephales promelas) EC50: =84000mg/L (48h, Daphnia magna) Persistence/Degradability Not determined. Bioaccumulation There is no data for this product. Mobility Chemical name Partition coefficient Ethylene glycol 107-21-1 -1.36 Sodium Nitrite 7632-00-0 -3.7 Sodium benzoate 532-32-1 -2.13 Other adverse effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. SPLASH-042 - Heavy-Duty Green Coolant Concentrate Revision Date: 14-Feb-2023 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 California Hazardous Waste Status Chemical name California Hazardous Waste Status Sodium Nitrite 7632-00-0 Toxic Ignitable Reactive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated IMDG Marine Pollutant This material may meet the definition of a marine pollutant 15. REGULATORY INFORMATION International Inventories Chemical name TSCA TSCA Inventory Status DSL/NDSL EINECS/ELI NCS ENCS IECSC KECL PICCS AIIC Ethylene glycol X ACTIVE X X X X X X X Sodium Nitrite X ACTIVE X X X X X X X Sodium tolyltriazole X ACTIVE X X X X X X Sodium benzoate X ACTIVE X X X X X X X 2,2'-oxydiethanol X ACTIVE X X X X X X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Ethylene glycol 107-21-1 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ Sodium Nitrite 7632-00-0 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ SARA 313 Chemical name CAS No Weight-% SARA 313 - Threshold Values % Ethylene glycol - 107-21-1 107-21-1 >95 1.0 Sodium Nitrite - 7632-00-0 7632-00-0 0.1-1 1.0 SPLASH-042 - Heavy-Duty Green Coolant Concentrate Revision Date: 14-Feb-2023 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 CWA (Clean Water Act) Chemical name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium Nitrite 100 lb X US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Chemical name California Proposition 65 Ethylene glycol - 107-21-1 Developmental U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania Ethylene glycol 107-21-1 X X X Sodium Nitrite 7632-00-0 X X X 2,2'-oxydiethanol 111-46-6 X 16. OTHER INFORMATION NFPA Health hazards - Flammability - Instability - Special hazards - HMIS Health hazards - Flammability - Physical hazards - Personal Protection - Issue Date: 13-Feb-2023 Revision Date: 14-Feb-2023 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet