MULTI-STATE FORMULA (B101-50) INSTANT GUM CUTTER Revision: March 20, 2019 Page: 1/7 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product identifier Chemical Name Mixture CAS No. Mixture Trade Name BERKEBILE MULTI-STATE INSTANT GUM CUTTER Product Code B101-50 Relevant identified uses of the substance or mixture and uses advised against Identified Use(s) Automotive care Uses Advised Against None Company Identification BERKEBILE OIL COMPANY PO BOX 715 Somerset, PA 15501 Telephone (814) 443 -1656 Fax (814) 443 - 2873 E-Mail (competent person) This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number Emergency Phone No. Transportation Emergency: CHEMTREC 24 hr. 1-800-424- 9300 / 1 (703) 527-3887 (Collect calls accepted) SECTION 2: HAZARDS IDENTIFICATION Classification of the substance or mixture OSHA HCS (29 CFR 1910.1200) Flam. Aerosol 1; Compressed dissolved gas; Skin Irrit. 2; Eye Irrit. 2; STOT SE 3; Asp. Tox. 1 Label elements Hazard Symbol Signal word(s) DANGER Hazard Statement(s) Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes serious eye irritation. Repeated exposure may cause skin dryness or cracking. May cause drowsiness or dizziness. Precautionary Statement(s) Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Do not spray on an open flame or other ignition source. Avoid breathing spray. Protect from sunlight and do not expose to temperatures exceeding 50 ?C/122 ?F. Wash hands and exposed skin after use. Keep out of reach of children. Other hazards None SAFETY DATA SHEET OSHA HCS (29 CFR 1910.1200) MULTI-STATE FORMULA (B101-50) INSTANT GUM CUTTER Revision: March 20, 2019 Page: 2/7 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredient(s) % wt. * CAS No. Hazard classification Acetone 70 - 90 67-64-1 Flam. Liq. 2; H225 Eye Irrit. 2; H319 STOT SE 3; H336 Heptane, branched, cyclic and linear 5-15 426260-76-6 Flam. Liq. 2; H225 Asp. Tox. 1; H304 Skin Irrit. 2; H315 STOT SE 3; H336 Carbon dioxide 4 - 10 124-38-9 Compressed dissolved gas Additional Information - None * The exact percentage withheld as a trade secret in accordance with 29 CFR 1910.1200. SECTION 4: FIRST AID MEASURES Description of first aid measures Inhalation Move person to fresh air. If breathing is labored, administer oxygen. If symptoms develop, obtain medical attention. Skin Contact Wash affected skin with soap and water. If symptoms develop, obtain medical attention. Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If symptoms occur obtain medical attention. Ingestion Do not give anything by mouth to an unconscious person. Seek medical treatment. Most important symptoms and effects, both acute and delayed May cause damage to organs: (Optic nerve, Central nervous system) Indication of any immediate medical attention and special treatment needed IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media -Suitable Extinguishing Media Extinguish with carbon dioxide, dry chemical, foam or water spray. -Unsuitable Extinguishing Media Do not use water jet. Special hazards arising from the substance or mixture Highly flammable vapor (flash point below 23?C). Advice for fire-fighters A self contained breathing apparatus and suitable protective clothing should be worn in fire conditions. Keep containers cool by spraying with water if exposed to fire. MULTI-STATE FORMULA (B101-50) INSTANT GUM CUTTER Revision: March 20, 2019 Page: 3/7 SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Take precautionary measures against static discharges. Avoid contact with skin and eyes. Avoid breathing vapors. Environmental precautions Prevent liquid entering sewers, basements and work pits. Methods and material for containment and cleaning up Cover spills with inert absorbent material. Transfer to a container for disposal or recovery. Reference to other sections None Additional Information None SECTION 7: HANDLING AND STORAGE Precautions for safe handling Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Avoid contact with skin and eyes. Use product in a well- ventilated area only. Conditions for safe storage, including any incompatibilities -Storage temperature Keep in a cool, well ventilated place. Store at temperatures not exceeding 50 ?C / 122 ?F. -Incompatible materials This product should be stored away from sources of strong heat or oxidizing chemicals. Specific end use(s) Brake cleaner SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits SUBSTANCE. CAS No. (8hr TWA) (STEL) Note: PEL (OSHA) TLV (ACGIH) PEL (OSHA) TLV (ACGIH) Acetone 67-64-1 1000 500 ------ 750 ^NIC Heptane, branched, cylic and linear 426260-76-6 500 ppm* 1500 mg/m3 ----- ----- *n-heptane Carbon dioxide 124-38-9 5000 ppm 30,000 ppm ^NIC = Notice of Intended Changes (ACGIH?); Recommended monitoring method NIOSH 1300 (Ketones I); NIOSH 2000 (Methanol); NIOSH 1500 (hydrocarbons, B.P. 36 - 126 ?C) Exposure controls Appropriate engineering controls Provide adequate ventilation to ensure that the occupational exposure limit is not exceeded. Personal protection equipment Eye/face protection Wear protective eyewear (goggles, face shield, or safety glasses). Skin protection (Hand protection/ Other) Wear suitable gloves if prolonged skin contact is likely (Nitrile rubber) MULTI-STATE FORMULA (B101-50) INSTANT GUM CUTTER Revision: March 20, 2019 Page: 4/7 Respiratory protection Normally no personal respiratory protection is necessary. In case of insufficient ventilation, wear suitable respiratory equipment. Thermal hazards Not normally required. Use gloves with insulation for thermal protection, when needed. Environmental Exposure Controls None known SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Liquid Color. Colorless Odor Acetone-like Odor Threshold (ppm) Not available pH (Value) Not available Melting Point (?C) / Freezing Point (?C) Not available Boiling point/boiling range (?C): 56 (Acetone) Flash Point (?C) -17 (Acetone) Evaporation Rate Not available Flammability (solid, gas) Not applicable Explosive Limit Ranges 2.5% - 12.8% v/v (Acetone) Vapor pressure (Pascal) 2.4 x 104 (Acetone) Vapor Density (Air=1) Not available Density (g/ml) Not available Solubility (Water) Not available Solubility (Other) Not available Partition Coefficient (n-Octanol/water) Not available Auto Ignition Point (?C) 465 (Acetone) Decomposition Temperature (?C) Not available Kinematic Viscosity <20 Explosive properties Not explosive. Oxidizing properties Not oxidizing. Other information Not available SECTION 10: STABILITY AND REACTIVITY Reactivity Stable under normal conditions. Chemical stability Stable. Possibility of hazardous reactions None anticipated. Conditions to avoid Avoid contact with heat and ignition sources. Incompatible materials Strong oxidizing agents Hazardous decomposition product(s) Carbon monoxide, Carbon dioxide, Acrid smoke SECTION 11: TOXICOLOGICAL INFORMATION Heptane, branched, cylic and linear (CAS# 426260-76-6) - By analogy with similar materials: Acute toxicity Oral NOAEL = 900 mg/kg/day (rat) (90-days) Inhalation NOAEL > 19,000 ppm (rat) Irritation/Corrosivity It is unlikely to present a carcinogenic hazard to man. MULTI-STATE FORMULA (B101-50) INSTANT GUM CUTTER Revision: March 20, 2019 Page: 5/7 Sensitization Repeated dose toxicity Negative Carcinogenicity Negative NTP IARC ACGIH OSHA NIOSH No. No. No. No. No. Mutagenicity Reproductive toxicity Oral: LD50 >5 g/kg-bw Dermal: LD50 >2 g/kg-bw Inhalation: LC50 = 65 - 103 mg/L (Vapor), 4-hr. rat May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Information on toxicological effects None known Acetone (CAS No. 67-64-1) Acute toxicity Oral LD50 = 5800 mg/kg (rat) Dermal LD50 >15800 mg/kg (rabbit) Inhalation LC50 76 mg/L (4 hour(s)) (rat) - Vapours may cause drowsiness and dizziness. Irritation / Corrosivity Causes serious eye irritation. Repeated exposure may cause skin dryness or cracking. Sensitisation It is not a skin sensitiser. Repeated dose toxicity Oral NOAEL = 900 mg/kg/day (rat) (90-days) Inhalation NOAEL > 19,000 ppm (rat) Carcinogenicity It is unlikely to present a carcinogenic hazard to man. NTP IARC ACGIH OSHA NIOSH No. No. No. No. No. Mutagenicity Negative Toxicity for reproduction Negative Other information None known. SECTION 12: ECOLOGICAL INFORMATION Toxicity - Substances in preparations / mixtures Heptane, branched, cylic and linear (CAS# 426260-76-6) - By analogy with similar materials: Short term LL50 (96 hour): >13.4 mg/L (Oncorhynchus mykiss) EL50 (48 hour): 3 mg/l (Daphnia magna, mobility) EC50 (96 hour): 13 mg/l (Pseudokirchnerella subcapitata) Long Term NOELR (28 days) 1.5 mg/l (Fish) QSAR LOEC (21 days): 0.32 mg/l (Daphnia magna) NOEL (96 hour) 6.3 mg/l (Algae) Persistence and degradability Readily biodegradable. Bioaccumulative potential The product has no potential for bioaccumulation. Mobility in soil Not available. Results of PBT and vPvB assessment Not classified as PBT or vPvB. Other adverse effects None known. MULTI-STATE FORMULA (B101-50) INSTANT GUM CUTTER Revision: March 20, 2019 Page: 6/7 SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Disposal should be in accordance with local, state or national legislation. Consult an accredited waste disposal contractor or the local authority for advice. SECTION 14: TRANSPORT INFORMATION U.S. DOT Sea transport (IMDG) Air transport (ICAO/IATA) UN number 1950 1950 1950 Proper Shipping Name Aerosols, flammable Aerosols, flammable Aerosols, flammable Transport hazard class(es) 2.1 2.1 2.1 Packing group Not applicable Not applicable Not applicable Environmental hazards None assigned None assigned None assigned Special precautions for user None assigned None assigned None assigned Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: TSCA (Toxic Substance Control Act) - Inventory Status: All components listed or polymer exempt. Designated Hazardous Substances and Reportable Quantities (40 CFR 302.4): Chemical Name CAS No. Typical %wt. RQ (Pounds) Acetone 67-64-1 70 - 90 5000 SARA 311/312 - Hazard Categories: See SECTION 2: HAZARDS IDENTIFICATION SARA 313 - Toxic Chemicals (40 CFR 372): Chemical Name CAS No. Typical %wt. none ------ ----- SARA 302 - Extremely Hazardous Substances(40 CFR 355): Chemical Name CAS No. Typical %wt. TPQ (pounds) None ---- ---- ---- California Proposition 65 List: Chemical Name CAS No. Type of Toxicity None -------- --------- SECTION 16: OTHER INFORMATION The following sections contain revisions or new statements: 1-16. Date of preparation: February 8,2019 Hazard Statement(s) and Risk Phrases Listed in: SECTION 2:/ SECTION 3: Hazard Statement(s) - H225: Highly flammable liquid and vapor. - H301: Toxic if swallowed. - H304: May be fatal if swallowed and enters airways. - H311: Toxic in contact with skin. - H315: Causes skin irritation. - H319: Causes serious eye irritation. - H331: Toxic if inhaled. - H336: May cause drowsiness or dizziness. - H370: Causes damage to organs. MULTI-STATE FORMULA (B101-50) INSTANT GUM CUTTER Revision: March 20, 2019 Page: 7/7 Training advice: None. Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use.