SAFETY DATA SHEET Issuing Date 10-Dec-2012 Revision Date 1/5/2022 Revision Number 2 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING GHS product identifier B1400/ B1401/ B1402/ B1405/ B14055 Product Name Description DOT 3 Brake Fluid Other means of identification Synonyms Automotive brake fluid Recommended use of the chemical and restrictions on use Recommended Use Uses advised against Automotive brake fluid No information available Supplier's details Supplier Address Manufacturer Name Address The Berkebile Oil Company 1216 Red Brant Road Somerset, PA 15501 814-443-1656 This email address is being protected from spambots. You need JavaScript enabled to view it. 814-443-2873 Phone Email Fax Emergency telephone number Chemtrec Emergency Telephone number 800-424-9300 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous according to the OSHA Hazard Communication Standard 2012 (29 CFR 1910.1200) Acute Oral Toxicity Category 4 Category 1 Serious Eye Damage/Eye Irritation GHS Label elements, including precautionary statements Emergency Overview Signal Word Danger Hazard Statements ? Harmful if swallowed ? Causes serious eye damage Page 1 / 8 B1400/ B1401/ B1402/ B1405/ B14055 Revision Date 3/21/2019 Appearance Amber Physical State Liquid. Odor Etheric Precautionary Statements Prevention ? Wash face, hands and any exposed skin thoroughly after handling ? Do not eat, drink or smoke when using this product ? Wear eye/face protection General Advice ? None Eyes ? IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing ? Immediately call a POISON CENTER or doctor/physician. Ingestion ? IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell ? Rinse mouth Storage ? None Disposal ? Dispose of contents/container to an approved waste disposal plant Hazard Not Otherwise Classified (HNOC) Not applicable Other information No information available. 3. COMPOSITION/INFORMATION ON INGREDIENTS Synonyms Automotive brake fluid Chemical Name CAS-No 143-22-6 111-46-6 112-34-5 6881-94-3 Weight % Trade secret Triethylene glycol, monobutyl ether Diethylene glycol 15-30 15-25 10-20 5-10 * * * * Diethylene glycol monobutyl ether Ethanol, 2-(2-propoxyethoxy)- *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of necessary first-aid measures Eye Contact Immediately flush with plenty of water. After initial flushing, remove any contact lenses and continue flushing for at least 15 minutes. Call a physician or Poison Control Center immediately. Page 2 / 8 B1400/ B1401/ B1402/ B1405/ B14055 Revision Date 3/21/2019 Skin Contact Wash off immediately with soap and plenty of water. Get medical attention immediately if symptoms occur. Inhalation Ingestion Get medical attention immediately if symptoms occur. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Drink plenty of water. Call a POISON CENTER or doctor/physician if exposed or you feel unwell. Most important symptoms/effects, acute and delayed Most Important Symptoms/Effects Burning. Red eyes Tearing Indication of immediate medical attention and special treatment needed, if necessary Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media None Specific Hazards Arising from the Chemical None known Explosion Data Sensitivity to Mechanical Impact Sensitivity to Static Discharge None. None Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment. Do not get in eyes Environmental Precautions Environmental Precautions See Section 12 for additional Ecological Information Methods and materials for containment and cleaning up Methods for Containment Methods for Cleaning Up Prevent further leakage or spillage if safe to do so. Dam up. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Use personal protective equipment. Clean contaminated surface thoroughly. 7. HANDLING AND STORAGE Precautions for safe handling Handling Wear personal protective equipment. Do not get in eyes Page 3 / 8 B1400/ B1401/ B1402/ B1405/ B14055 Revision Date 3/21/2019 Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible Products Strong oxidizing agents. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Control parameters Exposure Guidelines This product does not contain any hazardous materials with occupational exposure limits established by the region specific regulatory bodies. Appropriate engineering controls Engineering Measures Showers. Eyewash stations. Individual protection measures, such as personal protective equipment Eye/Face Protection Skin and Body Protection Respiratory Protection Tightly fitting safety goggles. Protective gloves. No special protective equipment required. Hygiene Measures Provide regular cleaning of equipment, work area and clothing. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Odor Liquid Etheric Appearance Odor Threshold Amber No information available Property Values Remarks/ - Method pH 10.5 Not determined 205 ?C 203 ?C No data available No data available None known None known None known None known None known None known Melting Point/Range Boiling Point/Boiling Range Flash Point Evaporation rate Flammability (solid, gas) Flammability Limits in Air upper flammability limit lower flammability limit Vapor Pressure Vapor Density Relative Density Specific Gravity Water Solubility Solubility in other solvents Partition coefficient: n-octanol/waterNo data available Autoignition Temperature Decomposition Temperature Viscosity No data available No data available No data available No data available No data available 1.06 Completely soluble Completely soluble. None known None known None known None known None known None known None known None known None known None known No data available No data available <1500 CST Flammable Properties Not flammable Explosive Properties Oxidizing Properties No data available No data available Other information VOC Content (%) None Page 4 / 8 B1400/ B1401/ B1402/ B1405/ B14055 Revision Date 3/21/2019 10. STABILITY AND REACTIVITY Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of hazardous reactions None under normal processing. Hazardous polymerization does not occur. Conditions to avoid None known based on information supplied. Incompatible materials Strong oxidizing agents. Hazardous decomposition products Carbon oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Inhalation May cause irritation of respiratory tract. Eye Contact Skin Contact Ingestion Causes serious eye damage. May cause irritation. Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea. Symptoms related to the physical, chemical and toxicological characteristics Symptoms Eye contact with liquid may cause irritation including stinging, burning, tearing, or reddening of the eyes. Delayed and immediate effects and also chronic effects from short and long term exposure Sensitization No information available. Mutagenic Effects Carcinogenicity No information available. Contains no ingredient listed as a carcinogen. Reproductive Toxicity STOT - single exposure STOT - repeated exposure Aspiration Hazard No information available. No information available. No information available. No information available. Numerical measures of toxicity ? - Product The following values are calculated based on chapter 3.1 of the GHS document: LD50 Oral LD50 Dermal 1667 mg/kg; Acute toxicity estimate 4606 mg/kg; Acute toxicity estimate Page 5 / 8 B1400/ B1401/ B1402/ B1405/ B14055 Revision Date 3/21/2019 12. ECOLOGICAL INFORMATION Ecotoxicity The environmental impact of this product has not been fully investigated. Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Triethylene glycol, monobutyl ether EC50 72 h: > 500 mg/L (Desmodesmus subspicatus) LC50 96 h: 2200-4600 mg/L static (Leuciscus idus) LC50 96 h: = 2400 mg/L (Pimephales promelas) LC50 96 h: = 2400 mg/L static (Pimephales EC50 48 h: > 500 mg/L (Daphnia magna) promelas) Diethylene glycol LC50 96 h: = 75200 mg/L flow-through (Pimephales promelas) EC50 = 29228 mg/L 15 min EC50 48 h: = 84000 mg/L (Daphnia magna) Diethylene glycol monobutyl ether EC50 96 h: > 100 mg/L (Desmodesmus subspicatus) LC50 96 h: = 1300 mg/L static (Lepomis macrochirus) EC50 24 h: = 2850 mg/L (Daphnia magna) EC50 48 h: > 100 mg/L (Daphnia magna) Tetraethylene glycol Triethylene glycol EC50 96 h: > 1000 mg/L (Pseudokirchneriella subcapitata) LC50 96 h: > 1000 mg/L static (Oncorhynchus mykiss) EC50 > 100 mg/L 6 h EC50 48 h: > 1000 mg/L (Daphnia magna) LC50 96 h: 56200-63700 mg/L flow-through EC50 = 850 mg/L 5 min EC50 48 h: = 42426 mg/L (Daphnia magna) (Pimephales promelas) LC50 96 h: = 10000 mg/L static (Lepomis macrochirus) LC50 96 h: = 61000 mg/L flow-through (Lepomis macrochirus) Persistence and Degradability Bioaccumulation No information available. No information available. Chemical Name Log Pow 0.51 Triethylene glycol, monobutyl ether Diethylene glycol -1.98 Other Adverse Effects No information available. 13. DISPOSAL CONSIDERATIONS Waste Disposal Methods This material, as supplied, is not a hazardous waste according to Federal regulations (40 CFR 261). This material could become a hazardous waste if it is mixed with or otherwise comes in contact with a hazardous waste, if chemical additions are made to this material, or if the material is processed or otherwise altered. Consult 40 CFR 261 to determine whether the altered material is a hazardous waste. Consult the appropriate state, regional, or local regulations for additional requirements. Contaminated Packaging Do not re-use empty containers. Empty containers should be taken to an approved waste handling site for recycling or disposal. 14. TRANSPORT INFORMATION DOT TDG MEX ICAO Not regulated Not regulated Not regulated. Not regulated Page 6 / 8 B1400/ B1401/ B1402/ B1405/ B14055 Revision Date 3/21/2019 IATA Not regulated Not regulated Not regulated Not regulated IMDG/IMO RID ADR 15. REGULATORY INFORMATION International Inventories TSCA DSL Complies Complies Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372: Chemical Name CAS-No Weight % SARA 313 - Threshold Values % Triethylene glycol, monobutyl ether Diethylene glycol monobutyl ether Ethanol, 2-(2-propoxyethoxy)- SARA 311/312 Hazard Categories Acute Health Hazard 143-22-6 112-34-5 6881-94-3 15-30 10-20 5-10 1.0 1.0 1.0 Yes No No No No Chronic Health Hazard Fire Hazard Sudden Release of Pressure Hazard Reactive Hazard Clean Water Act This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material. U.S. State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Illinois Rhode Island Triethylene glycol, monobutyl ether X X Diethylene glycol X X X Diethylene glycol monobutyl X ether U.S. EPA Label Information Page 7 / 8 B1400/ B1401/ B1402/ B1405/ B14055 Revision Date 3/21/2019 EPA Pesticide Registration Number Not applicable 16. OTHER INFORMATION NFPA HMIS Health Hazard 0 Health Hazard 0 Flammability 0 Instability 0 Physical and Chemical Hazards - Personal Protection X Flammability 0 Physical Hazard 0 Prepared By Zach Sherbine 1-800-572-6501 10-Dec-2012 5/15/15 Issuing Date Revision Date Revision Note Initial Release. General Disclaimer The information provided on this MSDS is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text. End of Safety Data Sheet Page 8 / 8