THE BERKEBILE OIL COMPANY, INC. PAGE 1 OF 8 PAGES UPDATED: 6/10/2020 Telephone: 814-443-1656 Page 1 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 SAFETY DATA SHEET 1. Product Identifier Product form Substance Trade name Product Number(s) Airline Antifreeze B1800, B1805, B18055 Relevant Uses Uses of Mixture: Airline Antifreeze Supplier Details Manufacturer Name Address: City, State, Zip Phone Fax Emergency Contact The Berkebile Oil Company, Inc. 1216 Red Brant Road Somerset, PA 15501 814-443-1656 814-443-2873 Chemtrec Emergency Tel # 800-424-9300 2. HAZARDS IDENTIFICATION 2.1 Classification of the Substance or Mixture Flam.Liq.2 H225 Acute Tox. 3 (Oral) H301 Acute Tox 3 (Dermal) H311 Acute Tox 3 (Inhalation) H331 Eye Irrit. 2A H319 Repr. 1B H360 STOT SE 1 H370 2.2 Label Elements Signal Word (GHS-US) Danger THE BERKEBILE OIL COMPANY, INC. PAGE 2 OF 8 PAGES UPDATED: 6/10/2020 Telephone: 814-443-1656 Page 2 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 Hazzard Statements (GHS-US) H225 ? Highly flammable liquid and vapor H301+311+H331 ? Toxic if swallowed, in contact with skin, or inhaled H319 ? Causes serious eye irritation H360 ? May damage fertility or the unborn child H370 ? Causes damage to organs Precautionary Statements (GHS-US) P202 - Do not handle until all safety precautions have been read and met P210 - Keep away from heat, sparks, open flames, hot surfaces ? No Smoking P233 ? Keep container tightly closed P240 ? Ground/bond container and receiving equipment P241 - Use explosion-proof electrical, ventilating, lighting equipment P242 - Use only non-sparking tools P243 - Take precautionary measures against static discharge P261 ? Do not breathe vapors P264 - Wash hands thoroughly after handling P270 - Do not eat, drink or smoke when using this product P271 - Use only outdoors or in a well-ventilated area P280 - Wear protective gloves, protective clothing, eye protection, face protection P301+P310 - If swallowed: Immediately call a doctor P303+P361+P353 - If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P307+P311 - If exposed: Call a poison center/doctor P330 - Rinse mouth P361 - Take off immediately all contaminated clothing P363 - Wash contaminated clothing before reuse P370+P378 - In case of fire: Use Water spray to extinguish P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to licensed waste management site - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention - Obtain special instructions before use. - Keep Cool 3. Composition / Information on Ingredients THE BERKEBILE OIL COMPANY, INC. PAGE 3 OF 8 PAGES UPDATED: 6/10/2020 Telephone: 814-443-1656 Page 3 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 Chemical name Common name and synonyms CAS number % Methanol 67-56-1 95-100 4. First Aid Measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Call a POISON CENTER or doctor/physician. Methanol is toxic and flammable. Take proper precautions to ensure your own safety before attempting rescue (e.g. wear appropriate protective equipment and remove any sources of ignition). First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. If breathing is difficult, give oxygen. Obtain medical attention. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. First-aid measures after eye contact : Rinse immediately and thoroughly, pulling the eyelids well away from the eye (15 minutes minimum). Remove contact lenses, if present and easy to do. Continue rinsing. Ensure that folded skin of eyelids is thoroughly washed with water. Obtain medical attention if pain, blinking or redness persist. First-aid measures after ingestion 4.2 Most Important Symptoms : : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. Never give anything by mouth to an unconscious person. Symptoms may include: dizziness, headache, nausea and loss of coordination. Coma and death may occur is medical treatment is not sought. 5. Fire-Fighting Measures Flammable Properties: As defined by OSHA, this product is a Class IB flammable liquid. Suitable Extinguishing Media: Dry chemical, alcohol-resistant foam, carbon dioxide (CO2) Products of Combustion: Carbon dioxide and carbon monoxide. Explosion Hazards: Containers, when exposed to heat from fire, may build pressure and rupture. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye THE BERKEBILE OIL COMPANY, INC. PAGE 4 OF 8 PAGES UPDATED: 6/10/2020 Telephone: 814-443-1656 Page 4 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. 6. Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. If run-off occurs, notify the proper authorities as required, that a spill has occurred. Methods for Containment & Clean-up: Eliminate all ignition sources. Dike area to contain spill. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. 7. Handling and Storage Handling Procedures: Avoid contact with skin and eyes. Do not use near sources of ignition or energized equipment. Static ignition hazard can result from handling and use. Electrically bond and ground all containers and equipment before transfer or use of material. For product use instructions, please see the product label. Storage Procedures: Store in a cool dry area out of direct sunlight. Keep containers closed when not in use. Keep out of reach of children and pets. Aerosol Storage Level: NA 8. Exposure Controls / Personal Protection Exposure Guidelines: OSHA ACGIH OTHER COMPONENT TWA STEL TWA STEL TWA TWA SOURCE UNIT Methanol NE 200 NE 200 (s) 250 (s) NE ppm N.E.- Not Established (c)-Ceiling (s)-Skin (v)-Vacated Controls and Protection: Engineering Controls: Area should have ventilation to provide fresh air. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at the source, preventing dispersion into the general work area. Use mechanical means if necessary to maintain vapor levels below the exposure guidelines. If working in a confined space, follow applicable OSHA regulations. Respiratory Protection: None required for normal work where adequate ventilation is provided. If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with organic vapor cartridge. Air monitoring is needed to THE BERKEBILE OIL COMPANY, INC. PAGE 5 OF 8 PAGES UPDATED: 6/10/2020 Telephone: 814-443-1656 Page 5 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 determine actual employee exposure levels. Use a self-contained breathing apparatus in confined spaces and for emergencies. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Skin Protection: Use protective gloves such as nitrile or natural rubber. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. 9. Physical and Chemical Properties Physical state : Liquid Appearance : Clear. Molecular mass : 32.04 g/mol Color : Colorless. Odor : alcohol odor. Odor threshold : 4.2 - 5960 ppm pH : Not applicable Relative evaporation rate (butyl acetate=1) : 4.1 Melting point : -97.8 ?C Freezing point : -97.6 ?C Boiling point : 64.7 ?C Flash point : 11 ?C Auto-ignition temperature : 464 ?C Decomposition temperature : Not available Flammability (solid, gas) : No data available Vapor pressure : 12.8 kPa @ 20?C Relative vapor density at 20 ?C : 1.1 Relative density : 0.791 - 0.793 @ 20?C Relative density of saturated gas/air mixture : 1.0 Specific gravity / density : 792 kg/m? Solubility : Miscible with water. Log Pow : 0.82 Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : 0.8 cP (25 ?C) Explosive properties : vapors may form explosive mixture with air. Oxidizing properties : Not oxidizing. Explosive limits : 5.5 - 36.5 vol % 10. Stability and Reactivity Stability: Stable Conditions to Avoid: Sources of ignition. Incompatible Materials: Hypochlorites, peroxides, reactive metals such as aluminum and magnesium, sodium, strong acids, strong bases, strong oxidizing agents, zinc Hazardous Decomposition Products: Carbon dioxide and carbon monoxide Possibility of Hazardous Reactions: No THE BERKEBILE OIL COMPANY, INC. PAGE 6 OF 8 PAGES UPDATED: 6/10/2020 Telephone: 814-443-1656 Page 6 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 11. Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product. Methanol LD50 Oral (rat) 5600 mg/kg LD50 Dermal (rabbit) 15800 mg/kg Inhallation (rat) ppm 64000 ppm/4h (rat) Reproductive Toxicity: No information available Teratogenicity: Methanol has produced fetotoxicity in rats and teratogenicity in mice exposed by inhalation to high concentrations of methanol vapors. Mutagenicity: No information available Synergistic Effects: High concentrations of methanol can increase the toxicity of other chemicals, particularly liver toxins. 12. Ecological Information Ecological studies have not been conducted for this product. The following information is available for components of this product. Ecotoxicity: No information available Persistence / Degradability: No information available Bioaccumulation / Accumulation: No information available Mobility in Environment: No information available 13. Disposal Considerations Waste Classification: This product is a RCRA hazardous waste for the characteristic of ignitability with the following potential waste codes: D001, F003, U154. (See 40 CFR Part 261.20 ? 261.33) Empty containers may be recycled. All disposal activities must comply with federal, state, provincial and local regulations. Local regulations may be more stringent than state, provincial or national requirements. 14. Transport Information US DOT (ground): 05532, 75532 UN1230, Methanol, 3, PGII, Limited Quantity** 05528, 05555, 75528 UN1230, Methanol, 3, PG II ICAO/IATA (air): 05532, 75532 UN1230, Methanol, 3 (6.1), PG II, Limited Quantity 05528, 05555, 75528 UN1230, Methanol, 3 (6.1), PGII IMO/IMDG (water): 05532, 75532 UN1230, Methanol, 3 (6.1), PG II, Limited Quantity 05528, 05555, 75528 UN1230, Methanol, 3 (6.1), PGII 15. Regulatory Information THE BERKEBILE OIL COMPANY, INC. PAGE 7 OF 8 PAGES UPDATED: 6/10/2020 Telephone: 814-443-1656 Page 7 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 U.S. Federal Regulations: Toxic Substances Control Act (TSCA): All ingredients are either listed on the TSCA inventory or are exempt. Comprehensive Environmental Response, Compensation and Liability Act (CERCLA): Reportable Quantities (RQ?s) exist for the following ingredients: Methanol (5000 lbs) Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Superfund Amendments Reauthorization Act (SARA) Title III: Section 302 Extremely Hazardous Substances (EHS): None Section 311/312 Hazard Categories: Fire Hazard Yes Reactive Hazard No Release of Pressure No Acute Health Hazard Yes Chronic Health Hazard No Section 313 Toxic Chemicals: This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: Methanol (> 99%) Clean Air Act: Section 112 Hazardous Air Pollutants (HAPs): Methanol Occupational Safety and Health Administration: This product is regulated by the Hazard Communications Standard. U.S. State Regulations: California Safe Drinking Water and Toxic Enforcement Act (Prop 65): This product may contain the following chemicals known to the state of California to cause cancer, birth defects or other reproductive harm: Methanol Consumer Products VOC Regulations: This product is not regulated. State Right to Know: New Jersey: 67-56-1 Pennsylvania: 67-56-1 Massachusetts: 67-56-1 Rhode Island : 67-56-1 Canadian Regulations: THE BERKEBILE OIL COMPANY, INC. PAGE 8 OF 8 PAGES UPDATED: 6/10/2020 Telephone: 814-443-1656 Page 8 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 Controlled Products Regulations: This product has been classified in accordance with the hazard criteria of the Controlled Product Regulation and the MSDS contains all the information required by the Controlled Products Regulations. WHMIS Hazard Class: B2, D1B, D2A, D2B Canadian DSL Inventory: All ingredients are either listed on the DSL Inventory or are exempt. European Union Regulations: RoHS Compliance: This product is compliant with Directive 2002/95/EC of the European Parliament and of the Council of 27 January 2003. This product does not contain any of the restricted substances as listed in Article 4(1) of the RoHS Directive. Additional Regulatory Information: None 16. Other Information FPPA Fire: HMIS II HEALTH 1 FLAMABALITY 3 PHYSICAL HAZZARD 0 Prepared By: Kirk Sherbine Berkebile Oil #: B1800-030115 Revision Date: 3/1/2015 Changes since last revision: All The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of Berkebile Oil?s knowledge or obtained from sources believed by Berkebile Oil to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or Berkebile Oil Company.