B800 BERKEBILE WHITE GREASE Page: 1/7 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION Product identifier Chemical Name Mixture CAS No. Mixture Trade Name BERKEBILE WHITE GREASE Product Code B800 Relevant identified uses of the substance or mixture and uses advised against Supplier Details Manufacturer Name The Berkebile Oil Company Address 1216 Red Brant Road Somerset, PA 15501, PO BOX 715 Phone 814-443-1656 Email This email address is being protected from spambots. You need JavaScript enabled to view it. Fax 814-443-2873 Chemtrec Emergency Tel # 800-424-9300 SECTION 2: HAZARDS IDENTIFICATION Classification of the substance or mixture OSHA HCS (29 CFR 1910.1200) Flam. Aerosol 1; Liquefied gas; Skin Irrit. 2; STOT SE 3; Asp. Tox. 1 Label elements Hazard Symbol Signal word(s) DANGER Hazard Statement(s) Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Precautionary Statement(s) Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Wear protective gloves/eye protection. Wash hands and exposed skin after use. Avoid breathing spray. Use only outdoors or in a well-ventilated area. Protect from sunlight and do not expose to temperatures exceeding 50 ?C/122 ?F. Other hazards Toxic to aquatic life. Harmful to aquatic life with long lasting effects. SAFETY DATA SHEET OSHA HCS (29 CFR 1910.1200) B800 BERKEBILE WHITE GREASE Page: 2/7 SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredient(s) % wt. CAS No. Hazard classification Heptanes, branched, cyclic and linear 30 - 40 426260-76-6 Flam. Liq. 2; H225 Asp. Tox. 1; H304 Skin Irrit. 2; H315 STOT SE 3; H336 Aquatic Acute 2; H401 Aquatic Chronic 3; H412 Petroleum distillates 30 - 50 64742-52-5 Flam. Liq. 3; H226 Asp. Tox. 1; H304 Propane 5 - 15 74-98-6 Flam. Gas 1; H220 Liquefied gas; H280 n-Butane 5 - 15 106-97-8 Flam. Gas 1; H220 Liquefied gas; H280 Additional Information ? None * The exact percentage withheld as a trade secret in accordance with 29 CFR 1910.1200. SECTION 4: FIRST AID MEASURES Description of first aid measures Inhalation Move person to fresh air. If breathing is laboured, administer oxygen. If symptoms develop, obtain medical attention. Skin Contact Wash affected skin with soap and water. If symptoms develop, obtain medical attention. Take off contaminated clothing and wash it before reuse. Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists, get medical advice/attention. Ingestion Immediately call a POISON CENTER or doctor/physician. Do not induce vomiting. Do not give anything by mouth to an unconscious person. Most important symptoms and effects, both acute and delayed Aspiration of droplets may cause pulmonary oedema. Indication of any immediate medical attention and special treatment needed IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media -Suitable Extinguishing Media Extinguish with carbon dioxide, dry chemical, foam or water spray. -Unsuitable Extinguishing Media Do not use water jet. Special hazards arising from the substance or mixture Flammable vapor. Advice for fire-fighters A self contained breathing apparatus and suitable protective clothing should be worn in fire conditions. Keep containers cool by spraying with water if exposed to fire. B800 BERKEBILE WHITE GREASE Page: 3/7 SECTION 6: ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Eliminate sources of ignition. Avoid contact with skin and eyes. Avoid breathing vapors. Environmental precautions Prevent liquid entering sewers, basements and work pits. Avoid release to the environment. Methods and material for containment and cleaning up Cover spills with inert absorbent material. Transfer to a container for disposal or recovery. Reference to other sections None Additional Information None SECTION 7: HANDLING AND STORAGE Precautions for safe handling Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid contact with skin and eyes. Use product in a well-ventilated area only. Avoid breathing spray. Conditions for safe storage, including any incompatibilities -Storage temperature Store in a well-ventilated place. Protect from sunlight. Do not expose to temperatures exceeding 50?C/ 122?F. -Incompatible materials This product should be stored away from sources of strong heat, strong acids, oxidizing chemicals and reducing agents. Specific end use(s) Lubricant SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION Occupational Exposure Limits SUBSTANCE. CAS No. (8hr TWA) (STEL) Note: PEL (OSHA) TLV (ACGIH) PEL (OSHA) TLV (ACGIH) Alkanes (C9-C15) ------- ------- 1200 mg/m3 ------- ------- ------- Heptane, branched, cylic and linear 426260-76-6 500 ppm** 1500 mg/m3 ----- ----- **n-heptane Mineral oils / Oil Mist ------- 5 mg/m3 5 mg/m3(I) ----- ----- (I)Inhalable Propane 74-98-6 1000 ppm Aspyx.# ----- ----- # n-Butane 106-97-8 ----- 250 ppm ----- ----- ----- #Assure minimum oxygen content of work atmosphere. Recommended monitoring method NIOSH 1550 (Naphthas); NIOSH 1500 (hydrocarbons, B.P. 36 - 216 ?C); NIOSH 5026 (Oil mist; mineral) Exposure controls Appropriate engineering controls Ensure adequate ventilation. Personal protection equipment Eye/face protection Wear protective eyewear (goggles, face shield, or safety glasses). Skin protection (Hand protection/ Other) Wear suitable gloves if prolonged skin contact is likely (Nitrile rubber or Butyl rubber). Check with protective equipment manufacturer's data. B800 BERKEBILE WHITE GREASE Page: 4/7 Respiratory protection Normally no personal respiratory protection is necessary. In case of insufficient ventilation, wear suitable respiratory equipment. Check with protective equipment manufacturer's data. Thermal hazards Not normally required. Use gloves with insulation for thermal protection, when needed. Environmental Exposure Controls Avoid release to the environment. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Appearance Aerosol spray Color. White Odor Mild petroleum, Solvent-like. Odor Threshold (ppm) Not available pH (Value) Not available Melting Point (?C) / Freezing Point (?C) Not available. Boiling point/boiling range (?C): Not available. Flash Point (?C) -104 (Propane) Evaporation Rate Not available. Flammability (solid, gas) Extremely flammable Explosive Limit Ranges 2.1% - 9.5% v/v (Propane) Vapor pressure (Pascal) ca. 95 x 104 (Propane) Vapor Density (Air=1) ca. 1.56 @ 0?C (Propane) Density (g/ml) Not available Solubility (Water) Not available Solubility (Other) Not available Partition Coefficient (n-Octanol/water) Not available Auto Ignition Point (?C) 450 (Propane) Decomposition Temperature (?C) Not available Kinematic Viscosity (cSt) < 20.5 @ 40 ?C Explosive properties Not explosive. Oxidizing properties Not oxidizing. Other information None SECTION 10: STABILITY AND REACTIVITY Reactivity Stable under normal conditions. Chemical stability Stable. Possibility of hazardous reactions None anticipated. Conditions to avoid Avoid contact with heat and ignition sources. Incompatible materials This product should be stored away from sources of strong heat , strong acids, oxidizing chemicals and reducing agents. Hazardous decomposition product(s) Carbon monoxide, Carbon dioxide, Metal oxides, Acrid smoke SECTION 11: TOXICOLOGICAL INFORMATION Exposure routes: Inhalation, Skin Contact, Eye Contact Information on toxicological effects Heptane, branched, cyclic and linear (CAS# 426260-76-6) - By analogy with similar materials: B800 BERKEBILE WHITE GREASE Page: 5/7 Acute toxicity Oral: LD50 >5 g/kg-bw Dermal: LD50 >2 g/kg-bw Inhalation: LC50 = 65 - 103 mg/L (Vapor), 4-hr. rat May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Irritation/Corrosivity Causes skin irritation. Repeated exposure may cause skin dryness or cracking. May cause eye irritation. Sensitization It is not a skin sensitizer. Repeated dose toxicity NOAEC: 12350 mg/m3 (2 yr, inhal., rat, Systemic effects) LOAEC: 1650 mg/m3 (2 hr, inhal., rat, CNS effects) May cause drowsiness or dizziness. Carcinogenicity No data. It is unlikely to present a carcinogenic hazard to man. NTP IARC ACGIH OSHA NIOSH No. No. No. No. No. Mutagenicity There is no evidence of mutagenic potential. Reproductive toxicity Not available Propane (CAS# 74-98-6): Acute toxicity Inhalation: LC50 = 1237 mg/L (2-hr, mouse, gas) Irritation/Corrosivity No evidence of irritant effects from normal handling and use. Sensitisation It is not a skin sensitiser. Repeated dose toxicity NOAEC: >19678 mg/m3 (28-day, rat, Systemic effects) LOAEC: 21641 mg/m3 (28-day, rat, effects: Body weight) Carcinogenicity No data. It is unlikely to present a carcinogenic hazard to man. Mutagenicity There is no evidence of mutagenic potential. Reproductive toxicity None anticipated SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity Heptane, branched, cyclic and linear (CAS# 426260-76-6) - By analogy with similar materials: Short term LL50 (96 hour): >13.4 mg/L (Oncorhynchus mykiss) EL50 (48 hour): 3 mg/l (Daphnia magna, mobility) EC50 (96 hour): 13 mg/l (Pseudokirchnerella subcapitata) Long Term NOELR (28 days) 1.5 mg/l (Fish) QSAR LOEC (21 days): 0.32 mg/l (Daphnia magna) NOEL (96 hour) 6.3 mg/l (Algae) Propane (CAS# 74-98-6): Short term (estimate) LC50 (96 hour): 27.98 mg/L (fish) LC50 (48 hour): 14.22 mg/L (crustacea) EC50 (96 hour): 7.71 mg/L (algae) Long Term No data. Persistence and degradability Readily biodegradable. Bioaccumulative potential The product has no potential for bioaccumulation. Mobility in soil Not available. Results of PBT and vPvB assessment Not classified as PBT or vPvB. Other adverse effects None known. SECTION 13: DISPOSAL CONSIDERATIONS Waste treatment methods Disposal should be in accordance with local, state or national legislation. Consult an accredited waste disposal contractor or the local authority for advice. B800 BERKEBILE WHITE GREASE Page: 6/7 SECTION 14: TRANSPORT INFORMATION U.S. DOT Sea transport (IMDG) Air transport (ICAO/IATA) UN number 1950 1950 1950 Proper Shipping Name Aerosols, flammable Aerosols, flammable Aerosols, flammable Transport hazard class(es) 2.1 2.1 2.1 Packing group Not applicable Not applicable Not applicable Environmental hazards None assigned None assigned None assigned Special precautions for user None assigned None assigned None assigned Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code: Not applicable SECTION 15: REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture: TSCA (Toxic Substance Control Act) - Inventory Status: All components listed or polymer exempt. Designated Hazardous Substances and Reportable Quantities (40 CFR 302.4): Chemical Name CAS No. Typical %wt. RQ (Pounds) None ---- ---- ---- SARA 311/312 - Hazard Categories: Fire Sudden Release Reactivity Immediate (acute) Chronic (delayed) SARA 313 - Toxic Chemicals (40 CFR 372): Chemical Name CAS No. Typical %wt. Zinc compounds (Zinc oxide) 1314-13-2 <1 SARA 302 - Extremely Hazardous Substances (40 CFR 355): Chemical Name CAS No. Typical %wt. TPQ (pounds) None ---- ---- ---- California Proposition 65 List: Chemical Name CAS No. Type of Toxicity Lead monoxide* 1317-36-8 Cancer Cadmuim oxide* 1306-19-0 Cancer, Reproductive *Trace to none. SECTION 16: OTHER INFORMATION The following sections contain revisions or new statements: 1-16. Date of preparation: June 9, 2015 Hazard Statement(s) and Risk Phrases Listed in: SECTION 2:/ SECTION 3: Hazard Statement(s) - H220: Extremely flammable gas. - H225: Highly flammable liquid and vapor. - H226: Flammable liquid and vapour. - H280: Contains gas under pressure; may explode if heated. - H304: May be fatal if swallowed and enters airways. - H315: Causes skin irritation. - H336: May cause drowsiness or dizziness. - H400: Very toxic to aquatic life. - H401: Toxic to aquatic life. - H410: Very toxic to aquatic life with long lasting effects. - H412: Harmful to aquatic life with long lasting effects. Training advice: None. B800 BERKEBILE WHITE GREASE Page: 7/7 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use.