SAFETY DATA SHEET Revision Date 16-Mar-2021 Version 8 1. IDENTIFICATION Product identifier Product Name Gumout Multi-System Tune-Up Other means of identification Product Code 31048 Document SKU 510011, 510103,510062, 510158 Recommended use of the chemical and restrictions on use Recommended Use Fuel additive, Consumer Use Uses advised against Uses other than recommended use. Details of the supplier of the safety data sheet Company Phone Number 1-855-888-1988 24-hour emergency phone number (CHEMTREC) 1-800-424-9300 or 1-703-527-3887 (U.S.) (RMPDC) 1-877-504-9352 (U.S.) E-mail address: This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Emergency Overview Supplier Address ITW Global Brands 16200 Park Row, Suite 120 Houston, TX 77084 Manufacturer Address Manufactured and Distributed by: Distributor May Also Be Distributed by: ITW Permatex Canada 101-2360 Bristol Circle Oakville, ON Canada L6H 6M5 Telephone: (800) 924-6994 Flammable liquids Category 4 Signal word Warning Combustible liquid _____________________________________________________________________________________________ Page 1 / 9 _____________________________________________________________________________________________ 31048 - Gumout Multi-System Tune-Up Revision Date 16-Mar-2021 Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention In case of fire: Use CO2, dry chemical, or foam to extinguish. Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information May be harmful in contact with skin. Toxic to aquatic life with long lasting effects. Unknown acute toxicity 11.9316 % of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical name CAS No Weight-% Hydrotreated middle distillates 64742-46-7 40 - 70 Distillates (petroleum), solvent-refined heavy paraffinic 64741-88-4 10 - 30 Polyetheramine TRADE SECRET 5 - 10 Distillates (petroleum), hydrotreated light 64742-47-8 3 - 7 Naphthalene 91-20-3 0.1 - 1 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Take off contaminated clothing and wash before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Appearance Clear liquid Physical state Liquid Odor Mild petroleum odor _____________________________________________________________________________________________ Page 2 / 9 _____________________________________________________________________________________________ 31048 - Gumout Multi-System Tune-Up Revision Date 16-Mar-2021 Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Use dry chemical, Foam Unsuitable extinguishing media Do not use a solid water stream as it may scatter and spread fire Specific hazards arising from the chemical Flammable. May be ignited by heat, sparks or flames. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Remove all sources of ignition. Environmental precautions Environmental precautions See section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Slippery, can cause falls if walked on. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep out of the reach of children. Keep containers tightly closed in a cool, well-ventilated place. Do not expose to temperatures exceeding 50 ?C/122 ?F. Keep away from heat, _____________________________________________________________________________________________ Page 3 / 9 _____________________________________________________________________________________________ 31048 - Gumout Multi-System Tune-Up Revision Date 16-Mar-2021 sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Naphthalene 91-20-3 TWA: 10 ppm S* TWA: 10 ppm TWA: 50 mg/m3 (vacated) TWA: 10 ppm (vacated) TWA: 50 mg/m3 (vacated) STEL: 15 ppm (vacated) STEL: 75 mg/m3 IDLH: 250 ppm TWA: 10 ppm TWA: 50 mg/m3 STEL: 15 ppm STEL: 75 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective natural rubber, nitrile rubber, Neoprene? or PVC gloves. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES 9.1. Information on basic physical and chemical properties Physical state Liquid Appearance Clear liquid Odor Mild petroleum odor Color Yellow Odor threshold No information available Property Values Remarks ? Method pH Not applicable Melting point / freezing point No information available Boiling point / boiling range No information available Flash point 79 ?C / 174 ?F Pensky-Martens Closed Cup (PMCC) Evaporation rate No information available Flammability (solid, gas) No information available Flammability Limit in Air Upper flammability limit: No information available Lower flammability limit: No information available Vapor pressure No information available Vapor density No information available Relative density 0.83 _____________________________________________________________________________________________ Page 4 / 9 _____________________________________________________________________________________________ 31048 - Gumout Multi-System Tune-Up Revision Date 16-Mar-2021 Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available Density 7.02#/gal @ 68?F Bulk density No information available SADT (self-accelerating decomposition temperature) No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under normal conditions Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Temperatures >50 ?C / 122 ?F. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Vapors may be irritating to eyes, nose, throat, and lungs. May cause central nervous system depression with nausea, headache, dizziness, vomiting, and incoordination. May be harmful by inhalation. Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Aspiration may cause pulmonary edema and pneumonitis. May be harmful if swallowed. Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Hydrotreated middle distillates 64742-46-7 = 7400 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) = 4.6 mg/L ( Rat ) 4 h Distillates (petroleum), solvent-refined heavy paraffinic 64741-88-4 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5530 mg/m3 ( Rat ) 4 h Distillates (petroleum), hydrotreated light > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h Water solubility Negligible Solubility(ies) No information available Partition coefficient No information available Autoignition temperature No information available Hyphen No information available Kinematic viscosity No information available Dynamic viscosity No information available No information available _____________________________________________________________________________________________ Page 5 / 9 _____________________________________________________________________________________________ 31048 - Gumout Multi-System Tune-Up Revision Date 16-Mar-2021 64742-47-8 Naphthalene 91-20-3 = 1110 mg/kg ( Rat ) = 1120 mg/kg ( Rabbit ) > 0.4 mg/L ( Rat ) 4 h Symptoms related to the physical, chemical and toxicological characteristics Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical name ACGIH IARC NTP OSHA Distillates (petroleum), solvent-refined heavy paraffinic 64741-88-4 A2 Group 1 Known X Naphthalene 91-20-3 A3 Group 2B Reasonably Anticipated X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 3 - Not classifiable as a human carcinogen Group 2B - Possibly Carcinogenic to Humans NTP (National Toxicology Program) Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target organ effects Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document ATEmix (oral) 6444 mg/kg ATEmix (dermal) 2032 mg/kg ATEmix (inhalation-dust/mist) 726 mg/l ATEmix (inhalation-vapor) 21275.2 mg/l 12. ECOLOGICAL INFORMATION This product contains a chemical which is listed as a severe marine pollutant according to DOT. Ecotoxicity 11.9316 % of the mixture consists of component(s) of unknown hazards to the aquatic environment Persistence and degradability No information available. Bioaccumulation No information available. Mobility Disperses in water. Chemical name Partition coefficient Naphthalene 91-20-3 3.6 Other adverse effects No information available _____________________________________________________________________________________________ Page 6 / 9 _____________________________________________________________________________________________ 31048 - Gumout Multi-System Tune-Up Revision Date 16-Mar-2021 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Dispose of in accordance with federal, state and local regulations. Do not reuse container. US EPA Waste Number D001 Chemical name RCRA - Halogenated Organic Compounds RCRA - P Series Wastes RCRA - F Series Wastes RCRA - K Series Wastes Naphthalene 91-20-3 - - Toxic waste waste number F025 Waste description: Condensed light ends, spent filters and filter aids, and spent desiccant wastes from the production of certain chlorinated aliphatic hydrocarbons, by free radical catalyzed processes. These chlorinated aliphatic hydrocarbons are those having carbon chain lengths ranging from one to and including five, with varying amounts and positions of chlorine substitution. - This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical name California Hazardous Waste Status Naphthalene 91-20-3 Toxic 14. TRANSPORT INFORMATION DOT Proper shipping name Not regulated Marine pollutant This product contains a chemical which is listed as a severe marine pollutant according to DOT. IATA Proper shipping name Not regulated IMDG Proper shipping name Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Does not comply IECSC Complies KECL Complies PICCS Complies AICS Complies _____________________________________________________________________________________________ Page 7 / 9 _____________________________________________________________________________________________ 31048 - Gumout Multi-System Tune-Up Revision Date 16-Mar-2021 Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard No Chronic Health Hazard No Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Naphthalene 91-20-3 100 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Naphthalene 91-20-3 100 lb 1 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ RQ 1 lb final RQ RQ 0.454 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical name New Jersey Massachusetts Pennsylvania 2-Ethylhexanol 104-76-7 - X X Naphthalene 91-20-3 X X X Diphenylamine 122-39-4 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable WHMIS Hazard Class B2 - Flammable liquid, D2B - Toxic materials, D2A - Very toxic materials 16. OTHER INFORMATION, INCLUDING DATE OF PREPARATION OF THE LAST REVISION _____________________________________________________________________________________________ Page 8 / 9 _____________________________________________________________________________________________ 31048 - Gumout Multi-System Tune-Up Revision Date 16-Mar-2021 NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 16-Mar-2021 Revision Note SDS sections updated Disclaimer Illinois Tool Works Inc. believes the information contained in this data sheet is accurate as of the date compiled. However, Illinois Tool Works Inc. makes no warranty, express or implied, as to the accuracy, reliability or completeness of the information. User is responsible for evaluating whether such information or this product is fit for a particular purpose and suitable for a particular use or application. The information in this data sheet may not be valid if this product is used in combination with other products or in processes for which it was not designed. Illinois Tool Works Inc. disclaims any liability for consequential or incidental damages of any kind, including lost profits, arising from the sale or use of this product. Ensure you have the most current version of this data sheet by contacting us or reviewing our web site. End of Safety Data Sheet NFPA Health hazards 2 Flammability 2 Instability 0 - HMIS Health hazards 2 Flammability 2 Physical hazards 1 Personal protection - B _____________________________________________________________________________________________ Page 9 / 9