SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 1 / 13 SECTION 1. IDENTIFICATION Product name : GOJO? SUPRO MAX? Cherry Hand Cleaner Manufacturer or supplier's details Company name of supplier : GOJO Industries, Inc. Address : One GOJO Plaza, Suite 500 Akron, Ohio 44311 Telephone : 1 (330) 255-6000 Emergency telephone number : CHEMTREC 1-800-424-9300 CHEMTREC +1-703-527-3887: Outside USA & CANADA Recommended use of the chemical and restrictions on use Recommended use : Skin-care Restrictions on use : This is a personal care or cosmetic product that is safe for consumers and other users under normal and reasonably foreseeable use. Cosmetics and consumer products, specifically defined by regulations around the world, are exempt from the requirement of an SDS for the consumer. While this material is not considered hazardous, this SDS contains valuable information critical to the safe handling and proper use of the product for industrial workplace conditions as well as unusual and unintended exposures such as large spills. This SDS should be retained and available for employees and other users of this product. For specific intended-use guidance, please refer to the information provided on the package or instruction sheet. SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture. GHS label elements Not a hazardous substance or mixture. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous components Chemical name CAS-No. Concentration (%) C11-15 Alkane/cycloalkane 64742-47-8 >= 10 - < 20 Sodium Laureth Sulfate 68585-34-2 >= 5 - < 10 Cocamidopropyl Betaine 61789-40-0 >= 1 - < 5 Titanium Dioxide (CI 77891) 13463-67-7 > 0.1 - < 1 SECTION 4. FIRST AID MEASURES SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 2 / 13 General advice : In the case of accident or if you feel unwell, seek medical advice immediately. When symptoms persist or in all cases of doubt seek medical advice. If inhaled : If inhaled, remove to fresh air. If symptoms persist, call a physician. In case of skin contact : Get medical attention if irritation develops and persists. In case of eye contact : Rinse thoroughly with plenty of water, also under the eyelids. If easy to do, remove contact lens, if worn. Get medical attention if irritation develops and persists. If swallowed : If swallowed, DO NOT induce vomiting. Rinse mouth with water. Obtain medical attention. Most important symptoms and effects, both acute and delayed : None known. Protection of first-aiders : First Aid responders should pay attention to self-protection and use the recommended protective clothing SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide. Unsuitable extinguishing media : None known. Hazardous combustion products : Carbon oxides Sulphur oxides Metal oxides Nitrogen oxides (NOx) Chlorine compounds Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Use water spray to cool unopened containers. Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Use personal protective equipment. Ensure adequate ventilation. Evacuate personnel to safe areas. Material can create slippery conditions. Environmental precautions : Discharge into the environment must be avoided. Prevent further leakage or spillage if safe to do so. Prevent spreading over a wide area (e.g. by containment or oil barriers). Retain and dispose of contaminated wash water. Local authorities should be advised if significant spillages cannot be contained. SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 3 / 13 Methods and materials for containment and cleaning up : Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Keep in suitable, closed containers for disposal. Clean contaminated floors and objects thoroughly while observing environmental regulations. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Do not swallow. Avoid contact with eyes. Keep container closed when not in use. Conditions for safe storage : Keep in properly labelled containers. Keep containers tightly closed in a dry, cool and well- ventilated place. Store in accordance with the particular national regulations. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis C11-15 Alkane/cycloalkane 64742-47-8 TWA (Mist) 5 mg/m3 OSHA Z-1 TWA 200 mg/m3 (as total hydrocarbon vapor) ACGIH TWA (Mist) 5 mg/m3 NIOSH REL ST (Mist) 10 mg/m3 NIOSH REL Titanium Dioxide (CI 77891) 13463-67-7 TWA (total dust) 15 mg/m3 OSHA Z-1 TWA 10 mg/m3 (Titanium dioxide) ACGIH Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Eye protection : No special protective equipment required. Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : No special protective equipment required. Protective measures : Choose body protection in relation to its type, to the concentration and amount of dangerous substances, and to the specific work-place. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 4 / 13 Appearance : liquid Colour : opaque, tan Odour : like fruit Odour Threshold : No data available pH : 4.5 - 8.0, (20 ?C) Melting point/freezing point : No data available Solidification / Setting point 5.5 ?C Initial boiling point and boiling range : 94 ?C Flash point : > 100 ?C Evaporation rate : No data available Flammability (solid, gas) : Not applicable Flammability (liquids) : No data available Upper explosion limit : No data available Lower explosion limit : No data available Vapour pressure : No data available Relative vapour density : No data available Density : 1.02 g/cm3 Solubility(ies) Water solubility : soluble Partition coefficient: n- octanol/water : Not applicable Auto-ignition temperature : No data available Thermal decomposition : The substance or mixture is not classified self-reactive. Viscosity Viscosity, kinematic : 12000 - 40000 mm2/s (20 ?C) Explosive properties : Not explosive Oxidizing properties : The substance or mixture is not classified as oxidizing. SECTION 10. STABILITY AND REACTIVITY Reactivity : Not classified as a reactivity hazard. Chemical stability : Stable under normal conditions. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : No hazardous decomposition products are known. SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 5 / 13 SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Eye contact Skin contact Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate : > 5,000 mg/kg Method: Calculation method Components: C11-15 Alkane/cycloalkane: Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 5.3 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Sodium Laureth Sulfate: Acute oral toxicity : LD50 (Rat): > 2,000 mg/kg Assessment: The substance or mixture has no acute oral toxicity Cocamidopropyl Betaine: Acute oral toxicity : LD50 : > 5,000 mg/kg Method: OECD Test Guideline 401 Remarks: Based on data from similar materials Acute dermal toxicity : LD50 (Rat): > 2,000 mg/kg Method: OECD Test Guideline 402 Assessment: The substance or mixture has no acute dermal toxicity Remarks: Based on data from similar materials Titanium Dioxide (CI 77891): Acute oral toxicity : LD50 (Rat): > 5,000 mg/kg Acute inhalation toxicity : LC50 (Rat): > 6.82 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: The substance or mixture has no acute inhalation toxicity SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 6 / 13 Skin corrosion/irritation Not classified based on available information. Product: Assessment: Not irritating when applied to human skin. Result: No skin irritation Components: C11-15 Alkane/cycloalkane: Assessment: Repeated exposure may cause skin dryness or cracking. Sodium Laureth Sulfate: Result: Skin irritation Cocamidopropyl Betaine: Result: Skin irritation Titanium Dioxide (CI 77891): Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Not classified based on available information. Components: C11-15 Alkane/cycloalkane: Species: Rabbit Result: No eye irritation Sodium Laureth Sulfate: Result: Eye irritation Remarks: Severe eye irritation Cocamidopropyl Betaine: Result: Eye irritation Remarks: Severe eye irritation Titanium Dioxide (CI 77891): Species: Rabbit Result: No eye irritation Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: C11-15 Alkane/cycloalkane: Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials Cocamidopropyl Betaine: SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 7 / 13 Test Type: Maximisation Test (GPMT) Exposure routes: Skin contact Species: Guinea pig Result: negative Remarks: Based on data from similar materials Titanium Dioxide (CI 77891): Test Type: Local lymph node assay (LLNA) Exposure routes: Skin contact Species: Mouse Result: negative Germ cell mutagenicity Not classified based on available information. Components: C11-15 Alkane/cycloalkane: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: Chromosomal aberration Test species: Rat Application Route: Intraperitoneal injection Result: negative Remarks: Based on data from similar materials Cocamidopropyl Betaine: Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Method: OECD Test Guideline 471 Result: negative Remarks: Based on data from similar materials Genotoxicity in vivo : Test Type: Mammalian erythrocyte micronucleus test (in vivo cytogenetic assay) Test species: Mouse Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Titanium Dioxide (CI 77891): Genotoxicity in vitro : Test Type: Bacterial reverse mutation assay (AMES) Result: negative Genotoxicity in vivo : Test Type: In vivo micronucleus test Test species: Mouse Result: negative Carcinogenicity Not classified based on available information. Components: Titanium Dioxide (CI 77891): Species: Rat Application Route: inhalation (dust/mist/fume) SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 8 / 13 Method: OECD Test Guideline 453 Result: positive Remarks: The mechanism or mode of action may not be releva nt in humans., The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard. IARC Group 2B: Possibly carcinogenic to humans Titanium Dioxide (CI 77891) 13463-67-7 OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Components: C11-15 Alkane/cycloalkane: Effects on fertility : Test Type: One-generation reproduction toxicity study Species: Rat Application Route: Ingestion Result: negative Remarks: Based on data from similar materials Effects on foetal development : Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Result: negative Cocamidopropyl Betaine: Effects on foetal development : Test Type: Embryo-foetal development Species: Rat Application Route: Ingestion Method: OECD Test Guideline 414 Result: negative Remarks: Based on data from similar materials STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Repeated dose toxicity Components: C11-15 Alkane/cycloalkane: Species: Rat NOAEL: > 10.4 mg/l Application Route: inhalation (vapour) Exposure time: 90 d Remarks: Based on data from similar materials SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 9 / 13 Cocamidopropyl Betaine: Species: Rat NOAEL: 250 mg/kg Application Route: Ingestion Exposure time: 90 d Method: OECD Test Guideline 408 Remarks: Based on data from similar materials Titanium Dioxide (CI 77891): Species: Rat NOAEL: 24,000 mg/kg Application Route: Ingestion Species: Rat NOAEL: 10 mg/m3 Application Route: inhalation (dust/mist/fume) Exposure time: 2 y Remarks: The substance is inextricably bound in the product and therefore does not contribute to a dust inhalation hazard. Aspiration toxicity Not classified based on available information. Components: C11-15 Alkane/cycloalkane: The substance or mixture is known to cause human aspiration toxicity hazards or has to be regarded as if it causes a human aspiration toxicity hazard. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: C11-15 Alkane/cycloalkane: Toxicity to fish : LL50 (Danio rerio (zebra fish)): > 250 mg/l Exposure time: 96 h Test substance: Water Accommodated Fraction Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EL50 (Acartia tonsa): > 3,193 mg/l Exposure time: 48 h Test substance: Water Accommodated Fraction Toxicity to algae : EL50 (Skeletonema costatum (marine diatom)): > 3,200 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction NOELR (Skeletonema costatum (marine diatom)): 993 mg/l Exposure time: 72 h Test substance: Water Accommodated Fraction Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOELR (Ceriodaphnia Dubia (water flea)): > 70 mg/l Exposure time: 8 d Test substance: Water Accommodated Fraction SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 10 / 13 Toxicity to bacteria : EC50: > 100 mg/l Exposure time: 3 h Cocamidopropyl Betaine: Toxicity to fish : LC50: > 1 - 10 mg/l Exposure time: 96 h Method: ISO 7346/2 Remarks: Based on data from similar materials Toxicity to bacteria : EC50: > 100 mg/l Method: OECD Test Guideline 209 Remarks: Based on data from similar materials Titanium Dioxide (CI 77891): Toxicity to fish : LC50 (Oncorhynchus mykiss (rainbow trout)): > 100 mg/l Exposure time: 96 h Method: OECD Test Guideline 203 Toxicity to daphnia and other aquatic invertebrates : EC50 (Daphnia magna (Water flea)): > 100 mg/l Exposure time: 48 h Toxicity to algae : EC50 (Skeletonema costatum (marine diatom)): > 10,000 mg/l Exposure time: 72 h Toxicity to bacteria : EC50: > 1,000 mg/l Exposure time: 3 h Method: OECD Test Guideline 209 Persistence and degradability Components: C11-15 Alkane/cycloalkane: Biodegradability : Result: Readily biodegradable. Biodegradation: 82 % Exposure time: 24 d Method: OECD Test Guideline 301F Sodium Laureth Sulfate: Biodegradability : Result: Readily biodegradable. Cocamidopropyl Betaine: Biodegradability : Result: Readily biodegradable. Biodegradation: > 60 % Exposure time: 28 d Method: OECD Test Guideline 301 Remarks: Based on data from similar materials Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 11 / 13 Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Contaminated packaging : Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. SECTION 14. TRANSPORT INFORMATION International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good National Regulations 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act SARA 311/312 Hazards : No SARA Hazards SARA 302 : No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Air Act This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 12 (40 CFR 61). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). This product does not contain any VOC exemptions listed under the U.S. Clean Air Act Section 450. Clean Water Act SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 12 / 13 This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 California Prop 65 This product does not require a warning label under California Proposition 65. The components of this product are reported in the following inventories: TSCA : On the inventory, or in compliance with the inventory AICS : On the inventory, or in compliance with the inventory DSL : All components of this product are on the Canadian DSL. ENCS : On the inventory, or in compliance with the inventory ISHL : On the inventory, or in compliance with the inventory KECI : On the inventory, or in compliance with the inventory PICCS : On the inventory, or in compliance with the inventory IECSC : On the inventory, or in compliance with the inventory NZIoC : On the inventory, or in compliance with the inventory Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Revision Date : 02/10/2020 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release Flammability H ea lth Instability 0 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 0 Special hazard. 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET GOJO? SUPRO MAX? Cherry Hand Cleaner Version 1.1 SDS Number: 400000000216 Revision Date: 02/10/2020 13 / 13 and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.