DIESEL LIFELINE Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 Date of issue: 04/16/2018 Revision date: 07/13/2021 Supersedes: 03/01/2019 Version: 1.2 07/13/2021 EN (English) Page 1 SECTION 1: Identification 1.1. Identification Product name : DIESEL LIFELINE Product code : 103092 and 103093 1.2. Relevant identified uses of the substance or mixture and uses advised against Recommended use : Diesel Fuel Additive 1.3. Details of the supplier of the safety data sheet Manufacturer R.B. Howes & Co., Inc. 3511 North Ohio Street Wichita, KS 67219 - USA T 401-294-5500, 1-800 GET HOWES (438-4693) Manufacturer R.B. Howes & Co., Inc. 35 Regan Road Brampton, ON L7A 1B2 - Canada T 401-294-5500, 1-800 GET HOWES (438-4693) 1.4. Emergency telephone number Emergency number : CHEMTREC 1 (800) 424-9300 / 703-527-3887 SECTION 2: Hazard identification 2.1. Classification of the substance or mixture GHS classification Flam. Liq. 4 Skin Irrit. 2 Carc. 2 Asp. Tox. 1 2.2. Label elements GHS labelling Hazard pictograms (GHS) : GHS07 GHS08 Signal word (GHS) : Danger Hazard statements (GHS) : Combustible liquid. Causes skin irritation. Suspected of causing cancer. May be fatal if swallowed and enters airways. Precautionary statements (GHS) : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, open flames, sparks. No smoking. Wash hands thoroughly after handling. Wear protective gloves/protective clothing/eye protection/face protection. If exposed or concerned: Get medical advice/attention. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. Store in a well-ventilated place. Keep cool. Store locked up. Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity Not applicable DIESEL LIFELINE Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 07/13/2021 EN (English) 2/7 SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % Organic Solvent Trade Secret 15 - 40 Petroleum Distillates 1 Trade Secret 10 - 30 Petroleum Distillates 2 Trade Secret 10 - 30 Petroleum Distillates 3 Trade Secret 10 - 30 Aromatic Hydrocarbon Trade Secret 1 - 5 *The exact chemical identity and/or exact percentages (concentration) of each ingredient has been held as confidential business information (CBI). Refer to Section 15 for additional information regarding this CBI claim. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : IF ON SKIN: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : IF SWALLOWED: Immediately call a POISON CENTER/doctor. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : May cause irritation to the respiratory tract. Symptoms/effects after skin contact : Causes skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/effects after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. Symptoms/effects after ingestion : May be fatal if swallowed and enters airways. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. May result in aspiration into the lungs, causing chemical pneumonia. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may be delayed. In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire. Unsuitable extinguishing media : Do not use water jet. 5.2. Special hazards arising from the substance or mixture Fire hazard : Combustible liquid. Products of combustion may include, and are not limited to: oxides of carbon. Reactivity : No dangerous reactions known under normal conditions of use. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Cool closed containers exposed to fire with water spray. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. Use special care to avoid static electric charges. Eliminate sources of ignition. Use only non-sparking tools. Spilled material may present a slipping hazard. 6.1.1. For non-emergency personnel No additional information available 6.1.2. For emergency responders No additional information available DIESEL LIFELINE Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 07/13/2021 EN (English) 3/7 6.2. Environmental precautions Prevent entry to sewers and public waters. 6.3. Methods and material for containment and cleaning up For containment : Absorb and/or contain spill with inert material (sand, vermiculite or other appropriate material), then place in suitable container. Do not flush into surface water or sewer system. Wear recommended personal protective equipment. Methods for cleaning up : Sweep or shovel spills into appropriate container for disposal. Provide ventilation. 6.4. Reference to other sections For further information refer to section 8: "Exposure controls/personal protection" SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Avoid contact with skin, eyes and clothing. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Handle in well-ventilated areas. Hygiene measures : Wash contaminated clothing before reuse. Wash hands, forearms and face thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store locked up. Store in a well-ventilated place. Keep cool. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Organic Solvent ACGIH ACGIH TWA (ppm) 100 ppm ACGIH ACGIH STEL (ppm) 150 ppm OSHA OSHA PEL (TWA) (mg/m?) 600 mg/m? OSHA OSHA PEL (TWA) (ppm) 100 ppm OSHA Limit value category (OSHA) prevent or reduce skin absorption IDLH US IDLH (ppm) 600 ppm NIOSH NIOSH REL (TWA) (mg/m?) 600 mg/m? NIOSH NIOSH REL (TWA) (ppm) 100 ppm NIOSH NIOSH REL (STEL) (mg/m?) 900 mg/m? NIOSH NIOSH REL (STEL) (ppm) 150 ppm NIOSH US-NIOSH chemical category Potential for dermal absorption Petroleum Distillates 1 ACGIH ACGIH TWA (mg/m?) 200 mg/m? (application restricted to conditions in which there are negligible aerosol exposures-total hydrocarbon vapor) NIOSH NIOSH REL (TWA) (mg/m?) 100 mg/m? Petroleum Distillates 2 Not applicable Petroleum Distillates 3 Not applicable Aromatic Hydrocarbon ACGIH ACGIH TWA (ppm) 10 ppm OSHA OSHA PEL (TWA) (mg/m?) 50 mg/m? OSHA OSHA PEL (TWA) (ppm) 10 ppm DIESEL LIFELINE Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 07/13/2021 EN (English) 4/7 Aromatic Hydrocarbon IDLH US IDLH (ppm) 250 ppm NIOSH NIOSH REL (TWA) (mg/m?) 50 mg/m? NIOSH NIOSH REL (TWA) (ppm) 10 ppm NIOSH NIOSH REL (STEL) (mg/m?) 75 mg/m? NIOSH NIOSH REL (STEL) (ppm) 15 ppm 8.2. Exposure controls Appropriate engineering controls : Ensure good ventilation of the work station. Hand protection : Wear suitable gloves resistant to chemical penetration. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Avoid release to the environment. Other information : Handle in accordance with good industrial hygiene and safety procedures. Do not eat, drink or smoke when using this product. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : No data available Colour : Clear Odour : Distinctive Odour threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : 179.4 ?C IBP (354.92?F), FBP 294?C (561.2?F) ASTM D86 Flash point : ? 66 ?C (151 ?F) [Closed cup] Relative evaporation rate (butylacetate=1) : No data available Flammability (solid, gas) : Combustible liquid Vapour pressure : No data available Relative vapour density at 20 ?C : No data available Relative density : 26.88 @ 60?F ASTM D4052 Solubility : Water: insoluble in water Partition coefficient n-octanol/water : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : 1.805 cSt @ 40?C (104?F) Viscosity, dynamic : No data available Explosive limits : No data available Explosive properties : No data available Oxidising properties : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reactions known under normal conditions of use. 10.2. Chemical stability May form flammable/explosive vapour-air mixture. Stable under normal conditions. DIESEL LIFELINE Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 07/13/2021 EN (English) 5/7 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Heat. Sources of ignition. Incompatible materials. 10.5. Incompatible materials Strong oxidizers. 10.6. Hazardous decomposition products May release flammable gases. May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified. Organic Solvent LD50 oral rat 5.35 g/kg LD50 dermal rabbit 9500 mg/kg Petroleum Distillates 1 LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat > 5.28 mg/l/4h Petroleum Distillates 2 LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat 2180 mg/m? (Exposure time: 4 h) Petroleum Distillates 3 LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2 ml/kg LC50 inhalation rat > 590 mg/m? (Exposure time: 4 h) Aromatic Hydrocarbon LD50 oral rat 1110 mg/kg LD50 dermal rabbit 1120 mg/kg LC50 inhalation rat > 340 mg/m? (Exposure time: 1 h) Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Not classified. Respiratory or skin sensitisation : Not classified. Germ cell mutagenicity : Not classified. Carcinogenicity : Suspected of causing cancer. Aromatic Hydrocarbon IARC group 2B - Possibly carcinogenic to humans National Toxicology Program (NTP) Status Evidence of Carcinogenicity, Reasonably anticipated to be Human Carcinogen In OSHA Hazard Communication Carcinogen list Yes Reproductive toxicity : Not classified. STOT-single exposure : Not classified. STOT-repeated exposure : Not classified. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/effects after inhalation : May cause irritation to the respiratory tract. Symptoms/effects after skin contact : Causes skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/effects after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with possible redness and swelling. DIESEL LIFELINE Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 07/13/2021 EN (English) 6/7 Symptoms/effects after ingestion : May be fatal if swallowed and enters airways. May cause gastrointestinal irritation, nausea, vomiting and diarrhea. May result in aspiration into the lungs, causing chemical pneumonia. Other information : Likely routes of exposure: ingestion, inhalation, skin and eye. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. Organic Solvent LC50 fish 1 > 10000 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 Daphnia 1 1919 mg/l (Exposure time: 48 h - Species: Daphnia magna) Petroleum Distillates 2 LC50 fish 1 > 5000 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) EC50 Daphnia 1 > 1000 mg/l (Exposure time: 48 h - Species: Daphnia magna) Petroleum Distillates 3 LC50 fish 1 19 mg/l (Exposure time: 96 h - Species: Pimephales promelas [static]) EC50 Daphnia 1 0.95 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC50 fish 2 2.34 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss) Aromatic Hydrocarbon LC50 fish 1 5.74 - 6.44 mg/l (Exposure time: 96 h - Species: Pimephales promelas [flow-through]) EC50 Daphnia 1 2.16 mg/l (Exposure time: 48 h - Species: Daphnia magna) LC50 fish 2 1.6 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through]) EC50 Daphnia 2 1.96 mg/l (Exposure time: 48 h - Species: Daphnia magna [Flow through]) 12.2. Persistence and degradability DIESEL LIFELINE Persistence and degradability Not established. 12.3. Bioaccumulative potential DIESEL LIFELINE Bioaccumulative potential Not established. Organic Solvent Partition coefficient n-octanol/water -0.064 (at 20 ?C) Petroleum Distillates 3 BCF fish 1 61 - 159 Partition coefficient n-octanol/water 2.9 - 6.1 Aromatic Hydrocarbon BCF fish 1 30 - 430 Partition coefficient n-octanol/water 3.6 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Aromatic Hydrocarbon 1990 Hazardous Air Pollutant (Clean Air Act) Yes Other information : No other effects known. SECTION 13: Disposal considerations 13.1. Waste treatment methods Product/Packaging disposal recommendations : Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. Additional information : Handle empty containers with care because residual vapours are flammable. DIESEL LIFELINE Safety Data Sheet According to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012 and the Hazardous Products Regulations (HPR) WHMIS 2015 07/13/2021 EN (English) 7/7 SECTION 14: Transport information Department of Transportation (DOT) / Transportation of Dangerous Goods (TDG) In accordance with DOT / TDG UN-No.(DOT / TDG) : UN1268 Proper Shipping Name (DOT / TDG) : Petroleum distillates, n.o.s. Class (DOT / TDG) : Combustible liquid Packing group (DOT / TDG) : III Transport by sea This product is currently not packaged to comply with IMDG regulations. It is not intended to be shipped by sea. Transport by air This product is currently not packaged to comply with IATA regulations. It is not intended to be shipped by air. SECTION 15: Regulatory information 15.1. Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory. Aromatic Hydrocarbon Subject to reporting requirements of United States SARA Section 313 Listed on EPA Hazardous Air Pollutant (HAPS) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a final TSCA section 4 test rule. CERCLA RQ 100 lb All components of this product are listed, or excluded from listing, on the Canadian DSL (Domestic Substances List) and NDSL (Non-Domestic Substances List) inventories. Canada WHMIS Confidential Business Information (CBI): HMIRA registry number XXXXXXXX. The date of filing is YYYY-MM-DD. 15.2. International regulations No additional information available 15.3. US State regulations WARNING: Cancer - www.P65Warnings.ca.gov. SECTION 16: Other information Date of issue : 04/16/2018 Revision date : 07/13/2021 Other information : None. Prepared by : Nexreg Compliance Inc. www.Nexreg.com NFPA health hazard : 2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury. NFPA fire hazard : 2 - Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. NFPA reactivity : 0 - Material that in themselves are normally stable, even under fire conditions. Indication of changes: HMIRA registry number. HMIRA submission date. Physical and chemical properties. 07/13/2021? Logo (Howes) SDS HazCom 2012 - WHMIS 2015 (NexReg) - Section 15 Disclaimer: We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user?s responsibility to satisfy oneself as to the suitability and completeness of this information for the user?s own particular use.