D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 1 of 12 Safety Data Sheet Copyright,2019Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 31-5448-1 Version Number: 2.02 Issue Date: 01/08/19 Supercedes Date: 08/31/17 SECTION 1: Identification 1.1. Product identifier D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 Product Identification Numbers 14-1000-0168-5, 14-1000-0169-3, 14-1000-0170-1 7100062614, 7100178554, 7100178555 1.2. Recommended use and restrictions on use Recommended use Automotive 1.3. Supplier?s details MANUFACTURER: Meguiar's, Inc. DIVISION: Meguiar's ADDRESS: 17991 Mitchell South, Irvine, CA 92614, USA Telephone: 949-752-8000 (Fax: 949-752-5784) 1.4. Emergency telephone number CHEMTREC 1-800-424-9300 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Corrosive to metal: Category 1. Serious Eye Damage/Irritation: Category 1. Skin Corrosion/Irritation: Category 1C. Specific Target Organ Toxicity (single exposure): Category 3. 2.2. Label elements Signal word Danger D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 2 of 12 Symbols Corrosion | Exclamation mark | Pictograms Hazard Statements May be corrosive to metals. Causes severe skin burns and eye damage. May cause respiratory irritation. Precautionary Statements General: Keep out of reach of children. Prevention: Keep only in original container. Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves, protective clothing, and eye/face protection. Wash thoroughly after handling. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Call a POISON CENTER or doctor/physician if you feel unwell. Absorb spillage to prevent material damage. Storage: Store in a corrosive resistant container with a resistant inner liner. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. 2.3. Hazards not otherwise classified May cause chemical gastrointestinal burns. May cause chemical respiratory tract burns. D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 3 of 12 SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Water 7732-18-5 75 - 95 Trade Secret * 2-Butoxyethanol 111-76-2 1 - 5 Trade Secret * Mixed Alkyl Sulfates 68439-57-6 1 - 5 Trade Secret * Sodium Metasilicate 6834-92-0 1 - 5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. Get immediate medical attention. Skin Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contaminated clothing. Get immediate medical attention. Wash clothing before reuse. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. Do not induce vomiting. Get immediate medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Irritant Vapors or Gases During Combustion 5.3. Special protective actions for fire-fighters No special protective actions for fire-fighters are anticipated. D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 4 of 12 Ingredient C.A.S. No. Agency Limit type Additional Comments 2-Butoxyethanol 111-76-2 ACGIH TWA:20 ppm A3: Confirmed animal carcin. 2-Butoxyethanol 111-76-2 OSHA TWA:240 mg/m3(50 ppm) SKIN SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. For large spills, if necessary, get assistance from professional spill clean up team. For small spills, carefully neutralize spill by adding appropriate dilute acid such as vinegar. Work slowly to avoid boiling or spattering. Continue to add neutralizing agent until reaction stops. Let cool before collecting. Or use a commercially available caustic (alkaline or basic) spill clean-up kit. Follow kit directions exactly. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a metal container approved for use in transportation by appropriate authorities. The container must be lined with polyethylene plastic or contain a plastic drum liner made of polyethylene. Clean up residue with water. Cover, but do not seal for 48 hours. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Keep away from reactive metals (eg. Aluminum, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Store in a corrosive resistant container with a resistant inner liner. Store away from acids. Store away from oxidizing agents. Store away from areas where product may come into contact with food or pharmaceuticals. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 5 of 12 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Odor, Color, Grade: Sweet odor; Green liquid Odor threshold No Data Available pH 13 Melting point Not Applicable Boiling Point 212 ?F Flash Point Flash point > 93 ?C (200 ?F) [Test Method:Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure No Data Available Vapor Density No Data Available Density 1 g/cm3 Specific Gravity 1 [Ref Std:WATER=1] Solubility in Water Complete Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature Not Applicable Decomposition Temperature No Data Available D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 6 of 12 Viscosity No Data Available Molecular weight No Data Available Volatile Organic Compounds 2.5 % weight [Test Method:calculated per CARB title 2] [Details:VOC of concentrate] Volatile Organic Compounds 27 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 93.2 % weight [Test Method:Estimated] VOC Less H2O & Exempt Solvents 290 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Corrosion: Signs/symptoms may include nasal discharge, severe nose and throat pain, chest tightness and pain, coughing up blood, wheezing, and breathlessness, possibly progressing to respiratory failure. D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 7 of 12 Skin Contact: Corrosive (Skin Burns): Signs/symptoms may include localized redness, swelling, itching, intense pain, blistering, ulceration, and tissue destruction. Eye Contact: Corrosive (Eye Burns): Signs/symptoms may include cloudy appearance of the cornea, chemical burns, severe pain, tearing, ulcerations, significantly impaired vision or complete loss of vision. Ingestion: Gastrointestinal Corrosion: Signs/symptoms may include severe mouth, throat and abdominal pain; nausea; vomiting; and diarrhea; blood in the feces and/or vomitus may also be seen. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Sodium Metasilicate Dermal Rabbit LD50 > 4,640 mg/kg Sodium Metasilicate Ingestion Rat LD50 500 mg/kg Mixed Alkyl Sulfates Dermal Rat LD50 > 2,000 mg/kg Mixed Alkyl Sulfates Ingestion Rat LD50 578 mg/kg 2-Butoxyethanol Dermal Guinea pig LD50 > 2,000 mg/kg 2-Butoxyethanol Inhalation- Vapor (4 hours) Guinea pig LC50 > 2.6 mg/l 2-Butoxyethanol Ingestion Guinea pig LD50 1,414 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Overall product In vitro data Corrosive Sodium Metasilicate Rabbit Corrosive Mixed Alkyl Sulfates Rabbit Mild irritant 2-Butoxyethanol Rabbit Irritant Serious Eye Damage/Irritation Name Species Value Overall product similar health hazards Corrosive Sodium Metasilicate Rabbit Corrosive Mixed Alkyl Sulfates Rabbit Corrosive 2-Butoxyethanol Rabbit Severe irritant Skin Sensitization Name Species Value Sodium Metasilicate Mouse Not classified Mixed Alkyl Sulfates Guinea pig Not classified 2-Butoxyethanol Guinea pig Not classified Respiratory Sensitization D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 8 of 12 Name Route Target Organ(s) Value Species Test Result Exposure Duration Overall product Inhalation respiratory irritation May cause respiratory irritation similar health hazards Irritation Positive Sodium Metasilicate Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available 2-Butoxyethanol Dermal endocrine system Not classified Rabbit NOAEL 902 mg/kg 6 hours 2-Butoxyethanol Dermal liver Not classified Rabbit LOAEL 72 mg/kg not available 2-Butoxyethanol Dermal kidney and/or bladder Not classified Rabbit LOAEL 451 mg/kg 6 hours 2-Butoxyethanol Dermal blood Not classified Multiple animal species NOAEL Not available 2-Butoxyethanol Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Sodium Metasilicate In Vitro Not mutagenic Sodium Metasilicate In vivo Not mutagenic Mixed Alkyl Sulfates In Vitro Not mutagenic 2-Butoxyethanol In Vitro Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Mixed Alkyl Sulfates Dermal Rat Not carcinogenic Mixed Alkyl Sulfates Ingestion Rat Not carcinogenic 2-Butoxyethanol Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Sodium Metasilicate Ingestion Not classified for development Mouse NOAEL 200 mg/kg/day during gestation Mixed Alkyl Sulfates Ingestion Not classified for female reproduction Rat NOAEL 871 mg/kg 2 generation Mixed Alkyl Sulfates Ingestion Not classified for male reproduction Rat NOAEL 891 mg/kg 2 generation Mixed Alkyl Sulfates Ingestion Not classified for development Rabbit NOAEL 600 mg/kg during organogenesi s 2-Butoxyethanol Dermal Not classified for development Rat NOAEL 1,760 mg/kg/day during gestation 2-Butoxyethanol Ingestion Not classified for development Rat NOAEL 100 mg/kg/day during organogenesi s 2-Butoxyethanol Inhalation Not classified for development Multiple animal species NOAEL 0.48 mg/l during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 9 of 12 2-Butoxyethanol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human NOAEL Not available 2-Butoxyethanol Inhalation blood Not classified Multiple animal species NOAEL Not available 2-Butoxyethanol Ingestion central nervous system depression May cause drowsiness or dizziness Professional judgement NOAEL Not available 2-Butoxyethanol Ingestion blood Not classified Multiple animal species NOAEL Not available 2-Butoxyethanol Ingestion kidney and/or bladder Not classified Human NOAEL Not available poisoning and/or abuse Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Sodium Metasilicate Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Dog LOAEL 2,400 mg/kg/day 4 weeks Sodium Metasilicate Ingestion endocrine system | blood Not classified Rat NOAEL 804 mg/kg/day 3 months Sodium Metasilicate Ingestion heart | liver Not classified Rat NOAEL 1,259 mg/kg/day 8 weeks Mixed Alkyl Sulfates Ingestion liver Not classified Rat NOAEL 500 mg/kg/day 6 months Mixed Alkyl Sulfates Ingestion kidney and/or bladder Not classified Rat NOAEL 500 mg/kg 6 months 2-Butoxyethanol Dermal blood Not classified Multiple animal species NOAEL Not available not available 2-Butoxyethanol Dermal endocrine system Not classified Rabbit NOAEL 150 mg/kg/day 90 days 2-Butoxyethanol Inhalation liver Not classified Rat NOAEL 2.4 mg/l 14 weeks 2-Butoxyethanol Inhalation kidney and/or bladder Not classified Rat NOAEL 0.15 mg/l 14 weeks 2-Butoxyethanol Inhalation blood Not classified Rat LOAEL 0.15 mg/l 6 months 2-Butoxyethanol Inhalation endocrine system Not classified Dog LOAEL 1.9 mg/l 8 days 2-Butoxyethanol Ingestion blood Not classified Rat LOAEL 69 mg/kg/day 13 weeks 2-Butoxyethanol Ingestion kidney and/or bladder Not classified Multiple animal species NOAEL Not available not available Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 10 of 12 Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information DOTG- Department of Transportation ? Ground (United States): 1 Gallon: LIMITED QUANTITY 5/55 Gallon: UN3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (SODIUM METASILICATE), 8, III DOTW-Department of Transportation ? Vessel (United States): 1 Gallon: UN3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (SODIUM METASILICATE), 8, III, LIMITED QUANTITY 5/55 Gallon: UN3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (SODIUM METASILICATE), 8, III IATA-International Air Transport Association (United Nations) : 1/5 Gallon: UN3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (CONTAINS SODIUM METASILICATE), 8, III 55 Gallon: Package Size Exceeds IATA Quantity Limitations IMO ? International Maritime Organization (United Nations): 1 Gallon: UN3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (CONTAINS SODIUM METASILICATE), 8, III, LIMITED QUANTITY 5/55 Gallon: UN3266, CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S. (CONTAINS SODIUM METASILICATE), 8, III Please contact the emergency numbers listed on the first page of the SDS for Transportation Information for this material. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact manufacturer for more information EPCRA 311/312 Hazard Classifications: Physical Hazards Corrosive to metal Health Hazards Hazard Not Otherwise Classified (HNOC) Serious eye damage or eye irritation Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure) D101, Detailer All Purpose Cleaner (22-135B): D10101, D10105 01/08/19 Page 11 of 12 Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt 2-Butoxyethanol (GLYCOL ETHERS) 111-76-2 1 - 5 15.2. State Regulations Contact manufacturer for more information 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact manufacturer for more information 15.4. International Regulations Contact manufacturer for more information This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 3 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 31-5448-1 Version Number: 2.02 Issue Date: 01/08/19 Supercedes Date: 08/31/17 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. Meguiar's, Inc. MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the Meguiar's, Inc. product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a Meguiar's, Inc. product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the Meguiar's, Inc. product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Meguiar's, Inc. provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, Meguiar's, Inc. makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from Meguiar's, Inc. Meguiar's, Inc. USA SDSs are available at www.Meguiars.com