G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 1 of 11 Safety Data Sheet Copyright,2017Meguiar's, Inc. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing Meguiar's, Inc. products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from Meguiar's, Inc., and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 32-6368-8 Version Number: 4.04 Issue Date: 09/06/17 Supercedes Date: 04/13/17 SECTION 1: Identification 1.1. Product identifier G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 Product Identification Numbers LB-1100-1471-4, 14-1000-9049-8 1.2. Recommended use and restrictions on use Recommended use Automotive 1.3. Supplier?s details MANUFACTURER: Meguiar's, Inc. DIVISION: Meguiar's ADDRESS: 17991 Mitchell South, Irvine, CA 92614, USA Telephone: 949-752-8000 (Fax: 949-752-5784) 1.4. Emergency telephone number CHEMTREC 1-800-424-9300 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Aerosol: Category 1. Gas Under Pressure: Liquefied gas. Skin Sensitizer: Category 1. Simple Asphyxiant. Specific Target Organ Toxicity (single exposure): Category 3. G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 2 of 11 2.2. Label elements Signal word Danger Symbols Flame | Gas cylinder | Exclamation mark | Pictograms Hazard Statements Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May cause an allergic skin reaction. May cause drowsiness or dizziness. May displace oxygen and cause rapid suffocation. Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 3 of 11 2.3. Hazards not otherwise classified SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Propellant 29118-24-9 50 - 90 Trade Secret * Ethyl Alcohol 64-17-5 10 - 30 Trade Secret * Fragrance Oils Trade Secret* 0.5 - 1.5 Trade Secret * Odor Eliminator Trade Secret* < 0.5 Trade Secret * Any remaining components do not contribute to the hazards of this material. *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Flush eyes with large amounts of water. If signs/symptoms persist, get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed See Section 11.1. Information on toxicological effects. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media Use a fire fighting agent suitable for the surrounding fire. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Fluoride During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. When fire fighting conditions are severe and total thermal decomposition of the product is G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 4 of 11 possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up If possible, seal leaking container. Place leaking containers in a well-ventilated area, preferably an operating exhaust hood, or if necessary outdoors on an impermeable surface until appropriate packaging for the leaking container or its contents is available. Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not breathe thermal decomposition products. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not pierce or burn, even after use. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed. Protect from sunlight. Do not expose to temperatures exceeding 50C/122F. Store away from heat. Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments 1-Propene, 1,3,3,3-tetrafluoro- 29118-24-9 AIHA TWA:800 ppm Ethyl Alcohol 64-17-5 OSHA TWA:1900 mg/m3(1000 ppm) Ethyl Alcohol 64-17-5 ACGIH STEL:1000 ppm A3: Confirmed animal carcin. Fragrance Oils Trade Secret Manufacturer determined TWA:100 ppm;STEL:150 ppm SKIN G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 5 of 11 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide appropriate local exhaust when product is heated. Do not remain in area where available oxygen may be reduced. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Full Face Shield Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties General Physical Form: Liquid Specific Physical Form: Aerosol Odor, Color, Grade: Sweet lemon odor Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point >=-13 ?F G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 6 of 11 Flash Point >=58 ?F Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) No Data Available Flammable Limits(UEL) No Data Available Vapor Pressure No Data Available Vapor Density No Data Available Density 0.815 g/ml Specific Gravity 0.815 [Ref Std:WATER=1] Solubility In Water No Data Available Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0 % weight Molecular weight No Data Available Volatile Organic Compounds 26.6 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 225 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 99.5 % weight [Test Method:Estimated] VOC Less H2O & Exempt Solvents 342 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 7 of 11 relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Intentional concentration and inhalation may be harmful or fatal. Simple Asphyxiation: Signs/symptoms may include increased heart rate, rapid respirations, drowsiness, headache, incoordination, altered judgement, nausea, vomiting, lethargy, seizures, coma, and may be fatal. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Sprayed material may cause eye irritation. Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Central Nervous System (CNS) Depression: Signs/symptoms may include headache, dizziness, drowsiness, incoordination, nausea, slowed reaction time, slurred speech, giddiness, and unconsciousness. Carcinogenicity: Ingredient CAS No. Class Description Regulation Generic: ALCOHOLIC BEVERAGES 64-17-5 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Generic: ALCOHOLIC BEVERAGES 64-17-5 Known human carcinogen National Toxicology Program Carcinogens Additional Information: This product contains ethanol. Alcoholic beverages and ethanol in alcoholic beverages have been classified by the International Agency for Research on Cancer as carcinogenic to humans. There are also data associating human consumption of alcoholic beverages with developmental toxicity and liver toxicity. Exposure to ethanol during the foreseeable use of this product is not expected to cause cancer, developmental toxicity, or liver toxicity. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Ethyl Alcohol Dermal Rabbit LD50 > 15,800 mg/kg G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 8 of 11 Ethyl Alcohol Inhalation-Vapor (4 hours) Rat LC50 124.7 mg/l Ethyl Alcohol Ingestion Rat LD50 17,800 mg/kg Fragrance Oils Dermal Rat LD50 > 2,000 mg/kg Fragrance Oils Inhalation-Dust/Mist (4 hours) Rat LC50 > 5.7 mg/l Fragrance Oils Ingestion Rat LD50 > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Ethyl Alcohol Rabbit No significant irritation Fragrance Oils Rabbit No significant irritation Serious Eye Damage/Irritation Name Species Value Ethyl Alcohol Rabbit Severe irritant Fragrance Oils Rabbit No significant irritation Skin Sensitization Name Species Value Ethyl Alcohol Human Not classified Fragrance Oils Guinea pig Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Ethyl Alcohol In Vitro Some positive data exist, but the data are not sufficient for classification Ethyl Alcohol In vivo Some positive data exist, but the data are not sufficient for classification Fragrance Oils In Vitro Not mutagenic Fragrance Oils In vivo Not mutagenic Carcinogenicity Name Route Species Value Ethyl Alcohol Ingestion Multiple animal species Some positive data exist, but the data are not sufficient for classification Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Ethyl Alcohol Inhalation Not classified for development Rat NOAEL 38 mg/l during gestation Ethyl Alcohol Ingestion Not classified for development Rat NOAEL 5,200 mg/kg/day premating & during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Ethyl Alcohol Inhalation central nervous system depression May cause drowsiness or dizziness Human LOAEL 2.6 mg/l 30 minutes Ethyl Alcohol Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Human LOAEL 9.4 mg/l not available Ethyl Alcohol Ingestion central nervous system depression May cause drowsiness or dizziness Multiple animal species NOAEL not available G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 9 of 11 Ethyl Alcohol Ingestion kidney and/or bladder Not classified Dog NOAEL 3,000 mg/kg Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Ethyl Alcohol Inhalation liver Some positive data exist, but the data are not sufficient for classification Rabbit LOAEL 124 mg/l 365 days Ethyl Alcohol Inhalation hematopoietic system | immune system Not classified Rat NOAEL 25 mg/l 14 days Ethyl Alcohol Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat LOAEL 8,000 mg/kg/day 4 months Ethyl Alcohol Ingestion kidney and/or bladder Not classified Dog NOAEL 3,000 mg/kg/day 7 days Fragrance Oils Ingestion liver | heart | endocrine system | hematopoietic system | kidney and/or bladder Not classified Rat NOAEL 1,000 mg/kg/day 4 weeks Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Incinerate in a permitted waste incineration facility. Facility must be capable of handling aerosol cans. Combustion products will include HF. Facility must be capable of handling halogenated materials. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information DOTG: LIMITED QUANTITY G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 10 of 11 DOTW: UN 1950, AEROSOLS, 2.1, LIMITED QUANTITY IATA: UN1950, AEROSOLS, FLAMMABLE, 2.1 IMO: UN 1950, AEROSOLS, 2.1, LIMITED QUANTITY Please contact the emergency numbers listed on the first page of the SDS for Transportation Information for this material. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact manufacturer for more information 311/312 Hazard Categories: Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No EPCRA 311/312 Hazard Classifications (effective January 1, 2018): Physical Hazards Flammable (gases, aerosols, liquids, or solids) Gas under pressure Health Hazards Respiratory or Skin Sensitization Simple Asphyxiant Specific target organ toxicity (single or repeated exposure) 15.2. State Regulations Contact manufacturer for more information 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. Contact manufacturer for more information 15.4. International Regulations Contact manufacturer for more information This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 4 Instability: 0 Special Hazards: None G166, Car Odor Aerosol (27-61B) - Sweet Summer Breeze (13111302): G16602 09/06/17 __________________________________________________________________________________________ Page 11 of 11 National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 32-6368-8 Version Number: 4.04 Issue Date: 09/06/17 Supersedes Date: 04/13/17 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. Meguiar's, Inc. MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the Meguiar's, Inc. product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a Meguiar's, Inc. product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the Meguiar's, Inc. product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. Meguiar's, Inc. provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, Meguiar's, Inc. makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from Meguiar's, Inc. Meguiar's, Inc. USA SDSs are available at www.Meguiars.com