SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 1 / 15 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name : Valvoline? VR1 Racing? SAE 30 Racing Oil Product code : 822401 Details of the supplier of the safety data sheet Valvoline LLC 100 Valvoline Way Lexington, KY 40509 United States of America (USA) 1-800-TEAMVAL (1-800-832-6825) This email address is being protected from spambots. You need JavaScript enabled to view it. Emergency telephone number 1-800-VALVOLINE (1-800-825-8654) Regulatory Information Number 1-800-TEAMVAL (1-800-832-6825) Product Information 1-800-TEAMVAL (1-800-832-6825) SECTION 2. HAZARDS IDENTIFICATION GHS Classification Eye irritation : Category 2A GHS label elements Hazard pictograms : Signal Word : Warning Hazard Statements : Causes serious eye irritation. Precautionary Statements : Prevention: Wear eye protection/ face protection. Wash skin thoroughly after handling. Response: If eye irritation persists: Get medical advice/ attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 2 / 15 Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Classification Concentration (%) DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 Not a hazardous substance or mixture. >=80.00 - < 90.00 Zinc O,O,O',O'-tetrakis(1,3- dimethylbutyl) bis(phosphorodithioate 2215-35-2 Skin Irrit. 2; H315 Eye Dam. 1; H318 >=1.50 - < 5.00 Actual concentration is withheld as a trade secret SECTION 4. FIRST AID MEASURES General advice : Do not leave the victim unattended. Show this safety data sheet to the doctor in attendance. Move out of dangerous area. If inhaled : If breathed in, move person into fresh air. If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Wash contaminated clothing before re-use. If on skin, rinse well with water. Remove contaminated clothing. If irritation develops, get medical attention. In case of eye contact : Protect unharmed eye. Remove contact lenses. Immediately flush eye(s) with plenty of water. If swallowed : Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Causes serious eye irritation. No symptoms known or expected. SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 3 / 15 Notes to physician : No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : carbon dioxide and carbon monoxide Specific extinguishing methods : Product is compatible with standard fire-fighting agents. Further information : Standard procedure for chemical fires. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Use personal protective equipment. Environmental precautions : Prevent further leakage or spillage if safe to do so. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. Other information : Comply with all applicable federal, state, and local regulations. SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 4 / 15 SECTION 7. HANDLING AND STORAGE Advice on safe handling : Dispose of rinse water in accordance with local and national regulations. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Avoid contact with skin and eyes. Container hazardous when empty. Do not smoke. Do not breathe vapours/dust. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC 64742-54-7 TWA 5 mg/m3 Mist OSHA Z-1 TWA 5 mg/m3 Inhalable particulate matter ACGIH TWA 5 mg/m3 Mist OSHA P0 TWA 5 mg/m3 Mist NIOSH REL ST 10 mg/m3 Mist NIOSH REL PEL 5 mg/m3 particulate CAL PEL Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Respiratory protection : No personal respiratory protective equipment normally required. Hand protection Remarks : The suitability for a specific workplace should be discussed SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 5 / 15 with the producers of the protective gloves. Eye protection : Wear chemical splash goggles when there is the potential for exposure of the eyes to liquid, vapor or mist. Skin and body protection : Wear resistant gloves (consult your safety equipment supplier). Choose body protection according to the amount and concentration of the dangerous substance at the work place. Safety shoes Impervious clothing Wear as appropriate: Hygiene measures : When using do not smoke. When using do not eat or drink. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Odour : No data available Odour Threshold : No data available pH : No data available Melting point/freezing point : No data available Boiling point/boiling range : No data available Flash point : 394 - 480 ?F / 201 - 249 ?C Method: Cleveland open cup Evaporation rate : No data available Flammability (solid, gas) : No data available Self-ignition : No data available Upper explosion limit / Upper flammability limit : 6 %(V) GLP: Calculated Explosive Limit Lower explosion limit / Lower flammability limit : 1 %(V) GLP: Calculated Explosive Limit SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 6 / 15 Vapour pressure : 0.0133333 hPa (70.00 ?F / 21.11 ?C) Calculated Vapor Pressure Relative vapour density : No data available Relative density : No data available Density : 0.8816 g/cm3 (60.01 ?F / 15.56 ?C) Solubility(ies) Water solubility : No data available Solubility in other solvents : No data available Partition coefficient: n- octanol/water : No data available Decomposition temperature : No data available Viscosity Viscosity, dynamic : No data available Viscosity, kinematic : No data available Oxidizing properties : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : Stable under recommended storage conditions. Possibility of hazardous reactions : Product will not undergo hazardous polymerization. Conditions to avoid : None known. Incompatible materials : Strong oxidizing agents Acids Hazardous decomposition products No hazardous decomposition products are known. SECTION 11. TOXICOLOGICAL INFORMATION SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 7 / 15 Information on likely routes of exposure Inhalation Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Acute oral toxicity : LD50 (Rat): > 15 g/kg Acute dermal toxicity : LD50 (Rabbit): > 5 g/kg Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate: Acute oral toxicity : LD50 (Rat): 2,230 mg/kg GLP: no Acute inhalation toxicity : LC50 (Rat): > 2.3 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: Not classified as acutely toxic by inhalation under GHS. Remarks: Information given is based on data obtained from similar substances. Acute dermal toxicity : LD50 (Rabbit): > 3,160 mg/kg Method: OECD Test Guideline 402 Assessment: Not classified as acutely toxic by dermal absorption under GHS. Skin corrosion/irritation Not classified based on available information. Product: Remarks : May cause skin irritation in susceptible persons. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Assessment : Slight, transient irritation Result : Slight, transient irritation Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate: Species : Rabbit Method : OECD Test Guideline 404 Result : Irritating to skin. GLP : yes SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 8 / 15 Serious eye damage/eye irritation Causes serious eye irritation. Product: Remarks : Causes serious eye irritation. Vapours may cause irritation to the eyes, respiratory system and the skin. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Result : No eye irritation Assessment : No eye irritation Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate: Result : Corrosive Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Components: Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate: Species : Guinea pig Assessment : Did not cause sensitisation on laboratory animals. Method : OECD Test Guideline 406 Result : Did not cause sensitisation on laboratory animals. GLP : yes Germ cell mutagenicity Not classified based on available information. Components: Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate: Genotoxicity in vitro : Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without metabolic activation Result: negative Carcinogenicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Carcinogenicity - Assessment : Classified based on DMSO extract content < 3% (Regulation (EC) 1272/2008, Annex VI, Part 3, Note L) IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 9 / 15 NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: No aspiration toxicity classification Further information Product: Remarks : No data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Short-term (acute) aquatic hazard : Not classified based on available information. Long-term (chronic) aquatic hazard : Not classified based on available information. Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: Toxicity to fish : LL50 (Fish): > 100 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates : EL50 (Aquatic invertebrates): > 10,000 mg/l Exposure time: 48 h Toxicity to algae : EL50 (Algae, algal mat (Algae)): > 100 mg/l Exposure time: 72 h Toxicity to fish (Chronic toxicity) : NOEC (Fish): 10 mg/l Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Aquatic invertebrates): 10 mg/l SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 10 / 15 Ecotoxicology Assessment Short-term (acute) aquatic hazard : Not classified based on available information. Long-term (chronic) aquatic hazard : Not classified based on available information. Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate: Toxicity to fish : LL50 (Oncorhynchus mykiss (rainbow trout)): 4.5 mg/l Exposure time: 96 h Test Type: semi-static test Method: OECD Test Guideline 203 Remarks: Information given is based on data obtained from similar substances. Toxicity to daphnia and other aquatic invertebrates : EL50 (Daphnia magna (Water flea)): 23 mg/l Exposure time: 48 h Method: OECD Test Guideline 202 GLP: yes Toxicity to algae : NOEL (Desmodesmus subspicatus (green algae)): 10 mg/l End point: Growth inhibition Exposure time: 72 h Test Type: static test Test substance: WAF Method: OECD Test Guideline 201 Remarks: Information given is based on data obtained from similar substances. Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity) : NOEC (Daphnia magna (Water flea)): 0.4 mg/l Exposure time: 21 d Test substance: WAF Method: OECD Test Guideline 211 Remarks: Information given is based on data obtained from similar substances. Persistence and degradability Components: Zinc O,O,O',O'-tetrakis(1,3-dimethylbutyl) bis(phosphorodithioate: Biodegradability : Result: Not readily biodegradable. Biodegradation: 1.5 % Exposure time: 28 d Method: OECD Test Guideline 301B Remarks: Information given is based on data obtained from similar substances. No data available Bioaccumulative potential Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY PARAFFINIC: SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 11 / 15 Partition coefficient: n- octanol/water : log Pow: Expected > 7 No data available Mobility in soil Components: No data available Other adverse effects No data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information : No data available Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice : Dispose of in accordance with all applicable local, state and federal regulations. Send to a licensed waste management company. Do not contaminate ponds, waterways or ditches with chemical or used container. Do not dispose of waste into sewer. Contaminated packaging : Do not re-use empty containers. Empty containers should be taken to an approved waste handling site for recycling or disposal. Dispose of as unused product. Empty remaining contents. SECTION 14. TRANSPORT INFORMATION International Regulations UNRTDG Not regulated as a dangerous good IATA-DGR Not regulated as a dangerous good IMDG-Code SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 12 / 15 Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR Not regulated as a dangerous good Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Serious eye damage or eye irritation SARA 313 : The following components are subject to reporting levels established by SARA Title III, Section 313: Zinc O,O,O',O'- tetrakis(1,3- dimethylbutyl) bis(phosphorodit hioate 2215-35-2 >= 1 - < 5 % Zinc, bis[O,O- bis(2-ethylhexyl) phosphorodithioa to-S,S']-, (T-4)- 4259-15-8 >= 0.1 - < 1 % Clean Air Act This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Section 112 (40 CFR 61). SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 13 / 15 This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489). Clean Water Act This product does not contain any Hazardous Substances listed under the U.S. CleanWater Act, Section 311, Table 116.4A. This product does not contain any Hazardous Chemicals listed under the U.S. CleanWater Act, Section 311, Table 117.3. This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section 307 Zinc O,O,O',O'- tetrakis(1,3- dimethylbutyl) bis(phosphorodithioate 2215-35-2 >= 1 - < 5 % This product does not contain any priority pollutants related to the U.S. Clean Water Act The components of this product are reported in the following inventories: DSL : All components of this product are on the Canadian DSL AICS : On the inventory, or in compliance with the inventory ENCS : Contact your sales representative for additional information. KECI : On the inventory, or in compliance with the inventory IECSC : q (quantity restricted) PICCS : On the inventory, or in compliance with the inventory TCSI : On the inventory, or in compliance with the inventory TSCA : On TSCA Inventory TSCA list No substances are subject to TSCA 12(b) export notification requirements. Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TCSI (Taiwan), TSCA (USA) SECTION 16. OTHER INFORMATION Further information Internal information : R0173131 NFPA: HMIS III: SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 14 / 15 NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class IIIB Full text of H-Statements H315 Causes skin irritation. H318 Causes serious eye damage. Sources of key data used to compile the Safety Data Sheet Valvoline internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Valvoline's Environmental Health and Safety Department (1-800-VALVOLINE). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR : Dangerous Goods Regulation by the ?International Air Transport Association? (IATA). Flammability H e a lt h In s ta b ility 2 1 0 FLAMMABILITY PHYSICAL HAZARD HEALTH 1 0 2 Special hazard 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic SAFETY DATA SHEET Valvoline? VR1 Racing? SAE 30 Racing Oil Version: 1.3 Revision Date: 04/29/2020 Print Date: 06/21/2023 15 / 15 ICAO : International Civil Aviation Organization ICAO-TI (ICAO) : Technical Instructions by the ?International Civil Aviation Organization? IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization logPow : octanol-water partition coefficient LCxx : Lethal Concentration, for xx percent of test population LDxx : Lethal Dose, for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent , Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV : Threshold Limit Value TWA : Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA : Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS : Workplace Hazardous Materials Information System