SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 1 / 12 SECTION 1. IDENTIFICATION Product name : MM AIRBRAKE SYS ANTIFRZ 12/32OZ Product code : M2832 Manufacturer or supplier's details Company name of supplier : Niteo Products, LLC Address : Dallas TX 75225 Email Address : This email address is being protected from spambots. You need JavaScript enabled to view it. Telephone : 1-844-696-4836 Emergency telephone num- ber : 1-800-424-9300 / 1-703-741-5970 Recommended use of the chemical and restrictions on use Recommended use : Anti-freezing agents Restrictions on use : Use only outdoors or in a well-ventilated area. SECTION 2. HAZARDS IDENTIFICATION GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable liquids : Category 2 Acute toxicity (Oral) : Category 3 Acute toxicity (Inhalation) : Category 3 Acute toxicity (Dermal) : Category 3 Specific target organ toxicity - single exposure : Category 1 (Central nervous system, Eyes) GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Highly flammable liquid and vapour. SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 2 / 12 Toxic if swallowed, in contact with skin or if inhaled. Causes damage to organs (Central nervous system, Eyes). Precautionary statements : Prevention: Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ ventilating/ lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/ eye protection/ face protection. Response: IF SWALLOWED: Immediately call a POISON CENTER/ doctor. Rinse mouth. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor. IF exposed: Call a POISON CENTER or doctor/ physician. Take off contaminated clothing and wash before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration (% w/w) Methanol 67-56-1 >= 90 - < 100 Any concentration shown as a range is to protect confidentiality or is due to batch variation. SECTION 4. FIRST AID MEASURES SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 3 / 12 General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : If on clothes, remove clothes. Call a physician or poison control centre immediately. If on skin, rinse well with water. In case of eye contact : Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If swallowed : Get medical attention immediately. Rinse mouth with water. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms and effects, both acute and delayed : Toxic if swallowed, in contact with skin or if inhaled. Causes damage to organs. This product contains methanol which can cause intoxication and central nervous system depression. Methanol is metabo- lized to formic acid and formaldehyde. These metabolites can cause metabolic acidosis, visual disturbances and blindness. Since metabolism is required for these toxic symptoms, their onset may be delayed from 6 to 30 hours following ingestion. Ethanol competes for the same metabolic pathway and has been used to prevent methanol metabolism. Ethanol admin- istration is indicated in symptomatic patients or at blood meth- anol concentrations above 20 ug/dl. Methanol is effectively removed by hemodialysis. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Carbon dioxide (CO2) Dry chemical Alcohol-resistant foam Unsuitable extinguishing media : High volume water jet Specific hazards during fire- fighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion prod- ucts : Carbon oxides SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 4 / 12 Specific extinguishing meth- ods : Product is compatible with standard fire-fighting agents. Further information : Use extinguishing measures that are appropriate to local cir- cumstances and the surrounding environment. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use a water spray to cool fully closed containers. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protective equipment. Remove all sources of ignition. Ensure adequate ventilation. Avoid breathing dust. Beware of vapours accumulating to form explosive concentra- tions. Vapours can accumulate in low areas. Evacuate personnel to safe areas. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Contain spillage, and then collect with non-combustible ab- sorbent material, (e.g. sand, earth, diatomaceous earth, ver- miculite) and place in container for disposal according to local / national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Electrically bond and ground all containers, personnel and equipment before transfer or use of material. Special precau- tions may be necessary to dissipate static electricity for non- conductive containers. Use proper bonding and grounding during product transfer as described in National Fire Protec- tion Association document NFPA 77. Keep away from open flames, hot surfaces and sources of ignition. Use only explosion-proof equipment. Do not spray on a naked flame or any incandescent material. Advice on safe handling : Open drum carefully as content may be under pressure. Avoid formation of aerosol. Provide sufficient air exchange and/or exhaust in work rooms. SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 5 / 12 Do not breathe vapours/dust. Do not smoke. Take precautionary measures against static discharges. Dispose of rinse water in accordance with local and national regulations. Container hazardous when empty. Smoking, eating and drinking should be prohibited in the ap- plication area. For personal protection see section 8. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. No smoking. Further information on stor- age stability : No decomposition if stored and applied as directed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis Methanol 67-56-1 TWA 200 ppm ACGIH STEL 250 ppm ACGIH TWA 200 ppm 260 mg/m3 NIOSH REL ST 250 ppm 325 mg/m3 NIOSH REL TWA 200 ppm 260 mg/m3 OSHA Z-1 STEL 250 ppm 325 mg/m3 OSHA P0 TWA 200 ppm 260 mg/m3 OSHA P0 Biological occupational exposure limits Components CAS-No. Control parameters Biological specimen Sam- pling time Permissible concentra- tion Basis Methanol 67-56-1 Methanol Urine End of shift (As soon as possible after exposure ceases) 15 mg/l ACGIH BEI Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 6 / 12 applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Hand protection Remarks : Wear resistant gloves (consult your safety equipment suppli- er). The suitability for a specific workplace should be dis- cussed with the producers of the protective gloves. Discard gloves that show tears, pinholes, or signs of wear. Eye protection : Not required under normal conditions of use. Wear splash- proof safety goggles if material could be misted or splashed into eyes. Skin and body protection : Choose body protection according to the amount and con- centration of the dangerous substance at the work place. Wear as appropriate: Impervious clothing Flame-resistant clothing Safety shoes Remove and wash contaminated clothing before re-use. Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : blue Odour : pungent Odour Threshold : not determined pH : not determined Melting point/freezing point : not determined Boiling point/boiling range : 64.7 ?C (1013.250 hPa) Value for Component Flash point : 12 ?C Method: closed cup Value for Component Evaporation rate : not determined Flammability (solid, gas) : No data available SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 7 / 12 Self-ignition : not determined Upper explosion limit / Upper flammability limit : not determined Lower explosion limit / Lower flammability limit : not determined Vapour pressure : not determined Relative vapour density : not determined Density : 0.7922 g/cm3 Solubility(ies) Water solubility : completely miscible Partition coefficient: n- octanol/water : not determined Decomposition temperature : not determined Viscosity Viscosity, dynamic : not determined Viscosity, kinematic : not determined Molecular weight : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : No decomposition if stored and applied as directed. Possibility of hazardous reac- tions : No decomposition if stored and applied as directed. Vapours may form explosive mixture with air. Conditions to avoid : Heat, flames and sparks. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Eye contact Skin contact Ingestion SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 8 / 12 Acute toxicity Toxic if swallowed, in contact with skin or if inhaled. Product: Acute oral toxicity : Acute toxicity estimate: 100.15 mg/kg Method: Calculation method Acute inhalation toxicity : Acute toxicity estimate: 3 mg/l Exposure time: 4 h Test atmosphere: vapour Method: Calculation method Acute dermal toxicity : Acute toxicity estimate: 300.45 mg/kg Method: Calculation method Components: Methanol: Acute oral toxicity : LDLo (Humans): 300 mg/kg Assessment: The component/mixture is toxic after single in- gestion. Acute inhalation toxicity : Test atmosphere: dust/mist Assessment: The component/mixture is toxic after short term inhalation. Acute dermal toxicity : LD50 (Rabbit): 12,800 mg/kg Assessment: The component/mixture is toxic after single con- tact with skin. Skin corrosion/irritation Not classified based on available information. Components: Methanol: Species: Rabbit Result: No skin irritation Serious eye damage/eye irritation Not classified based on available information. Product: Remarks: Unlikely to cause eye irritation or injury. Components: Methanol: Species: Rabbit Result: Possibly irritating to eyes SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 9 / 12 Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Components: Methanol: Test Type: Maximisation Test Species: Guinea pig Assessment: Does not cause skin sensitisation. Method: OECD Test Guideline 406 Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. STOT - single exposure Causes damage to organs (Central nervous system, Eyes). Components: Methanol: Target Organs: Central nervous system, Eyes Assessment: The substance or mixture is classified as specific target organ toxicant, single ex- posure, category 1. STOT - repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Further information Product: Remarks: No data available SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 10 / 12 SECTION 12. ECOLOGICAL INFORMATION Toxicity Additional ecological information : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION Dangerous goods descriptions (if indicated below) may not reflect quantity, end-use, or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. International Regulations IATA-DGR UN/ID No. : UN 1230 Proper shipping name : Methanol Class : 3 Subsidiary risk : 6.1 Packing group : II Labels : 3 (6.1) Packing instruction (cargo aircraft) : 364 IMDG-Code UN number : UN 1230 Proper shipping name : METHANOL Class : 3 Subsidiary risk : 6.1 Packing group : II Labels : 3 (6.1) EmS Code : F-E, S-D Marine pollutant : no Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 11 / 12 UN/ID/NA number : UN 1230 Proper shipping name : Methanol Class : 3 Packing group : II Labels : 3 ERG Code : 131 Marine pollutant : no SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Methanol 67-56-1 100 100 (F003) Xylene 1330-20-7 100 100 (F003) Ethylbenzene 100-41-4 100 100 (F003) Methanol 67-56-1 5000 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Flammable (gases, aerosols, liquids, or solids) Acute toxicity (any route of exposure) Specific target organ toxicity (single or repeated exposure) SARA 313 : The following components are subject to reporting levels es- tablished by SARA Title III, Section 313: Methanol 67-56-1 >= 90 - <= 100 % California Prop. 65 WARNING: This product can expose you to chemicals including Ethylbenzene, which is/are known to the State of California to cause cancer, and Methanol, Toluene, which is/are known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. SAFETY DATA SHEET MOTOR MEDIC? AIR BRAKE SYS ANTI- FREEZE & RUST GUARD Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001949 Date of last issue: 09/04/2019 Date of first issue: 09/04/2019 12 / 12 SECTION 16. OTHER INFORMATION Further information NFPA: Revision Date : 03/29/2023 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / EN Flammability H e a lt h In s ta b ility 2 3 0 Special hazard