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M4434 MM BRAKE FLUID DOT 3- 4/1GA
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SDS_SDS_US_GHS_E_-_M4434.pdf
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SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 1 / 12 SECTION 1. IDENTIFICATION Product name : MM BF DOT 3 4/1GA Product code : M4434 Manufacturer or supplier's details Company name of supplier : Niteo Products, LLC Address : Dallas TX 75225 Email Address : This email address is being protected from spambots. You need JavaScript enabled to view it. Telephone : 1-844-696-4836 Emergency telephone num- ber : 1-800-424-9300 / 1-703-741-5970 Recommended use of the chemical and restrictions on use Recommended use : BRAKE FLUID Restrictions on use : Use only outdoors or in a well-ventilated area. SECTION 2. HAZARDS IDENTIFICATION GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Serious eye damage : Category 1 Specific target organ toxicity - repeated exposure (Oral) : Category 2 (Kidney) GHS label elements Hazard pictograms : Signal word : Danger Hazard statements : Causes serious eye damage. May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed. Precautionary statements : Prevention: Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Wear eye protection/ face protection. SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 2 / 12 Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/ doctor. Get medical advice/ attention if you feel unwell. Disposal: Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration (% w/w) Triethylene glycol monobutyl ether 143-22-6 >= 15 - <= 50 Diethylene glycol 111-46-6 >= 15 - <= 25 Diethylene glycol monobutyl ether 112-34-5 >= 5 - <= 15 Ethanol, 2-(2-propoxyethoxy)- 6881-94-3 >= 2 - <= 5 Any concentration shown as a range is to protect confidentiality or is due to batch variation. SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : If on skin, rinse well with water. In case of eye contact : In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If swallowed : Obtain medical attention. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms : Causes serious eye damage. SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 3 / 12 and effects, both acute and delayed May cause damage to organs through prolonged or repeated exposure if swallowed. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Water spray Carbon dioxide (CO2) Unsuitable extinguishing media : High volume water jet Specific hazards during fire- fighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion prod- ucts : Carbon oxides Specific extinguishing meth- ods : Product is compatible with standard fire-fighting agents. Further information : Use extinguishing measures that are appropriate to local cir- cumstances and the surrounding environment. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : In the event of fire, wear self-contained breathing apparatus. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protective equipment. Avoid breathing dust. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions : Prevent further leakage or spillage if safe to do so. Prevent product from entering drains. Do not flush into surface water or sanitary sewer system. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Normal measures for preventive fire protection. Advice on safe handling : Do not breathe vapours/dust. Do not smoke. Avoid contact with skin and eyes. Dispose of rinse water in accordance with local and national SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 4 / 12 regulations. Container hazardous when empty. Smoking, eating and drinking should be prohibited in the ap- plication area. For personal protection see section 8. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Further information on stor- age stability : No decomposition if stored and applied as directed. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis Diethylene glycol 111-46-6 TWA 10 mg/m3 US WEEL Diethylene glycol monobutyl ether 112-34-5 TWA (Inhal- able fraction and vapor) 10 ppm ACGIH Hazardous components without workplace control parameters Components CAS-No. Triethylene glycol monobutyl ether 143-22-6 Ethanol, 2-(2-propoxyethoxy)- 6881-94-3 Engineering measures : Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable) or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Hand protection Remarks : Wear resistant gloves (consult your safety equipment suppli- er). The suitability for a specific workplace should be dis- cussed with the producers of the protective gloves. Eye protection : Wear chemical splash goggles and face shield when there is potential for exposure of the eyes or face to liquid, vapor or mist. Skin and body protection : Choose body protection according to the amount and con- centration of the dangerous substance at the work place. Wear as appropriate: Impervious clothing Safety shoes Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. When using do not smoke. SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 5 / 12 When using do not eat or drink. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : amber Odour : ether-like Odour Threshold : not determined pH : 10.5 Melting point/freezing point : not determined Boiling point/boiling range : 205 ?C Flash point : 203 ?C Evaporation rate : not determined Flammability (solid, gas) : No data available Self-ignition : not determined Upper explosion limit / Upper flammability limit : not determined Lower explosion limit / Lower flammability limit : not determined Vapour pressure : not determined Relative vapour density : not determined Density : not determined Solubility(ies) Water solubility : not determined Partition coefficient: n- octanol/water : not determined Decomposition temperature : not determined Viscosity Viscosity, dynamic : not determined Viscosity, kinematic : not determined Molecular weight : Not applicable SECTION 10. STABILITY AND REACTIVITY SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 6 / 12 Reactivity : No decomposition if stored and applied as directed. Chemical stability : No decomposition if stored and applied as directed. Possibility of hazardous reac- tions : No decomposition if stored and applied as directed. Hazardous polymerisation does not occur. Conditions to avoid : No data available Incompatible materials : Strong oxidizing agents Strong acids Strong bases Hazardous decomposition products : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Eye contact Skin contact Ingestion Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: 3,723 mg/kg Method: Calculation method Remarks: Ingestion of medications contaminated with diethy- lene glycol has caused kidney failure and death in humans. Products containing diethylene glycol should be considered toxic by ingestion. Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Remarks: Skin absorption of this material (or a component) may be increased through injured skin. Components: Triethylene glycol monobutyl ether: Acute oral toxicity : LD50 (Rat): 5,300 mg/kg Acute dermal toxicity : LD50 (Rabbit): 3,502 mg/kg Diethylene glycol: Acute oral toxicity : LD50 (Humans): Expected 1,120 mg/kg Acute inhalation toxicity : LC50 (Rat): > 4.6 mg/l Exposure time: 4 h Test atmosphere: dust/mist SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 7 / 12 Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity : LD50 (Rabbit): 13,300 mg/kg Diethylene glycol monobutyl ether: Acute oral toxicity : LD50 (Rat): 3,305 mg/kg Acute dermal toxicity : LD50 (Rabbit): 2,734 mg/kg Ethanol, 2-(2-propoxyethoxy)-: Acute oral toxicity : LD50 (Rat): 6,661 mg/kg Acute dermal toxicity : LD50 (Guinea pig): 5,048 mg/kg Skin corrosion/irritation Not classified based on available information. Components: Triethylene glycol monobutyl ether: Result: No skin irritation Diethylene glycol: Species: human skin Result: Possibly irritating to skin Diethylene glycol monobutyl ether: Result: Possibly irritating to skin Ethanol, 2-(2-propoxyethoxy)-: Species: Rabbit Result: Possibly irritating to skin Serious eye damage/eye irritation Causes serious eye damage. Product: Remarks: May cause irreversible eye damage. Components: Triethylene glycol monobutyl ether: Result: Irreversible effects on the eye Diethylene glycol: Species: Rabbit Result: Possibly irritating to eyes SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 8 / 12 Diethylene glycol monobutyl ether: Result: Irritating to eyes. Ethanol, 2-(2-propoxyethoxy)-: Species: Rabbit Result: Irritating to eyes. Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Components: Diethylene glycol: Test Type: Maximisation Test Species: Guinea pig Method: Directive 67/548/EEC, Annex V, B.6. Result: Did not cause sensitisation on laboratory animals. Diethylene glycol monobutyl ether: Test Type: Maximisation Test Species: Guinea pig Result: Did not cause sensitisation on laboratory animals. Ethanol, 2-(2-propoxyethoxy)-: Species: Guinea pig Assessment: Does not cause skin sensitisation. Germ cell mutagenicity Not classified based on available information. Components: Diethylene glycol: Genotoxicity in vitro : Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 479 Result: negative Genotoxicity in vivo : Test Type: In vivo micronucleus test Species: Mouse Method: OECD Test Guideline 474 Result: negative Diethylene glycol monobutyl ether: Genotoxicity in vitro : Remarks: In vitro tests did not show mutagenic effects Genotoxicity in vivo : Result: In vivo tests did not show mutagenic effects SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 9 / 12 Carcinogenicity Not classified based on available information. IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. Components: Diethylene glycol monobutyl ether: Effects on foetal develop- ment : Remarks: No teratogenic effects STOT - single exposure Not classified based on available information. STOT - repeated exposure May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed. Components: Diethylene glycol: Exposure routes: Ingestion Target Organs: Kidney Assessment: May cause damage to organs through prolonged or repeated exposure. Repeated dose toxicity Components: Diethylene glycol monobutyl ether: NOAEL: 250 mg/kg LOAEL: 1,000 mg/kg Application Route: Oral Target Organs: Blood Aspiration toxicity Not classified based on available information. Further information Product: Remarks: No data available SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 10 / 12 SECTION 12. ECOLOGICAL INFORMATION Toxicity Additional ecological information : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SECTION 14. TRANSPORT INFORMATION Dangerous goods descriptions (if indicated below) may not reflect quantity, end-use, or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. International Regulations IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR Not regulated as a dangerous good 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ (lbs) Calculated product RQ (lbs) Diethanolamine 111-42-2 100 * *: Calculated RQ exceeds reasonably attainable upper limit. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 11 / 12 SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) SARA 313 : The following components are subject to reporting levels es- tablished by SARA Title III, Section 313: Triethylene glycol mono- butyl ether 143-22-6 >= 15 - <= 50 % Triethylene glycol mo- noethyl ether 112-50-5 >= 10 - <= 15 % Diethylene glycol mono- butyl ether 112-34-5 >= 5 - <= 15 % California Prop. 65 WARNING: This product can expose you to chemicals including Diethanolamine, which is/are known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. SECTION 16. OTHER INFORMATION Further information NFPA: Revision Date : 03/29/2023 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific Flammability H e a lt h In s ta b ility 3 1 0 Special hazard SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 3 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000001626 Date of last issue: 01/02/2019 Date of first issue: 01/02/2019 12 / 12 material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / EN