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M4532 MM BRAKE FLUID DOT 4 12/32OZ
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SDS_SDS_US_GHS_E_-_M4532.pdf
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SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 1 / 10 SECTION 1. IDENTIFICATION Product name : MM BF DOT 4 12/32OZ Product code : M4532 Manufacturer or supplier's details Company name of supplier : Niteo Products, LLC Address : Dallas TX 75225 Email Address : This email address is being protected from spambots. You need JavaScript enabled to view it. Telephone : 1-844-696-4836 Emergency telephone num- ber : 1-800-424-9300 / 1-703-741-5970 Recommended use of the chemical and restrictions on use Recommended use : BRAKE FLUID Restrictions on use : Use only outdoors or in a well-ventilated area. SECTION 2. HAZARDS IDENTIFICATION GHS classification in accordance with the OSHA Hazard Communication Standard (29 CFR 1910.1200) Specific target organ toxicity - repeated exposure (Oral) : Category 2 (Kidney) GHS label elements Hazard pictograms : Signal word : Warning Hazard statements : May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed. Precautionary statements : Prevention: Do not breathe dust/ fume/ gas/ mist/ vapours/ spray. Response: Get medical advice/ attention if you feel unwell. Disposal: SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 2 / 10 Dispose of contents/ container to an approved waste disposal plant. Other hazards None known. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical name CAS-No. Concentration (% w/w) Diethylene glycol 111-46-6 >= 5 - < 10 Polyethylene glycol 25322-68-3 >= 1 - < 5 Triethylene glycol monobutyl ether 143-22-6 >= 1 - < 5 Any concentration shown as a range is to protect confidentiality or is due to batch variation. SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious, place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of eye contact : Small amounts splashed into eyes can cause irreversible tis- sue damage and blindness. In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed : Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. Most important symptoms and effects, both acute and delayed : May cause damage to organs through prolonged or repeated exposure if swallowed. Notes to physician : Treat symptomatically. SECTION 5. FIREFIGHTING MEASURES SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 3 / 10 Unsuitable extinguishing media : High volume water jet Specific hazards during fire- fighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion prod- ucts : Carbon oxides Further information : Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if nec- essary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- tive equipment and emer- gency procedures : Use personal protective equipment. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Keep in suitable, closed containers for disposal. SECTION 7. HANDLING AND STORAGE Advice on protection against fire and explosion : Normal measures for preventive fire protection. Advice on safe handling : Do not breathe vapours/dust. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the ap- plication area. To avoid spills during handling keep bottle on a metal tray. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. Further information on stor- age stability : No decomposition if stored and applied as directed. SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 4 / 10 SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parame- ters / Permissible concentration Basis Diethylene glycol 111-46-6 TWA 10 mg/m3 US WEEL Polyethylene glycol 25322-68-3 TWA (aero- sol) 10 mg/m3 US WEEL Personal protective equipment Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Skin and body protection : Impervious clothing Choose body protection according to the amount and con- centration of the dangerous substance at the work place. Hygiene measures : When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : liquid Colour : amber Odour : ether-like Odour Threshold : not determined pH : 8.6 Melting point/freezing point : < -50 ?C Boiling point/boiling range : > 232 ?C Flash point : not determined Evaporation rate : not determined Flammability (solid, gas) : No data available Self-ignition : not determined Upper explosion limit / Upper : not determined SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 5 / 10 flammability limit Lower explosion limit / Lower flammability limit : not determined Vapour pressure : not determined Relative vapour density : not determined Density : 1.06 g/cm3 (20 ?C) Solubility(ies) Water solubility : not determined Partition coefficient: n- octanol/water : not determined Decomposition temperature : not determined Viscosity Viscosity, dynamic : not determined Viscosity, kinematic : not determined Molecular weight : No data available SECTION 10. STABILITY AND REACTIVITY Reactivity : No decomposition if stored and applied as directed. Chemical stability : No decomposition if stored and applied as directed. Possibility of hazardous reac- tions : No decomposition if stored and applied as directed. Conditions to avoid : No data available Incompatible materials : Not applicable Hazardous decomposition products : Carbon oxides SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation Eye contact Skin contact Ingestion Acute toxicity Not classified based on available information. Product: Acute oral toxicity : Acute toxicity estimate: > 5,000 mg/kg SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 6 / 10 Method: Calculation method Acute dermal toxicity : Acute toxicity estimate: > 5,000 mg/kg Method: Calculation method Components: Diethylene glycol: Acute oral toxicity : LD50 (Humans): Expected 1,120 mg/kg Acute inhalation toxicity : LC50 (Rat): > 4.6 mg/l Exposure time: 4 h Test atmosphere: dust/mist Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity : LD50 (Rabbit): 13,300 mg/kg Polyethylene glycol: Acute oral toxicity : LD50 (Rat): > 20 g/kg Acute dermal toxicity : LD50 (Rabbit): > 20 g/kg Triethylene glycol monobutyl ether: Acute oral toxicity : LD50 (Rat): 5,300 mg/kg Acute dermal toxicity : LD50 (Rabbit): 3,502 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Remarks: Extremely corrosive and destructive to tissue. Components: Diethylene glycol: Species: human skin Result: Possibly irritating to skin Polyethylene glycol: Assessment: No skin irritation Result: No skin irritation Triethylene glycol monobutyl ether: Result: No skin irritation Serious eye damage/eye irritation Not classified based on available information. SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 7 / 10 Product: Remarks: May cause irreversible eye damage. Components: Diethylene glycol: Species: Rabbit Result: Possibly irritating to eyes Polyethylene glycol: Result: No eye irritation Assessment: No eye irritation Triethylene glycol monobutyl ether: Result: Irreversible effects on the eye Respiratory or skin sensitisation Skin sensitisation Not classified based on available information. Respiratory sensitisation Not classified based on available information. Components: Diethylene glycol: Test Type: Maximisation Test Species: Guinea pig Method: Directive 67/548/EEC, Annex V, B.6. Result: Did not cause sensitisation on laboratory animals. Germ cell mutagenicity Not classified based on available information. Components: Diethylene glycol: Genotoxicity in vitro : Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 479 Result: negative Genotoxicity in vivo : Test Type: In vivo micronucleus test Species: Mouse Method: OECD Test Guideline 474 Result: negative Carcinogenicity Not classified based on available information. IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 8 / 10 OSHA No component of this product present at levels greater than or equal to 0.1% is on OSHA?s list of regulated carcinogens. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. Reproductive toxicity Not classified based on available information. STOT - single exposure Not classified based on available information. STOT - repeated exposure May cause damage to organs (Kidney) through prolonged or repeated exposure if swallowed. Components: Diethylene glycol: Exposure routes: Ingestion Target Organs: Kidney Assessment: May cause damage to organs through prolonged or repeated exposure. Aspiration toxicity Not classified based on available information. Further information Product: Remarks: No data available SECTION 12. ECOLOGICAL INFORMATION Toxicity Additional ecological information : No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemi- cal or used container. Send to a licensed waste management company. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 9 / 10 SECTION 14. TRANSPORT INFORMATION Dangerous goods descriptions (if indicated below) may not reflect quantity, end-use, or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. International Regulations IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. National Regulations 49 CFR Not regulated as a dangerous good 49 CFR Not regulated as a dangerous good SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 311/312 Hazards : Specific target organ toxicity (single or repeated exposure) SARA 313 : The following components are subject to reporting levels es- tablished by SARA Title III, Section 313: Triethylene glycol monomethyl ether 112-35-6 >= 30 - < 50 % Triethylene glycol mono- butyl ether 143-22-6 >= 1 - < 5 % California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SAFETY DATA SHEET MOTOR MEDIC? BRAKE FLUID DOT 4 Version 1.1 Revision Date: 03/29/2023 SDS Number: 600000002575 Date of last issue: 10/11/2022 Date of first issue: 10/11/2022 10 / 10 SECTION 16. OTHER INFORMATION Further information NFPA: Revision Date : 03/29/2023 The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. US / EN Flammability H e a lt h In s ta b ility 0 1 0 Special hazard