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M709 14OZ GUNK BRAKE CLEANER - NON-CHLOR 9%
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SAFETY DATA SHEET1. Identification Gunk Brake Parts Cleaner - Non-ChlorinaledProduct identifierOther means of identification M709SDS number M709, M709TPart No. 3814.00.5090Tariff code CleanerRecommended use None known.Recommended restrictionsManufacturer/Importer/Supplier/Distributor informationManufacturer Blumenthal Brands Integrated, LLCAddress 600 Radiator RoadCompany nameWebsiteTelephone Customer Service/Technical (704) 821-7643Emergency phone number INFOTRAC (United States) (800) 535-5053INFOTRAC (International) (352) 323-3500E-mail This email address is being protected from spambots. You need JavaScript enabled to view it. Trail, NC 280792. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Category 2Skin corrosion/irritationHealth hazards Category 2Serious eye damage/eye irritation Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazardNot classified.Environmental hazards Not classified.OSHA defined hazardsLabel elementsSignal word DangerHazard statement Extremely flammable aerosol. Pressurized container: May burst if heated. May be fatal ifswallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May causedrowsiness or dizziness.Precautionary statementPrevention Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an openflame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoidbreathing mist/vapor. Wash thoroughly after handling. Use only outdoors or in a well-ventilatedarea. Wear eye protection/face protection. Wear protective gloves.Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Washwith plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. Ifin eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing. Call a poison center/doctor if you feel unwell. If skin irritation occurs:Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take offcontaminated clothing and wash before reuse.Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect fromsunlight. Do not expose to temperatures exceeding 50?C/122?F. 1 / 9Material name: Gunk Brake Parts Cleaner - Non-ChlorinaledM709, M709T Version #: 04 Revision date: 03-30-2020 Issue date: 05-06-2015 SDS US Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded andgrounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion.Supplemental information NOTE: This product is a consumer product and is labeled in accordance with the US ConsumerProduct Safety Commission regulations which take precedence over OSHA HazardCommunication labeling. The container label may not include the OSHA label elements listed inthis document. Always carefully review the entire SDS and the product label prior to use in theworkplace.3. Composition/information on ingredientsMixtures CAS number %Chemical name Common name and synonyms 67-64-1Acetone 80 - < 90124-38-9Carbon Dioxide 5 - < 15426260-76-6Heptanes (cyclic and linear) 5 - < 10*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poisoncenter or doctor/physician if you feel unwell.Inhalation Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Getmedical advice/attention. Wash contaminated clothing before reuse.Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.Ingestion Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.Most importantsymptoms/effects, acute anddelayed Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.Indication of immediatemedical attention and specialtreatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions toprotect themselves.General information5. Fire-fighting measures Water fog. Alcohol resistant foam. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide,sand or earth may be used for small fires only.Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishingmedia Contents under pressure. Pressurized container may explode when exposed to heat or flame. Thisproduct is a poor conductor of electricity and can become electrostatically charged. If sufficientcharge is accumulated, ignition of flammable mixtures can occur. To reduce potential for staticdischarge, use proper bonding and grounding procedures. This liquid may accumulate staticelectricity when filling properly grounded containers. Static electricity accumulation may besignificantly increased by the presence of small quantities of water or other contaminants. Materialwill float and may ignite on surface of water. During fire, gases hazardous to health may beformed.Specific hazards arising fromthe chemical Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipmentand precautions for firefighters Move containers from fire area if you can do so without risk. Containers should be cooled withwater to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hoseholder or monitor nozzles, if possible. If not, withdraw and let fire burn out.Fire fightingequipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Movecontainers from fire area if you can do so without risk. In the event of fire and/or explosion do notbreathe fumes.Specific methods Extremely flammable aerosol.General fire hazards 2 / 9Material name: Gunk Brake Parts Cleaner - Non-ChlorinaledM709, M709T Version #: 04 Revision date: 03-30-2020 Issue date: 05-06-2015 SDS US 6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Remove allpossible sources of ignition in the surrounding area. Wear appropriate protective equipment andclothing during clean-up. Avoid breathing mist/vapor. Do not touch damaged containers or spilledmaterial unless wearing appropriate protective clothing. Ventilate closed spaces before enteringthem. Use appropriate containment to avoid environmental contamination. Transfer by mechanicalmeans such as vacuum truck to a salvage tank or other suitable container for recovery or safedisposal. Local authorities should be advised if significant spillages cannot be contained. Forpersonal protection, see section 8 of the SDS.Personal precautions,protective equipment andemergency procedures Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so withoutrisk. Move the cylinder to a safe and open area if the leak is irreparable. Eliminate all ignitionsources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood,paper, oil, etc.) away from spilled material. Absorb in vermiculite, dry sand or earth and place intocontainers. Following product recovery, flush area with water.Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination. For waste disposal, see section 13 of the SDS.Methods and materials forcontainment and cleaning up Avoid discharge into drains, water courses or onto the ground. Use appropriate containment toavoid environmental contamination.Environmental precautions7. Handling and storage Minimize fire risks from flammable and combustible materials (including combustible dust andstatic accumulating liquids) or dangerous reactions with incompatible materials. Handlingoperations that can promote accumulation of static charges include but are not limited to: mixing,filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and containerfilling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurizedcontainer: Do not pierce or burn, even after use. Do not use if spray button is missing or defective.Do not spray on a naked flame or any other incandescent material. Do not smoke while using oruntil sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers toheat, flame, sparks, or other sources of ignition. All equipment used when handling the productmust be grounded. Do not re-use empty containers. Avoid contact with eyes, skin, and clothing.Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protectiveequipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices.For additional information on equipment bonding and grounding, refer to the Canadian ElectricalCode in Canada, (CSA C22.1), or the American Petroleum Institute (API) Recommended Practice2003, "Protection Against Ignitions Arising out of Static, Lightning, and Stray Currents" or NationalFire Protection Association (NFPA) 77, "Recommended Practice on Static Electricity" or NationalFire Protection Association (NFPA) 70, "National Electrical Code".Precautions for safe handling Level 2 Aerosol.Store locked up. Pressurized container. Protect from sunlight and do not expose to temperaturesexceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an openflame, heat or other sources of ignition. This material can accumulate static charge which maycause spark and become an ignition source. Avoid spark promoters. Ground/bond container andequipment. These alone may be insufficient to remove static electricity. Store in tightly closedcontainer. Store away from incompatible materials (see Section 10 of the SDS).Conditions for safe storage,including any incompatibilities8. Exposure controls/personal protectionOccupational exposure limitsThe following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.At this time, the other constituents have no known exposure limits.US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents TypePEL 2400 mg/m3Acetone (CAS 67-64-1) 1000 ppmPEL 9000 mg/m3Carbon Dioxide (CAS124-38-9) 5000 ppm 3 / 9Material name: Gunk Brake Parts Cleaner - Non-ChlorinaledM709, M709T Version #: 04 Revision date: 03-30-2020 Issue date: 05-06-2015 SDS US US. ACGIH Threshold Limit Values ValueComponents TypeSTEL 500 ppmAcetone (CAS 67-64-1) TWA 250 ppmSTEL 30000 ppmCarbon Dioxide (CAS124-38-9) TWA 5000 ppmUS. NIOSH: Pocket Guide to Chemical Hazards ValueComponents TypeTWA 590 mg/m3Acetone (CAS 67-64-1) 250 ppmSTEL 54000 mg/m3Carbon Dioxide (CAS124-38-9) 30000 ppmTWA 9000 mg/m35000 ppmBiological limit valuesACGIH Biological Exposure IndicesValueComponents Determinant Specimen Sampling Time25 mg/l Acetone Urine *Acetone (CAS 67-64-1)* - For sampling details, please see the source document.Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Provideeyewash station and safety shower.Appropriate engineeringcontrolsIndividual protection measures, such as personal protective equipmentChemical respirator with organic vapor cartridge and full facepiece.Eye/face protectionSkin protection Wear appropriate chemical resistant gloves. Nitrile, butyl rubber or neoprene gloves arerecommended.Hand protection Wear appropriate chemical resistant clothing.Other Chemical respirator with organic vapor cartridge and full facepiece. Chemical respirator withorganic vapor cartridge and full facepiece if threshold limits are exceeded.Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washingafter handling the material and before eating, drinking, and/or smoking. Routinely wash workclothing and protective equipment to remove contaminants.General hygieneconsiderations9. Physical and chemical propertiesClear. LiquidAppearance Liquid.Physical state Aerosol.Form ColorlessColor AromaticOdorOdor threshold Not available.pH Not available.Melting point/freezing point -133.25 ?F (-91.8 ?C) estimatedInitial boiling point and boilingrange 120.45 ?F (49.14 ?C) estimatedFlash point 4.0 ?F (-15.6 ?C) Tag Closed CupEvaporation rate Not available.Not applicable.Flammability (solid, gas) 4 / 9Material name: Gunk Brake Parts Cleaner - Non-ChlorinaledM709, M709T Version #: 04 Revision date: 03-30-2020 Issue date: 05-06-2015 SDS US Upper/lower flammability or explosive limitsFlammability limit - lower(%) 2.6 % estimatedFlammability limit - upper(%) 12.8 % estimatedExplosive limit - lower (%) Not available.Explosive limit - upper (%) Not available.Vapor pressure 4783.35243 hPa estimatedVapor density Not available.Relative density Not available.Solubility(ies)Solubility (water) Not available.Partition coefficient(n-octanol/water) Not available.Auto-ignition temperature 869 ?F (465 ?C) estimatedDecomposition temperature Not available.Viscosity Not available.Other informationDensity 6.5 lbs/galNot explosive.Explosive propertiesFlammability class Flammable IB estimatedHeat of combustion (NFPA30B) 23.57 kJ/g estimatedNot oxidizing.Oxidizing propertiesPercent volatile 93 % estimatedSpecific gravity 0.78VOC 7.9 % w/w10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability Hazardous polymerization does not occur.Possibility of hazardousreactions Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoidtemperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoid Acids. Aluminum.Incompatible materials No hazardous decomposition products are known.Hazardous decompositionproducts11. Toxicological informationInformation on likely routes of exposureInhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may beharmful.Skin contact Causes skin irritation.Eye contact Causes serious eye irritation.Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.Symptoms related to thephysical, chemical andtoxicological characteristics Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.Information on toxicological effectsAcute toxicity May be fatal if swallowed and enters airways. 5 / 9Material name: Gunk Brake Parts Cleaner - Non-ChlorinaledM709, M709T Version #: 04 Revision date: 03-30-2020 Issue date: 05-06-2015 SDS US Test ResultsComponents SpeciesAcetone (CAS 67-64-1)InhalationAcuteLC50 Rat 50.1 mg/l, 8 HoursOralLD50 Rat 5800 mg/kgCauses skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eyeirritationRespiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicityCarcinogenicity Not classifiable as to carcinogenicity to humans.IARC Monographs. Overall Evaluation of CarcinogenicityNot listed.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Not regulated.US. National Toxicology Program (NTP) Report on CarcinogensNot listed. This product is not expected to cause reproductive or developmental effects.Reproductive toxicitySpecific target organ toxicity -single exposure May cause drowsiness and dizziness.Specific target organ toxicity -repeated exposure Not classified.Aspiration hazard May be fatal if swallowed and enters airways.Chronic effects Prolonged inhalation may be harmful.12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude thepossibility that large or frequent spills can have a harmful or damaging effect on the environment.EcotoxicityComponents Test ResultsSpeciesAcetone (CAS 67-64-1)Aquatic EC50Crustacea 10294 - 17704 mg/l, 48 hoursWater flea (Daphnia magna)LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss) No data is available on the degradability of any ingredients in the mixture. Persistence and degradability Bioaccumulative potentialPartition coefficient n-octanol / water (log Kow)Acetone -0.24No data available.Mobility in soilOther adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. Contentsunder pressure. Do not puncture, incinerate or crush. Incinerate the material under controlledconditions in an approved incinerator. If discarded, this product is considered a RCRA ignitablewaste, D001. Dispose of contents/container in accordance with local/regional/national/internationalregulations.Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations 6 / 9Material name: Gunk Brake Parts Cleaner - Non-ChlorinaledM709, M709T Version #: 04 Revision date: 03-30-2020 Issue date: 05-06-2015 SDS US D001: Waste Flammable material with a flash point <140 FThe waste code should be assigned in discussion between the user, the producer and the wastedisposal company.Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).Waste from residues / unusedproducts Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal. Do not re-use empty containers.Contaminated packaging14. Transport informationDOT UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group NoMarine pollutantEnvironmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptionsIATA UN1950UN number Aerosol, flammable, Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group NoEnvironmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for userIMDG UN1950UN number AerosolsUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group NoMarine pollutantEnvironmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Not established.Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC CodeDOT 7 / 9Material name: Gunk Brake Parts Cleaner - Non-ChlorinaledM709, M709T Version #: 04 Revision date: 03-30-2020 Issue date: 05-06-2015 SDS US IATAIMDG15. Regulatory informationThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulationsTSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.CERCLA Hazardous Substance List (40 CFR 302.4)Acetone (CAS 67-64-1) Listed.SARA 304 Emergency release notificationNot regulated.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Not regulated.SARA 302 Extremely hazardous substanceSuperfund Amendments and Reauthorization Act of 1986 (SARA)Not listed. YesSARA 311/312 Hazardouschemical Flammable (gases, aerosols, liquids, or solids)Skin corrosion or irritationSerious eye damage or eye irritationSpecific target organ toxicity (single or repeated exposure)Aspiration hazardHazard not otherwise classified (HNOC)Classified hazardcategoriesSARA 313 (TRI reporting)Not regulated.Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListNot regulated.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Not regulated. Not regulated.Safe Drinking Water Act(SDWA)Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) andChemical Code NumberAcetone (CAS 67-64-1) 6532Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))Acetone (CAS 67-64-1) 35 %WV 8 / 9Material name: Gunk Brake Parts Cleaner - Non-ChlorinaledM709, M709T Version #: 04 Revision date: 03-30-2020 Issue date: 05-06-2015 SDS US DEA Exempt Chemical Mixtures Code NumberAcetone (CAS 67-64-1) 6532FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing WorkplaceAcetone (CAS 67-64-1) Low priorityUS state regulationsCalifornia Proposition 65California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This materialis not known to contain any chemicals currently listed as carcinogens or reproductive toxins. Formore information go to www.P65Warnings.ca.gov.US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,subd. (a))Acetone (CAS 67-64-1)International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*NoAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS) YesTaiwan Taiwan Chemical Substance Inventory (TCSI) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).16. Other information, including date of preparation or last revision05-06-2015Issue date 03-30-2020Revision dateVersion # 04Health: 3Flammability: 4Physical hazard: 0HMIS? ratings Health: 2Flammability: 4Instability: 0NFPA ratingsNFPA ratings 02 4The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.Disclaimer Physical & Chemical Properties: Multiple PropertiesRevision information 9 / 9Material name: Gunk Brake Parts Cleaner - Non-ChlorinaledM709, M709T Version #: 04 Revision date: 03-30-2020 Issue date: 05-06-2015 SDS US