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M720 19OZ GUNK BRAKE CLEANER - CHLOR 0%
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SAFETY DATA SHEET1. Identification Gunk Brake Parts Cleaner - ChlorinatedProduct identifierOther means of identification M720, M720TSDS number M720, M720TPart No. 2903.23.0000Tariff code Brake CleanerRecommended use None known.Recommended restrictions2. Hazard(s) identification Classification not possibleFlammable aerosolsPhysical hazards Category 2Skin corrosion/irritationHealth hazards Category 2BSerious eye damage/eye irritation Category 1BSensitization, skin Category 1BCarcinogenicity Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 2Specific target organ toxicity, repeatedexposure Category 2Hazardous to the aquatic environment, acutehazardEnvironmental hazards Category 3Hazardous to the aquatic environment,long-term hazardNot classified.OSHA defined hazardsLabel elementsSignal word DangerHazard statement Contains gas under pressure; may explode if heated. Causes skin irritation. May cause an allergicskin reaction. Causes eye irritation. May cause drowsiness or dizziness. May cause cancer. Maycause damage to organs through prolonged or repeated exposure. Toxic to aquatic life. Harmfulto aquatic life with long lasting effects.Precautionary statementPrevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Do not breathe mist or vapor. Wash thoroughly after handling. Use only outdoorsor in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace.Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/faceprotection. 1 / 10Material name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015 SDS USManufacturer/Importer/Supplier/Distributor informationManufacturerCompany nameAddressEmergency phone numberTelephoneWebsite Blaster LLC8500 Sweet Valley Drive Valley View, Ohio 44125 - USA T(216)901-5800F (216)901-5801www.blastercorp.comChemtrec (800) 424-9300 Response If on skin: Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortablefor breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses,if present and easy to do. Continue rinsing. If exposed or concerned: Get medicaladvice/attention. Call a poison center/doctor if you feel unwell. If skin irritation or rash occurs: Getmedical advice/attention. If eye irritation persists: Get medical advice/attention. Take offcontaminated clothing and wash before reuse.Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up.Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC) GHS Level 3 Non-flammable aerosol (version 7 - July 2017)Supplemental information 2.56, 2.56% of the mixture consists of component(s) of unknown acute oral toxicity. 2.56% of themixture consists of component(s) of unknown acute dermal toxicity. 97.44% of the mixtureconsists of component(s) of unknown acute inhalation toxicity.NOTE: This product is a consumer product and is labeled in accordance with the US ConsumerProduct Safety Commission regulations which take precedence over OSHA HazardCommunication labeling. The container label may not include the OSHA label elements listed inthis document. Always carefully review the entire SDS and the product label prior to use in theworkplace.3. Composition/information on ingredientsMixtures CAS number %Chemical name Common name and synonyms 127-18-4Perchloroethylene 90 - 100124-38-9Carbon Dioxide 1 - < 3*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poisoncenter or doctor/physician if you feel unwell.Inhalation Remove contaminated clothing immediately and wash skin with soap and water. In case ofeczema or other skin disorders: Seek medical attention and take along these instructions. Washcontaminated clothing before reuse.Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.Eye contact In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth.Ingestion May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of eyes. Exposedindividuals may experience eye tearing, redness, and discomfort. Skin irritation. May causeredness and pain. May cause an allergic skin reaction. Dermatitis. Rash. Prolonged exposure maycause chronic effects.Most importantsymptoms/effects, acute anddelayed Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.Indication of immediatemedical attention and specialtreatment needed IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice(show the label where possible). Ensure that medical personnel are aware of the material(s)involved, and take precautions to protect themselves. Wash contaminated clothing before reuse.General information5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishingmedia During fire, gases hazardous to health may be formed.Specific hazards arising fromthe chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipmentand precautions for firefighters Containers should be cooled with water to prevent vapor pressure build up.Fire fightingequipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods No unusual fire or explosion hazards noted.General fire hazards 2 / 10SDS USMaterial name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015 6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wearappropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Donot touch damaged containers or spilled material unless wearing appropriate protective clothing.Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot becontained. For personal protection, see section 8 of the SDS.Personal precautions,protective equipment andemergency procedures Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so withoutrisk. Move the cylinder to a safe and open area if the leak is irreparable. Keep combustibles (wood,paper, oil, etc.) away from spilled material. Prevent product from entering drains. Absorb invermiculite, dry sand or earth and place into containers. Following product recovery, flush areawith water.Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination. Put material in suitable, covered, labeled containers. For wastedisposal, see section 13 of the SDS.Methods and materials forcontainment and cleaning up Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground.Environmental precautions7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spraybutton is missing or defective. Do not spray on a naked flame or any other incandescent material.Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,grind, or expose containers to heat, flame, sparks, or other sources of ignition. Ground and bondcontainers when transferring material. Do not re-use empty containers. Avoid contact with eyes,skin, and clothing. Avoid prolonged exposure. Should be handled in closed systems, if possible.Use only in well-ventilated areas. Wear appropriate personal protective equipment. Avoid releaseto the environment. Observe good industrial hygiene practices.Precautions for safe handling Level 1 Aerosol.Store locked up. Contents under pressure. Do not expose to heat or store at temperatures above120?F/49?C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near anopen flame, heat or other sources of ignition. Store in tightly closed container. Keep out of thereach of children. Store away from incompatible materials (see Section 10 of the SDS).Conditions for safe storage,including any incompatibilities8. Exposure controls/personal protectionOccupational exposure limitsThe following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.At this time, the other constituents have no known exposure limits.US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents TypePEL 9000 mg/m3Carbon Dioxide (CAS124-38-9) 5000 ppmUS. OSHA Table Z-2 (29 CFR 1910.1000) ValueComponents TypeCeiling 200 ppmPerchloroethylene (CAS127-18-4) TWA 100 ppmUS. ACGIH Threshold Limit Values ValueComponents TypeSTEL 30000 ppmCarbon Dioxide (CAS124-38-9) TWA 5000 ppmSTEL 100 ppmPerchloroethylene (CAS127-18-4) TWA 25 ppm 3 / 10SDS USMaterial name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015 US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents TypeSTEL 54000 mg/m3Carbon Dioxide (CAS124-38-9) 30000 ppmTWA 9000 mg/m35000 ppmBiological limit valuesACGIH Biological Exposure IndicesValueComponents Determinant Specimen Sampling Time0.5 mg/l Tetrachloroethylene Blood *Perchloroethylene (CAS127-18-4) 3 ppm Tetrachloroethylene End-exhaledair ** - For sampling details, please see the source document.Exposure guidelinesUS - Minnesota Haz Subs: Skin designation appliesPerchloroethylene (CAS 127-18-4) Skin designation applies.Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Provideeyewash station and safety shower.Appropriate engineeringcontrolsIndividual protection measures, such as personal protective equipmentChemical respirator with organic vapor cartridge and full facepiece. Applicable for industrialsettings only.Eye/face protectionSkin protection Wear appropriate chemical resistant gloves. Nitrile gloves are recommended. Applicable forindustrial settings only.Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Applicable for industrial settings only.Other Chemical respirator with organic vapor cartridge and full facepiece. Chemical respirator withorganic vapor cartridge and full facepiece if threshold limits are exceeded. Applicable for industrialsettings only.Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards Observe any medical surveillance requirements. When using do not smoke. Always observe goodpersonal hygiene measures, such as washing after handling the material and before eating,drinking, and/or smoking. Routinely wash work clothing and protective equipment to removecontaminants. Contaminated work clothing should not be allowed out of the workplace.General hygieneconsiderations9. Physical and chemical propertiesClear. LiquidAppearance Liquid.Physical state Aerosol.Form ColorlessColor Sweet chloroform likeOdorOdor threshold Not available.pH Not available.Melting point/freezing point -8.14 ?F (-22.3 ?C) estimatedInitial boiling point and boilingrange 250.34 ?F (121.3 ?C) estimatedFlash point NoneEvaporation rate Not available.Not applicable.Flammability (solid, gas) 4 / 10SDS USMaterial name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015 Upper/lower flammability or explosive limitsFlammability limit - lower(%) Not available. estimatedFlammability limit - upper(%) Not available. estimatedExplosive limit - lower (%) Not available.Explosive limit - upper (%) Not available.Vapor pressure 13 mm Hg @20?CVapor density Not available.Relative density Not available.Solubility(ies)Solubility (water) 530 ppmPartition coefficient(n-octanol/water) Not available.Auto-ignition temperature Not available.Decomposition temperature Not available.Viscosity Not available.Other informationDensity 13.51775 lbs/galNot explosive.Explosive propertiesHeat of combustion (NFPA30B) 1.03 kJ/gNot oxidizing.Oxidizing propertiesPercent volatile 100 %Specific gravity 1.61986VOC 0 % w/w10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardousreactions Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Contact withincompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials Hydrogen chloride.Hazardous decompositionproducts11. Toxicological informationInformation on likely routes of exposureInhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may beharmful.Skin contact Causes skin irritation. May cause an allergic skin reaction.Eye contact Causes eye irritation.Ingestion Expected to be a low ingestion hazard.Symptoms related to thephysical, chemical andtoxicological characteristics May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of eyes. Exposedindividuals may experience eye tearing, redness, and discomfort. Skin irritation. May causeredness and pain. May cause an allergic skin reaction. Dermatitis. Rash.Information on toxicological effectsAcute toxicity Not known. 5 / 10SDS USMaterial name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015 Test ResultsComponents SpeciesPerchloroethylene (CAS 127-18-4)DermalAcuteLD50 Rabbit > 10000 mg/kgLiquidOralLD50 Rat 2400 mg/kgCauses skin irritation.Skin corrosion/irritation Causes eye irritation.Serious eye damage/eyeirritationRespiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.May cause an allergic skin reaction.Skin sensitization No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicityCarcinogenicity May cause cancer.IARC Monographs. Overall Evaluation of CarcinogenicityPerchloroethylene (CAS 127-18-4) 2A Probably carcinogenic to humans.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Not regulated.US. National Toxicology Program (NTP) Report on CarcinogensPerchloroethylene (CAS 127-18-4) Reasonably Anticipated to be a Human Carcinogen.This product is not expected to cause reproductive or developmental effects.Reproductive toxicitySpecific target organ toxicity -single exposure May cause drowsiness and dizziness.Specific target organ toxicity -repeated exposure May cause damage to organs through prolonged or repeated exposure.Aspiration hazard Not an aspiration hazard.Chronic effects May cause damage to organs through prolonged or repeated exposure. Prolonged inhalation maybe harmful. Prolonged exposure may cause chronic effects.12. Ecological information Toxic to aquatic life. Harmful to aquatic life with long lasting effects.EcotoxicityComponents Test ResultsSpeciesPerchloroethylene (CAS 127-18-4)Aquatic EC50Crustacea 6.1 - 9 mg/l, 48 hoursWater flea (Daphnia magna)LC50Fish 4.82 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)No data is available on the degradability of any ingredients in the mixture.Persistence and degradabilityBioaccumulative potentialPartition coefficient n-octanol / water (log Kow)Perchloroethylene 3.4No data available.Mobility in soilOther adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creationpotential, endocrine disruption, global warming potential) are expected from this component.13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. Contentsunder pressure. Do not puncture, incinerate or crush. Incinerate the material under controlledconditions in an approved incinerator. Do not allow this material to drain into sewers/watersupplies. Do not contaminate ponds, waterways or ditches with chemical or used container.Dispose of contents/container in accordance with local/regional/national/international regulations.Disposal instructions 6 / 10SDS USMaterial name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015 Dispose in accordance with all applicable regulations.Local disposal regulations D039: Waste TetrachloroethyleneThe waste code should be assigned in discussion between the user, the producer and the wastedisposal company.Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).Waste from residues / unusedproducts Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal. Do not re-use empty containers.Contaminated packaging14. Transport informationDOT UN1950UN number Aerosols, non-flammable, (each not exceeding 1 L capacity), MARINE POLLUTANT(Perchloroethylene), Limited QuantityUN proper shipping name 2.2ClassTransport hazard class(es) -Subsidiary risk 2.2Label(s) Not available.Packing group YesMarine pollutantEnvironmental hazards Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 306Packaging exceptions NonePackaging non bulk NonePackaging bulkIATA UN1950UN number Aerosols, non-flammable, Limited QuantityUN proper shipping name 2.2ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group YesEnvironmental hazards 2LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed with restrictions.Passenger and cargoaircraftOther information Allowed with restrictions.Cargo aircraft onlyIMDG UN1950UN number AEROSOLS, MARINE POLLUTANT (Perchloroethylene), Limited QuantityUN proper shipping name 2ClassTransport hazard class(es) 6.1(PGIII)Subsidiary risk Not available.Packing group YesMarine pollutantEnvironmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for userPerchloroethylene Not established.Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC Code 7 / 10SDS USMaterial name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015 DOTIATAIMDGMarine pollutant IMDG Regulated Marine Pollutant.General information15. Regulatory informationThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulationsTSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Not regulated.CERCLA Hazardous Substance List (40 CFR 302.4)Perchloroethylene (CAS 127-18-4) Listed.SARA 304 Emergency release notificationNot regulated.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Not regulated.SARA 302 Extremely hazardous substanceSuperfund Amendments and Reauthorization Act of 1986 (SARA)Not listed. 8 / 10SDS USMaterial name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015 No (Exempt)SARA 311/312 HazardouschemicalSARA 313 (TRI reporting)Chemical name % by wt.CAS numberPerchloroethylene 90 - 100127-18-4Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListPerchloroethylene (CAS 127-18-4)Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Not regulated. Not regulated.Safe Drinking Water Act(SDWA)US state regulationsCalifornia Proposition 65 This product can expose you to Perchloroethylene, which is known to the State of California tocause cancer. For more information go to www.P65Warnings.ca.gov.WARNING:California Proposition 65 - CRT: Listed date/Carcinogenic substancePerchloroethylene (CAS 127-18-4) Listed: April 1, 1988US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,subd. (a))Perchloroethylene (CAS 127-18-4)International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) YesJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS) YesTaiwan Taiwan Chemical Substance Inventory (TCSI) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).16. Other information, including date of preparation or last revision04-24-2015Issue dateRevision dateVersion #HMIS? ratings 12-14-202213Health: 2* Flammability: 0 Physical hazard: 0Health: 2 Flammability: 0 Instability: 0NFPA ratings 9 / 10SDS USMaterial name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015 NFPA ratings 02 0The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.Disclaimer 10 / 10SDS USMaterial name: Gunk Brake Parts Cleaner - ChlorinatedM720, M720T Version #: 13 Revision date: 12-14-22 Issue date: 04-24-2015