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M914 11OZ LIQUID WRENCH SILICONE SPRAY
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SAFETY DATA SHEET1. Identification Liquid Wrench Silicone SprayProduct identifierOther means of identification M914SDS number M914, M914/4, M914/6Part No. 3403.19.1000Tariff code LubricantRecommended use None known.Recommended restrictionsManufacturer/Importer/Supplier/Distributor informationManufacturerAddressCompany nameEmergency phone number Chem (United States) (800) 255-3924INFOTRAC (International) (352) 323-3500TelephoneWebsite www.blastercorp.com Blaster LLC8500 Sweet Valley DriveValley View, Ohio 44125 - USAT (216) 901-5800 - F (216) 901-58012. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Category 2Skin corrosion/irritationHealth hazards Category 2ASerious eye damage/eye irritation Category 1AReproductive toxicity Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 1Aspiration hazard Category 1Hazardous to the aquatic environment, acutehazardEnvironmental hazards Category 1Hazardous to the aquatic environment,long-term hazardNot classified.OSHA defined hazardsLabel elementsSignal word DangerHazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal ifswallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May causedrowsiness or dizziness. May damage fertility or the unborn child. Very toxic to aquatic life. Verytoxic to aquatic life with long lasting effects.Precautionary statementPrevention Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do notspray on an open flame or other ignition source. Pressurized container: Do not pierce or burn,even after use. Avoid breathing mist/vapor. Wash thoroughly after handling. Use only outdoors orin a well-ventilated area. Avoid release to the environment. Wear protective gloves/protectiveclothing/eye protection/face protection. 1 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If on skin: Washwith plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. Ifin eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present andeasy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poisoncenter/doctor if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eyeirritation persists: Get medical advice/attention. Take off contaminated clothing and wash beforereuse. Collect spillage.Storage Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect fromsunlight. Do not expose to temperatures exceeding 50?C/122?F.Disposal Dispose of contents/container in accordance with local/regional/national/international regulations.Hazard(s) not otherwiseclassified (HNOC) Combustible.Supplemental information NOTE: This product is a consumer product and is labeled in accordance with the US ConsumerProduct Safety Commission regulations which take precedence over OSHA HazardCommunication labeling. The container label may not include the OSHA label elements listed inthis document. Always carefully review the entire SDS and the product label prior to use in theworkplace.3. Composition/information on ingredientsMixtures CAS number %Chemical name Common name and synonyms 64742-47-8ISOPARAFFINIC PETROLEUMDISTILLATE 30 - < 40(8052-41-3 and/or 64742-88-7 and /or64742-48-9) Trade SecretLight Aromatic Hydrocarbon 30 - < 4095-63-61,2,4-Trimethylbenzene 3 - < 563148-62-9Dimethicone 3 - < 564742-52-5Distillates (petroleum),Hydrotreated Heavy Naphthenic 3 - < 5111-84-2Nonane 3 - < 525551-13-7Trimethylbenzene 3 - < 51330-20-7Xylene 3 - < 5124-38-9Carbon Dioxide 1 - < 398-82-8Cumene 1 - < 3100-41-4Ethylbenzene 1 - < 3110-54-3Hexane 1 - < 3108-88-3Toluene 1 - < 371-43-2Benzene < 1< 1Other components below reportable levels 91-20-3Naphthalene < 1*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.4. First-aid measures Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poisoncenter or doctor/physician if you feel unwell.Inhalation Remove contaminated clothing. Wash with plenty of soap and water. If skin irritation occurs: Getmedical advice/attention. Wash contaminated clothing before reuse.Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, ifpresent and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.Eye contact Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. Ifvomiting occurs, keep head low so that stomach content doesn't get into the lungs.Ingestion Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.Most importantsymptoms/effects, acute anddelayed Provide general supportive measures and treat symptomatically. Keep victim under observation.Symptoms may be delayed.Indication of immediatemedical attention and specialtreatment needed 2 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice(show the label where possible). Ensure that medical personnel are aware of the material(s)involved, and take precautions to protect themselves. Show this safety data sheet to the doctor inattendance.General information5. Fire-fighting measures Alcohol resistant foam. Powder. Dry chemicals. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishingmedia Contents under pressure. Pressurized container may explode when exposed to heat or flame.During fire, gases hazardous to health may be formed.Specific hazards arising fromthe chemical Firefighters must use standard protective equipment including flame retardant coat, helmet withface shield, gloves, rubber boots, and in enclosed spaces, SCBA.Special protective equipmentand precautions for firefighters Move containers from fire area if you can do so without risk. Cool containers exposed to heat withwater spray and remove container, if no risk is involved. Containers should be cooled with water toprevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder ormonitor nozzles, if possible. If not, withdraw and let fire burn out.Fire fightingequipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials. Movecontainers from fire area if you can do so without risk. In the event of fire and/or explosion do notbreathe fumes.Specific methods Extremely flammable aerosol. Combustible.General fire hazards6. Accidental release measuresKeep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wearappropriate protective equipment and clothing during clean-up. Avoid breathing mist/vapor. Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing.Ventilate closed spaces before entering them. Local authorities should be advised if significantspillages cannot be contained. For personal protection, see section 8 of the SDS.Personal precautions,protective equipment andemergency procedures Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so withoutrisk. Move the cylinder to a safe and open area if the leak is irreparable. Use water spray to reducevapors or divert vapor cloud drift. Eliminate all ignition sources (no smoking, flares, sparks, orflames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material.The product is immiscible with water and will spread on the water surface. Prevent entry intowaterways, sewer, basements or confined areas. Absorb in vermiculite, dry sand or earth andplace into containers. Following product recovery, flush area with water.Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly toremove residual contamination. For waste disposal, see section 13 of the SDS.Methods and materials forcontainment and cleaning up Avoid release to the environment. Inform appropriate managerial or supervisory personnel of allenvironmental releases. Prevent further leakage or spillage if safe to do so. Avoid discharge intodrains, water courses or onto the ground.Environmental precautions7. Handling and storage Obtain special instructions before use. Do not handle until all safety precautions have been readand understood. Pressurized container: Do not pierce or burn, even after use. Do not use if spraybutton is missing or defective. Do not spray on a naked flame or any other incandescent material.Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill,grind, or expose containers to heat, flame, sparks, or other sources of ignition. All equipment usedwhen handling the product must be grounded. Do not re-use empty containers. Avoid contact witheyes, skin, and clothing. Avoid prolonged or repeated contact with skin. Avoid prolonged exposure.Pregnant or breastfeeding women must not handle this product. Should be handled in closedsystems, if possible. Use only in well-ventilated areas. Wear appropriate personal protectiveequipment. Wash hands thoroughly after handling. Avoid release to the environment. Observegood industrial hygiene practices.Precautions for safe handling Level 3 Aerosol.Store locked up. Pressurized container. Protect from sunlight and do not expose to temperaturesexceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an openflame, heat or other sources of ignition. This material can accumulate static charge which maycause spark and become an ignition source. Store in tightly closed container. Store away fromincompatible materials (see Section 10 of the SDS).Conditions for safe storage,including any incompatibilities 3 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US 8. Exposure controls/personal protectionOccupational exposure limitsThe following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit.At this time, the other constituents have no known exposure limits.US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) ValueComponents TypeSTEL 5 ppmBenzene (CAS 71-43-2) TWA 1 ppmUS. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) FormValueComponents TypePEL 9000 mg/m3Carbon Dioxide (CAS124-38-9) 5000 ppmPEL 245 mg/m3Cumene (CAS 98-82-8) 50 ppmPEL 5 mg/m3 Mist.Distillates (petroleum),Hydrotreated HeavyNaphthenic (CAS64742-52-5) 2000 mg/m3500 ppmPEL 435 mg/m3Ethylbenzene (CAS100-41-4) 100 ppmPEL 1800 mg/m3Hexane (CAS 110-54-3) 500 ppmPEL 400 mg/m3ISOPARAFFINICPETROLEUM DISTILLATE(CAS 64742-47-8) 100 ppmPEL 50 mg/m3Naphthalene (CAS 91-20-3) 10 ppmPEL 435 mg/m3Xylene (CAS 1330-20-7) 100 ppmUS. OSHA Table Z-2 (29 CFR 1910.1000) ValueComponents TypeCeiling 25 ppmBenzene (CAS 71-43-2) TWA 10 ppmCeiling 300 ppmToluene (CAS 108-88-3) TWA 200 ppmUS. ACGIH Threshold Limit Values FormValueComponents TypeTWA 25 ppm1,2,4-Trimethylbenzene(CAS 95-63-6) STEL 2.5 ppmBenzene (CAS 71-43-2) TWA 0.5 ppmSTEL 30000 ppmCarbon Dioxide (CAS124-38-9) TWA 5000 ppmTWA 50 ppmCumene (CAS 98-82-8) 4 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US US. ACGIH Threshold Limit Values FormValueComponents TypeTWA 5 mg/m3 Inhalable fraction.Distillates (petroleum),Hydrotreated HeavyNaphthenic (CAS64742-52-5) TWA 20 ppmEthylbenzene (CAS100-41-4) TWA 50 ppmHexane (CAS 110-54-3) TWA 10 ppmNaphthalene (CAS 91-20-3) TWA 200 ppmNonane (CAS 111-84-2) TWA 20 ppmToluene (CAS 108-88-3) TWA 25 ppmTrimethylbenzene (CAS25551-13-7) STEL 150 ppmXylene (CAS 1330-20-7) TWA 100 ppmUS. NIOSH: Pocket Guide to Chemical Hazards FormValueComponents TypeTWA 125 mg/m31,2,4-Trimethylbenzene(CAS 95-63-6) 25 ppmSTEL 1 ppmBenzene (CAS 71-43-2) TWA 0.1 ppmSTEL 54000 mg/m3Carbon Dioxide (CAS124-38-9) 30000 ppmTWA 9000 mg/m35000 ppmTWA 245 mg/m3Cumene (CAS 98-82-8) 50 ppmCeiling 1800 mg/m3Distillates (petroleum),Hydrotreated HeavyNaphthenic (CAS64742-52-5) STEL 10 mg/m3 Mist.STEL 545 mg/m3Ethylbenzene (CAS100-41-4) 125 ppmTWA 435 mg/m3100 ppmTWA 180 mg/m3Hexane (CAS 110-54-3) 50 ppmSTEL 75 mg/m3Naphthalene (CAS 91-20-3) 15 ppmTWA 50 mg/m310 ppmTWA 1050 mg/m3Nonane (CAS 111-84-2) 200 ppmSTEL 560 mg/m3Toluene (CAS 108-88-3) 150 ppmTWA 375 mg/m3100 ppm 5 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US US. NIOSH: Pocket Guide to Chemical Hazards FormValueComponents TypeTWA 125 mg/m3Trimethylbenzene (CAS25551-13-7) 25 ppmSTEL 655 mg/m3Xylene (CAS 1330-20-7) 150 ppmTWA 435 mg/m3100 ppmBiological limit valuesACGIH Biological Exposure IndicesValueComponents Determinant Specimen Sampling Time25 ?g/g S-Phenylmercapturic acid Creatinine inurine *Benzene (CAS 71-43-2) 0.15 g/g Sum ofmandelic acidandphenylglyoxylicacid Creatinine inurine *Ethylbenzene (CAS100-41-4) 0.4 mg/l 2,5-Hexanedione, withouthydrolysis Urine *Hexane (CAS 110-54-3) 0.3 mg/g o-Cresol, withhydrolysis Creatinine inurine *Toluene (CAS 108-88-3) 0.03 mg/l Toluene Urine *0.02 mg/l Toluene Blood *1.5 g/g Methylhippuricacids Creatinine inurine *Xylene (CAS 1330-20-7)* - For sampling details, please see the source document.Exposure guidelinesUS - California OELs: Skin designationBenzene (CAS 71-43-2) Can be absorbed through the skin.Cumene (CAS 98-82-8) Can be absorbed through the skin.Hexane (CAS 110-54-3) Can be absorbed through the skin.Naphthalene (CAS 91-20-3) Can be absorbed through the skin.Toluene (CAS 108-88-3) Can be absorbed through the skin.US - Minnesota Haz Subs: Skin designation appliesCumene (CAS 98-82-8) Skin designation applies.Toluene (CAS 108-88-3) Skin designation applies.US - Tennessee OELs: Skin designationCumene (CAS 98-82-8) Can be absorbed through the skin.US ACGIH Threshold Limit Values: Skin designationBenzene (CAS 71-43-2) Can be absorbed through the skin.Hexane (CAS 110-54-3) Can be absorbed through the skin.Naphthalene (CAS 91-20-3) Can be absorbed through the skin.US NIOSH Pocket Guide to Chemical Hazards: Skin designationCumene (CAS 98-82-8) Can be absorbed through the skin.US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)Cumene (CAS 98-82-8) Can be absorbed through the skin.Good general ventilation (typically 10 air changes per hour) should be used. Ventilation ratesshould be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,or other engineering controls to maintain airborne levels below recommended exposure limits. Ifexposure limits have not been established, maintain airborne levels to an acceptable level. Provideeyewash station and safety shower.Appropriate engineeringcontrolsIndividual protection measures, such as personal protective equipmentChemical respirator with organic vapor cartridge and full facepiece.Eye/face protection 6 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US Skin protection Wear appropriate chemical resistant gloves.Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other Chemical respirator with organic vapor cartridge and full facepiece. Chemical respirator withorganic vapor cartridge and full facepiece if threshold limits are exceeded.Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards Observe any medical surveillance requirements. When using do not smoke. Always observe goodpersonal hygiene measures, such as washing after handling the material and before eating,drinking, and/or smoking. Routinely wash work clothing and protective equipment to removecontaminants.General hygieneconsiderations9. Physical and chemical propertiesClear. LiquidAppearance Liquid.Physical state Aerosol.Form Pale yellowColor PetroleumOdorOdor threshold Not available.pH Not available.Melting point/freezing point -49 ?F (-45 ?C) estimatedInitial boiling point and boilingrange 329.63 ?F (165.35 ?C) estimatedFlash point 117.0 ?F (47.2 ?C)Evaporation rate Not available.Not applicable.Flammability (solid, gas)Upper/lower flammability or explosive limitsFlammability limit - lower(%) 0.7 % estimatedFlammability limit - upper(%) 5 % estimatedExplosive limit - lower (%) Not available.Explosive limit - upper (%) Not available.Vapor pressure 2.75254 hPa estimatedVapor density Not available.Relative density Not available.Solubility(ies)Solubility (water) InsolublePartition coefficient(n-octanol/water) Not available.Auto-ignition temperature 271.84 ?F (133.25 ?C) estimatedDecomposition temperature Not available.Viscosity Not available.Other informationDensity 6.8 lbs/galNot explosive.Explosive propertiesFlammability (flash back) NoFlammability class Combustible II estimatedHeat of combustion (NFPA30B) 38.3 kJ/g estimatedMoisture < 0.03 %Not oxidizing.Oxidizing propertiesRefractive index 1.44 7 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US Specific gravity 0.816VOC 56.85 % estimated10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability Hazardous polymerization does not occur.Possibility of hazardousreactions Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Avoidtemperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoid Strong acids. Strong oxidizing agents. Halogens.Incompatible materials No hazardous decomposition products are known.Hazardous decompositionproducts11. Toxicological informationInformation on likely routes of exposureInhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may beharmful.Skin contact Causes skin irritation.Eye contact Causes serious eye irritation.Ingestion Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a seriouschemical pneumonia.Symptoms related to thephysical, chemical andtoxicological characteristics Aspiration may cause pulmonary edema and pneumonitis. May cause drowsiness and dizziness.Headache. Nausea, vomiting. Severe eye irritation. Symptoms may include stinging, tearing,redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.Information on toxicological effectsAcute toxicity May be fatal if swallowed and enters airways. Test ResultsComponents Species1,2,4-Trimethylbenzene (CAS 95-63-6)DermalAcuteLD50 Rabbit > 3160 mg/kgOralLD50 Rat 6 g/kgBenzene (CAS 71-43-2)OralAcuteLD50 Rat 3306 mg/kg690 - 1230 mg/kgCumene (CAS 98-82-8)DermalAcuteLD50 Rabbit > 3160 mg/kg, 24 HoursInhalationLC50 Mouse 10 mg/l, 7 HoursVaporOralLD50 Rat 2260 mg/kgDistillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5)DermalAcuteLD50 Rabbit > 2000 mg/kg, 24 Hours 8 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US Test ResultsComponents SpeciesInhalationLC50 Rat > 3.9 mg/l, 4 HoursOralLD50 Rat > 2000 mg/kgEthylbenzene (CAS 100-41-4)OralAcuteLD50 Rat 3500 mg/kgHexane (CAS 110-54-3)DermalAcuteLD50 Rabbit > 2000 mg/kg, 4 HoursInhalationLC50 Rat > 31.86 mg/l, 4 HoursVaporOralLD50 Rat 28710 mg/kgLight Aromatic HydrocarbonDermalAcuteLD50 Rabbit > 2000 mg/kgLiquidOralLD50 Rat > 5000 mg/kgLiquidNaphthalene (CAS 91-20-3)DermalAcuteLD50 Rabbit > 2 g/kgOralLD50 Rat 490 mg/kgToluene (CAS 108-88-3)DermalAcuteLD50 Rabbit > 5000 mg/kg, 24 HoursInhalationLC50 Rat 12.5 - 28.8 mg/l, 4 HoursOralLD50 Rat 2.6 g/kgTrimethylbenzene (CAS 25551-13-7)OralAcuteLD50 Rat 8970 mg/kgXylene (CAS 1330-20-7)DermalAcuteLD50 Rabbit 12130 mg/kg, 24 HoursInhalationLC50 Rat 6350 mg/l, 4 Hours 9 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US Test ResultsComponents SpeciesOralLD50 Rat 3523 - 8600 mg/kgCauses skin irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eyeirritationRespiratory or skin sensitizationRespiratory sensitization Not a respiratory sensitizer.This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% aremutagenic or genotoxic.Germ cell mutagenicityCarcinogenicity Risk of cancer cannot be excluded with prolonged exposure.IARC Monographs. Overall Evaluation of CarcinogenicityBenzene (CAS 71-43-2) 1 Carcinogenic to humans.Cumene (CAS 98-82-8) 2B Possibly carcinogenic to humans.Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans.Naphthalene (CAS 91-20-3) 2B Possibly carcinogenic to humans.Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans.Xylene (CAS 1330-20-7) 3 Not classifiable as to carcinogenicity to humans.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Benzene (CAS 71-43-2) CancerUS. National Toxicology Program (NTP) Report on CarcinogensBenzene (CAS 71-43-2) Known To Be Human Carcinogen.Cumene (CAS 98-82-8) Reasonably Anticipated to be a Human Carcinogen.Naphthalene (CAS 91-20-3) Reasonably Anticipated to be a Human Carcinogen.Components in this product have been shown to cause birth defects and reproductive disorders inlaboratory animals. May damage fertility or the unborn child.Reproductive toxicitySpecific target organ toxicity -single exposure May cause drowsiness and dizziness.Specific target organ toxicity -repeated exposure Not classified.Aspiration hazard May be fatal if swallowed and enters airways.Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects.12. Ecological information Very toxic to aquatic life with long lasting effects.EcotoxicityComponents Test ResultsSpecies1,2,4-Trimethylbenzene (CAS 95-63-6)Aquatic LC50Fish 7.19 - 8.28 mg/l, 96 hoursFathead minnow (Pimephales promelas)Benzene (CAS 71-43-2)Aquatic EC50Crustacea 8.76 - 15.6 mg/l, 48 hoursWater flea (Daphnia magna)LC50Fish 7.2 - 11.7 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)Cumene (CAS 98-82-8)Aquatic EC50Crustacea 3.55 - 11.29 mg/l, 48 hoursBrine shrimp (Artemia sp.)LC50Fish 2.7 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)Dimethicone (CAS 63148-62-9)Aquatic LC50Fish 2.36 - 4.15 mg/l, 96 hoursChannel catfish (Ictalurus punctatus) 10 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US Components Test ResultsSpeciesEthylbenzene (CAS 100-41-4)Aquatic EC50Crustacea 1.37 - 4.4 mg/l, 48 hoursWater flea (Daphnia magna)LC50Fish 7.5 - 11 mg/l, 96 hoursFathead minnow (Pimephales promelas)Hexane (CAS 110-54-3)Aquatic LC50Fish 2.101 - 2.981 mg/l, 96 hoursFathead minnow (Pimephales promelas)ISOPARAFFINIC PETROLEUM DISTILLATE (CAS 64742-47-8)Aquatic EC50Crustacea 2.7 - 5.1 mg/l, 48 hoursWater flea (Daphnia pulex)LC50Fish 2.9 mg/l, 96 hoursRainbow trout,donaldson trout(Oncorhynchus mykiss)Naphthalene (CAS 91-20-3)Aquatic EC50Crustacea 1.09 - 3.4 mg/l, 48 hoursWater flea (Daphnia magna)LC50Fish 1.11 - 1.68 mg/l, 96 hoursPink salmon (Oncorhynchus gorbuscha)Toluene (CAS 108-88-3)Aquatic EC50Crustacea 5.46 - 9.83 mg/l, 48 hoursWater flea (Daphnia magna)LC50Fish 8.11 mg/l, 96 hoursCoho salmon,silver salmon(Oncorhynchus kisutch)Xylene (CAS 1330-20-7)Aquatic LC50Fish 7.711 - 9.591 mg/l, 96 hoursBluegill (Lepomis macrochirus)No data is available on the degradability of any ingredients in the mixture.Persistence and degradabilityBioaccumulative potentialPartition coefficient n-octanol / water (log Kow)Benzene 2.13Cumene 3.66Ethylbenzene 3.15Hexane 3.9Naphthalene 3.3Nonane 5.46Toluene 2.73Xylene 3.12 - 3.2No data available.Mobility in soilOther adverse effects The product contains volatile organic compounds which have a photochemical ozone creationpotential.13. Disposal considerationsCollect and reclaim or dispose in sealed containers at licensed waste disposal site. Contentsunder pressure. Do not puncture, incinerate or crush. Incinerate the material under controlledconditions in an approved incinerator. Do not allow this material to drain into sewers/watersupplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Ifdiscarded, this product is considered a RCRA ignitable waste, D001. Dispose ofcontents/container in accordance with local/regional/national/international regulations.Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations D001: Waste Flammable material with a flash point <140 FD018: Waste BenzeneThe waste code should be assigned in discussion between the user, the producer and the wastedisposal company.Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain someproduct residues. This material and its container must be disposed of in a safe manner (see:Disposal instructions).Waste from residues / unusedproducts 11 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US Since emptied containers may retain product residue, follow label warnings even after container isemptied. Empty containers should be taken to an approved waste handling site for recycling ordisposal. Do not re-use empty containers.Contaminated packaging14. Transport informationDOT UN1950UN number Aerosols, flammable, (each not exceeding 1 L capacity), Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk 2.1Label(s) Not available.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulkIATA UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group YesEnvironmental hazards 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed with restrictions.Passenger and cargoaircraftOther information Allowed with restrictions.Cargo aircraft onlyIMDG UN1950UN number Aerosols, MARINE POLLUTANT (Petroleum distillates)UN proper shipping name 2.1ClassTransport hazard class(es) -Subsidiary risk Not available.Packing group YesMarine pollutantEnvironmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for userPetroleum distillates Not established.Transport in bulk according toAnnex II of MARPOL 73/78 andthe IBC CodeDOT 12 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US IATAIMDGMarine pollutant IMDG Regulated Marine Pollutant.General information15. Regulatory informationThis product is a "Hazardous Chemical" as defined by the OSHA Hazard CommunicationStandard, 29 CFR 1910.1200.US federal regulationsTSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)Nonane (CAS 111-84-2) 1.0 % One-Time Export Notification only.CERCLA Hazardous Substance List (40 CFR 302.4)Benzene (CAS 71-43-2) Listed.Cumene (CAS 98-82-8) Listed.Ethylbenzene (CAS 100-41-4) Listed.Hexane (CAS 110-54-3) Listed.Naphthalene (CAS 91-20-3) Listed.Nonane (CAS 111-84-2) Listed.Toluene (CAS 108-88-3) Listed.Xylene (CAS 1330-20-7) Listed.SARA 304 Emergency release notificationNot regulated.OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052)Benzene (CAS 71-43-2) CancerCentral nervous systemBloodAspirationSkinEyerespiratory tract irritationFlammability 13 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US SARA 302 Extremely hazardous substanceSuperfund Amendments and Reauthorization Act of 1986 (SARA)Not listed. YesSARA 311/312 Hazardouschemical Flammable (gases, aerosols, liquids, or solids)Skin corrosion or irritationSerious eye damage or eye irritationGerm cell mutagenicityReproductive toxicitySpecific target organ toxicity (single or repeated exposure)Aspiration hazardClassified hazardcategoriesSARA 313 (TRI reporting)Chemical name % by wt.CAS number1,2,4-Trimethylbenzene 3 - < 595-63-6Benzene < 171-43-2Cumene 1 - < 398-82-8Ethylbenzene 1 - < 3100-41-4Hexane 1 - < 3110-54-3Naphthalene < 191-20-3Toluene 1 - < 3108-88-3Xylene 3 - < 51330-20-7Other federal regulationsClean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) ListBenzene (CAS 71-43-2)Cumene (CAS 98-82-8)Ethylbenzene (CAS 100-41-4)Hexane (CAS 110-54-3)Naphthalene (CAS 91-20-3)Toluene (CAS 108-88-3)Xylene (CAS 1330-20-7)Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)Not regulated. Not regulated.Safe Drinking Water Act(SDWA)Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) andChemical Code NumberToluene (CAS 108-88-3) 6594Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c))Toluene (CAS 108-88-3) 35 %WVDEA Exempt Chemical Mixtures Code NumberToluene (CAS 108-88-3) 594US state regulationsCalifornia Proposition 65 This product can expose you to chemicals including ethylbenzene, which are known to the State ofCalifornia to cause cancer, and toluene, which is known to the State of California to cause birthdefects or other reproductive harm. For more information go to www.P65Warnings.ca.gov.WARNING:California Proposition 65 - CRT: Listed date/Carcinogenic substanceBenzene (CAS 71-43-2) Listed: February 27, 1987Cumene (CAS 98-82-8) Listed: April 6, 2010Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004Naphthalene (CAS 91-20-3) Listed: April 19, 2002California Proposition 65 - CRT: Listed date/Developmental toxinBenzene (CAS 71-43-2) Listed: December 26, 1997Toluene (CAS 108-88-3) Listed: January 1, 1991California Proposition 65 - CRT: Listed date/Male reproductive toxinBenzene (CAS 71-43-2) Listed: December 26, 1997 14 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 010 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3,subd. (a))1,2,4-Trimethylbenzene (CAS 95-63-6)Benzene (CAS 71-43-2)Cumene (CAS 98-82-8)Distillates (petroleum), Hydrotreated Heavy Naphthenic (CAS 64742-52-5)Ethylbenzene (CAS 100-41-4)Hexane (CAS 110-54-3)Naphthalene (CAS 91-20-3)Toluene (CAS 108-88-3)Trimethylbenzene (CAS 25551-13-7)Xylene (CAS 1330-20-7)International InventoriesCountry(s) or region Inventory name On inventory (yes/no)*NoAustralia Australian Inventory of Chemical Substances (AICS) NoCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial ChemicalSubstances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances(PICCS) NoTaiwan Taiwan Chemical Substance Inventory (TCSI) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governingcountry(s).16. Other information, including date of preparation or last revision06-01-2015Issue dateRevision dateVersion #HMIS? ratings 03-04-202310Health: 3* Flammability: 4 Physical hazard: 0Health: 2 Flammability: 4 Instability: 0NFPA ratingsNFPA ratings 02 4The information provided in this Safety Data Sheet is correct to the best of our knowledge,information and belief at the date of its publication. The information given is designed only as aguidance for safe handling, use, processing, storage, transportation, disposal and release and isnot to be considered a warranty or quality specification. The information relates only to the specificmaterial designated and may not be valid for such material used in combination with any othermaterials or in any process, unless specified in the text.Disclaimer Physical & Chemical Properties: Multiple PropertiesRevision information 15 / 15Material name: Liquid Wrench Silicone SprayM914, M914/4, M914/6 Version #: 10 Revision date: 03-04-2023 Issue date: 06-01-2015 SDS US