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Axalta
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Cromax® Pro Mixing Color Transoxide Red WB91
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SDS_WB91_CRMX_US_en.pdf
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Cromax? Pro Mixing Color Transoxide Red 1250013656; 1250064397 (CHEMTREC) - 800-424-9300 SAFETY DATA SHEET Product identifier Other means of identification Emergency telephone number Section 1. Identification : : : Supplier's details : Axalta Coating Systems, LLC 50 Applied Bank Blvd. Suite 300 Glen Mills, PA 19342 USA Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against Product name : WB91 Coating component. Not for sale to or use by consumers. Product information 855-6AXALTA : : Date of issue Version : : 8/1/2022 8.01 ENGLISHUS : Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 4 EYE IRRITATION - Category 2A Classification of the substance or mixture : Signal word : Warning Hazard statements : H227 - Combustible liquid. H319 - Causes serious eye irritation. Hazard pictograms : Precautionary statements Prevention : P280 - Wear eye or face protection. P210 - Keep away from flames and hot surfaces. No smoking. Response : P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P337 + P313 - If eye irritation persists: Get medical advice or attention. Storage : P403 + P235 - Store in a well-ventilated place. Keep cool. GHS label elements OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue : 8/1/2022 Version : 8.01 1/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : Section 2. Hazards identification Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients 2-butoxyethanol ?3 111-76-2 2-amino-2-methylpropanol <3 124-68-5 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Substance/mixture : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention if adverse health effects persist or are severe. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Potential acute health effects Date of issue : 8/1/2022 Version : 8.01 2/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Combustible liquid. In a fire or if heated, a pressure increase will occur and the container may burst. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media : : : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue : 8/1/2022 Version : 8.01 3/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store between the following temperatures: 5 to 35?C (41 to 95?F). Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Do not ingest. Avoid contact with eyes, skin and clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Storage code IIIA: Date of issue : 8/1/2022 Version : 8.01 4/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : 2-butoxyethanol ACGIH TLV (United States, 1/2021). TWA: 20 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. TWA: 25 ppm 8 hours. TWA: 120 mg/m? 8 hours. NIOSH REL (United States, 10/2020). Absorbed through skin. TWA: 5 ppm 10 hours. TWA: 24 mg/m? 10 hours. OSHA PEL (United States, 5/2018). Absorbed through skin. TWA: 50 ppm 8 hours. TWA: 240 mg/m? 8 hours. 2-amino-2-methylpropanol None. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Date of issue : 8/1/2022 Version : 8.01 5/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : Section 8. Exposure controls/personal protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respiratory protection : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Density Vapor density Solubility Liquid. Not applicable. 1.091 g/cm? Not available. 2.4 kPa (18.3 mm Hg) Soluble in the following materials: cold water. Not available.Odor pH Red.Color Evaporation rate Not available. Auto-ignition temperature Flash point 207?C (404.6?F) Closed cup: 80?C (176?F) [Product does not sustain combustion.] Not applicable. 8.3 to 8.5 Viscosity Dynamic (room temperature): 119 mPa?s (119 cP) Kinematic (room temperature): 109 mm2/s (109 cSt) Kinematic (40?C (104?F)): 0 mm2/s (0 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Boiling point : 100 to 100.1?C (212 to 212.2?F) Flammability (solid, gas) : Not available. Decomposition temperature : Not applicable. Flow time (ISO 2431) : 81 s (room temperature) [Jet diameter: 4 mm] Appearance Lower and upper explosive (flammable) limits : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue : 8/1/2022 Version : 8.01 6/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : Section 11. Toxicological information Acute toxicity 2-butoxyethanol LD50 Dermal Rat 2010 mg/kg - LD50 Oral Rat 917 mg/kg - 2-amino-2-methylpropanol LD50 Oral Rat 2900 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion 2-butoxyethanol Eyes - Moderate irritant Rabbit - 24 hours 100 mg - Skin - Mild irritant Rabbit - 500 mg - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : No known significant effects or critical hazards. Causes serious eye irritation.:Eye contact Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Information on toxicological effects : Not available. Potential acute health effects Classification 2-butoxyethanol - 3 - Product/ingredient name NTPIARCOSHA Date of issue : 8/1/2022 Version : 8.01 7/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : Section 11. Toxicological information Not available. No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 57713.02 mg/kg Dermal 86805.56 mg/kg Inhalation (vapors) 868.06 mg/l Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information There are no data available on the product itself. The product should not be allowed to enter drains or watercourses waterways. Date of issue : 8/1/2022 Version : 8.01 8/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : - - - - - - - Not regulated. - - Not regulated. Not regulated. DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. No. No. TDG Classification Not regulated. - - - No. Mexico Classification Not regulated. - - - No. The actual shipping description for this product may vary based several factors including, but not limited to, the volume of material, size of the container, mode of transport and use of exemptions or exceptions found in the applicable regulations. The information provided in Section 14 is one possible shipping description for this product. Consult your shipping specialist or supplier for appropriate assignment information. Section 15. Regulatory information Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Not listed SARA 304 RQ SARA 304 RQ : Not applicable. SARA 311/312 Date of issue : 8/1/2022 Version : 8.01 9/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : Section 15. Regulatory information SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. 2-butoxyethanol 111-76-2 ?3 2-butoxyethanol 111-76-2 ?3 Form R - Reporting requirements Supplier notification Inventory list Canada : All components are listed or exempted. United States : All components are listed or exempted. Classification : FLAMMABLE LIQUIDS - Category 4 EYE IRRITATION - Category 2A Section 16. Other information History Date of issue Version : : Key to abbreviations : ATE = Acute Toxicity Estimate GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 8/1/2022 8.01 Hazardous Material Information System (U.S.A.) 2 2 0 0 2 3 / National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Product stewardship and regulatory compliance. Date of issue : 8/1/2022 Version : 8.01 10/11 Cromax? Pro Mixing Color Transoxide Red WB91ENGLISHUS : Section 16. Other information This product is intended for industrial use only. Safety Data Sheet (SDS) content is believed to be accurate as of its issue date, but is subject to change as new information is received by Axalta Coatings Systems, LLC or any of its subsidiaries or affiliates (Axalta). This SDS may incorporate information that has been provided to Axalta by its suppliers. Users should ensure that they are referring to the most current version of the SDS. Users are responsible for following the precautions identified in this SDS. It is the users? responsibility to comply with all laws and regulations applicable to the safe handling, use, and disposal of the product. Users of Axalta products should read all relevant product information prior to use, and make their own determination as to the suitability of the products for their intended use. Except as otherwise required by applicable law, AXALTA MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. The information on this SDS relates only to the specific product identified in Section 1, Identification, and does not relate to its possible use in combination with any other material or in any specific process. If this product is to be used in combination with other products, Axalta encourages you to read and understand the SDS for all products prior to use. Notice to reader Indicates information that has changed from previously issued version. as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations ? 2018 Axalta Coating Systems, LLC and all affiliates. All rights reserved. Copies may be made only for those using Axalta Coating Systems products. Date of issue : 8/1/2022 Version : 8.01 11/11