STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Issue date: 2/19/2019 Revision date: 1/19/2024 Supersedes: 11/7/2023 Version: 1.8 1/19/2024 (Revision date) USA - en 1/10 SECTION 1: Identification 1.1. Identification Product form : Mixture Trade name : STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Synonym : 584094 Part numbers : 22269; 22281; 22286; 22282; 22275; 22274; 22268; 22265; 22264; 22232; 22294; 22291; 22288; 22284; 22266; 22266-F; 22309 1.2. Recommended use and restrictions on use Recommended use : Read label before use. Restrictions on use : Use per the label directions 1.3. Supplier Manufacturer Gold Eagle Co 4400 S Kildare Ave Chicago, IL, 60632-4372 T 773-376-4400 https://www.goldeagle.com/ 1.4. Emergency telephone number Emergency number : INFOTrac: 1-800-535-5053 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS US classification Flammable liquids Category 4 H227 Combustible liquid Skin corrosion/irritation Category 2 H315 Causes skin irritation Serious eye damage/eye irritation Category 2 H319 Causes serious eye irritation Carcinogenicity Category 2 H351 Suspected of causing cancer Aspiration hazard Category 1 H304 May be fatal if swallowed and enters airways Full text of H statements : see section 16 2.2. GHS Label elements, including precautionary statements GHS US labeling Hazard pictograms (GHS US) : Signal word (GHS US) : Danger Hazard statements (GHS US) : H227 - Combustible liquid H304 - May be fatal if swallowed and enters airways H315 - Causes skin irritation H319 - Causes serious eye irritation H351 - Suspected of causing cancer STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/19/2024 (Revision date) USA - en 2/10 Precautionary statements (GHS US) : P101 - If medical advice is needed, have product container or label at hand. P102 - Keep out of reach of children. P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P264 - Wash hands, forearms and face thoroughly after handling. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P301+P310 - If swallowed: Immediately call a poison center or doctor. P302+P352 - If on skin: Wash with plenty of water. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - If exposed or concerned: Get medical advice/attention. P321 - Specific treatment (see supplemental first aid instruction on this label). P331 - Do NOT induce vomiting. P332+P313 - If skin irritation occurs: Get medical advice/attention. P337+P313 - If eye irritation persists: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P370+P378 - In case of fire: Use media other than water to extinguish. P403+P235 - Store in a well-ventilated place. Keep cool. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. 2.3. Other hazards which do not result in classification No additional information available 2.4. Unknown acute toxicity (GHS US) No additional information available SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS US classification Distillates (petroleum), hydrotreated light CAS-No.: 64742-47-8 65 ? 85 Flam. Liq. 3, H226 Asp. Tox. 1, H304 Sweetened middle distillate CAS-No.: 64741-86-2 2.5 ? 10 Carc. 1B, H350 Ethylene glycol monobutyl ether CAS-No.: 111-76-2 1 ? 5 Flam. Liq. 2, H225 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Inhalation), H332 Skin Irrit. 2, H315 Eye Irrit. 2, H319 Solvent naphtha CAS-No.: 64742-94-5 1 ? 5 Flam. Liq. 2, H225 Asp. Tox. 1, H304 Naphthalene CAS-No.: 91-20-3 0.01 ? 0.35 Acute Tox. 4 (Oral), H302 Carc. 2, H351 Full text of hazard classes and H-statements : see section 16 STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/19/2024 (Revision date) USA - en 3/10 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Call a physician immediately. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Do not induce vomiting. Call a physician immediately. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact : Irritation. Symptoms/effects after eye contact : Eye irritation. Symptoms/effects after ingestion : Risk of lung edema. 4.3. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. 5.2. Specific hazards arising from the chemical Fire hazard : Combustible liquid. Hazardous decomposition products in case of fire : Toxic fumes may be released. 5.3. Special protective equipment and precautions for fire-fighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Ventilate spillage area. No open flames, no sparks, and no smoking. Avoid contact with skin and eyes. 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into absorbent material. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site. STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/19/2024 (Revision date) USA - en 4/10 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Wear personal protective equipment. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid contact with skin and eyes. Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool. Store locked up. SECTION 8: Exposure controls/personal protection 8.1. Control parameters STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection No additional information available Sweetened middle distillate (64741-86-2) No additional information available Distillates (petroleum), hydrotreated light (64742-47-8) No additional information available Naphthalene (91-20-3) No additional information available Ethylene glycol monobutyl ether (111-76-2) USA - ACGIH - Occupational Exposure Limits Local name 2-Butoxyethanol (EGBE) ACGIH OEL TWA [ppm] 20 ppm Remark (ACGIH) TLV? Basis: Eye & URT irr. Notations: A3 (Confirmed Animal Carcinogen with Unknown Relevance to Humans); BEI Regulatory reference ACGIH 2019 USA - OSHA - Occupational Exposure Limits Local name 2-Butoxyethanol OSHA PEL (TWA) [1] 240 mg/m? OSHA PEL (TWA) [2] 50 ppm Regulatory reference (US-OSHA) OSHA Annotated Table Z-1 Solvent naphtha (64742-94-5) No additional information available STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/19/2024 (Revision date) USA - en 5/10 8.2. Appropriate engineering controls Appropriate engineering controls : Ensure good ventilation of the work station. Environmental exposure controls : Avoid release to the environment. 8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Gloves. Wear eye protection. Hand protection: Protective gloves Eye protection: Safety glasses Respiratory protection: In case of insufficient ventilation, wear suitable respiratory equipment Personal protective equipment symbol(s): SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Color : Mixture contains one or more component(s) which have the following colour(s): Colourless Odor : There may be no odour warning properties, odour is subjective and inadequate to warn of overexposure. Mixture contains one or more component(s) which have the following odour: Pleasant odour Sweet odour Odor threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : 180 ?F Flash point : > 141.5 ?F Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : Not applicable. Vapor pressure : No data available Relative vapor density at 20 ?C : No data available Relative density : 0.83 Solubility : Water: < 0.1 % Partition coefficient n-octanol/water (Log Pow) : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : 3000000 mm?/s (40 ?C) Viscosity, dynamic : No data available Explosion limits : Lower explosion limit: 0.8 Upper explosion limit: 7 Explosive properties : No data available Oxidizing properties : No data available STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/19/2024 (Revision date) USA - en 6/10 9.2. Other information VOC content : 100 SECTION 10: Stability and reactivity 10.1. Reactivity The product is non-reactive under normal conditions of use, storage and transport. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid Avoid contact with hot surfaces. Heat. No flames, no sparks. Eliminate all sources of ignition. 10.5. Incompatible materials No additional information available 10.6. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Not classified Naphthalene (91-20-3) ATE US (oral) 500 mg/kg body weight Ethylene glycol monobutyl ether (111-76-2) LD50 oral rat 1746 mg/kg body weight (Equivalent or similar to OECD 401, Rat, Male, Experimental value, Oral) LD50 oral 1414 mg/kg body weight (OECD 401: Acute Oral Toxicity, Guinea pig, Male / female, Experimental value, Oral, 14 day(s)) LD50 dermal rat > 2000 mg/kg body weight (OECD 402: Acute Dermal Toxicity, Rat, Male / female, Experimental value, Dermal, 14 day(s)) LC50 Inhalation - Rat [ppm] 450 ppm (Equivalent or similar to OECD 403, 4 h, Rat, Female, Experimental value, Inhalation (vapours)) ATE US (oral) 1414 mg/kg body weight ATE US (gases) 450 ppmV/4h ATE US (vapors) 11 mg/l/4h ATE US (dust, mist) 1.5 mg/l/4h Skin corrosion/irritation : Causes skin irritation. STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/19/2024 (Revision date) USA - en 7/10 Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Suspected of causing cancer. Naphthalene (91-20-3) IARC group 2B - Possibly carcinogenic to humans National Toxicity Program (NTP) Status Reasonably anticipated to be Human Carcinogen Ethylene glycol monobutyl ether (111-76-2) IARC group 3 - Not classifiable Reproductive toxicity : Not classified STOT-single exposure : Not classified STOT-repeated exposure : Not classified Aspiration hazard : May be fatal if swallowed and enters airways. Viscosity, kinematic : 3000000 mm?/s (40 ?C) Distillates (petroleum), hydrotreated light (64742-47-8) Viscosity, kinematic 0.9 mm?/s Naphthalene (91-20-3) Viscosity, kinematic 0.826 (80.3 ?C) Ethylene glycol monobutyl ether (111-76-2) Viscosity, kinematic 3.49 mm?/s (25 ?C) Symptoms/effects after skin contact : Irritation. Symptoms/effects after eye contact : Eye irritation. Symptoms/effects after ingestion : Risk of lung edema. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. Ethylene glycol monobutyl ether (111-76-2) LC50 - Fish [1] 1474 mg/l (OECD 203: Fish, Acute Toxicity Test, 96 h, Oncorhynchus mykiss, Static system, Fresh water, Experimental value, Nominal concentration) EC50 - Crustacea [1] 1550 mg/l (OECD 202: Daphnia sp. Acute Immobilisation Test, 48 h, Daphnia magna, Static system, Fresh water, Experimental value, Nominal concentration) EC50 72h - Algae [1] 911 mg/l (OECD 201: Alga, Growth Inhibition Test, Pseudokirchneriella subcapitata, Static system, Fresh water, Experimental value, Nominal concentration) 12.2. Persistence and degradability Ethylene glycol monobutyl ether (111-76-2) Persistence and degradability Readily biodegradable in water. 12.3. Bioaccumulative potential Naphthalene (91-20-3) Partition coefficient n-octanol/water (Log Kow) 3.3 STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/19/2024 (Revision date) USA - en 8/10 Ethylene glycol monobutyl ether (111-76-2) Partition coefficient n-octanol/water (Log Pow) 0.81 (Test data, 20 ?C) Partition coefficient n-octanol/water (Log Kow) 0.83 Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil Ethylene glycol monobutyl ether (111-76-2) Surface tension 65.03 mN/m (20 ?C, 2 g/l) Ecology - soil Low potential for adsorption in soil. 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector?s sorting instructions. SECTION 14: Transport information In accordance with DOT / IMDG 14.1. UN number Not regulated for transport 14.2. UN proper shipping name Proper Shipping Name (DOT) : Not applicable Proper Shipping Name (IMDG) : Not applicable 14.3. Transport hazard class(es) DOT Transport hazard class(es) (DOT) : Not applicable IMDG Transport hazard class(es) (IMDG) : Not applicable 14.4. Packing group Packing group (DOT) : Not applicable Packing group (IMDG) : Not applicable 14.5. Environmental hazards Other information : No supplementary information available. 14.6. Special precautions for user Special transport precautions : Not regulated for transport in Non Bulk Container sizes of 119 gallons or less. Bulk UN number is 1268 STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/19/2024 (Revision date) USA - en 9/10 DOT No data available IMDG No data available 14.7. Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code Not applicable SECTION 15: Regulatory information 15.1. US Federal regulations Commercial status of components according to the United States Environmental Protection Agency?s Toxic Substances Control Act (TSCA): Name CAS-No. Listing Commercial status Flags Sweetened middle distillate 64741-86-2 Present Active Distillates (petroleum), hydrotreated light 64742-47-8 Present Active Naphthalene 91-20-3 Present Active Ethylene glycol monobutyl ether 111-76-2 Present Active Solvent naphtha 64742-94-5 Present Active Naphthalene (91-20-3) Subject to reporting requirements of United States SARA Section 313 Listed on EPA Hazardous Air Pollutant (HAPS) CERCLA RQ 100 lb 15.2. International regulations CANADA Sweetened middle distillate (64741-86-2) Listed on the Canadian DSL (Domestic Substances List) Distillates (petroleum), hydrotreated light (64742-47-8) Listed on the Canadian DSL (Domestic Substances List) Naphthalene (91-20-3) Listed on the Canadian DSL (Domestic Substances List) Ethylene glycol monobutyl ether (111-76-2) Listed on the Canadian DSL (Domestic Substances List) Solvent naphtha (64742-94-5) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available STA-BIL? Ethanol Fuel Treatment & Stabilizer - Protection Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 1/19/2024 (Revision date) USA - en 10/10 National regulations Distillates (petroleum), hydrotreated light (64742-47-8) Listed on INSQ (Mexican National Inventory of Chemical Substances) Naphthalene (91-20-3) Listed on IARC (International Agency for Research on Cancer) Listed as carcinogen on NTP (National Toxicology Program) Listed on INSQ (Mexican National Inventory of Chemical Substances) Solvent naphtha (64742-94-5) Listed on INSQ (Mexican National Inventory of Chemical Substances) 15.3. US State regulations WARNING: This product can expose you to Naphthalene, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. SECTION 16: Other information according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date : 1/19/2024 Full text of H-phrases H225 Highly flammable liquid and vapor H226 Flammable liquid and vapor H227 Combustible liquid H302 Harmful if swallowed H304 May be fatal if swallowed and enters airways H315 Causes skin irritation H319 Causes serious eye irritation H332 Harmful if inhaled H350 May cause cancer H351 Suspected of causing cancer Safety Data Sheet (SDS), USA This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.