3M? Lightweight Body Filler - PN 05800, 05801, 05803, 05804, 05805, 35801 06/27/23 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2023, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 18-1856-6 Version Number: 7.02 Issue Date: 06/27/23 Supercedes Date: 01/10/23 Product identifier 3M? Lightweight Body Filler - PN 05800, 05801, 05803, 05804, 05805, 35801 ID Number(s): LB-K100-0692-1, LB-K100-0692-2, 41-0003-6599-3, 41-0003-6644-7, 41-0003-6664-5, 41-0003-6730-4, 41-0003-6769-2, 60-4550- 6996-7, 60-9801-0559-1, 60-9801-0561-7, 60-9801-0579-9 7000045749, 7010364116 Recommended use Automotive, Automotive Body Filler Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 29-5993-0, 32-1433-5 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. 3M? Lightweight Body Filler - PN 05800, 05801, 05803, 05804, 05805, 35801 06/27/23 ________________________________________________________________________________________________________ Page 2 of 2 In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 1 of 15 Safety Data Sheet Copyright,2023, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 32-1433-5 Version Number: 6.01 Issue Date: 08/10/23 Supercedes Date: 06/27/23 SECTION 1: Identification 1.1. Product identifier 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 1.2. Recommended use and restrictions on use Recommended use Automotive, Body Repair 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Flammable Liquid: Category 3. Serious Eye Damage/Irritation: Category 2B. Carcinogenicity: Category 1A. Specific Target Organ Toxicity (single exposure): Category 1. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols Flame | Health Hazard | Pictograms 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 2 of 15 Hazard Statements Flammable liquid and vapor. Causes eye irritation. May cause cancer. Causes damage to organs: liver | sensory organs | Causes damage to organs through prolonged or repeated exposure: respiratory system | sensory organs | May cause damage to organs through prolonged or repeated exposure: liver | Precautionary Statements General: Keep out of reach of children. Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Keep container tightly closed. Use explosion-proof electrical/ventilating/lighting equipment. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Response: IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF exposed or concerned: Get medical advice/attention. In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. Storage: Store in a well-ventilated place. Keep cool. Store locked up. Disposal: 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 3 of 15 Dispose of contents/container in accordance with applicable local/regional/national/international regulations. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Polyester Resin 26123-45-5 20 - 30 Trade Secret * Talc 14807-96-6 15 - 30 Trade Secret * Styrene Monomer 100-42-5 < 20 Trade Secret * Magnesium Carbonate 546-93-0 5 - 15 Trade Secret * UNDISCLOSED MATERIAL None 5 - 10 Trade Secret * Inert Filler Trade Secret* 5 - 10 Trade Secret * Limestone 1317-65-3 1 - 5 Trade Secret * Silica Gel 112926-00-8 1 - 5 Trade Secret * Chlorite 1318-59-8 < 2 Trade Secret * Dolomite 16389-88-1 < 2 Trade Secret * Titanium Dioxide 13463-67-7 < 1 Trade Secret * Quartz Silica 14808-60-7 < 0.5 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water for at least 15 minutes. Remove contact lenses if easy to do. Continue rinsing. Immediately get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Target organ effects. See Section 11 for additional details. Target organ effects following prolonged or repeated exposure. See Section 11 for additional details. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for flammable liquids such as dry chemical or carbon dioxide to extinguish. 5.2. Special hazards arising from the substance or mixture Closed containers exposed to heat from fire may build pressure and explode. 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 4 of 15 Hazardous Decomposition or By-Products Substance Condition Hydrocarbons During Combustion Carbon monoxide During Combustion Carbon dioxide During Combustion 5.3. Special protective actions for fire-fighters Water may not effectively extinguish fire; however, it should be used to keep fire-exposed containers and surfaces cool and prevent explosive rupture. Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Cover spill area with a fire-extinguishing foam. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible using non-sparking tools. Place in a metal container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Keep out of reach of children. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) Wear low static or properly grounded shoes. Use personal protective equipment (gloves, respirators, etc.) as required. To minimize the risk of ignition, determine applicable electrical classifications for the process using this product and select specific local exhaust ventilation equipment to avoid flammable vapor accumulation. Ground/bond container and receiving equipment if there is potential for static electricity accumulation during transfer. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep cool. Keep container tightly closed. Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 5 of 15 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Styrene Monomer 100-42-5 ACGIH TWA:10 ppm;STEL:20 ppm A3: Confirmed animal carcin., Ototoxicant Styrene Monomer 100-42-5 OSHA TWA:100 ppm;CEIL:200 ppm SILICA, AMORPHOUS 112926-00- 8 OSHA TWA:20 millions of particles/cu. ft.;TWA concentration:0.8 mg/m3 Limestone 1317-65-3 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Particles (insoluble or poorly soluble) not otherwise specified, inhalable particles 1317-65-3 ACGIH TWA(inhalable particulates):10 mg/m3 Particles (insoluble or poorly soluble) not otherwise specified, respirable particles 1317-65-3 ACGIH TWA(respirable particles):3 mg/m3 Titanium Dioxide 13463-67-7 ACGIH TWA(Respirable nanoscale particles):0.2 mg/m3;TWA(Respirable finescale particles):2.5 mg/m3 A3: Confirmed animal carcin. Titanium Dioxide 13463-67-7 OSHA TWA(as total dust):15 mg/m3 Talc 14807-96-6 ACGIH TWA(respirable fraction):2 mg/m3 A4: Not class. as human carcin TALC 14807-96-6 OSHA TWA - Use asbestos limits: Talc 14807-96-6 OSHA TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.);TWA:20 millions of particles/cu. ft. Quartz Silica 14808-60-7 ACGIH TWA(respirable fraction):0.025 mg/m3 A2: Suspected human carcin. Quartz Silica 14808-60-7 OSHA TWA Table Z- 1(respirable):0.05 mg/m3;TWA Table Z- 3(respirable):0.1 mg/m3;TWA concentration(respirable):0.1 mg/m3(2.4 millions of particles/cu. ft.) DUST, INERT OR NUISANCE 16389-88-1 OSHA TWA(as total dust):15 mg/m3;TWA(as total dust):50 millions of particles/cu. ft.(15 mg/m3);TWA(respirable fraction):5 mg/m3;TWA(respirable fraction):15 millions of particles/cu. ft.(5 mg/m3) Particles (insoluble or poorly soluble) not otherwise specified, inhalable particles 16389-88-1 ACGIH TWA(inhalable particulates):10 mg/m3 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 6 of 15 Particles (insoluble or poorly soluble) not otherwise specified, respirable particles 16389-88-1 ACGIH TWA(respirable particles):3 mg/m3 Magnesium Carbonate 546-93-0 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Particles (insoluble or poorly soluble) not otherwise specified, inhalable particles 546-93-0 ACGIH TWA(inhalable particulates):10 mg/m3 Particles (insoluble or poorly soluble) not otherwise specified, respirable particles 546-93-0 ACGIH TWA(respirable particles):3 mg/m3 Inert Filler Trade Secret Manufacturer determined TWA(as non-fibrous, respirable)(8 hours):3 mg/m3;TWA(as non-fibrous, inhalable fraction)(8 hours):10 mg/m3 Inert Filler Trade Secret ACGIH TWA(as fiber):0.2 fiber/cc A2: Suspected human carcin. Inert Filler Trade Secret ACGIH TWA(as fiber):1 fiber/cc A3: Confirmed animal carcin. Inert Filler Trade Secret ACGIH TWA(as fiber):1 fiber/cc A4: Not class. as human carcin Inert Filler Trade Secret ACGIH TWA(inhalable fraction):5 mg/m3 A4: Not class. as human carcin ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Fluoroelastomer 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 7 of 15 Polyvinyl Alcohol (PVA) Polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Gray Specific Physical Form: Paste Odor Pungent Styrene Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point 293 ?F Flash Point 88 ?F [Test Method:Closed Cup] Evaporation rate No Data Available Flammability (solid, gas) Not Applicable Flammable Limits(LEL) 0.9 % [Details:based on styrene] Flammable Limits(UEL) 6.8 % [Details:based on styrene] Vapor Pressure No Data Available Vapor Density 3.6 [Ref Std:AIR=1] Density 1.14 g/ml Specific Gravity 1.14 [Ref Std:WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity 200,000 - 244,000 centipoise Hazardous Air Pollutants 0.355 lb HAPS/lb solids Volatile Organic Compounds 17.6 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 200 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile 17.9 % weight VOC Less H2O & Exempt Solvents 201 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. Stable under normal conditions. May become unstable at elevated temperatures and/or pressure. 10.3. Possibility of hazardous reactions 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 8 of 15 Hazardous polymerization will not occur. 10.4. Conditions to avoid Sparks and/or flames Heat 10.5. Incompatible materials Strong acids Strong oxidizing agents Alkali and alkaline earth metals Strong bases 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. May cause additional health effects (see below). Skin Contact: Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, and dryness. Eye Contact: Moderate Eye Irritation: Signs/symptoms may include redness, swelling, pain, tearing, and blurred or hazy vision. Ingestion: May be harmful if swallowed. Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 9 of 15 Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Prolonged or repeated exposure may cause target organ effects: Pneumoconiosis: Sign/symptoms may include persistent cough, breathlessness, chest pain, increased amounts of sputum, and changes in lung function tests. Ocular Effects: Signs/symptoms may include blurred or significantly impaired vision. Auditory Effects: Signs/symptoms may include hearing impairment, balance dysfunction and ringing in the ears. Liver Effects: Signs/symptoms may include loss of appetite, weight loss, fatigue, weakness, abdominal tenderness and jaundice. Carcinogenicity: Contains a chemical or chemicals which can cause cancer. Ingredient CAS No. Class Description Regulation Silica, Crystalline (Respirable Size) 14808-60-7 Known To Be Human Carcinogen. National Toxicology Program Carcinogens Inert Filler Trade Secret Grp. 2B: Possible human carc. International Agency for Research on Cancer Inert Filler Trade Secret Grp. 2B: Possible human carc. International Agency for Research on Cancer Inert Filler Trade Secret Anticipated human carcinogen National Toxicology Program Carcinogens Inert Filler Trade Secret Anticipated human carcinogen National Toxicology Program Carcinogens Talc containing asbestiform fibres 14807-96-6 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Silica dust, crystalline, in the form of quartz or cristobalite 14808-60-7 Grp. 1: Carcinogenic to humans International Agency for Research on Cancer Styrene 100-42-5 Grp. 2A: Probable human carc. International Agency for Research on Cancer Styrene 100-42-5 Anticipated human carcinogen National Toxicology Program Carcinogens Titanium dioxide 13463-67-7 Grp. 2B: Possible human carc. International Agency for Research on Cancer Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >50 mg/l Overall product Ingestion No data available; calculated ATE >2,000 - =5,000 mg/kg Talc Dermal LD50 estimated to be > 5,000 mg/kg Talc Ingestion LD50 estimated to be > 5,000 mg/kg Polyester Resin Dermal LD50 estimated to be > 5,000 mg/kg Polyester Resin Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Styrene Monomer Dermal Rat LD50 > 2,000 mg/kg Styrene Monomer Inhalation- Vapor (4 hours) Rat LC50 11.8 mg/l Styrene Monomer Ingestion Rat LD50 5,000 mg/kg Magnesium Carbonate Dermal Professio nal judgeme nt LD50 estimated to be 2,000 - 5,000 mg/kg Magnesium Carbonate Ingestion Rat LD50 > 2,000 mg/kg Inert Filler Dermal LD50 estimated to be > 5,000 mg/kg Inert Filler Ingestion LD50 estimated to be 2,000 - 5,000 mg/kg Limestone Dermal Rat LD50 > 2,000 mg/kg Limestone Inhalation- Rat LC50 3 mg/l 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 10 of 15 Dust/Mist (4 hours) Limestone Ingestion Rat LD50 6,450 mg/kg Silica Gel Dermal Rabbit LD50 > 5,000 mg/kg Silica Gel Inhalation- Dust/Mist (4 hours) Rat LC50 > 0.691 mg/l Silica Gel Ingestion Rat LD50 > 5,110 mg/kg Chlorite Dermal LD50 estimated to be > 5,000 mg/kg Chlorite Ingestion LD50 estimated to be > 5,000 mg/kg Dolomite Dermal LD50 estimated to be 2,000 - 5,000 mg/kg Dolomite Ingestion Rat LD50 > 2,000 mg/kg Titanium Dioxide Dermal Rabbit LD50 > 10,000 mg/kg Titanium Dioxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 6.82 mg/l Titanium Dioxide Ingestion Rat LD50 > 10,000 mg/kg Quartz Silica Dermal LD50 estimated to be > 5,000 mg/kg Quartz Silica Ingestion LD50 estimated to be > 5,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Talc Rabbit No significant irritation Styrene Monomer Professio nal judgeme nt Mild irritant Magnesium Carbonate In vitro data No significant irritation Inert Filler Professio nal judgeme nt No significant irritation Limestone Rabbit No significant irritation Silica Gel Rabbit No significant irritation Chlorite Professio nal judgeme nt No significant irritation Dolomite Professio nal judgeme nt No significant irritation Titanium Dioxide Rabbit No significant irritation Quartz Silica Professio nal judgeme nt No significant irritation Serious Eye Damage/Irritation Name Species Value Talc Rabbit No significant irritation Styrene Monomer Professio nal judgeme nt Moderate irritant Magnesium Carbonate Rabbit Mild irritant Inert Filler Professio nal judgeme nt No significant irritation 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 11 of 15 Limestone Rabbit No significant irritation Silica Gel Rabbit No significant irritation Chlorite Professio nal judgeme nt No significant irritation Dolomite Professio nal judgeme nt No significant irritation Titanium Dioxide Rabbit No significant irritation Skin Sensitization Name Species Value Styrene Monomer Guinea pig Not classified Silica Gel Human and animal Not classified Titanium Dioxide Human and animal Not classified Respiratory Sensitization Name Species Value Talc Human Not classified Germ Cell Mutagenicity Name Route Value Talc In Vitro Not mutagenic Talc In vivo Not mutagenic Styrene Monomer In Vitro Some positive data exist, but the data are not sufficient for classification Styrene Monomer In vivo Some positive data exist, but the data are not sufficient for classification Inert Filler In Vitro Some positive data exist, but the data are not sufficient for classification Silica Gel In Vitro Not mutagenic Titanium Dioxide In Vitro Not mutagenic Titanium Dioxide In vivo Not mutagenic Quartz Silica In Vitro Some positive data exist, but the data are not sufficient for classification Quartz Silica In vivo Some positive data exist, but the data are not sufficient for classification Carcinogenicity Name Route Species Value Talc Inhalation Rat Some positive data exist, but the data are not sufficient for classification Styrene Monomer Ingestion Mouse Carcinogenic Styrene Monomer Inhalation Human and animal Carcinogenic Inert Filler Inhalation Multiple animal species Some positive data exist, but the data are not sufficient for classification Silica Gel Not Specified Mouse Some positive data exist, but the data are not sufficient for classification Titanium Dioxide Ingestion Multiple animal species Not carcinogenic Titanium Dioxide Inhalation Rat Carcinogenic 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 12 of 15 Quartz Silica Inhalation Human and animal Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Talc Ingestion Not classified for development Rat NOAEL 1,600 mg/kg during organogenesi s Styrene Monomer Ingestion Not classified for female reproduction Rat NOAEL 21 mg/kg/day 3 generation Styrene Monomer Inhalation Not classified for female reproduction Rat NOAEL 2.1 mg/l 2 generation Styrene Monomer Inhalation Not classified for male reproduction Rat NOAEL 2.1 mg/l 2 generation Styrene Monomer Ingestion Not classified for male reproduction Rat NOAEL 400 mg/kg/day 60 days Styrene Monomer Ingestion Not classified for development Rat NOAEL 400 mg/kg/day during gestation Styrene Monomer Inhalation Not classified for development Multiple animal species NOAEL 2.1 mg/l during gestation Limestone Ingestion Not classified for development Rat NOAEL 625 mg/kg/day premating & during gestation Silica Gel Ingestion Not classified for female reproduction Rat NOAEL 509 mg/kg/day 1 generation Silica Gel Ingestion Not classified for male reproduction Rat NOAEL 497 mg/kg/day 1 generation Silica Gel Ingestion Not classified for development Rat NOAEL 1,350 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Styrene Monomer Inhalation auditory system Causes damage to organs Multiple animal species LOAEL 4.3 mg/l not available Styrene Monomer Inhalation liver Causes damage to organs Mouse LOAEL 2.1 mg/l not available Styrene Monomer Inhalation central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available occupational exposure Styrene Monomer Inhalation respiratory irritation May cause respiratory irritation Human and animal NOAEL Not available Styrene Monomer Inhalation endocrine system Not classified Rat NOAEL Not available not available Styrene Monomer Inhalation kidney and/or bladder Not classified Multiple animal species NOAEL 2.1 mg/l not available Limestone Inhalation respiratory system Not classified Rat NOAEL 0.812 mg/l 90 minutes Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Talc Inhalation pneumoconiosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 13 of 15 Talc Inhalation pulmonary fibrosis | respiratory system Not classified Rat NOAEL 18 mg/m3 113 weeks Styrene Monomer Inhalation auditory system Causes damage to organs through prolonged or repeated exposure Human NOAEL not available occupational exposure Styrene Monomer Inhalation eyes Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Styrene Monomer Inhalation liver May cause damage to organs though prolonged or repeated exposure Mouse LOAEL 0.85 mg/l 13 weeks Styrene Monomer Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Multiple animal species LOAEL 1.1 mg/l not available Styrene Monomer Inhalation hematopoietic system Not classified Rat NOAEL 0.85 mg/l 7 days Styrene Monomer Inhalation endocrine system Not classified Rat NOAEL 0.6 mg/l 10 days Styrene Monomer Inhalation respiratory system Not classified Multiple animal species LOAEL 0.09 mg/l not available Styrene Monomer Inhalation heart | gastrointestinal tract | bone, teeth, nails, and/or hair | muscles | kidney and/or bladder Not classified Multiple animal species NOAEL 4.3 mg/l 2 years Styrene Monomer Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 500 mg/kg/day 8 weeks Styrene Monomer Ingestion immune system Some positive data exist, but the data are not sufficient for classification Multiple animal species NOAEL Not available not available Styrene Monomer Ingestion liver | kidney and/or bladder Not classified Rat NOAEL 677 mg/kg/day 6 months Styrene Monomer Ingestion hematopoietic system Not classified Dog NOAEL 600 mg/kg/day 470 days Styrene Monomer Ingestion heart | respiratory system Not classified Rat NOAEL 35 mg/kg/day 105 weeks Inert Filler Inhalation respiratory system Not classified Human NOAEL not available occupational exposure Limestone Inhalation respiratory system Not classified Human NOAEL Not available occupational exposure Silica Gel Inhalation respiratory system | silicosis Not classified Human NOAEL Not available occupational exposure Titanium Dioxide Inhalation respiratory system Some positive data exist, but the data are not sufficient for classification Rat LOAEL 0.01 mg/l 2 years Titanium Dioxide Inhalation pulmonary fibrosis Not classified Human NOAEL Not available occupational exposure Quartz Silica Inhalation silicosis Causes damage to organs through prolonged or repeated exposure Human NOAEL Not available occupational exposure Aspiration Hazard Name Value Styrene Monomer Aspiration hazard Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 14 of 15 Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact manufacturer for more information EPCRA 311/312 Hazard Classifications: Physical Hazards Flammable (gases, aerosols, liquids, or solids) Health Hazards Carcinogenicity Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Styrene Monomer 100-42-5 Trade Secret < 20 15.2. State Regulations Contact manufacturer for more information 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact manufacturer for more information 15.4. International Regulations Contact manufacturer for more information 3M? Lightweight Body Filler PNs 05800, 05801, 05804, 05805 08/10/23 __________________________________________________________________________________________ Page 15 of 15 This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 1 Flammability: 3 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. Document Group: 32-1433-5 Version Number: 6.01 Issue Date: 08/10/23 Supercedes Date: 06/27/23 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 1 of 12 Safety Data Sheet Copyright,2022, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 29-5993-0 Version Number: 6.00 Issue Date: 02/24/22 Supercedes Date: 12/07/21 SECTION 1: Identification 1.1. Product identifier 3M? Cream Hardener (Red, White & Blue) Product Identification Numbers LB-K100-0965-7, LB-K100-0965-8, LB-K100-0965-9, LB-K100-0966-0, LB-K100-0966-1, LB-K100-0966-2, LB-K100- 0966-3, LB-K100-1035-6, LB-K100-1045-4, LB-K100-1286-7, 41-0003-6674-4, 41-0003-6682-7, 41-0003-6685-0, 41-0003- 6686-8, 41-0003-6687-6, 41-0003-7901-0, 41-0003-7903-6, 41-0003-7904-4, 41-0003-7922-6, 41-0003-7928-3, 41-0003- 7930-9, 41-0003-7931-7, 41-0003-7932-5, 41-0003-7933-3, 41-0003-7935-8, 41-0003-7987-9, 41-0003-8059-6, 41-0003- 8072-9, 41-0003-8073-7, 41-0003-8074-5, 41-0003-8146-1, 60-4550-6617-9, 60-4550-6830-8, 60-4550-6981-9, 60-4550- 6982-7, 60-4550-8123-6, 60-4551-0388-1 7000120090, 7010327931, 7000120133, 7100191003 1.2. Recommended use and restrictions on use Recommended use Automotive, hardener for body fillers & glazes 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Organic Peroxide: Type E. Serious Eye Damage/Irritation: Category 2A. Skin Sensitizer: Category 1B. Specific Target Organ Toxicity (single exposure): Category 1. 2.2. Label elements 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 2 of 12 Signal word Danger Symbols Flame | Exclamation mark | Health Hazard | Pictograms Hazard Statements Heating may cause a fire. Causes serious eye irritation. May cause an allergic skin reaction. Causes damage to organs: cardiovascular system | nervous system | kidney/urinary tract | respiratory system | Precautionary Statements General: Keep out of reach of children. Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep away from clothing and other combustible materials. Keep only in original container. Do not breathe dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. IF exposed: Call a POISON CENTER or doctor/physician. Specific treatment (see Notes to Physician on this label). Storage: Protect from sunlight. Store at temperatures not exceeding 32C/90F. Keep cool. Store locked up. Store away from other materials. 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 3 of 12 Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Notes to Physician: This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV) administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Benzoyl Peroxide 94-36-0 30 - 60 Trade Secret * Benzoic Acid, C9-11-Branched Alkyl Esters 131298-44-7 10 - 30 Trade Secret * Water 7732-18-5 10 - 30 Trade Secret * Calcium Sulfate 7778-18-9 1 - 10 Trade Secret * Zinc Stearate 557-05-1 1 - 10 Trade Secret * Ethylene Glycol 107-21-1 <= 7.5 Trade Secret * Iron Oxide (FE2O3) 1309-37-1 <= 5 Trade Secret * Oxirane, Polymer with Methyloxirane, Monobutyl Ether 9038-95-3 <= 5 Trade Secret * Ferric Ammonium Ferrocyanide 25869-00-5 <= 1 Trade Secret * Ferric Ferrocyanide 14038-43-8 <= 1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Allergic skin reaction (redness, swelling, blistering, and itching). Target organ effects. See Section 11 for additional details. 4.3. Indication of any immediate medical attention and special treatment required This product contains ethylene glycol. If there is reasonable suspicion of ethylene glycol poisoning, intravenous (IV) administration with either fomepizole (preferred) or ethanol (if fomepizole is unavailable) should be considered as part of the medical management. SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 4 of 12 Closed containers exposed to heat from fire may build pressure and explode. Part of the oxygen for combustion is supplied by the peroxide itself. 5.3. Special protective actions for fire-fighters Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Eliminate all ignition sources if safe to do so. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use only non-sparking tools. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition source and could cause flammable gases or vapors in the spill area to burn or explode. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Collect as much of the spilled material as possible using non-sparking tools. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Keep out of reach of children. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage including any incompatibilities Keep container tightly closed. Protect from sunlight. Store away from heat. Store at temperatures not exceeding 32C/90F. Keep cool. Keep only in original container. Store away from other materials. Keep/store away from clothing and other combustible materials. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments Ethylene Glycol 107-21-1 ACGIH TWA(Vapor fraction):25 ppm;STEL(Vapor fraction):50 ppm;STEL(Inhalable aerosol):10 mg/m3 A4: Not class. as human carcin Iron Oxide (FE2O3) 1309-37-1 ACGIH TWA(respirable fraction):5 mg/m3 A4: Not class. as human carcin 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 5 of 12 Iron Oxide (FE2O3) 1309-37-1 OSHA TWA(as fume):10 mg/m3 CYANIDES 14038-43-8 OSHA TWA(as CN):5 mg/m3 SKIN Zinc Stearate 557-05-1 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Calcium Sulfate 7778-18-9 ACGIH TWA(inhalable fraction):10 mg/m3 Calcium Sulfate 7778-18-9 OSHA TWA(as total dust):15 mg/m3;TWA(respirable fraction):5 mg/m3 Benzoyl Peroxide 94-36-0 ACGIH TWA:5 mg/m3 A4: Not class. as human carcin Benzoyl Peroxide 94-36-0 OSHA TWA:5 mg/m3 ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Provide ventilation adequate to maintain dust concentration below minimum explosive concentrations. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 6 of 12 SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Solid Red Specific Physical Form: Paste Odor Slight Ester Odor threshold No Data Available pH No Data Available Melting point No Data Available Boiling Point No Data Available Flash Point 111 ?C [Test Method:Estimated] Evaporation rate No Data Available Flammability (solid, gas) Organic Peroxide: Type E. Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density Not Applicable Density 1.2 g/cm3 Specific Gravity 1.2 [@ 25 ?C] [Ref Std:WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature No Data Available Decomposition temperature No Data Available Viscosity No Data Available Hazardous Air Pollutants 0 - 0.1209 lb HAPS/lb solids [Test Method:Calculated] Molecular weight Not Applicable Volatile Organic Compounds 0 - 90 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 0 % weight [Test Method:calculated per CARB title 2] Percent volatile 21 - 28.5 % VOC Less H2O & Exempt Solvents 0 - 121 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. Stable unless exposed to heat, flames and drying conditions. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid Heat 10.5. Incompatible materials Accelerators 10.6. Hazardous decomposition products Substance Condition Carbon monoxide Not Specified 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 7 of 12 Carbon dioxide Not Specified Toxic Vapor, Gas, Particulate Not Specified SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: May be harmful in contact with skin. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. May cause additional health effects (see below). Additional Health Effects: Single exposure may cause target organ effects: Cardiac Effects: Signs/symptoms may include irregular heartbeat (arrhythmia), changes in heart rate, damage to heart muscle, heart attack, and may be fatal. Neurological Effects: Signs/symptoms may include personality changes, lack of coordination, sensory loss, tingling or numbness of the extremities, weakness, tremors, and/or changes in blood pressure and heart rate. Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Kidney/Bladder Effects: Signs/symptoms may include changes in urine production, abdominal or lower back pain, increased protein in urine, increased blood urea nitrogen (BUN), blood in urine, and painful urination. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 8 of 12 Overall product Dermal No data available; calculated ATE >2,000 - ?5,000 mg/kg Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE >12.5 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Benzoyl Peroxide Dermal LD50 estimated to be 2,000 - 5,000 mg/kg Benzoyl Peroxide Inhalation- Dust/Mist (4 hours) Rat LC50 > 24.3 mg/l Benzoyl Peroxide Ingestion Rat LD50 > 5,000 mg/kg Benzoic Acid, C9-11-Branched Alkyl Esters Dermal Rabbit LD50 > 2,000 mg/kg Benzoic Acid, C9-11-Branched Alkyl Esters Inhalation- Dust/Mist (4 hours) Rat LC50 > 5 mg/l Benzoic Acid, C9-11-Branched Alkyl Esters Ingestion Rat LD50 > 5,000 mg/kg Calcium Sulfate Dermal Professio nal judgeme nt LD50 estimated to be > 5,000 mg/kg Calcium Sulfate Ingestion Rat LD50 > 5,000 mg/kg Zinc Stearate Dermal Rabbit LD50 > 2,000 mg/kg Zinc Stearate Inhalation- Dust/Mist (4 hours) Rat LC50 > 50 mg/l Zinc Stearate Ingestion Rat LD50 > 5,000 mg/kg Ethylene Glycol Ingestion Human LD50 1,600 mg/kg Ethylene Glycol Inhalation- Dust/Mist (4 hours) Other LC50 estimated to be 5 - 12.5 mg/l Ethylene Glycol Dermal Rabbit 9,530 mg/kg Iron Oxide (FE2O3) Dermal Not available LD50 3,100 mg/kg Iron Oxide (FE2O3) Ingestion Not available LD50 3,700 mg/kg Oxirane, Polymer with Methyloxirane, Monobutyl Ether Dermal Rabbit LD50 > 16,960 mg/kg Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation- Dust/Mist (4 hours) Rat LC50 > 5 mg/l Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion Rat LD50 4,240 mg/kg Ferric Ammonium Ferrocyanide Dermal LD50 estimated to be > 5,000 mg/kg Ferric Ferrocyanide Dermal LD50 estimated to be > 5,000 mg/kg Ferric Ammonium Ferrocyanide Ingestion Rat LD50 > 5,110 mg/kg Ferric Ferrocyanide Ingestion Rat LD50 > 8,000 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Benzoyl Peroxide Rabbit Minimal irritation Zinc Stearate Rabbit No significant irritation Ethylene Glycol Rabbit Minimal irritation Iron Oxide (FE2O3) Rabbit No significant irritation Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit Minimal irritation Serious Eye Damage/Irritation Name Species Value Benzoyl Peroxide Rabbit Severe irritant Zinc Stearate Rabbit No significant irritation Ethylene Glycol Rabbit Mild irritant Iron Oxide (FE2O3) Rabbit No significant irritation Oxirane, Polymer with Methyloxirane, Monobutyl Ether Rabbit No significant irritation 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 9 of 12 Skin Sensitization Name Species Value Benzoyl Peroxide Guinea pig Sensitizing Ethylene Glycol Human Not classified Iron Oxide (FE2O3) Human Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Benzoyl Peroxide In Vitro Not mutagenic Benzoyl Peroxide In vivo Not mutagenic Ethylene Glycol In Vitro Not mutagenic Ethylene Glycol In vivo Not mutagenic Iron Oxide (FE2O3) In Vitro Not mutagenic Carcinogenicity Name Route Species Value Benzoyl Peroxide Ingestion Multiple animal species Not carcinogenic Benzoyl Peroxide Dermal Mouse Some positive data exist, but the data are not sufficient for classification Ethylene Glycol Ingestion Multiple animal species Not carcinogenic Iron Oxide (FE2O3) Inhalation Human Some positive data exist, but the data are not sufficient for classification Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion Rat Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Benzoyl Peroxide Ingestion Not classified for female reproduction Rat NOAEL 1,000 mg/kg/day premating & during gestation Benzoyl Peroxide Ingestion Not classified for male reproduction Rat NOAEL 500 mg/kg/day premating & during gestation Benzoyl Peroxide Ingestion Not classified for development Rat NOAEL 500 mg/kg/day premating & during gestation Ethylene Glycol Dermal Not classified for development Mouse NOAEL 3,549 mg/kg/day during organogenesi s Ethylene Glycol Ingestion Not classified for development Mouse LOAEL 750 mg/kg/day during organogenesi s Ethylene Glycol Inhalation Not classified for development Mouse NOAEL 1,000 mg/kg/day during organogenesi s Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation Not classified for male reproduction Rat NOAEL 1 mg/l 2 weeks Target Organ(s) Specific Target Organ Toxicity - single exposure 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 10 of 12 Name Route Target Organ(s) Value Species Test Result Exposure Duration Ethylene Glycol Ingestion heart | nervous system | kidney and/or bladder | respiratory system Causes damage to organs Human NOAEL Not available poisoning and/or abuse Ethylene Glycol Ingestion central nervous system depression May cause drowsiness or dizziness Human NOAEL Not available poisoning and/or abuse Ethylene Glycol Ingestion liver Not classified Human NOAEL Not available poisoning and/or abuse Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion nervous system Not classified Rat NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Ethylene Glycol Ingestion kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 200 mg/kg/day 2 years Ethylene Glycol Ingestion vascular system Not classified Rat NOAEL 200 mg/kg/day 2 years Ethylene Glycol Ingestion heart | hematopoietic system | liver | immune system | muscles Not classified Rat NOAEL 1,000 mg/kg/day 2 years Ethylene Glycol Ingestion respiratory system Not classified Mouse NOAEL 12,000 mg/kg/day 2 years Ethylene Glycol Ingestion skin | endocrine system | bone, teeth, nails, and/or hair | nervous system | eyes Not classified Multiple animal species NOAEL 1,000 mg/kg/day 2 years Iron Oxide (FE2O3) Inhalation pulmonary fibrosis | pneumoconiosis Not classified Human NOAEL Not available occupational exposure Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation endocrine system | hematopoietic system | liver | nervous system Not classified Rat NOAEL 1 mg/l 2 weeks Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation kidney and/or bladder Not classified Rat NOAEL 0.005 mg/l 2 weeks Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation respiratory system Not classified Rat LOAEL 0.001 mg/l 2 weeks Oxirane, Polymer with Methyloxirane, Monobutyl Ether Inhalation heart Not classified Rat NOAEL 0.5 mg/l 2 weeks Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion liver | kidney and/or bladder Some positive data exist, but the data are not sufficient for classification Rat NOAEL 145 mg/kg/day 90 days Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion hematopoietic system Not classified Rat NOAEL 500 mg/kg/day 2 years Oxirane, Polymer with Methyloxirane, Monobutyl Ether Ingestion heart | endocrine system | respiratory system Not classified Rat NOAEL 3,770 mg/kg/day 90 days Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 11 of 12 SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information For Transport Information, please visit http://3M.com/Transportinfo or call 1-800-364-3577 or 651-737-6501. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Organic peroxide Health Hazards Respiratory or Skin Sensitization Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt Ethylene Glycol 107-21-1 Trade Secret <= 7.5 Zinc Stearate (ZINC COMPOUNDS) 557-05-1 Trade Secret 1 - 10 Benzoyl Peroxide 94-36-0 Trade Secret 30 - 60 Ferric Ferrocyanide (CYANIDES) 14038-43-8 Trade Secret <= 1 15.2. State Regulations Contact 3M for more information. 3M? Cream Hardener (Red, White & Blue) 02/24/22 __________________________________________________________________________________________ Page 12 of 12 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: Oxidizer National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 4 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 29-5993-0 Version Number: 6.00 Issue Date: 02/24/22 Supercedes Date: 12/07/21 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com