Epoxy Primer 1250044145 (CHEMTREC) - 800-424-9300 SAFETY DATA SHEET Product identifier Other means of identification Emergency telephone number Section 1. Identification : : : Supplier's details : Axalta Coating Systems, LLC 50 Applied Bank Blvd. Suite 300 Glen Mills, PA 19342 USA Relevant identified uses of the substance or mixture and uses advised against Identified uses Uses advised against Product name : 13550S Coating component. Not for sale to or use by consumers. Product information 855-6AXALTA : : Date of issue Version : : 2/7/2024 9 ENGLISHUS : Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (inhalation) - Category 3 SERIOUS EYE DAMAGE - Category 1 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 GERM CELL MUTAGENICITY - Category 1 CARCINOGENICITY - Category 1A TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 14.5% OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue : 2/7/2024 Version : 9 1/17 Epoxy Primer 13550SENGLISHUS : Section 2. Hazards identification Hazard statements : H225 - Highly flammable liquid and vapor. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H331 - Toxic if inhaled. H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled. H335 - May cause respiratory irritation. H340 - May cause genetic defects. H350 - May cause cancer. H361 - Suspected of damaging fertility or the unborn child. Precautionary statements Prevention : P201 - Obtain special instructions before use. P280 - Wear protective gloves, protective clothing and eye or face protection. P284 - Wear respiratory protection. P210 - Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P241 - Use explosion-proof electrical, ventilating or lighting equipment. P242 - Use non-sparking tools. P243 - Take action to prevent static discharges. P261 - Avoid breathing vapor. Response : P308 + P313 - IF exposed or concerned: Get medical advice or attention. P304 + P340, P311 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor. P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor. P363 - Wash contaminated clothing before reuse. P302 + P352 - IF ON SKIN: Wash with plenty of water. P333 + P313 - If skin irritation or rash occurs: Get medical advice or attention. P305 + P351 + P338, P310 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor. Storage : P403 + P233 - Store in a well-ventilated place. Keep container tightly closed. P403 + P235 - Keep cool. Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : None known. Section 3. Composition/information on ingredients Ingredient name ConcentrationCAS number Substance/mixture : Mixture titanium dioxide 13463-67-7 ?10 - ?25 strontium chromate 7789-06-2 ?6.7 acetone 67-64-1 ?8.5 2,6-dimethylheptan-4-one 108-83-8 ?10 Normal butyl alcohol 71-36-3 ?4.4 solvent naphtha (petroleum), light aromatic 64742-95-6 ?3 4-chloro-?,?,?-trifluorotoluene 98-56-6 ?3 heptan-2-one 110-43-0 ?1.5 Date of issue : 2/7/2024 Version : 9 2/17 Epoxy Primer 13550SENGLISHUS : Section 3. Composition/information on ingredients There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. 4,6-dimethylheptan-2-one 19549-80-5 ?3 ethylbenzene 100-41-4 ?0.3 barium chromate 10294-40-3 ?0.3 Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Chemical burns must be treated promptly by a physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately. Call a poison center or physician. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. Get medical attention immediately. Call a poison center or physician. Wash with plenty of soap and water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Chemical burns must be treated promptly by a physician. In the event of any complaints or symptoms, avoid further exposure. Wash clothing before reuse. Clean shoes thoroughly before reuse. Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. In the event of any complaints or symptoms, avoid further exposure. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Toxic if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin contact : May cause an allergic skin reaction. Causes serious eye damage.:Eye contact Potential acute health effects Date of issue : 2/7/2024 Version : 9 3/17 Epoxy Primer 13550SENGLISHUS : Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. No known significant effects or critical hazards.:Ingestion Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing wheezing and breathing difficulties asthma reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Specific hazards arising from the chemical Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue : 2/7/2024 Version : 9 4/17 Epoxy Primer 13550SENGLISHUS : Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides phosphorus oxides halogenated compounds carbonyl halides metal oxide/oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue : 2/7/2024 Version : 9 5/17 Epoxy Primer 13550SENGLISHUS : Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems or asthma, allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Storage code IA: titanium dioxide OSHA PEL 1989 (United States, 3/1989). TWA: 10 mg/m? 8 hours. Form: Total dust OSHA PEL (United States, 5/2018). TWA: 15 mg/m? 8 hours. Form: Total dust CAL OSHA PEL (United States, 5/2018). TWA: 5 mg/m?, (as Ti) 8 hours. Form: respirable fraction TWA: 10 mg/m?, (as Ti) 8 hours. Form: total dust ACGIH TLV (United States, 1/2023). TWA: 2.5 mg/m? 8 hours. Form: respirable fraction, finescale particles strontium chromate ACGIH TLV (United States, 1/2023). TWA: 0.0005 mg/m?, (measured as Cr) 8 hours. OSHA PEL 1989 (United States, 3/1989). [Chromic acid and chromates (as CrO3)] CEIL: 0.1 mg/m?, (as CrO3) Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue : 2/7/2024 Version : 9 6/17 Epoxy Primer 13550SENGLISHUS : Section 8. Exposure controls/personal protection OSHA PEL Z2 (United States, 2/2013). [Chromic acid and chromates] CEIL: 1 mg/10m? NIOSH REL (United States, 10/2020). [chromic acid and chromates] TWA: 0.0002 mg/m?, (as Cr) 8 hours. OSHA PEL (United States, 5/2018). [Chromium (VI) compounds] TWA: 0.005 mg/m?, (as Cr) 8 hours. CAL OSHA PEL (United States, 5/2018). TWA: 0.0005 mg/m?, (as Cr) 8 hours. acetone ACGIH TLV (United States, 1/2023). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. OSHA PEL 1989 (United States, 3/1989). TWA: 750 ppm 8 hours. TWA: 1800 mg/m? 8 hours. STEL: 1000 ppm 15 minutes. STEL: 2400 mg/m? 15 minutes. NIOSH REL (United States, 10/2020). TWA: 250 ppm 10 hours. TWA: 590 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 1000 ppm 8 hours. TWA: 2400 mg/m? 8 hours. CAL OSHA PEL (United States, 5/2018). STEL: 1780 mg/m? 15 minutes. STEL: 750 ppm 15 minutes. C: 3000 ppm TWA: 1200 mg/m? 8 hours. TWA: 500 ppm 8 hours. 2,6-dimethylheptan-4-one ACGIH TLV (United States, 1/2023). TWA: 25 ppm 8 hours. TWA: 145 mg/m? 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 25 ppm 8 hours. TWA: 150 mg/m? 8 hours. NIOSH REL (United States, 10/2020). TWA: 25 ppm 10 hours. TWA: 150 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 50 ppm 8 hours. TWA: 290 mg/m? 8 hours. CAL OSHA PEL (United States, 5/2018). TWA: 150 mg/m? 8 hours. TWA: 25 ppm 8 hours. butan-1-ol ACGIH TLV (United States, 1/2023). TWA: 20 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). Absorbed through skin. CEIL: 50 ppm CEIL: 150 mg/m? Date of issue : 2/7/2024 Version : 9 7/17 Epoxy Primer 13550SENGLISHUS : Section 8. Exposure controls/personal protection NIOSH REL (United States, 10/2020). Absorbed through skin. CEIL: 50 ppm CEIL: 150 mg/m? OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 300 mg/m? 8 hours. CAL OSHA PEL (United States, 5/2018). Absorbed through skin. C: 150 mg/m? C: 50 ppm solvent naphtha (petroleum), light aromatic None. 4-chloro-?,?,?-trifluorotoluene None. heptan-2-one ACGIH TLV (United States, 1/2023). TWA: 50 ppm 8 hours. TWA: 233 mg/m? 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 465 mg/m? 8 hours. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 465 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 465 mg/m? 8 hours. CAL OSHA PEL (United States, 5/2018). TWA: 235 mg/m? 8 hours. TWA: 50 ppm 8 hours. 4,6-dimethylheptan-2-one None. ethylbenzene ACGIH TLV (United States, 1/2023). Ototoxicant. TWA: 20 ppm 8 hours. OSHA PEL 1989 (United States, 3/1989). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m? 15 minutes. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 435 mg/m? 10 hours. STEL: 125 ppm 15 minutes. STEL: 545 mg/m? 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. CAL OSHA PEL (United States, 5/2018). STEL: 130 mg/m? 15 minutes. STEL: 30 ppm 15 minutes. TWA: 22 mg/m? 8 hours. TWA: 5 ppm 8 hours. barium chromate OSHA PEL 1989 (United States, 3/1989). [Chromic acid Date of issue : 2/7/2024 Version : 9 8/17 Epoxy Primer 13550SENGLISHUS : Section 8. Exposure controls/personal protection and chromates (as CrO3)] CEIL: 0.1 mg/m?, (as CrO3) OSHA PEL Z2 (United States, 2/2013). [Chromic acid and chromates] CEIL: 1 mg/10m? NIOSH REL (United States, 10/2020). [chromic acid and chromates] TWA: 0.0002 mg/m?, (as Cr) 8 hours. ACGIH TLV (United States, 1/2023). [inorganic chromium VI compounds] TWA: 0.0002 mg/m?, (measured as Cr) 8 hours. Form: Inhalable fraction STEL: 0.0005 mg/m?, (measured as Cr) 15 minutes. Form: Inhalable fraction OSHA PEL (United States, 5/2018). [Chromium (VI) compounds] TWA: 0.005 mg/m?, (as Cr) 8 hours. CAL OSHA PEL (United States, 5/2018). [chromium (vi) compounds] C: 0.1 mg/m?, (as Cr) TWA: 0.005 mg/m?, (as Cr) 8 hours. Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles and/ or face shield. If inhalation hazards exist, a full-face respirator may be required instead. Eye/face protection : : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Date of issue : 2/7/2024 Version : 9 9/17 Epoxy Primer 13550SENGLISHUS : Section 8. Exposure controls/personal protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Vapor pressure Density Vapor density Solubility(ies) Liquid. Technically not possible to measure 1.495 g/cm? Not available. 1.6 kPa (12.3 mm Hg) Not available.Odor pH Green.Color Evaporation rate Not available. Auto-ignition temperature Flash point 280?C (536?F) Closed cup: 3.389?C (38.1?F) Not applicable. Not applicable. Viscosity Not available. Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : : Boiling point : 56 to 3000?C (132.8 to 5432?F) Flammability (solid, gas) : Not available. Decomposition temperature : Not applicable. Flow time (ISO 2431) : Not available. Appearance Lower and upper explosive (flammable) limits : Lower: 0.8% Upper: 12.8% cold water Partially soluble Media Result Date of issue : 2/7/2024 Version : 9 10/17 Epoxy Primer 13550SENGLISHUS : Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity strontium chromate LD50 Oral Rat 3118 mg/kg - acetone LC50 Inhalation Vapor Rat 21 mg/l 4 hours LD50 Dermal Rabbit 2001 mg/kg - LD50 Oral Rat 5800 mg/kg - 2,6-dimethylheptan-4-one LD50 Dermal Rabbit 16120 mg/kg - LD50 Oral Rat 5750 mg/kg - butan-1-ol LC50 Inhalation Vapor Rat 24000 mg/m? 4 hours LD50 Dermal Rabbit 3400 mg/kg - LD50 Oral Rat 790 mg/kg - solvent naphtha (petroleum), light aromatic LD50 Dermal Rabbit 3492 mg/kg - LD50 Oral Rat 8400 mg/kg - 4-chloro-?,?,?-trifluorotoluene LD50 Oral Rat 13 g/kg - heptan-2-one LC50 Inhalation Vapor Rat 16.8 mg/l 4 hours LD50 Dermal Rabbit 10332 mg/kg - LD50 Oral Rat 1600 mg/kg - ethylbenzene LD50 Dermal Rabbit >5000 mg/kg - LD50 Oral Rat 3500 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Information on toxicological effects Date of issue : 2/7/2024 Version : 9 11/17 Epoxy Primer 13550SENGLISHUS : Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. acetone Eyes - Mild irritant Human - 186300 ppm - Eyes - Mild irritant Rabbit - 10 uL - Eyes - Moderate irritant Rabbit - 24 hours 20 mg - Eyes - Severe irritant Rabbit - 20 mg - Skin - Mild irritant Rabbit - 395 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - butan-1-ol Eyes - Cornea opacity Rabbit 2.11 - 7 days Eyes - Severe irritant Rabbit - 0.005 Ml - Eyes - Severe irritant Rabbit - 24 hours 2 mg - Skin - Moderate irritant Rabbit - 24 hours 20 mg - heptan-2-one Skin - Mild irritant Rabbit - 24 hours 14 mg - ethylbenzene Skin - Mild irritant Rabbit - 24 hours 15 mg - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Specific target organ toxicity (single exposure) strontium chromate Category 3 - Respiratory tract irritation acetone Category 3 - Narcotic effects 2,6-dimethylheptan-4-one Category 3 - Respiratory tract irritation butan-1-ol Category 3 - Respiratory tract irritation Category 3 Narcotic effects solvent naphtha (petroleum), light aromatic Category 3 - Respiratory tract Name Category Route of exposure Target organs Classification titanium dioxide - 2B - strontium chromate + 1 Known to be a human carcinogen. 4-chloro-?,?,?-trifluorotoluene - 2B - ethylbenzene - 2B - barium chromate + 1 Known to be a human carcinogen. Product/ingredient name NTPIARCOSHA Date of issue : 2/7/2024 Version : 9 12/17 Epoxy Primer 13550SENGLISHUS : Section 11. Toxicological information Information on the likely routes of exposure Inhalation : Toxic if inhaled. May cause respiratory irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. No known significant effects or critical hazards.:Ingestion Skin contact : May cause an allergic skin reaction. Causes serious eye damage.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing wheezing and breathing difficulties asthma reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: pain or irritation redness blistering may occur reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact : Adverse symptoms may include the following: pain watering redness Specific target organ toxicity (repeated exposure) irritation Category 3 Narcotic effects 4-chloro-?,?,?-trifluorotoluene Category 3 - Respiratory tract irritation heptan-2-one Category 3 - Narcotic effects 4,6-dimethylheptan-2-one Category 3 - Respiratory tract irritation Name Category ethylbenzene Category 2 - - barium chromate Category 1 - liver, respiratory tract Aspiration hazard Name Result solvent naphtha (petroleum), light aromatic ASPIRATION HAZARD - Category 1 ethylbenzene ASPIRATION HAZARD - Category 1 Route of exposure Target organs : Not available. Potential acute health effects Date of issue : 2/7/2024 Version : 9 13/17 Epoxy Primer 13550SENGLISHUS : Section 11. Toxicological information Not available. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels. General : May cause cancer. Risk of cancer depends on duration and level of exposure.Carcinogenicity : May cause genetic defects.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : Suspected of damaging fertility. Ingestion Adverse symptoms may include the following: stomach pains reduced fetal weight increase in fetal deaths skeletal malformations : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 5050.71 mg/kg Dermal 20527.92 mg/kg Inhalation (vapors) 944.16 mg/l Inhalation (dusts and mists) 0.64 mg/l Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information There are no data available on the product itself. The product should not be allowed to enter drains or watercourses waterways. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a :Disposal methods Date of issue : 2/7/2024 Version : 9 14/17 Epoxy Primer 13550SENGLISHUS : Section 13. Disposal considerations safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Section 14. Transport information Reportable quantity 150.69 lbs / 68.413 kg [12.089 gal / 45.761 L]. Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. The marine pollutant mark is not required when transported in sizes of ?5 L or ?5 kg. The environmentally hazardous substance mark may appear if required by other transportation regulations. Additional information Special precautions for user Transport in bulk according to IMO instruments Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3), 2.26-2.36 (Class 6). DOT Classification TDG Classification IMDG IATA : : : : FLAMMABLE LIQUID, TOXIC, N. O.S. (acetone, strontium chromate) 3 (6.1) II FLAMMABLE LIQUID, TOXIC, N. O.S. (acetone, strontium chromate) 3 (6.1) II FLAMMABLE LIQUID, TOXIC, N. O.S. (acetone, strontium chromate) UN1992 3 (6.1) II UN1992 UN1992 DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. Yes. Yes. The environmentally hazardous substance mark is not required. TDG Classification UN1992 FLAMMABLE LIQUID, TOXIC, N. O.S. (acetone, strontium chromate) 3 (6.1) II No. Mexico Classification UN1992 FLAMMABLE LIQUID, TOXIC, N. O.S. (acetone, strontium chromate) 3 (6.1) II No. Date of issue : 2/7/2024 Version : 9 15/17 Epoxy Primer 13550SENGLISHUS : Section 14. Transport information The actual shipping description for this product may vary based several factors including, but not limited to, the volume of material, size of the container, mode of transport and use of exemptions or exceptions found in the applicable regulations. The information provided in Section 14 is one possible shipping description for this product. Consult your shipping specialist or supplier for appropriate assignment information. Section 15. Regulatory information SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. strontium chromate 7789-06-2 ?6.7 butan-1-ol 71-36-3 ?4.4 trizinc bis(orthophosphate) 7779-90-0 ?3 ethylbenzene 100-41-4 ?0.3 barium chromate 10294-40-3 ?0.3 strontium chromate 7789-06-2 ?6.7 butan-1-ol 71-36-3 ?4.4 trizinc bis(orthophosphate) 7779-90-0 ?3 ethylbenzene 100-41-4 ?0.3 barium chromate 10294-40-3 ?0.3 Form R - Reporting requirements Supplier notification Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) : Listed SARA 304 RQ SARA 304 RQ : Not applicable. Inventory list Canada : At least one component is not listed. United States : All components are listed or exempted. SARA 311/312 Classification : FLAMMABLE LIQUIDS - Category 2 ACUTE TOXICITY (inhalation) - Category 3 SERIOUS EYE DAMAGE - Category 1 RESPIRATORY SENSITIZATION - Category 1 SKIN SENSITIZATION - Category 1 GERM CELL MUTAGENICITY - Category 1 CARCINOGENICITY - Category 1A TOXIC TO REPRODUCTION - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Section 16. Other information Hazardous Material Information System (U.S.A.) 3 3 0 *Health Flammability Physical hazards Date of issue : 2/7/2024 Version : 9 16/17 Epoxy Primer 13550SENGLISHUS : Section 16. Other information History Date of issue Version This product is intended for industrial use only. Safety Data Sheet (SDS) content is believed to be accurate as of its issue date, but is subject to change as new information is received by Axalta Coatings Systems, LLC or any of its subsidiaries or affiliates (Axalta). This SDS may incorporate information that has been provided to Axalta by its suppliers. Users should ensure that they are referring to the most current version of the SDS. Users are responsible for following the precautions identified in this SDS. It is the users? responsibility to comply with all laws and regulations applicable to the safe handling, use, and disposal of the product. Users of Axalta products should read all relevant product information prior to use, and make their own determination as to the suitability of the products for their intended use. Except as otherwise required by applicable law, AXALTA MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE. The information on this SDS relates only to the specific product identified in Section 1, Identification, and does not relate to its possible use in combination with any other material or in any specific process. If this product is to be used in combination with other products, Axalta encourages you to read and understand the SDS for all products prior to use. Notice to reader : : Indicates information that has changed from previously issued version. Key to abbreviations : ATE = Acute Toxicity Estimate GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 2/7/2024 9 0 3 3 National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Product stewardship and regulatory compliance. ? 2022 Axalta Coating Systems, LLC and all affiliates. All rights reserved. Copies may be made only for those using Axalta Coating Systems products. Date of issue : 2/7/2024 Version : 9 17/17