3M? Super-Fast Repair Adhesive PN 04747 05/09/24 ________________________________________________________________________________________________________ Page 1 of 2 Safety Data Sheet Copyright,2024, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 28-1002-6 Version Number: 5.00 Issue Date: 05/09/24 Supercedes Date: 08/27/19 Product identifier 3M? Super-Fast Repair Adhesive PN 04747 ID Number(s): 41-0003-6764-3, 60-4550-5242-7 7100006276 Recommended use Automotive Supplier's details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) This product is a kit or a multipart product which consists of multiple, independently packaged components. A Safety Data Sheet (SDS), Article Information Sheet (AIS), or Article Information Letter (AIL) for each of these components is included. Please do not separate the component documents from this cover page. The document numbers for components of this product are: 22-1807-1, 22-1870-9 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M? Super-Fast Repair Adhesive PN 04747 05/09/24 ________________________________________________________________________________________________________ Page 2 of 2 3M USA SDSs are available at www.3M.com 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 1 of 12 Safety Data Sheet Copyright,2022, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 22-1807-1 Version Number: 8.02 Issue Date: 06/07/22 Supercedes Date: 04/25/19 SECTION 1: Identification 1.1. Product identifier 3M? Super-Fast Repair Adhesive PN 04747 - Part A Product Identification Numbers LB-K100-0780-5, LA-D100-0021-7 1.2. Recommended use and restrictions on use Recommended use Two-part urethane system., Industrial use 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Respiratory Sensitizer: Category 1. Skin Sensitizer: Category 1. Specific Target Organ Toxicity (single exposure): Category 3. Specific Target Organ Toxicity (repeated exposure): Category 1. 2.2. Label elements Signal word Danger Symbols 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 2 of 12 Exclamation mark | Health Hazard | Pictograms Hazard Statements Causes serious eye irritation. Causes skin irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation. Causes damage to organs through prolonged or repeated exposure: respiratory system | Precautionary Statements Prevention: Do not breathe dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. In case of inadequate ventilation wear respiratory protection. Wear protective gloves and eye/face protection. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF INHALED: Remove person to fresh air and keep comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Get medical advice/attention if you feel unwell. Storage: Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Supplemental Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. 39% of the mixture consists of ingredients of unknown acute oral toxicity. 39% of the mixture consists of ingredients of unknown acute dermal toxicity. 2% of the mixture consists of ingredients of unknown acute inhalation toxicity. 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 3 of 12 SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt P,P'-Methylenebis(phenyl isocyanate) 101-68-8 30 - 65 Trade Secret * Castor Oil, Polymer With 1,1'-Methylenebis[4- Isocyanatobenzene] 68424-09-9 15 - 40 Trade Secret * 4,4'-Diisocyanatodiphenylmethane Polymer 25686-28-6 5 - 25 Trade Secret * 3-(Trimethoxysilyl)Propyl Glycidyl Ether 2530-83-8 < 5 Trade Secret * Isocyanic Acid, 3-(Triethyoxysilyl)propyl Ester 24801-88-5 < 1 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Irritating to the respiratory tract (coughing, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain). Allergic respiratory reaction (difficulty breathing, wheezing, cough, and tightness of chest). Allergic skin reaction (redness, swelling, blistering, and itching). Target organ effects following prolonged or repeated exposure. See Section 11 for additional details. 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Hydrogen Cyanide During Combustion Oxides of Nitrogen During Combustion Toxic Vapor, Gas, Particulate During Combustion 5.3. Special protective actions for fire-fighters 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 4 of 12 Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Contain spill. Pour isocyanate decontaminant solution (90% water, 8% concentrated ammonia, 2% detergent) on spill and allow to react for 10 minutes. Or pour water on spill and allow to react for more than 30 minutes. Cover with absorbent material. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a container approved for transportation by appropriate authorities, but do not seal the container for 48 hours to avoid pressure build-up. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. SECTION 7: Handling and storage 7.1. Precautions for safe handling Do not use in a confined area with minimal air exchange. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. 7.2. Conditions for safe storage including any incompatibilities Store in a well-ventilated place. Keep container tightly closed to prevent contamination with water or air. If contamination is suspected, do not reseal container. Store away from acids. Store away from strong bases. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments P,P'-Methylenebis(phenyl isocyanate) 101-68-8 ACGIH TWA:0.005 ppm P,P'-Methylenebis(phenyl isocyanate) 101-68-8 OSHA CEIL:0.2 mg/m3(0.02 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 5 of 12 CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity. Gloves made from the following material(s) are recommended: Polymer laminate If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate Respiratory protection In case of inadequate ventilation wear respiratory protection. An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Colorless Specific Physical Form: Viscous Odor Low Odor, Odorless Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point >=400 ?F Flash Point >=290 ?F [Test Method:Tagliabue Closed Cup] Evaporation rate <=1 [Details:Gels with exposure to humidity.] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 6 of 12 Flammable Limits(UEL) Not Applicable Vapor Pressure <=0.000004 mmHg [@ 68 ?F] Vapor Density >=1 [Ref Std:AIR=1] Density 1.1 g/ml Specific Gravity 1.1 [Ref Std:WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature Not Applicable Decomposition temperature No Data Available Viscosity 1,000 - 2,000 centipoise Hazardous Air Pollutants 42.133 lb HAPS/lb solids Molecular weight No Data Available Volatile Organic Compounds 22 g/l [Test Method:calculated SCAQMD rule 443.1] Volatile Organic Compounds 2.0 % weight [Test Method:calculated per CARB title 2] Percent volatile 2.0 % weight [Test Method:Estimated] VOC Less H2O & Exempt Solvents 22 g/l [Test Method:calculated SCAQMD rule 443.1] SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials Water Strong acids Strong bases 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 7 of 12 Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: May be harmful if inhaled. Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Allergic Respiratory Reaction: Signs/symptoms may include difficulty breathing, wheezing, cough, and tightness of chest. May cause additional health effects (see below). Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Additional Health Effects: Prolonged or repeated exposure may cause target organ effects: Respiratory Effects: Signs/symptoms may include cough, shortness of breath, chest tightness, wheezing, increased heart rate, bluish colored skin (cyanosis), sputum production, changes in lung function tests, and/or respiratory failure. Additional Information: Persons previously sensitized to isocyanates may develop a cross-sensitization reaction to other isocyanates. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Vapor(4 hr) No data available; calculated ATE >20 - =50 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Dermal Rabbit LD50 > 5,000 mg/kg P,P'-Methylenebis(phenyl isocyanate) Inhalation- Dust/Mist (4 hours) Rat LC50 0.368 mg/l P,P'-Methylenebis(phenyl isocyanate) Ingestion Rat LD50 31,600 mg/kg 4,4'-Diisocyanatodiphenylmethane Polymer Dermal Rabbit LD50 > 5,000 mg/kg 4,4'-Diisocyanatodiphenylmethane Polymer Inhalation- Dust/Mist (4 hours) Rat LC50 0.368 mg/l 4,4'-Diisocyanatodiphenylmethane Polymer Ingestion Rat LD50 31,600 mg/kg 3-(Trimethoxysilyl)Propyl Glycidyl Ether Dermal Rabbit LD50 4,000 mg/kg 3-(Trimethoxysilyl)Propyl Glycidyl Ether Inhalation- Dust/Mist (4 hours) Rat LC50 > 5.3 mg/l 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Rat LD50 7,010 mg/kg Isocyanic Acid, 3-(Triethyoxysilyl)propyl Ester Dermal Rabbit LD50 1,259 mg/kg 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 8 of 12 Isocyanic Acid, 3-(Triethyoxysilyl)propyl Ester Inhalation- Vapor (4 hours) Rat LC50 0.36 mg/l Isocyanic Acid, 3-(Triethyoxysilyl)propyl Ester Ingestion Rat LD50 706 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value P,P'-Methylenebis(phenyl isocyanate) official classifica tion Irritant 4,4'-Diisocyanatodiphenylmethane Polymer official classifica tion Irritant 3-(Trimethoxysilyl)Propyl Glycidyl Ether Rabbit Mild irritant Isocyanic Acid, 3-(Triethyoxysilyl)propyl Ester Rabbit Corrosive Serious Eye Damage/Irritation Name Species Value P,P'-Methylenebis(phenyl isocyanate) official classifica tion Severe irritant 4,4'-Diisocyanatodiphenylmethane Polymer official classifica tion Severe irritant 3-(Trimethoxysilyl)Propyl Glycidyl Ether Rabbit Corrosive Isocyanic Acid, 3-(Triethyoxysilyl)propyl Ester Rabbit Corrosive Skin Sensitization Name Species Value P,P'-Methylenebis(phenyl isocyanate) official classifica tion Sensitizing 4,4'-Diisocyanatodiphenylmethane Polymer official classifica tion Sensitizing 3-(Trimethoxysilyl)Propyl Glycidyl Ether Guinea pig Not classified Isocyanic Acid, 3-(Triethyoxysilyl)propyl Ester similar compoun ds Sensitizing Respiratory Sensitization Name Species Value P,P'-Methylenebis(phenyl isocyanate) Human Sensitizing 4,4'-Diisocyanatodiphenylmethane Polymer Human Sensitizing Isocyanic Acid, 3-(Triethyoxysilyl)propyl Ester similar compoun ds Sensitizing Germ Cell Mutagenicity Name Route Value P,P'-Methylenebis(phenyl isocyanate) In Vitro Some positive data exist, but the data are not sufficient for classification 4,4'-Diisocyanatodiphenylmethane Polymer In Vitro Some positive data exist, but the data are not sufficient for classification 3-(Trimethoxysilyl)Propyl Glycidyl Ether In vivo Not mutagenic 3-(Trimethoxysilyl)Propyl Glycidyl Ether In Vitro Some positive data exist, but the data are not sufficient for classification 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 9 of 12 Carcinogenicity Name Route Species Value P,P'-Methylenebis(phenyl isocyanate) Inhalation Rat Some positive data exist, but the data are not sufficient for classification 4,4'-Diisocyanatodiphenylmethane Polymer Inhalation Rat Some positive data exist, but the data are not sufficient for classification 3-(Trimethoxysilyl)Propyl Glycidyl Ether Dermal Mouse Not carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration P,P'-Methylenebis(phenyl isocyanate) Inhalation Not classified for development Rat NOAEL 0.004 mg/l during organogenesi s 4,4'-Diisocyanatodiphenylmethane Polymer Inhalation Not classified for development Rat NOAEL 0.004 mg/l during organogenesi s 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Not classified for female reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Not classified for male reproduction Rat NOAEL 1,000 mg/kg/day 1 generation 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion Not classified for development Rat NOAEL 3,000 mg/kg/day during organogenesi s Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available 4,4'- Diisocyanatodiphenylmeth ane Polymer Inhalation respiratory irritation May cause respiratory irritation official classifica tion NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration P,P'-Methylenebis(phenyl isocyanate) Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks 4,4'- Diisocyanatodiphenylmeth ane Polymer Inhalation respiratory system Causes damage to organs through prolonged or repeated exposure Rat LOAEL 0.004 mg/l 13 weeks 3-(Trimethoxysilyl)Propyl Glycidyl Ether Ingestion heart | endocrine system | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | nervous system | kidney and/or bladder | respiratory system Not classified Rat NOAEL 1,000 mg/kg/day 28 days Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 10 of 12 on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory requirements. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Not applicable Health Hazards Respiratory or Skin Sensitization Serious eye damage or eye irritation Skin Corrosion or Irritation Specific target organ toxicity (single or repeated exposure) 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 11 of 12 Section 313 Toxic Chemicals subject to the reporting requirements of that section and 40 CFR part 372 (EPCRA): Ingredient C.A.S. No % by Wt P,P'-Methylenebis(phenyl isocyanate) 101-68-8 Trade Secret 30 - 65 P,P'-Methylenebis(phenyl isocyanate) (Benzene, 1,1'- methylenebis[4-isocyanato-) 101-68-8 Trade Secret 30 - 65 P,P'-Methylenebis(phenyl isocyanate) (DIISOCYANATES (CERTAIN CHEMICALS ONLY)) 101-68-8 Trade Secret 30 - 65 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: *3 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 22-1807-1 Version Number: 8.02 Issue Date: 06/07/22 Supercedes Date: 04/25/19 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer 3M? Super-Fast Repair Adhesive PN 04747 - Part A 06/07/22 __________________________________________________________________________________________ Page 12 of 12 may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 1 of 12 Safety Data Sheet Copyright,2024, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit thereon. Document Group: 22-1870-9 Version Number: 5.02 Issue Date: 05/08/24 Supercedes Date: 05/15/19 SECTION 1: Identification 1.1. Product identifier 3M? Super Fast Adhesive PN 04747 (Part B) Product Identification Numbers LB-K100-0780-6, LA-D100-0023-3 1.2. Recommended use and restrictions on use Recommended use Two-part urethane system., Industrial use 1.3. Supplier?s details MANUFACTURER: 3M DIVISION: Automotive Aftermarket ADDRESS: 3M Center, St. Paul, MN 55144-1000, USA Telephone: 1-888-3M HELPS (1-888-364-3577) 1.4. Emergency telephone number 1-800-364-3577 or (651) 737-6501 (24 hours) SECTION 2: Hazard identification The label elements below were prepared in accordance with OSHA Hazard Communication Standard, 29 CFR 1910.1200. This information may be different from the actual product label information for labels regulated by other agencies. 2.1. Hazard classification Serious Eye Damage/Irritation: Category 2A. Skin Corrosion/Irritation: Category 2. Skin Sensitizer: Category 1. 2.2. Label elements Signal word Warning Symbols Exclamation mark | Pictograms 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 2 of 12 Hazard Statements Causes serious eye irritation. Causes skin irritation. May cause an allergic skin reaction. Precautionary Statements General: Keep out of reach of children. Prevention: Avoid breathing dust/fume/gas/mist/vapors/spray. Wear protective gloves and eye/face protection. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Response: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. Take off contaminated clothing and wash it before reuse. Disposal: Dispose of contents/container in accordance with applicable local/regional/national/international regulations. Supplemental Information: Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines. 18% of the mixture consists of ingredients of unknown acute inhalation toxicity. SECTION 3: Composition/information on ingredients Ingredient C.A.S. No. % by Wt Polyether Polyol 9082-00-2 40 - 70 Trade Secret * Propoxylated Glycerol 25791-96-2 10 - 30 Trade Secret * Tetrakis(2-Hydroxypropyl)Ethylenediamine 102-60-3 10 - 30 Trade Secret * M-Xylene-Alpha,Alpha'-Diamine 1477-55-0 < 3 Trade Secret * BHT 128-37-0 < 0.5 Trade Secret * Propylene Oxide 75-56-9 < 0.001 Trade Secret * *The specific chemical identity and/or exact percentage (concentration) of this composition has been withheld as a trade secret. SECTION 4: First aid measures 4.1. Description of first aid measures 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 3 of 12 Inhalation: Remove person to fresh air. If you feel unwell, get medical attention. Skin Contact: Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention. Eye Contact: Immediately flush with large amounts of water. Remove contact lenses if easy to do. Continue rinsing. Get medical attention. If Swallowed: Rinse mouth. If you feel unwell, get medical attention. 4.2. Most important symptoms and effects, both acute and delayed Allergic skin reaction (redness, swelling, blistering, and itching). 4.3. Indication of any immediate medical attention and special treatment required Not applicable SECTION 5: Fire-fighting measures 5.1. Suitable extinguishing media In case of fire: Use a dry chemical extinguisher to extinguish. 5.2. Special hazards arising from the substance or mixture None inherent in this product. Hazardous Decomposition or By-Products Substance Condition Carbon monoxide During Combustion Carbon dioxide During Combustion Oxides of Nitrogen During Combustion 5.3. Special protective actions for fire-fighters Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment. 6.2. Environmental precautions Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water. 6.3. Methods and material for containment and cleaning up Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations. 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 4 of 12 SECTION 7: Handling and storage 7.1. Precautions for safe handling Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.) 7.2. Conditions for safe storage including any incompatibilities Store away from acids. Store away from oxidizing agents. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Occupational exposure limits If a component is disclosed in section 3 but does not appear in the table below, an occupational exposure limit is not available for the component. Ingredient C.A.S. No. Agency Limit type Additional Comments BHT 128-37-0 ACGIH TWA(inhalable fraction and vapor):2 mg/m3 A4: Not class. as human carcin M-Xylene-Alpha,Alpha'-Diamine 1477-55-0 ACGIH CEIL:0.018 ppm Danger of cutaneous absorption Propylene Oxide 75-56-9 ACGIH TWA:2 ppm A3: Confirmed animal carcin., Dermal Sensitizer Propylene Oxide 75-56-9 OSHA TWA:240 mg/m3(100 ppm) ACGIH : American Conference of Governmental Industrial Hygienists AIHA : American Industrial Hygiene Association CMRG : Chemical Manufacturer's Recommended Guidelines OSHA : United States Department of Labor - Occupational Safety and Health Administration TWA: Time-Weighted-Average STEL: Short Term Exposure Limit CEIL: Ceiling 8.2. Exposure controls 8.2.1. Engineering controls Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment. 8.2.2. Personal protective equipment (PPE) Eye/face protection Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended: Safety Glasses with side shields Indirect Vented Goggles Skin/hand protection Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 5 of 12 clothing. Gloves made from the following material(s) are recommended: Butyl Rubber Neoprene Natural Rubber If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron ? Butyl rubber Apron - Neoprene Apron - polymer laminate Respiratory protection An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure: Half facepiece or full facepiece air-purifying respirator suitable for organic vapors and particulates For questions about suitability for a specific application, consult with your respirator manufacturer. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Appearance Physical state Color Liquid Colorless Specific Physical Form: Gel Odor Slight Ammoniacal Odor threshold No Data Available pH Not Applicable Melting point No Data Available Boiling Point >=400 ?F Flash Point >=290 ?F [Test Method:Tagliabue Closed Cup] Evaporation rate <=1 [Ref Std:WATER=1] Flammability (solid, gas) Not Applicable Flammable Limits(LEL) Not Applicable Flammable Limits(UEL) Not Applicable Vapor Pressure Not Applicable Vapor Density >=1 [Ref Std:AIR=1] Density 1.02 g/ml Specific Gravity 1.02 [Ref Std:WATER=1] Solubility in Water Negligible Solubility- non-water No Data Available Partition coefficient: n-octanol/ water No Data Available Autoignition temperature Not Applicable Decomposition temperature No Data Available Viscosity 1,300 - 2,000 centipoise Hazardous Air Pollutants 0 lb HAPS/lb solids [Test Method:Calculated] Molecular weight No Data Available Volatile Organic Compounds 0 % weight [Test Method:calculated per CARB title 2] Volatile Organic Compounds 0 g/l [Test Method:calculated SCAQMD rule 443.1] Percent volatile <=1 % weight [Test Method:Estimated] VOC Less H2O & Exempt Solvents 0 g/l [Test Method:calculated SCAQMD rule 443.1] 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 6 of 12 SECTION 10: Stability and reactivity 10.1. Reactivity This material may be reactive with certain agents under certain conditions - see the remaining headings in this section. 10.2. Chemical stability Stable. 10.3. Possibility of hazardous reactions Hazardous polymerization will not occur. 10.4. Conditions to avoid None known. 10.5. Incompatible materials Strong acids Strong oxidizing agents 10.6. Hazardous decomposition products Substance Condition None known. Refer to section 5.2 for hazardous decomposition products during combustion. SECTION 11: Toxicological information The information below may not be consistent with the material classification in Section 2 if specific ingredient classifications are mandated by a competent authority. In addition, toxicological data on ingredients may not be reflected in the material classification and/or the signs and symptoms of exposure, because an ingredient may be present below the threshold for labeling, an ingredient may not be available for exposure, or the data may not be relevant to the material as a whole. 11.1. Information on Toxicological effects Signs and Symptoms of Exposure Based on test data and/or information on the components, this material may produce the following health effects: Inhalation: Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and throat pain. Skin Contact: Skin Irritation: Signs/symptoms may include localized redness, swelling, itching, dryness, cracking, blistering, and pain. Allergic Skin Reaction (non-photo induced): Signs/symptoms may include redness, swelling, blistering, and itching. Eye Contact: Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and impaired vision. Ingestion: Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea. Carcinogenicity: 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 7 of 12 Ingredient CAS No. Class Description Regulation Propylene oxide 75-56-9 Grp. 2B: Possible human carc. International Agency for Research on Cancer Propylene Oxide 75-56-9 Anticipated human carcinogen National Toxicology Program Carcinogens Additional Information: Persons previously sensitized to amines may develop a cross-sensitization reaction to certain other amines. Toxicological Data If a component is disclosed in section 3 but does not appear in a table below, either no data are available for that endpoint or the data are not sufficient for classification. Acute Toxicity Name Route Species Value Overall product Dermal No data available; calculated ATE >5,000 mg/kg Overall product Inhalation- Dust/Mist(4 hr) No data available; calculated ATE >12.5 mg/l Overall product Ingestion No data available; calculated ATE >5,000 mg/kg Polyether Polyol Dermal similar compoun ds LD50 > 2,000 mg/kg Polyether Polyol Inhalation- Dust/Mist (4 hours) similar compoun ds LC50 > 3.2 mg/l Polyether Polyol Ingestion similar compoun ds LD50 > 5,000 mg/kg Propoxylated Glycerol Dermal Rat LD50 > 2,000 mg/kg Propoxylated Glycerol Inhalation- Dust/Mist (4 hours) Rat LC50 > 50 mg/l Propoxylated Glycerol Ingestion Rat LD50 4,600 mg/kg Tetrakis(2-Hydroxypropyl)Ethylenediamine Dermal Rat LD50 > 2,000 mg/kg Tetrakis(2-Hydroxypropyl)Ethylenediamine Ingestion Rat LD50 2,890 mg/kg M-Xylene-Alpha,Alpha'-Diamine Dermal Rabbit LD50 > 2,000 mg/kg M-Xylene-Alpha,Alpha'-Diamine Inhalation- Dust/Mist (4 hours) Rat LC50 1.2 mg/l M-Xylene-Alpha,Alpha'-Diamine Ingestion Rat LD50 980 mg/kg BHT Dermal Rat LD50 > 2,000 mg/kg BHT Ingestion Rat LD50 > 2,930 mg/kg Propylene Oxide Dermal Rabbit LD50 950 mg/kg Propylene Oxide Inhalation- Vapor (4 hours) Rat LC50 9.5 mg/l Propylene Oxide Ingestion Rat LD50 520 mg/kg ATE = acute toxicity estimate Skin Corrosion/Irritation Name Species Value Polyether Polyol similar compoun ds Minimal irritation Propoxylated Glycerol Rabbit No significant irritation Tetrakis(2-Hydroxypropyl)Ethylenediamine Rabbit No significant irritation M-Xylene-Alpha,Alpha'-Diamine Rat Corrosive BHT Human and animal Minimal irritation Propylene Oxide Rabbit Irritant 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 8 of 12 Serious Eye Damage/Irritation Name Species Value Polyether Polyol similar compoun ds Mild irritant Propoxylated Glycerol Rabbit Mild irritant Tetrakis(2-Hydroxypropyl)Ethylenediamine Rabbit Severe irritant M-Xylene-Alpha,Alpha'-Diamine Rabbit Corrosive BHT Rabbit Mild irritant Propylene Oxide Rabbit Severe irritant Skin Sensitization Name Species Value Polyether Polyol similar compoun ds Not classified Tetrakis(2-Hydroxypropyl)Ethylenediamine Guinea pig Not classified M-Xylene-Alpha,Alpha'-Diamine Guinea pig Sensitizing BHT Human Not classified Propylene Oxide Human Not classified Respiratory Sensitization For the component/components, either no data are currently available or the data are not sufficient for classification. Germ Cell Mutagenicity Name Route Value Polyether Polyol In Vitro Not mutagenic Tetrakis(2-Hydroxypropyl)Ethylenediamine In Vitro Not mutagenic M-Xylene-Alpha,Alpha'-Diamine In Vitro Not mutagenic M-Xylene-Alpha,Alpha'-Diamine In vivo Not mutagenic BHT In Vitro Not mutagenic BHT In vivo Not mutagenic Propylene Oxide In Vitro Some positive data exist, but the data are not sufficient for classification Propylene Oxide In vivo Mutagenic Carcinogenicity Name Route Species Value BHT Ingestion Multiple animal species Some positive data exist, but the data are not sufficient for classification Propylene Oxide Ingestion Rat Carcinogenic Propylene Oxide Inhalation Multiple animal species Carcinogenic Reproductive Toxicity Reproductive and/or Developmental Effects Name Route Value Species Test Result Exposure Duration Tetrakis(2-Hydroxypropyl)Ethylenediamine Ingestion Not classified for female reproduction Rat NOAEL 1,000 mg/kg/day premating into lactation Tetrakis(2-Hydroxypropyl)Ethylenediamine Ingestion Not classified for male reproduction Rat NOAEL 1,000 mg/kg/day 30 days Tetrakis(2-Hydroxypropyl)Ethylenediamine Ingestion Not classified for development Rat NOAEL 1,000 mg/kg/day premating into lactation M-Xylene-Alpha,Alpha'-Diamine Ingestion Not classified for female reproduction Rat NOAEL 450 1 generation 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 9 of 12 mg/kg/day M-Xylene-Alpha,Alpha'-Diamine Ingestion Not classified for male reproduction Rat NOAEL 450 mg/kg 1 generation M-Xylene-Alpha,Alpha'-Diamine Ingestion Not classified for development Rat NOAEL 450 mg/kg/day 1 generation BHT Ingestion Not classified for female reproduction Rat NOAEL 500 mg/kg/day 2 generation BHT Ingestion Not classified for male reproduction Rat NOAEL 500 mg/kg/day 2 generation BHT Ingestion Not classified for development Rat NOAEL 100 mg/kg/day 2 generation Propylene Oxide Inhalation Not classified for male reproduction Rat NOAEL 0.71 mg/l 14 weeks Propylene Oxide Inhalation Not classified for female reproduction Multiple animal species LOAEL 1.2 mg/l premating & during gestation Propylene Oxide Inhalation Not classified for development Multiple animal species LOAEL 1.2 mg/l premating & during gestation Target Organ(s) Specific Target Organ Toxicity - single exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Tetrakis(2- Hydroxypropyl)Ethylenedi amine Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification similar health hazards NOAEL Positive M-Xylene-Alpha,Alpha'- Diamine Inhalation respiratory irritation Some positive data exist, but the data are not sufficient for classification Not available NOAEL Not avaliable Propylene Oxide Inhalation respiratory irritation May cause respiratory irritation NOAEL Not available Specific Target Organ Toxicity - repeated exposure Name Route Target Organ(s) Value Species Test Result Exposure Duration Tetrakis(2- Hydroxypropyl)Ethylenedi amine Ingestion nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 300 mg/kg/day 30 days Tetrakis(2- Hydroxypropyl)Ethylenedi amine Ingestion heart | skin | endocrine system | gastrointestinal tract | bone, teeth, nails, and/or hair | hematopoietic system | liver | immune system | muscles | eyes | kidney and/or bladder | respiratory system | vascular system Not classified Rat NOAEL 1,000 mg/kg/day 30 days M-Xylene-Alpha,Alpha'- Diamine Ingestion endocrine system | blood | bone marrow Not classified Rat NOAEL 600 mg/kg/day 28 days BHT Ingestion liver Some positive data exist, but the data are not sufficient for classification Rat NOAEL 250 mg/kg/day 28 days BHT Ingestion kidney and/or bladder Not classified Rat NOAEL 500 mg/kg/day 2 generation BHT Ingestion blood Not classified Rat LOAEL 420 mg/kg/day 40 days BHT Ingestion endocrine system Not classified Rat NOAEL 25 mg/kg/day 2 generation BHT Ingestion heart Not classified Mouse NOAEL 10 weeks 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 10 of 12 3,480 mg/kg/day Propylene Oxide Inhalation nervous system Some positive data exist, but the data are not sufficient for classification Rat NOAEL 0.7 mg/l 24 weeks Propylene Oxide Inhalation heart | skin | endocrine system | gastrointestinal tract | bone, teeth, nails, and/or hair | hematopoietic system | immune system | muscles | eyes | kidney and/or bladder Not classified Multiple animal species NOAEL 1 mg/l 103 weeks Propylene Oxide Inhalation liver Not classified Mouse NOAEL 1 mg/l 103 weeks Aspiration Hazard For the component/components, either no data are currently available or the data are not sufficient for classification. Please contact the address or phone number listed on the first page of the SDS for additional toxicological information on this material and/or its components. SECTION 12: Ecological information Ecotoxicological information Please contact the address or phone number listed on the first page of the SDS for additional ecotoxicological information on this material and/or its components. Chemical fate information Please contact the address or phone number listed on the first page of the SDS for additional chemical fate information on this material and/or its components. SECTION 13: Disposal considerations 13.1. Disposal methods Dispose of contents/ container in accordance with the local/regional/national/international regulations. Dispose of completely cured (or polymerized) material in a permitted industrial waste facility. As a disposal alternative, incinerate uncured product in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities. SECTION 14: Transport Information Not regulated per U.S. DOT, IATA or IMO. These transportation classifications are provided as a customer service. As the shipper YOU remain responsible for complying with all applicable laws and regulations, including proper transportation classification and packaging. 3M transportation classifications are based on product formulation, packaging, 3M policies and 3M understanding of applicable current regulations. 3M does not guarantee the accuracy of this classification information. This information applies only to transportation classification and not the packaging, labeling, or marking requirements. The original 3M package is certified for U.S. ground shipment only. If you are shipping by air or ocean, the package may not meet applicable regulatory 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 11 of 12 requirements. SECTION 15: Regulatory information 15.1. US Federal Regulations Contact 3M for more information. EPCRA 311/312 Hazard Classifications: Physical Hazards Not applicable Health Hazards Respiratory or Skin Sensitization Serious eye damage or eye irritation Skin Corrosion or Irritation 15.2. State Regulations Contact 3M for more information. 15.3. Chemical Inventories The components of this product are in compliance with the chemical notification requirements of TSCA. All required components of this product are listed on the active portion of the TSCA Inventory. Contact 3M for more information. 15.4. International Regulations Contact 3M for more information. This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200. SECTION 16: Other information NFPA Hazard Classification Health: 2 Flammability: 1 Instability: 0 Special Hazards: None National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to be generated in significant quantities. HMIS Hazard Classification Health: 2 Flammability: 1 Physical Hazard: 0 Personal Protection: X - See PPE section. Hazardous Material Identification System (HMIS? IV) hazard ratings are designed to inform employees of chemical hazards in the workplace. These ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency situations. HMIS? IV ratings are to be used with a fully implemented HMIS? IV program. HMIS? is a registered mark of the American Coatings Association (ACA). Document Group: 22-1870-9 Version Number: 5.02 Issue Date: 05/08/24 Supercedes Date: 05/15/19 DISCLAIMER: The information in this Safety Data Sheet (SDS) is believed to be correct as of the date issued. 3M MAKES 3M? Super Fast Adhesive PN 04747 (Part B) 05/08/24 __________________________________________________________________________________________ Page 12 of 12 NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a particular purpose and suitable for user's method of use or application. 3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy. In addition, information obtained from a database may not be as current as the information in the SDS available directly from 3M. 3M USA SDSs are available at www.3M.com