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FVP Marine Grease FVPMG-14 Lubricating grease; Material Code: 665523453 FVP MARINE GREASE SAFETY DATA SHEET GHS product identifier Synonyms Emergency telephone number (with hours of operation) Section 1. Identification : : : Supplier's details : Factory Motor Parts 665523453:Code 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 866-387-3343 INFOTRAC 1-800-535-5053 Relevant identified uses of the substance or mixture and uses advised against Not applicable. Section 2. Hazards identification Not classified.Classification of the substance or mixture : Signal word : No signal word. Hazard statements : No known significant effects or critical hazards. Precautionary statements Prevention : Do not get in eyes, on skin, or on clothing. Response : Wash with plenty of soap and water or use a recognized skin cleanser. Storage : Store in accordance with all local, regional, national and international regulations. Store in a dry place and a closed container. Empty containers may contain material residues which can ignite with explosive force. Misuse of empty containers can be dangerous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers can cause fire, explosion, or release of toxic fumes from residues. Do not pressurize or expose empty containers to open flame, sparks, or heat. Keep container closed and drum bungs in place. All label warnings and precautions must be observed. Return empty drums to a qualified reconditioner. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling, or disposing of empty containers and/or waste residues of this material. Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Don't Pollute. Conserve Resources. Return used oil to collection centers. GHS label elements General : Keep out of reach of children. OSHA/HCS status : This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards not otherwise classified : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. Injection of petroleum hydrocarbons requires immediate medical attention. Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 1/11 Rev 7.16.24 FVP Marine Grease Section 3. Composition/information on ingredients Distillates (petroleum), hydrotreated heavy naphthenic ?75 - ?90 64742-52-5 calcium(2+) 12-hydroxyoctadecanoate ?10 3159-62-4 Ingredient name CAS number% Other means of identification : Lubricating grease; CITGO? Material Code: 665523453 CAS number : Not applicable. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to process variation. * = Various ** = Mixture *** = Proprietary There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. Get medical attention if symptoms occur. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if symptoms occur. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. Notes to physician : In the event of injection in underlying tissue, immediate treatment should include extensive incision, debridement and saline irrigation. Inadequate treatment can result in ischemia and gangrene. Early symptoms may be minimal. Description of necessary first aid measures Specific treatments : Treat symptomatically and supportively. Most important symptoms/effects, acute and delayed Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 2/11 FVP Marine Grease Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide sulfur oxides phosphorus oxides metal oxide/oxides No specific fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Move containers from spill area. Vacuum or sweep up material and place in a designated, labeled waste container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section 8).: Precautions for safe handling Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 3/11 FVP Marine Grease Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : Bulk Storage Conditions: Do not apply heat or flame to stockpiled material. Rotate stock to reduce the potential for hot spots. Do not store with oxidizers. Minimize dust creation by keeping material moist and/or covered. Section 8. Exposure controls/personal protection Hand protection Chemical-resistant gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If inhalation hazards exist, a full-face respirator may be required instead. Eye/face protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, vapor controls, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Good general ventilation should be sufficient to control worker exposure to airborne contaminants. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Control parameters Individual protection measures Occupational exposure limits Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Distillates (petroleum), hydrotreated heavy naphthenic OSHA PEL (United States, 5/2018). [Oil mist, mineral] TWA: 5 mg/m? 8 hours. ACGIH TLV (United States, 1/2023). [Mineral Oil, pure, highly and severely refined] TWA: 5 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). [OIL MIST MINERAL] TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist calcium(2+) 12-hydroxyoctadecanoate ACGIH TLV (United States). TWA: 10 mg/m? 8 hours. Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 4/11 FVP Marine Grease Section 8. Exposure controls/personal protection Avoid inhalation of gases, vapors, mists or dusts. Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Respiratory protection : Section 9. Physical and chemical properties Physical state Relative density Solubility Solid. [Smooth texture] 0.92 >1 [Air = 1] Insoluble in the following materials: cold water and hot water. Mild petroleum odorOdor pH Green.Color Evaporation rate <1 (n-butyl acetate. = 1) Not available. : : : : : : : : Appearance Lower and upper explosive (flammable) limits : Lower: 1% Upper: 7% Density lbs/gal Gravity, ?API : : Estimated 22 @ 60 F Estimated 7.67 lbs/gal NLGI Grade 2 : Density gm/cm3 : Not available. Flash point Open cup: >150?C (>302?F) [Estimated]: Boiling point, initial boiling point, and boiling range : Not available. Vapor pressure <0.0013 kPa (<0.01 mm Hg): Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Flow time (ISO 2431) : Not available. Particle characteristics Median particle size : Not available. Auto-ignition temperature : Lowest known value: >158?C (>316.4?F) (calcium(2+) 12-hydroxyoctadecanoate). Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : Not expected to be Explosive, Self-Reactive, Self-Heating, or an Organic Peroxide under US GHS Definition(s). Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 5/11 FVP Marine Grease Section 11. Toxicological information Acute toxicity Distillates (petroleum), hydrotreated heavy naphthenic LD50 Oral Rat >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Not available. Not available. Aspiration hazard Not available. Information on toxicological effects Conclusion/Summary : No additional information. No additional information. Conclusion/Summary : No additional information. Conclusion/Summary : Conclusion/Summary : No additional information. Skin Respiratory : : No additional information. No additional information. Skin Eyes Respiratory : : : No additional information. No additional information. No additional information. Conclusion/Summary : Distillates (petroleum), hydrotreated heavy naphthenic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts: INHALATION (LC50), Acute: > 1310 mg/L (Rat screen level)(4 hours). DRAIZE EYE, Acute: Severe eye irritant. (Rabbit). DRAIZE DERMAL, Acute: Mild to moderate skin irritant. (Rabbit). BUEHLER DERMAL, Acute: Non-sensitizing. (Guinea Pig). 28-Day DERMAL, Sub-Chronic: Severe skin irritant. (Rabbit). Reported reduced food consumption resulting in weight loss and testicular atrophy. Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 6/11 FVP Marine Grease Section 11. Toxicological information Information on the likely routes of exposure Inhalation : No known significant effects or critical hazards. No known significant effects or critical hazards.:Ingestion Skin contact : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. No known significant effects or critical hazards.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation No specific data. No specific data. No specific data. : : : Eye contact : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure : Routes of entry anticipated: Dermal. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Not available. No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Potential chronic health effects Numerical measures of toxicity Acute toxicity estimates Product/ingredient name FVP Marine Grease 241183.6 6322.6 N/A N/A N/A Oral (mg/ kg) Dermal (mg/kg) Inhalation (gases) (ppm) Inhalation (vapors) (mg/l) Inhalation (dusts and mists) (mg/ l) Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 7/11 FVP Marine Grease Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Distillates (petroleum), hydrotreated heavy naphthenic >6 - high Product/ingredient name Aquatic half-life Photolysis Biodegradability Distillates (petroleum), hydrotreated heavy naphthenic - - Inherent Toxicity Distillates (petroleum), hydrotreated heavy naphthenic Acute EC50 >10000 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 >100 mg/l Fresh water Fish - Pimephales promelas 96 hours Acute NOEL >100 mg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Conclusion/Summary : Not available. Conclusion/Summary : Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information - - Not available. Not available. Not available. Not regulated. DOT Classification IATA UN number UN proper shipping name Transport hazard class(es) IMDG Not available. Not available. Not available. Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 8/11 FVP Marine Grease Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : - -Packing group Environmental hazards No. No. - No. Oil: The product(s) represented by this SDS is (are) regulated as ?oil? under 49 CFR Part 130. Shipments by rail or highway in packaging having a capacity of 3500 gallons or more or in a quantity greater 42,000 gallons are subject to these requirements. In addition, mixtures containing 10% or more of this product may be subject to these requirements. Section 15. Regulatory information U.S. Federal regulations None of the components are listed.Massachusetts : : New York : None of the components are listed. New Jersey : The following components are listed: ZINC compounds Pennsylvania : The following components are listed: ZINC COMPOUNDS State regulations SARA 302/304 SARA 304 RQ : Not applicable. Composition/information on ingredients SARA 311/312 Classification : HNOC - Injection Hazards United States inventory (TSCA 8b): All components are listed and active or exempted. Clean Water Act (CWA) 307: Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts; tris(dipentyldithiocarbamato-S,S')antimony; ethylbenzene; chrysene; naphthalene Clean Water Act (CWA) 311: xylene; ethylbenzene; naphthalene This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts 68649-42-3 <2 chrysene 218-01-9 <0.001 Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts 68649-42-3 <2 chrysene 218-01-9 <0.001 Form R - Reporting requirements Supplier notification California Prop. 65 Clear and Reasonable Warnings (2018) No products were found. Composition/information on ingredients Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 9/11 FVP Marine Grease Section 15. Regulatory information International regulations Inventory list Australia : All components are listed or exempted. Canada : All components are listed or exempted. China : Not determined. Japan : Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Republic of Korea : All components are listed or exempted. Malaysia : Not determined New Zealand : All components are listed or exempted. Philippines : All components are listed or exempted. Taiwan : Not determined. Turkey : Not determined. United States : All components are active or exempted. Thailand : Not determined. Viet Nam : Not determined. ethylbenzene <0.001 Yes. No. Yes. - chrysene <0.001 Yes. No. Yes. - naphthalene <0.001 Yes. No. Yes. - Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level % WARNING: This product can expose you to chemicals including Ethylbenzene, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. Rotterdam Convention on Prior Informed Consent (PIC) Not listed. WARNING: This product can expose you to chemicals including Ethylbenzene, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. Section 16. Other information 7/9/2024 History Date of printing : Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification Not classified. 0 1 1 National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 10/11 FVP Marine Grease Section 16. Other information Date of issue/Date of revision Version Notice to reader Date of previous issue : : : Indicates information that has changed from previously issued version. References : Not available. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations 7/9/2024 6/17/2024 4.02 THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. CITGO is a registered trademark of CITGO Petroleum Corporation Date of issue/Date of revision : 7/9/2024 Date of previous issue : 6/17/2024 Version : 4.02 11/11