FVP General Purpose Grease Grease Code: 665408453 FVPMPG-14 GHS product identifier Synonyms Emergency telephone number (with hours of operation) Section 1. Identification : : : Supplier's details Factory Motor Parts Lubricating greaseMaterial uses : 665408453:Code MSDS # : 665408453 Relevant identified uses of the substance or mixture and uses advised against Not applicable. Section 2. Hazards identification TOXIC TO REPRODUCTION - Category 2 AQUATIC HAZARD (ACUTE) - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 1 Classification of the substance or mixture : Signal word : Warning Hazard statements : Suspected of damaging fertility or the unborn child. Very toxic to aquatic life with long lasting effects. Hazard pictograms : Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Avoid release to the environment. Do not get in eyes, on skin, or on clothing. Response Storage : Collect spillage. If exposed or concerned: Get medical advice or attention. Wash with plenty of soap and water or use a recognized skin cleanser. : Store in accordance with all local, regional, national and international regulations. Store locked up. Store in a dry place and a closed container. Empty containers may contain material residues which can ignite with explosive force. Misuse of empty containers can be dangerous if used to store toxic, flammable, or reactive materials. Cutting or welding of empty containers can cause fire, explosion, or release of toxic fumes from residues. Do not pressurize or expose empty containers to open flame, sparks, or heat. Keep container closed and drum bungs in place. All label warnings and precautions must be observed. Return empty drums to a qualified reconditioner. Consult appropriate federal, state and local authorities before reusing, reconditioning, reclaiming, recycling, or disposing of empty containers and/or waste residues of this material. GHS label elements General : Keep out of reach of children. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 1/16 FVP General Purpose Grease Safety Data Sheet Rev 7.2.24 INFOTRAC 1-800-535-5053 1380 Corporate Center Curve, Suite 200 Eagan, MN 55121 866-387-3343 FVP General Purpose Grease Section 2. Hazards identification Disposal : Dispose of contents and container in accordance with all local, regional, national and international regulations. Don't Pollute. Conserve Resources. Return used oil to collection centers. Hazards not otherwise classified : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. Injection of petroleum hydrocarbons requires immediate medical attention. Section 3. Composition/information on ingredients Distillates (petroleum), hydrotreated heavy paraffinic ?90 64742-54-7 Distillates (petroleum), hydrotreated heavy naphthenic ?75 - ?90 64742-52-5 Residual oils (petroleum), solvent-dewaxed ?10 - ?25 64742-62-7 molybdenum disulphide ?3.8 1317-33-5 calcium carbonate ?3.7 471-34-1 Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene) ?2.4 9003-29-6 Natural graphite ?3 7782-42-5 zinc oxide ?2 1314-13-2 Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene ?3 68411-46-1 Lead <0.1 7439-92-1 cadmium (non-pyrophoric) <0.1 7440-43-9 Ingredient name CAS number% Other means of identification : Grease ; CITGO? Material Code: 665408453 CAS number : Not applicable. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to process variation. * = Various ** = Mixture *** = Proprietary There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 2/16 FVP General Purpose Grease Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. In the event of injection in underlying tissue, immediate treatment should include extensive incision, debridement and saline irrigation. Inadequate treatment can result in ischemia and gangrene. Early symptoms may be minimal. Specific treatments : Treat symptomatically and supportively. Most important symptoms/effects, acute and delayed Inhalation : Serious effects may be delayed following exposure. Exposure to decomposition products may cause a health hazard. No known significant effects or critical hazards.:Ingestion Skin contact : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations No specific data. Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : No specific data. Potential acute health effects See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides sulfur oxides phosphorus oxides metal oxide/oxides This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain. Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 3/16 FVP General Purpose Grease Section 5. Fire-fighting measures Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage. Large spill : Move containers from spill area. Avoid dust generation. Do not dry sweep. Vacuum dust with equipment fitted with a HEPA filter and place in a closed, labeled waste container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid release to the environment. If during normal use the material presents a respiratory hazard, use only with adequate ventilation or wear appropriate respirator. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Bulk Storage Conditions: Do not apply heat or flame to stockpiled material. Rotate stock to reduce the potential for hot spots. Do not store with oxidizers. Minimize dust creation by keeping material moist and/or covered. Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 4/16 FVP General Purpose Grease Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits Distillates (petroleum), hydrotreated heavy paraffinic OSHA PEL (United States, 5/2018). [Oil mist, mineral] TWA: 5 mg/m? 8 hours. ACGIH TLV (United States, 1/2023). [Mineral Oil, pure, highly and severely refined] TWA: 5 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). [OIL MIST MINERAL] TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist Distillates (petroleum), hydrotreated heavy naphthenic OSHA PEL (United States, 5/2018). [Oil mist, mineral] TWA: 5 mg/m? 8 hours. ACGIH TLV (United States, 1/2023). [Mineral Oil, pure, highly and severely refined] TWA: 5 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). [OIL MIST MINERAL] TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist Residual oils (petroleum), solvent-dewaxed ACGIH TLV (United States, 1/2023). [Mineral Oil, pure, highly and severely refined] TWA: 5 mg/m? 8 hours. Form: Inhalable fraction OSHA PEL (United States, 5/2018). [Oil mist, mineral] TWA: 5 mg/m? 8 hours. NIOSH REL (United States, 10/2020). [OIL MIST MINERAL] TWA: 5 mg/m? 10 hours. Form: Mist STEL: 10 mg/m? 15 minutes. Form: Mist molybdenum disulphide ACGIH TLV (United States, 1/2023). [Molybdenum, Metal and insoluble compounds Inhalable fraction / Respirable fraction, as Mo] TWA: 10 mg/m?, (as Mo) 8 hours. Form: Inhalable fraction TWA: 3 mg/m?, (as Mo) 8 hours. Form: Respirable fraction OSHA PEL (United States, 5/2018). [Molybdenum Insoluble Compounds (as Mo)] TWA: 15 mg/m?, (as Mo) 8 hours. Form: Total dust calcium carbonate NIOSH REL (United States, 10/2020). [calcium carbonate] TWA: 5 mg/m? 10 hours. Form: Respirable fraction TWA: 10 mg/m? 10 hours. Form: Total Natural graphite OSHA PEL Z3 (United States, 6/2016). TWA: 15 mppcf 8 hours. ACGIH TLV (United States). TWA: 2 mg/m? 8 hours. Form: Respirable Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 5/16 FVP General Purpose Grease Section 8. Exposure controls/personal protection fraction ACGIH TLV (United States, 1/2023). TWA: 2 mg/m? 8 hours. Form: Respirable fraction NIOSH REL (United States, 10/2020). TWA: 2.5 mg/m? 10 hours. Form: Respirable fraction OSHA PEL (United States, 5/2018). TWA: 5 mg/m? 8 hours. Form: Respirable fraction TWA: 15 mg/m? 8 hours. Form: Total dust OSHA PEL (United States). TWA: 15 mg/m? 8 hours. Form: Total dust zinc oxide NIOSH REL (United States, 10/2020). CEIL: 15 mg/m? Form: Dust TWA: 5 mg/m? 10 hours. Form: Dust and fumes STEL: 10 mg/m? 15 minutes. Form: Fume OSHA PEL (United States, 5/2018). TWA: 5 mg/m? 8 hours. Form: Fume TWA: 5 mg/m? 8 hours. Form: Respirable fraction TWA: 15 mg/m? 8 hours. Form: Total dust ACGIH TLV (United States). TWA: 2 mg/m? 8 hours. Form: Respirable STEL: 10 mg/m? 15 minutes. Form: Respirable ACGIH TLV (United States, 1/2023). TWA: 2 mg/m? 8 hours. Form: Respirable fraction STEL: 10 mg/m? 15 minutes. Form: Respirable fraction OSHA PEL (United States). Notes: Respirable TWA: 5 mg/m? 8 hours. Form: Respirable dust OSHA PEL (United States). Notes: Total TWA: 15 mg/m? 8 hours. Form: Total dust Lead ACGIH TLV (United States, 1/2023). [Lead and inorganic compounds as Pb] TWA: 0.05 mg/m?, (as Pb) 8 hours. NIOSH REL (United States, 10/2020). TWA: 0.05 mg/m? 8 hours. OSHA PEL (United States, 5/2018). [Lead inorganic (as Pb)] TWA: 50 ?g/m?, (as Pb) 8 hours. cadmium (non-pyrophoric) OSHA PEL Z2 (United States, 2/2013). TWA: 0.2 mg/m? 8 hours. Form: Dust CEIL: 0.6 mg/m? Form: Dust TWA: 0.1 mg/m? 8 hours. Form: Fume CEIL: 0.3 mg/m? Form: Fume OSHA PEL (United States, 5/2018). TWA: 5 ?g/m?, (as Cd) 8 hours. ACGIH TLV (United States, 1/2023). [Cadmium and compounds] TWA: 0.002 mg/m?, (as Cd) 8 hours. Form: Respirable fraction Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 6/16 FVP General Purpose Grease Section 8. Exposure controls/personal protection Hand protection Avoid inhalation of gases, vapors, mists or dusts. Use a properly fitted, particulate filter respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. Safety glasses equipped with side shields are recommended as minimum protection in industrial settings. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If inhalation hazards exist, a full-face respirator may be required instead. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. : Environmental exposure controls : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, vapor controls, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Relative density Solid. [Smooth texture] 0.9 >10 [Air = 1] Petroleum.Odor pH Brown. [Dark]Color Evaporation rate <1 (n-butyl acetate. = 1) Not available. : : : : : : : Appearance Lower and upper explosive (flammable) limits : Lower: 1% Upper: 7% Gravity, ?API : Estimated 26 @ 60 F Density gm/cm3 : Not available. Flash point Open cup: >150?C (>302?F) [Estimated]: Boiling point, initial boiling point, and boiling range : Not available. Vapor pressure <0.0013 kPa (<0.01 mm Hg): Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 7/16 FVP General Purpose Grease Solubility Insoluble in the following materials: cold water and hot water.: NLGI Grade 2 : Flow time (ISO 2431) : Not available. Particle characteristics Median particle size : Not available. Auto-ignition temperature : Not available. Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid No specific data. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : Not expected to be Explosive, Self-Reactive, Self-Heating, or an Organic Peroxide under US GHS Definition(s). Section 11. Toxicological information Acute toxicity Distillates (petroleum), hydrotreated heavy paraffinic LD50 Dermal Rat >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - Distillates (petroleum), hydrotreated heavy naphthenic LD50 Oral Rat >5000 mg/kg - LD50 Oral Rat >5000 mg/kg - molybdenum disulphide LD50 Oral Rat >6000 mg/kg - LDLo Oral Rat 6 g/kg - LD Dermal Rat >2 g/kg - LD Oral Rat >2 g/kg - calcium carbonate LD50 Oral Rat 6450 mg/kg - Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene LD50 Oral Rat >5000 mg/kg - cadmium (non-pyrophoric) LD50 Oral Rat 2330 mg/kg - Product/ingredient name Result Species Dose Exposure Information on toxicological effects Conclusion/Summary : Distillates (petroleum), hydrotreated heavy paraffinic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. Distillates (petroleum), hydrotreated heavy naphthenic: Mineral oil mists derived from highly refined oils are reported to have low acute and sub-acute toxicities in animals. Effects from single and short-term repeated exposures to high concentrations of mineral oil mists well above applicable workplace exposure levels include lung inflammatory reaction, lipoid granuloma formation and lipoid pneumonia. In acute and sub-acute studies involving exposures to lower concentrations of mineral oil mists at or near current work place exposure levels produced no significant toxicological effects. Dec-1-ene, homopolymer, hydrogenated: Practically non-irritating to eyes. Practically Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 8/16 FVP General Purpose Grease Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion calcium carbonate Eyes - Mild irritant Rabbit - - - Respiratory - Irritant Rabbit - - - Skin - Moderate irritant Rabbit - 24 hours 500 mg - zinc oxide Eyes - Mild irritant Rabbit - 24 hours 500 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Classification Lead - 2B Reasonably anticipated to be a human carcinogen. cadmium (non-pyrophoric) + 1 Known to be a human carcinogen. Product/ingredient name NTPIARCOSHA Conclusion/Summary : No additional information. Conclusion/Summary : No additional information. Skin Respiratory : : No additional information. No additional information. Skin Eyes Respiratory : : : molybdenum disulphide: May cause skin irritation. molybdenum disulphide: May cause eye irritation. molybdenum disulphide: May cause respiratory irritation. non-irritating to the skin. Poly alpha olefins: Potential mild skin irritant from repeated or prolonged exposures. molybdenum disulphide: In general, insoluble compounds of molybdenum, such as molybdenum disulfide, exhibit a low order of toxicity. Natural graphite: Laboratory studies have associated graphite with mild pulmonary fibrotic reactions when administered to rats by intratracheal injection. Numerous epidemiological studies performed in the mining, milling and carbon electrode manufacturing industries have associated a form of pneumoconiosis with overexposure to both synthetic and natural graphite. These data are not expected to be relevant to graphic used in a grease or oil matrix. tris(dipentyldithiocarbamato-S,S')antimony: ORAL (LD50): Acute: 16,400 mg/kg (rat) DERMAL (LD50): Acute: 16,000 mg/kg (rabbit) DERMAL (Primary Skin Irritation): Mild Irritation (rabbit) EYE (Primary Eye Irritation): Mild Irritation (rabbit) Salmonella Mutagenicity Assay in the presence and absence of Aroclor - induced rat liver microsomal enzymes (Ames Test): Negative In micronucleus cytogenetic assay in mice, dose levels of 1250, 2500 and 5,000 mg/kg did not induce bone marrow toxicity in males or females. No significant increase in micronucleated polychromatic erythrocytes was observed in male mice. Mid and high dose produced an increase in micronucleated polychromatic erythrocytes in female mice. The compound is weakly positive in the mouse micronucleus assay. Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 9/16 FVP General Purpose Grease Section 11. Toxicological information Teratogenicity Not available. Information on the likely routes of exposure Inhalation : Serious effects may be delayed following exposure. Exposure to decomposition products may cause a health hazard. No known significant effects or critical hazards.:Ingestion Skin contact : Injection of pressurized hydrocarbons can cause severe permanent tissue damage. Initial symptoms may be minor. No known significant effects or critical hazards.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations No specific data. Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : No specific data. Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) molybdenum disulphide Category 3 - Respiratory tract irritation Name Category Name Category Lead Category 1 - central nervous system (CNS), peripheral nervous system Category 2 oral blood system, kidneys cadmium (non-pyrophoric) Category 1 - - Aspiration hazard Name Result Butene, homopolymer (products derived from either/or But-1-ene/But- 2-ene) ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs : Routes of entry anticipated: Dermal. Potential acute health effects Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Long term exposure Conclusion/Summary : No additional information. No additional information.Conclusion/Summary : Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 10/16 FVP General Purpose Grease Section 11. Toxicological information Potential immediate effects : Not available. Potential delayed effects : Not available. Not available. No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : Suspected of damaging the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : Suspected of damaging fertility. Potential chronic health effects Numerical measures of toxicity Acute toxicity estimates Product/ingredient name FVP General Purpose Grease N/A 17727.0 N/A N/A N/A calcium carbonate 6450 N/A N/A N/A N/A cadmium (non-pyrophoric) 2330 N/A N/A N/A 0.05 Oral (mg/ kg) Dermal (mg/kg) Inhalation (gases) (ppm) Inhalation (vapors) (mg/l) Inhalation (dusts and mists) (mg/ l) Section 12. Ecological information Toxicity Distillates (petroleum), hydrotreated heavy naphthenic Acute EC50 >10000 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 >100 mg/l Fresh water Fish - Pimephales promelas 96 hours Acute NOEL >100 mg/l Fresh water Algae - Pseudokirchneriella subcapitata 72 hours calcium carbonate Acute LC50 >56000 ppm Fresh water Fish - Gambusia affinis - Adult 96 hours Chronic NOEC 16.5 mg/l Fresh water Fish - Rhamdia quelen 30 days Butene, homopolymer (products derived from either/ or But-1-ene/But-2-ene) EC50 >1000 mg/l similar material Daphnia 48 hours LC50 >1000 mg/l similar material Fish 96 hours zinc oxide Acute IC50 1.85 mg/l Marine water Algae - Skeletonema costatum 96 hours Acute LC50 98 ?g/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 1.1 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours Lead Acute EC50 105 ppb Marine water Algae - Chaetoceros sp. - Exponential growth phase 72 hours Acute EC50 0.489 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 8000 ?g/l Fresh water Aquatic plants - Lemna minor 4 days Acute LC50 530 ?g/l Fresh water Crustaceans - Ceriodaphnia reticulata 48 hours Acute LC50 0.594 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 0.44 ppm Fresh water Fish - Cyprinus carpio - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Chronic NOEC 0.25 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.03 ?g/l Fresh water Fish - Cyprinus carpio 4 weeks cadmium (non-pyrophoric) Acute EC50 0.095 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 200 ?g/l Fresh water Aquatic plants - Lemna minor 4 days Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 11/16 FVP General Purpose Grease Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Distillates (petroleum), hydrotreated heavy naphthenic >6 - high Butene, homopolymer (products derived from either/ or But-1-ene/But-2-ene) 7.6 to 7.8 314 to 1882 high zinc oxide - 28960 high Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene 5.1 1730 high Product/ingredient name Aquatic half-life Photolysis Biodegradability Distillates (petroleum), hydrotreated heavy naphthenic - - Inherent Acute EC50 13.5 ?g/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 0.072 ?g/l Marine water Crustaceans - Amphipoda - Adult 48 hours Acute LC50 1 ?g/l Fresh water Fish - Pimephales promelas - Juvenile (Fledgling, Hatchling, Weanling) 96 hours Chronic NOEC 2 ?g/l Fresh water Algae - Parachlorella kessleri - Exponential growth phase 72 hours Chronic NOEC 0.02 ?g/l Fresh water Fish - Cyprinus carpio 4 weeks Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Conclusion/Summary : Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene): This product is unlikely to biodegrade at a significant rate. Conclusion/Summary : Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 12/16 FVP General Purpose Grease Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Transport within user?s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. : Not available. : - - - - Not regulated. - - Not regulated. DOT Classification IATA UN number UN proper shipping name Transport hazard class(es) Packing group Environmental hazards No. No. IMDG Not regulated. - - - No. Oil: The product(s) represented by this SDS is (are) regulated as ?oil? under 49 CFR Part 130. Shipments by rail or highway in packaging having a capacity of 3500 gallons or more or in a quantity greater 42,000 gallons are subject to these requirements. In addition, mixtures containing 10% or more of this product may be subject to these requirements. Section 15. Regulatory information U.S. Federal regulations : SARA 302/304 SARA 304 RQ : Not applicable. Composition/information on ingredients SARA 311/312 Classification : TOXIC TO REPRODUCTION - Category 2 HNOC - Injection Hazards United States inventory (TSCA 8b): All components are listed and active or exempted. Clean Water Act (CWA) 307: zinc oxide; tris(dipentyldithiocarbamato-S,S')antimony; Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts; Phosphorodithioic acid, O, O-di-C1-14-alkyl esters, zinc salts; Naphthenic acids, zinc salts; zinc neodecanoate; lead powder; Cadmium (Non-pyrophoric); ethylbenzene; naphthalene; mercury; arsenic; chromium Clean Water Act (CWA) 311: xylene; ethylbenzene; naphthalene; maleic anhydride This material is classified as an oil under Section 311 of the Clean Water Act (CWA) and the Oil Pollution Act of 1990 (OPA). Discharges or spills which produce a visible sheen on waters of the United States, their adjoining shorelines, or into conduits leading to surface waters must be reported to the EPA's National Response Center at (800) 424-8802. Composition/information on ingredients Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 13/16 FVP General Purpose Grease Section 15. Regulatory information The following components are listed: OIL MIST, MINERAL; OIL MIST, MINERAL; OIL MIST, MINERAL; OIL MIST, MINERAL; MOLYBDENUM DISULFIDE; ZINC OXIDE FUME; molybdenum disulphide Massachusetts : New York : The following components are listed: Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene) New Jersey : The following components are listed: Petroleum Oil (Grease) Pennsylvania : The following components are listed: Butene, homopolymer (products derived from either/or But-1-ene/But-2-ene); ZINC OXIDE FUME; ANTIMONY COMPOUNDS State regulations SARA 313 Product name CAS number % SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed. zinc oxide 1314-13-2 <2 tris(dipentyldithiocarbamato-S,S')antimony 15890-25-2 <2 lead powder 7439-92-1 <0.01 mercury 7439-97-6 trace zinc oxide 1314-13-2 <2 tris(dipentyldithiocarbamato-S,S')antimony 15890-25-2 <2 lead powder 7439-92-1 <0.01 mercury 7439-97-6 trace Form R - Reporting requirements Supplier notification lithium carbonate <0.1 No. Yes. - - molybdenum trioxide <0.01 Yes. No. - - lead powder <0.01 Yes. Yes. Yes. Yes. Cadmium (Non- pyrophoric) <0.01 Yes. Yes. Yes. Yes. ethylbenzene <0.01 Yes. No. Yes. - naphthalene <0.001 Yes. No. Yes. - cumene trace Yes. No. - - 4-methylpentan-2-one trace Yes. Yes. - - ethyl acrylate trace Yes. No. - - mercury trace No. Yes. - - Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level % WARNING: This product can expose you to chemicals including molybdenum trioxide, which is known to the State of California to cause cancer, and Lithium carbonate, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. California Prop. 65 Clear and Reasonable Warnings (2018) molybdenum disulphide ?3.8 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 HNOC - Injection Hazards calcium carbonate ?3.7 SKIN IRRITATION - Category 2 EYE IRRITATION - Category 2A HNOC - Injection Hazards Butene, homopolymer (products derived from either/or But-1-ene/ But-2-ene) ?2.4 SKIN IRRITATION - Category 2 ASPIRATION HAZARD - Category 1 HNOC - Injection Hazards zinc oxide ?2 EYE IRRITATION - Category 2B HNOC - Injection Hazards Benzenamine, N-phenyl-, reaction products with 2,4,4-trimethylpentene ?3 TOXIC TO REPRODUCTION - Category 2 HNOC - Injection Hazards Name % Classification Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 14/16 FVP General Purpose Grease Section 15. Regulatory information International regulations Inventory list Australia : Not determined. Canada : Not determined. China : At least one component is not listed. Japan : Japan inventory (CSCL): At least one component is not listed. Japan inventory (ISHL): Not determined. Republic of Korea : Not determined. Malaysia : Not determined New Zealand : Not determined. Philippines : Not determined. Taiwan : Not determined. Turkey : Not determined. United States : All components are active or exempted. Thailand : Not determined. Viet Nam : Not determined. arsenic trace Yes. No. Yes. - Rotterdam Convention on Prior Informed Consent (PIC) Not listed. WARNING: This product can expose you to chemicals including molybdenum trioxide, which is known to the State of California to cause cancer, and Lithium carbonate, which is known to the State of California to cause birth defects or other reproductive harm. For more information go to www.P65Warnings.ca.gov. Section 16. Other information 7/2/2024 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : 7/2/2024 6/18/2024 3.04 Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ?1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ?2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification TOXIC TO REPRODUCTION - Category 2 Calculation method AQUATIC HAZARD (ACUTE) - Category 1 Calculation method AQUATIC HAZARD (LONG-TERM) - Category 1 Calculation method 0 1 1 National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 15/16 FVP General Purpose Grease Section 16. Other information Notice to reader Indicates information that has changed from previously issued version. References : Not available. Key to abbreviations : ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations THE INFORMATION IN THIS SAFETY DATA SHEET (SDS) WAS OBTAINED FROM SOURCES WHICH WE BELIEVE ARE RELIABLE. HOWEVER, THE INFORMATION IS PROVIDED WITHOUT ANY WARRANTY, EXPRESSED OR IMPLIED REGARDING ITS CORRECTNESS OR ACCURACY. SOME INFORMATION PRESENTED AND CONCLUSIONS DRAWN HEREIN ARE FROM SOURCES OTHER THAN DIRECT TEST DATA ON THE SUBSTANCE ITSELF. THIS SDS WAS PREPARED AND IS TO BE USED ONLY FOR THIS PRODUCT. IF THE PRODUCT IS USED AS A COMPONENT IN ANOTHER PRODUCT, THIS SDS INFORMATION MAY NOT BE APPLICABLE. USERS SHOULD MAKE THEIR OWN INVESTIGATIONS TO DETERMINE THE SUITABILITY OF THE INFORMATION OR PRODUCTS FOR THEIR PARTICULAR PURPOSE OR APPLICATION. THE CONDITIONS OR METHODS OF HANDLING, STORAGE, USE, AND/OR DISPOSAL OF THE PRODUCT ARE BEYOND OUR CONTROL AND MAY BE BEYOND OUR KNOWLEDGE. FOR THIS AND OTHER REASONS, WE DO NOT ASSUME RESPONSIBILITY AND EXPRESSLY DISCLAIM LIABILITY FOR ANY LOSS, DAMAGE OR EXPENSE ARISING OUT OF OR IN ANY WAY CONNECTED WITH HANDLING, STORAGE, USE OR DISPOSAL OF THE PRODUCT. CITGO is a registered trademark of CITGO Petroleum Corporation Date of issue/Date of revision : 7/2/2024 Date of previous issue : 6/18/2024 Version : 3.04 16/16