Page 1/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/06/2022 Reviewed on 07/06/2022 54.0 * 1 Identification - Product identifier - Trade name: AC Delco Thread Sealant - Part number: 19333512 (10-2024) - Application of the substance / the mixture Thread Sealant Sealing Sealant - Details of the supplier of the safety data sheet - Manufacturer/Supplier: ND Industries, Inc 1000 North Crooks Road Clawson, MI 48017 USA Telephone: +1-248-288-0000 Email: This email address is being protected from spambots. You need JavaScript enabled to view it. Website: www.ndindustries.com - Information department: Product Safety Department - Emergency telephone number: United States: 1-800-424-9300 International: +1-703-527-3887 2 Hazard(s) identification - Classification of the substance or mixture GHS08 Health hazard Carc. 2 H351 Suspected of causing cancer. STOT RE 2 H373 May cause damage to organs through prolonged or repeated exposure. GHS07 Skin Irrit. 2 H315 Causes skin irritation. Eye Irrit. 2A H319 Causes serious eye irritation. STOT SE 3 H335 May cause respiratory irritation. - Label elements - GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). - Hazard pictograms GHS07 GHS08 - Signal word Warning - Hazard-determining components of labeling: 2-(2-methylprop-2-enoyloxy)ethyl 2-methylprop-2-enoate dimethylbenzyl hydroperoxide - Hazard statements H315 Causes skin irritation. H319 Causes serious eye irritation. H351 Suspected of causing cancer. H335 May cause respiratory irritation. H373 May cause damage to organs through prolonged or repeated exposure. - Precautionary statements P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust/fume/gas/mist/vapors/spray. P261 Avoid breathing dust/fume/gas/mist/vapors/spray P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P280 Wear protective gloves. P280 Wear eye protection / face protection. P302+P352 If on skin: Wash with plenty of water. (Contd. on page 2) BZS7M8 Stamp Page 2/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/06/2022 Reviewed on 07/06/2022 Trade name: AC Delco Thread Sealant (Contd. of page 1) 54.0 P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 IF exposed or concerned: Get medical advice/attention. P312 Call a poison center/doctor if you feel unwell. P321 Specific treatment (see on this label). P314 Get medical advice/attention if you feel unwell. P362+P364 Take off contaminated clothing and wash it before reuse. P332+P313 If skin irritation occurs: Get medical advice/attention. P337+P313 If eye irritation persists: Get medical advice/attention. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. - Other hazards - Results of PBT and vPvB assessment - PBT: Not applicable. - vPvB: Not applicable. 3 Composition/information on ingredients - Chemical characterization: Mixtures - Description: Mixture of the substances listed below with nonhazardous additions. - Dangerous components: CAS: 25852-47-5 2-(2-methylprop-2-enoyloxy)ethyl 2-methylprop-2-enoate Skin Irrit. 2, H315; Eye Irrit. 2A, H319; STOT SE 3, H335 40 ? 49% CAS: 9004-36-8 Cellulose Acetate Butyrate Combustible Dust 5 ? 9% CAS: 80-15-9 dimethylbenzyl hydroperoxide Self-react. F, H242; Org. Perox. E, H242; Acute Tox. 3, H331; STOT RE 2, H373; Asp. Tox. 1, H304; Skin Corr. 1B, H314; Eye Dam. 1, H318; Acute Tox. 4, H302; Acute Tox. 4, H312; STOT SE 3, H335; Flam. Liq. 4, H227 1 ? 4% CAS: 613-48-9 N,N-Diethyl-P-Toluidine Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 3, H331; STOT RE 2, H373; Eye Irrit. 2A, H319; Flam. Liq. 4, H227 ? 1% CAS: 609-72-3 N,N-dimethyl-o-toluidine Acute Tox. 3, H301; Acute Tox. 3, H311; Acute Tox. 3, H331; Skin Irrit. 2, H315; Eye Irrit. 2A, H319; Flam. Liq. 4, H227 ? 1% CAS: 98-82-8 cumene Flam. Liq. 3, H226; Carc. 2, H351; Asp. Tox. 1, H304; Acute Tox. 4, H302; STOT SE 3, H335 ? 1% 4 First-aid measures - Description of first aid measures - After inhalation: In case of unconsciousness place patient stably in side position for transportation. Supply fresh air; consult doctor in case of complaints. - After skin contact: Immediately wash with water and soap and rinse thoroughly. - After eye contact: Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor. - After swallowing: If symptoms persist consult doctor. - Information for doctor: - Most important symptoms and effects, both acute and delayed No further relevant information available. - Indication of any immediate medical attention and special treatment needed No further relevant information available. 5 Fire-fighting measures - Extinguishing media - Suitable extinguishing agents: Use fire fighting measures that suit the environment. - Special hazards arising from the substance or mixture No further relevant information available. - Advice for firefighters - Protective equipment: Wear self-contained respiratory protective device. Wear fully protective suit. 6 Accidental release measures - Personal precautions, protective equipment and emergency procedures Ensure adequate ventilation Wear protective clothing. (Contd. on page 3) Page 3/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/06/2022 Reviewed on 07/06/2022 Trade name: AC Delco Thread Sealant (Contd. of page 2) 54.0 - Environmental precautions: Do not allow to enter sewers/ surface or ground water. - Methods and material for containment and cleaning up: Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust). Ensure adequate ventilation. Dispose of the collected material according to regulations. - Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage - Handling: - Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. Prevent formation of aerosols. - Information about protection against explosions and fires: No special measures required. - Conditions for safe storage, including any incompatibilities - Storage: - Requirements to be met by storerooms and receptacles: No special requirements. - Information about storage in one common storage facility: Not required. - Further information about storage conditions: Keep receptacle tightly sealed. Store in cool, dry conditions in well sealed receptacles. - Specific end use(s) No further relevant information available. 8 Exposure controls/personal protection - Additional information about design of technical systems: No further data; see item 7. - Control parameters - Components with limit values that require monitoring at the workplace: At this time, the other constituents have no known exposure limits. CAS: 80-15-9 dimethylbenzyl hydroperoxide WEEL Long-term value: 6 mg/m?, 1 ppm Skin CAS: 98-82-8 cumene PEL Long-term value: 245 mg/m?, 50 ppm Skin REL Long-term value: 245 mg/m?, 50 ppm Skin TLV Long-term value: 5 ppm A3 - Additional information: The lists that were valid during the creation were used as basis. - Exposure controls - Personal protective equipment: - General protective and hygienic measures: Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin. - Breathing equipment: Not required. In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use respiratory protective device that is independent of circulating air. - Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation - Material of gloves The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the application. Nitrile rubber, NBR (Contd. on page 4) Page 4/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/06/2022 Reviewed on 07/06/2022 Trade name: AC Delco Thread Sealant (Contd. of page 3) 54.0 - Penetration time of glove material The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed. - Eye protection: Required use of safety glasses - Body protection: Protective work clothing 9 Physical and chemical properties - Information on basic physical and chemical properties - General Information - Appearance: - Form: Viscous - Color: White - Odor: Characteristic - Odor threshold: Not determined. - pH-value: Not determined. - Change in condition - Melting point/Melting range: Undetermined. - Boiling point/Boiling range: ? 200 ?C (? 392 ?F) - Flash point: 131 ?C (267.8 ?F) - Flammability (solid, gaseous): Not applicable. - Decomposition temperature: Not determined. - Auto igniting: Product is not selfigniting. - Danger of explosion: Product does not present an explosion hazard. - Explosion limits: - Lower: Not determined. - Upper: Not determined. - Vapor pressure at 20 ?C (68 ?F): ? 53 hPa (? 39.8 mm Hg) - Density: Not determined. - Relative density Not determined. - Vapor density Not determined. - Evaporation rate Not determined. - Solubility in / Miscibility with - Water: Not miscible or difficult to mix. - Partition coefficient (n-octanol/water): Not determined. - Viscosity: - Dynamic: Not determined. - Kinematic: Not determined. - Solvent content: - Organic solvents: 0.9 % - Water: 0.3 % - VOC content: 0.87 % 8.7 g/l / 0.07 lb/gal - Solids content: 65.0 % - Other information No further relevant information available. 10 Stability and reactivity - Reactivity No further relevant information available. - Chemical stability - Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications. - Possibility of hazardous reactions No dangerous reactions known. - Conditions to avoid No further relevant information available. - Incompatible materials: No further relevant information available. - Hazardous decomposition products: No dangerous decomposition products known. (Contd. on page 5) Page 5/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/06/2022 Reviewed on 07/06/2022 Trade name: AC Delco Thread Sealant (Contd. of page 4) 54.0 11 Toxicological information - Information on toxicological effects - Acute toxicity: - LD/LC50 values that are relevant for classification: ATE (Acute Toxicity Estimate) Oral LD50 6,663 mg/kg Dermal LD50 14,401 mg/kg Inhalative LC50/4 h 279 mg/l CAS: 9004-36-8 Cellulose Acetate Butyrate Oral LD50 > 6,400 mg/kg (rabbit) Dermal LD50 > 1,000 mg/kg (rabbit) CAS: 80-15-9 dimethylbenzyl hydroperoxide Oral LD50 382 mg/kg (rat) Dermal LD50 500 mg/kg (rat) Inhalative LC50/4 h 220 mg/l (rat) CAS: 613-48-9 N,N-Diethyl-P-Toluidine Oral LD50 100 mg/kg (ATE) Dermal LD50 300 mg/kg (ATE) Inhalative LC50/4 h 3 mg/l (ATE) CAS: 609-72-3 N,N-dimethyl-o-toluidine Oral LD50 100 mg/kg (ATE) Dermal LD50 300 mg/kg (ATE) Inhalative LC50/4 h 3 mg/l (ATE) CAS: 98-82-8 cumene Oral LD50 1,400 mg/kg (rat) Dermal LD50 12,300 mg/kg (rabbit) Inhalative LC50/4 h 24.7 mg/l (mouse) - Primary irritant effect: - on the skin: Irritant to skin and mucous membranes. - on the eye: Irritating effect. - Sensitization: No sensitizing effects known. - Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant - Carcinogenic categories - IARC (International Agency for Research on Cancer) CAS: 9002-84-0 Polytetrafluoroethylene 3 CAS: 13463-67-7 titanium dioxide 2B CAS: 98-82-8 cumene 2B CAS: 111-76-2 2-butoxyethanol 3 - NTP (National Toxicology Program) CAS: 98-82-8 cumene R - OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients is listed. 12 Ecological information - Toxicity - Aquatic toxicity: No further relevant information available. - Persistence and degradability No further relevant information available. - Behavior in environmental systems: - Bioaccumulative potential No further relevant information available. - Mobility in soil No further relevant information available. - Additional ecological information: - General notes: Water hazard class 1 (Self-assessment): slightly hazardous for water Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system. (Contd. on page 6) Page 6/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/06/2022 Reviewed on 07/06/2022 Trade name: AC Delco Thread Sealant (Contd. of page 5) 54.0 - Results of PBT and vPvB assessment - PBT: Not applicable. - vPvB: Not applicable. - Other adverse effects No further relevant information available. 13 Disposal considerations - Waste treatment methods - Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system. - Uncleaned packagings: - Recommendation: Disposal must be made according to official regulations. 14 Transport information - UN-Number - DOT, ADN, IMDG, IATA not regulated - UN proper shipping name - DOT, ADN, IMDG, IATA not regulated - Transport hazard class(es) - DOT, ADN, IMDG, IATA - Class not regulated - Packing group - DOT, IMDG, IATA not regulated - Environmental hazards: - Marine pollutant: No - Special precautions for user Not applicable. - Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. - UN "Model Regulation": not regulated 15 Regulatory information - Safety, health and environmental regulations/legislation specific for the substance or mixture No further relevant information available. - Sara - Section 355 (extremely hazardous substances): None of the ingredients is listed. - Section 313 (Specific toxic chemical listings): CAS: 80-15-9 dimethylbenzyl hydroperoxide CAS: 98-82-8 cumene CAS: 98-86-2 acetophenone CAS: 111-76-2 2-butoxyethanol - TSCA (Toxic Substances Control Act): All components have the value ACTIVE. - Hazardous Air Pollutants CAS: 98-82-8 cumene CAS: 98-86-2 acetophenone - Proposition 65 - Chemicals known to cause cancer: CAS: 13463-67-7 titanium dioxide CAS: 98-82-8 cumene - Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. - Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. - Chemicals known to cause developmental toxicity: None of the ingredients is listed. (Contd. on page 7) Page 7/7 Safety Data Sheet acc. to OSHA HCS Printing date 07/06/2022 Reviewed on 07/06/2022 Trade name: AC Delco Thread Sealant (Contd. of page 6) 54.0 - Carcinogenic categories - EPA (Environmental Protection Agency) CAS: 98-82-8 cumene D, CBD CAS: 98-86-2 acetophenone D CAS: 111-76-2 2-butoxyethanol NL - TLV (Threshold Limit Value) CAS: 13463-67-7 titanium dioxide A4 CAS: 111-76-2 2-butoxyethanol A3 - NIOSH-Ca (National Institute for Occupational Safety and Health) CAS: 13463-67-7 titanium dioxide - Chemical safety assessment: A Chemical Safety Assessment has not been carried out. 16 Other information This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. - Department issuing SDS: ND Industries, Inc. - Safety, Health and Environmental Affaires - Contact: Safety, Health and Environmental Affaires - Classification System: - HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY *2 1 0 Health = *2 Fire = 1 Reactivity = 0 - NFPA ratings (scale 0 - 4) 2 1 0 Health = 2 Fire = 1 Reactivity = 0 - Date of preparation / last revision 07/06/2022 / 88 - Abbreviations and acronyms: IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent PBT: Persistent, Bioaccumulative and Toxic vPvB: very Persistent and very Bioaccumulative NIOSH: National Institute for Occupational Safety OSHA: Occupational Safety & Health TLV: Threshold Limit Value PEL: Permissible Exposure Limit REL: Recommended Exposure Limit Flam. Liq. 3: Flammable liquids ? Category 3 Flam. Liq. 4: Flammable liquids ? Category 4 Self-react. F: Self-reactive substances and mixtures ? Type E/F Org. Perox. E: Organic peroxides ? Type E/F Acute Tox. 4: Acute toxicity ? Category 4 Acute Tox. 3: Acute toxicity ? Category 3 Skin Corr. 1B: Skin corrosion/irritation ? Category 1B Skin Irrit. 2: Skin corrosion/irritation ? Category 2 Eye Dam. 1: Serious eye damage/eye irritation ? Category 1 Eye Irrit. 2A: Serious eye damage/eye irritation ? Category 2A Carc. 2: Carcinogenicity ? Category 2 STOT SE 3: Specific target organ toxicity (single exposure) ? Category 3 STOT RE 2: Specific target organ toxicity (repeated exposure) ? Category 2 Asp. Tox. 1: Aspiration hazard ? Category 1 - * Data compared to the previous version altered. - Disclaimer The information set forth is based on information that ND Industries, Incorporated believes to be accurate. No warranty, expressed or implied, is intended. The information is provided solely for your information and consideration and ND Industries Inc. assumes no legal responsibility for use or reliance thereon. In the event of a discrepancy between the information on the non-English document and its English counterpart, the English version shall supersede. ?ND and ND Industries, Inc. are registered trademarks of ND Industries Incorporated, ?Vibra-TITE is a registered trademark of ND Industries, Inc.