ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) Not available. Liquid. US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Distributed by ACDelco 300 Renaissance Center Detroit, MI 48265 1-800-223-3526 Manufactured by THE SHERWIN-WILLIAMS COMPANY 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. 19367789 19367789Product code : Product Information Telephone Number : US / Canada: 1-800-474-3794 Mexico: Not Available Transportation Emergency Telephone Number : US / Canada: (800) 424-9300 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year National contact : Imported by and/or produced for and distributed by: Import? par et / ou produit pour et distribu? par: General Motors of Canada Company Compagnie General Motors du Canada 1908 Colonel Sam Drive Oshawa, Ontario L1H 8P7 Canada Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 2 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 47.8% (dermal), 18.6% (inhalation) Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 1/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 2. Hazards identification Signal word : Danger Hazard pictograms : Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Do not breathe vapor. Wash thoroughly after handling. Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : None known. Highly flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. FOR PROFESSIONAL USE ONLY. : Section 3. Composition/information on ingredients Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Mixture Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 2/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 3. Composition/information on ingredients Methyl Ethyl Ketone 22.62 78-93-3 Toluene 21.97 108-88-3 Ethyl 3-Ethoxypropionate 14.64 763-69-9 Titanium Dioxide 8.09 13463-67-7 Methyl Isobutyl Ketone 5.41 108-10-1 Ethanol 2.97 64-17-5 Cellulose Nitrate 2.78 9004-70-0 2-Propanol 1.2 67-63-0 Xylene, mixed isomers 0.2 1330-20-7 Ingredient name CAS number% by weight Occupational exposure limits, if available, are listed in Section 8. Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Potential acute health effects Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 3/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Specific hazards arising from the chemical Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 4/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides metal oxide/oxides Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters : : Flammable liquid.Remark : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept : Precautions for safe handling Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 5/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. Methyl Ethyl Ketone 78-93-3 ACGIH TLV (United States, 7/2023). Absorbed through skin. TWA: 75 ppm 8 hours. STEL: 150 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 200 ppm 10 hours. TWA: 590 mg/m? 10 hours. STEL: 300 ppm 15 minutes. STEL: 885 mg/m? 15 minutes. OSHA PEL (United States, 5/2018). TWA: 200 ppm 8 hours. TWA: 590 mg/m? 8 hours. Toluene 108-88-3 OSHA PEL Z2 (United States, 2/2013). TWA: 200 ppm 8 hours. CEIL: 300 ppm AMP: 500 ppm 10 minutes. NIOSH REL (United States, 10/2020). TWA: 100 ppm 10 hours. TWA: 375 mg/m? 10 hours. STEL: 150 ppm 15 minutes. STEL: 560 mg/m? 15 minutes. ACGIH TLV (United States, 7/2023). Ototoxicant. TWA: 20 ppm 8 hours. Ethyl 3-Ethoxypropionate 763-69-9 None. Titanium Dioxide 13463-67-7 OSHA PEL (United States, 5/2018). TWA: 15 mg/m? 8 hours. Form: Total dust ACGIH TLV (United States, 7/2023). TWA: 2.5 mg/m? 8 hours. Form: respirable fraction, finescale particles Methyl Isobutyl Ketone 108-10-1 ACGIH TLV (United States, 7/2023). Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) CAS # Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 6/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 8. Exposure controls/personal protection TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 50 ppm 10 hours. TWA: 205 mg/m? 10 hours. STEL: 75 ppm 15 minutes. STEL: 300 mg/m? 15 minutes. OSHA PEL (United States, 5/2018). TWA: 100 ppm 8 hours. TWA: 410 mg/m? 8 hours. Ethanol 64-17-5 ACGIH TLV (United States, 7/2023). STEL: 1000 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 1000 ppm 10 hours. TWA: 1900 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 1000 ppm 8 hours. TWA: 1900 mg/m? 8 hours. Cellulose Nitrate 9004-70-0 None. 2-Propanol 67-63-0 ACGIH TLV (United States, 7/2023). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 400 ppm 10 hours. TWA: 980 mg/m? 10 hours. STEL: 500 ppm 15 minutes. STEL: 1225 mg/m? 15 minutes. OSHA PEL (United States, 5/2018). TWA: 400 ppm 8 hours. TWA: 980 mg/m? 8 hours. Xylene, mixed isomers 1330-20-7 OSHA PEL (United States, 5/2018). [Xylenes] TWA: 100 ppm 8 hours. TWA: 435 mg/m? 8 hours. ACGIH TLV (United States, 7/2023). [p- xylene and mixtures containing p-xylene] Ototoxicant. TWA: 20 ppm 8 hours. Methyl ethyl ketone 78-93-3 CA Alberta Provincial (Canada, 3/2023). OEL: 300 ppm 15 minutes. OEL: 200 ppm 8 hours. OEL: 590 mg/m? 8 hours. OEL: 885 mg/m? 15 minutes. CA British Columbia Provincial (Canada, 8/2023). Absorbed through skin. TWA: 50 ppm 8 hours. STEL: 100 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 200 ppm 8 hours. STEL: 300 ppm 15 minutes. CA Quebec Provincial (Canada, 7/2023). TWAEV: 50 ppm 8 hours. TWAEV: 150 mg/m? 8 hours. Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 7/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 8. Exposure controls/personal protection STEV: 100 ppm 15 minutes. STEV: 300 mg/m? 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 300 ppm 15 minutes. TWA: 200 ppm 8 hours. Toluene 108-88-3 CA Alberta Provincial (Canada, 3/2023). Absorbed through skin. OEL: 50 ppm 8 hours. OEL: 188 mg/m? 8 hours. CA British Columbia Provincial (Canada, 8/2023). TWA: 20 ppm 8 hours. CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. CA Quebec Provincial (Canada, 7/2023). TWAEV: 20 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). Absorbed through skin. STEL: 60 ppm 15 minutes. TWA: 50 ppm 8 hours. Methyl isobutyl ketone 108-10-1 CA Alberta Provincial (Canada, 3/2023). OEL: 205 mg/m? 8 hours. OEL: 50 ppm 8 hours. OEL: 75 ppm 15 minutes. OEL: 307 mg/m? 15 minutes. CA British Columbia Provincial (Canada, 8/2023). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 20 ppm 8 hours. STEL: 75 ppm 15 minutes. CA Quebec Provincial (Canada, 7/2023). TWAEV: 20 ppm 8 hours. STEV: 75 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 75 ppm 15 minutes. TWA: 50 ppm 8 hours. Ethyl alcohol 64-17-5 CA Alberta Provincial (Canada, 3/2023). OEL: 1000 ppm 8 hours. OEL: 1880 mg/m? 8 hours. CA British Columbia Provincial (Canada, 8/2023). STEL: 1000 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). STEL: 1000 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 1250 ppm 15 minutes. TWA: 1000 ppm 8 hours. CA Quebec Provincial (Canada, 7/2023). STEV: 1000 ppm 15 minutes. Isopropyl alcohol 67-63-0 CA Alberta Provincial (Canada, 3/2023). OEL: 984 mg/m? 15 minutes. OEL: 200 ppm 8 hours. Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 8/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 8. Exposure controls/personal protection OEL: 400 ppm 15 minutes. OEL: 492 mg/m? 8 hours. CA British Columbia Provincial (Canada, 8/2023). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. CA Quebec Provincial (Canada, 7/2023). TWAEV: 200 ppm 8 hours. STEV: 400 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 7/2013). STEL: 400 ppm 15 minutes. TWA: 200 ppm 8 hours. Xylene 1330-20-7 CA Alberta Provincial (Canada, 3/2023). [Dimethylbenzene] OEL: 100 ppm 8 hours. OEL: 651 mg/m? 15 minutes. OEL: 150 ppm 15 minutes. OEL: 434 mg/m? 8 hours. CA British Columbia Provincial (Canada, 8/2023). [Xylene (o, m & p isomers)] TWA: 100 ppm 8 hours. STEL: 150 ppm 15 minutes. CA Quebec Provincial (Canada, 7/2023). [Xylene] TWAEV: 100 ppm 8 hours. TWAEV: 434 mg/m? 8 hours. STEV: 150 ppm 15 minutes. STEV: 651 mg/m? 15 minutes. CA Ontario Provincial (Canada, 6/2019). [Xylene (o-, m-, p-isomers)] STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. CA Saskatchewan Provincial (Canada, 7/2013). [Xylene] STEL: 150 ppm 15 minutes. TWA: 100 ppm 8 hours. Methyl Ethyl Ketone 78-93-3 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 200 ppm 8 hours. STEL: 300 ppm 15 minutes. Toluene 108-88-3 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 20 ppm 8 hours. Methyl Isobutyl Ketone 108-10-1 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 50 ppm 8 hours. STEL: 75 ppm 15 minutes. Ethanol 64-17-5 NOM-010-STPS-2014 (Mexico, 4/2016). STEL: 1000 ppm 15 minutes. 2-Propanol 67-63-0 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 200 ppm 8 hours. STEL: 400 ppm 15 minutes. Ingredient name Exposure limits Occupational exposure limits (Mexico) CAS # Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 9/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 8. Exposure controls/personal protection Biological exposure indices (United States) Methyl Ethyl Ketone ACGIH BEI (United States, 7/2023) BEI: 2 mg/l, methyl ethyl ketone [in urine]. Sampling time: end of shift. Toluene ACGIH BEI (United States, 7/2023) BEI: 0.03 mg/l, toluene [in urine]. Sampling time: end of shift. BEI: 0.3 mg/g creatinine, o-cresol [in urine]. Sampling time: end of shift. BEI: 0.02 mg/l, toluene [in blood]. Sampling time: prior to last shift of workweek. Methyl Isobutyl Ketone ACGIH BEI (United States, 7/2023) BEI: 1 mg/l, methyl isobutyl ketone [in urine]. Sampling time: end of shift. 2-Propanol ACGIH BEI (United States, 7/2023) BEI: 40 mg/l, acetone [in urine]. Sampling time: end of shift at end of workweek. Xylene, mixed isomers ACGIH BEI (United States, 7/2023) [xylenes (technical or commercial grades)] BEI: 0.3 g/g creatinine, methylhippuric acids [in urine]. Sampling time: end of shift. Ingredient name Exposure indices Biological exposure indices (Canada) Biological exposure indices (Mexico) No exposure indices known. Methyl Ethyl Ketone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 2 mg/L, MEK [in urine]. Sampling time: at the end of the work shift. Toluene Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 0.05 mg/L, toluene [in blood]. Sampling time: sample time not specified. BEI: 1.6 g/g creatinine [Basal level.The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu; non-specific.The determinant is nonspecific, since it can be found after exposure to other Ingredient name Exposure indices Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 10/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 8. Exposure controls/personal protection Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Environmental exposure controls : chemicals.], hippuric acid [in urine]. Sampling time: at the end of the work shift. BEI: 0.5 mg/L [Basal level.The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu], o-cresol [in urine]. Sampling time: at the end of the work shift. Methyl Isobutyl Ketone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 2 mg/L, MIBK [in urine]. Sampling time: at the end of the work shift. 2-Propanol Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 40 mg/L [non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], acetone [in urine]. Sampling time: at the end of the shift at the end of the work week. Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 11/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Respiratory protection : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Liquid. Not available. 0.96 1.5 [Air = 1] Not available.Odor pH White.Color Evaporation rate 5.6 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: 2?C (35.6?F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40?C (104?F)): >20.5 mm2/s (>20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : Appearance : 77?C (170.6?F) : Flammable liquid. : Lower: 1% Upper: 19% Decomposition temperature : Not available. Molecular weight : Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 12.1 kPa (90.6 mm Hg) Solubility(ies) : Media Result cold water Not soluble Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 12/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 9. Physical and chemical properties Heat of combustion : 21.732 kJ/g Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Methyl Ethyl Ketone LD50 Dermal Rabbit 6480 mg/kg - LD50 Oral Rat 2737 mg/kg - Toluene LC50 Inhalation Vapor Rat 49 g/m? 4 hours LD50 Oral Rat 636 mg/kg - Ethyl 3-Ethoxypropionate LD50 Oral Rat 3200 mg/kg - Methyl Isobutyl Ketone LD50 Oral Rat 2080 mg/kg - Ethanol LC50 Inhalation Vapor Rat 124700 mg/m? 4 hours LD50 Oral Rat 7 g/kg - Cellulose Nitrate LD50 Oral Rat >5 g/kg - 2-Propanol LD50 Dermal Rabbit 12800 mg/kg - LD50 Oral Rat 5000 mg/kg - Xylene, mixed isomers LC50 Inhalation Gas. Rat 6700 ppm 4 hours LD50 Oral Rat 4300 mg/kg - Product/ingredient name Result Species Dose Exposure Irritation/Corrosion Methyl Ethyl Ketone Skin - Mild irritant Rabbit - 24 hours 14 mg - Skin - Moderate irritant Rabbit - 24 hours 500 mg - Toluene Eyes - Mild irritant Rabbit - 0.5 minutes 100 mg - Eyes - Mild irritant Rabbit - 870 ug - Eyes - Severe irritant Rabbit - 24 hours 2 mg - Skin - Mild irritant Pig - 24 hours 250 uL - Skin - Mild irritant Rabbit - 435 mg - Skin - Moderate irritant Rabbit - 24 hours 20 - Product/ingredient name Result Score Exposure ObservationSpecies Information on toxicological effects Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 13/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 11. Toxicological information Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. mg Skin - Moderate irritant Rabbit - 500 mg - Ethyl 3-Ethoxypropionate Skin - Mild irritant Rabbit - 24 hours 500 mg - Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 ug I - Methyl Isobutyl Ketone Eyes - Moderate irritant Rabbit - 24 hours 100 uL - Eyes - Severe irritant Rabbit - 40 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - Ethanol Eyes - Mild irritant Rabbit - 24 hours 500 mg - Eyes - Moderate irritant Rabbit - 0.066666667 minutes 100 mg - Eyes - Moderate irritant Rabbit - 100 uL - Eyes - Severe irritant Rabbit - 500 mg - Skin - Mild irritant Rabbit - 400 mg - Skin - Moderate irritant Rabbit - 24 hours 20 mg - 2-Propanol Eyes - Moderate irritant Rabbit - 10 mg - Eyes - Moderate irritant Rabbit - 24 hours 100 mg - Eyes - Severe irritant Rabbit - 100 mg - Skin - Mild irritant Rabbit - 500 mg - Xylene, mixed isomers Eyes - Mild irritant Rabbit - 87 mg - Eyes - Severe irritant Rabbit - 24 hours 5 mg - Skin - Mild irritant Rat - 8 hours 60 uL - Skin - Moderate irritant Rabbit - 100 % - Skin - Moderate irritant Rabbit - 24 hours 500 mg - Sensitization Not available. Specific target organ toxicity (single exposure) Classification Toluene - 3 - Titanium Dioxide - 2B - Methyl Isobutyl Ketone - 2B - Ethanol - 1 - 2-Propanol - 3 - Xylene, mixed isomers - 3 - Product/ingredient name NTPIARCOSHA Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 14/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 11. Toxicological information Specific target organ toxicity (repeated exposure) Methyl Ethyl Ketone Category 3 - Respiratory tract irritation Category 3 Narcotic effects Toluene Category 3 - Narcotic effects Methyl Isobutyl Ketone Category 3 - Respiratory tract irritation Category 3 Narcotic effects Ethanol Category 3 - Narcotic effects 2-Propanol Category 3 - Narcotic effects Xylene, mixed isomers Category 3 - Respiratory tract irritation Category 3 Narcotic effects Name Category Name Category Methyl Ethyl Ketone Category 2 - - Toluene Category 2 - - Xylene, mixed isomers Category 2 - - Aspiration hazard Name Result Toluene ASPIRATION HAZARD - Category 1 Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Route of exposure Target organs Route of exposure Target organs Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness : Not available. Potential acute health effects Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 15/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 11. Toxicological information Not available. May cause damage to organs through prolonged or repeated exposure.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : May damage the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Skin contact Ingestion Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 6377.94 mg/kg Inhalation (vapors) 165.41 mg/l Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Toxicity Methyl Ethyl Ketone Acute EC50 >500000 ?g/l Marine water Algae - Skeletonema costatum 96 hours Acute EC50 5091000 ?g/l Fresh water Daphnia - Daphnia magna - Larvae 48 hours Acute LC50 3220000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Toluene Acute EC50 >433 ppm Marine water Algae - Skeletonema costatum 96 hours Acute EC50 11600 ?g/l Fresh water Crustaceans - Gammarus pseudolimnaeus - Adult 48 hours Acute EC50 6000 ?g/l Fresh water Daphnia - Daphnia magna - 48 hours Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 16/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Product/ingredient name Toluene - 90 Low Xylene, mixed isomers - 8.1 to 25.9 Low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl Ethyl Ketone - - Readily Toluene - - Readily Methyl Isobutyl Ketone - - Readily Ethanol - - Readily 2-Propanol - - Readily Xylene, mixed isomers - - Readily Juvenile (Fledgling, Hatchling, Weanling) Acute LC50 5500 ?g/l Fresh water Fish - Oncorhynchus kisutch - Fry 96 hours Chronic NOEC 1 mg/l Fresh water Daphnia - Daphnia magna 21 days Titanium Dioxide Acute LC50 >1000000 ?g/l Marine water Fish - Fundulus heteroclitus 96 hours Methyl Isobutyl Ketone Acute LC50 505000 ?g/l Fresh water Fish - Pimephales promelas 96 hours Chronic NOEC 78 mg/l Fresh water Daphnia - Daphnia magna 21 days Chronic NOEC 168 mg/l Fresh water Fish - Pimephales promelas - Embryo 33 days Ethanol Acute EC50 17.921 mg/l Marine water Algae - Ulva pertusa 96 hours Acute EC50 2 mg/l Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 25500 ?g/l Marine water Crustaceans - Artemia franciscana - Larvae 48 hours Acute LC50 42000 ?g/l Fresh water Fish - Oncorhynchus mykiss 4 days Chronic NOEC 4.995 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 100 ul/L Fresh water Daphnia - Daphnia magna - Neonate 21 days Chronic NOEC 0.375 ul/L Fresh water Fish - Gambusia holbrooki - Larvae 12 weeks 2-Propanol Acute EC50 7550 mg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours Acute LC50 1400000 ?g/l Marine water Crustaceans - Crangon crangon 48 hours Acute LC50 4200 mg/l Fresh water Fish - Rasbora heteromorpha 96 hours Xylene, mixed isomers Acute LC50 8500 ?g/l Marine water Crustaceans - Palaemonetes pugio 48 hours Acute LC50 13400 ?g/l Fresh water Fish - Pimephales promelas 96 hours Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 17/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 II PAINT 3 II UN1263 UN1263 - Emergency schedules F-E, S- E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. TDG Classification UN1263 PAINT 3 II No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1263 PAINT 3 II No. - IATA UN1263 PAINT 3 II No. - 128 ERG No. 128 128 ERG No. ERG No. Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 18/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. : Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Montreal Protocol Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Section 16. Other information Hazardous Material Information System (U.S.A.) 3 3 0 *Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. Procedure used to derive the classification Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 19/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Section 16. Other information 5/16/2024 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 5/16/2024 4/19/2024 21 FLAMMABLE LIQUIDS - Category 2 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 1B Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 20/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA Date of issue/Date of revision : 5/16/2024 Date of previous issue : 4/19/2024 Version : 21 21/21 19367789 ACDelco? Lacquer Touch-Up Paint White (40 WA 8554) SHW-85-NA-GHS-CA