THE BERKEBILE OIL COMPANY, INC. PAGE 1 OF 9 PAGES B1900, B1912, B1905, B19055 Telephone: 814-443-1656 Page 1 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 SAFETY DATA SHEET 1. Product Identifier Product form Substance Trade name Product Number(s) Diesel Fuel Conditioner and Anti-Gel B1900, B1912, B1905, B19055 Relevant Uses Uses of Mixture: Diesel Fuel Anti-Gel, Cleaner, and Conditioner Supplier Details Manufacturer Name Address: City, State, Zip Phone Fax Emergency Contact The Berkebile Oil Company, Inc. 1216 Red Brant Road Somerset, PA 15501 814-443-1656 814-443-2873 Chemtrec Emergency Tel # 800-424-9300 2. HAZARDS IDENTIFICATION 2.1 Classification of the Substance or Mixture GHS Classifications: Physical, Flammable Liquids, 3 Health, Acute toxicity, 4 Oral Health, Acute toxicity, 4 Dermal Health, Acute toxicity, 4 Inhalation Health, Specific target organ toxicity - Single exposure, 3 Health, Carcinogenicity, 2 Health, Aspiration hazard, 1 Health, Skin corrosion/irritation, 1 C Environmental, Hazards to the aquatic environment - Chronic, 2 2.2 Label Elements THE BERKEBILE OIL COMPANY, INC. PAGE 2 OF 9 PAGES B1900, B1912, B1905, B19055 Telephone: 814-443-1656 Page 2 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 Signal Word (GHS-US) Danger Hazzard Statements (GHS-US) Flammable liquid and vapor Harmful if swallowed, in contact with skin, or inhaled Causes severe skin burns and eye damage May be fatal if swallowed and enters airway Suspected of causing cancer May cause respiratory irritation Precautionary Statements (GHS-US) Do not handle until all safety precautions have been read and met Keep away from heat, sparks, open flames, hot surfaces ? No Smoking Do not breathe vapors Wash hands thoroughly after handling Use only outdoors or in a well-ventilated area Wear protective gloves, protective clothing, eye protection, face protection Do not eat, drink or smoke when using this product Ground/bond container and receiving equipment Use explosion proof electrical/ventilating/lighting equipment Use only non-sparking tools Take precautionary measures against static discharge Obtain special instructions before use. Response: If swallowed: Immediately call a doctor If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower IF INHALED: Remove person to fresh air and keep comfortable for breathing If exposed: Call a poison center/doctor Rinse mouth DO NOT Induce Vomiting Take off immediately all contaminated clothing Wash contaminated clothing before reuse If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. THE BERKEBILE OIL COMPANY, INC. PAGE 3 OF 9 PAGES B1900, B1912, B1905, B19055 Telephone: 814-443-1656 Page 3 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 In case of fire: Use dry sand, dry chemical or alcohol-resistant foam for extinction. Storage Store locked up. Keep container tightly closed. Keep Cool Disposal Dispose of contents/container to licensed waste management site 3. Composition / Information on Ingredients Chemical name Common name and synonyms CAS number % Light Aromatic Solvent Naptha Mineral Spirits 64742-95-6 75-85 1,2,4-Trimethylbenzene 95-63-6 5-15 1,3,5-Trimethylbenzene 108-67-8 3-5 Xylene 1330-20-7 <1 Cumene 98-82-8 <.5 Napthalene 91-20-3 <.5 Vinyl Acetate Monomer 108-05-4 <.2 Ethylbenzene <.1 4. First Aid Measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Call a POISON CENTER or doctor/physician. Methanol is toxic and flammable. Take proper precautions to ensure your own safety before attempting rescue (e.g. wear appropriate protective equipment and remove any sources of ignition). First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. If breathing is difficult, give oxygen. Obtain medical attention. First-aid measures after skin contact : Rinse skin with water/shower. Remove/Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Get medical attention if needed. First-aid measures after eye contact : Rinse immediately and thoroughly, pulling the eyelids well away from the eye (15 minutes minimum). Remove contact lenses, if present and easy to do. Continue rinsing. Ensure that folded skin of eyelids is thoroughly washed with water. Obtain medical attention if pain, blinking or redness persist. THE BERKEBILE OIL COMPANY, INC. PAGE 4 OF 9 PAGES B1900, B1912, B1905, B19055 Telephone: 814-443-1656 Page 4 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 First-aid measures after ingestion 4.2 Most Important Symptoms : : Rinse mouth with water and drink 2-4 cups of water. Do NOT induce vomiting. Obtain emergency medical attention. Never give anything by mouth to an unconscious person. Note to Physician: Activated charcoal may be administered. Symptoms may include: Irritation, Dermatitis, Nausea, Vomiting, Diarrhea, Breathing difficulties 5. Fire-Fighting Measures Flammable Properties: As defined by OSHA, this product is a Class 3A flammable liquid. Suitable Extinguishing Media: Dry chemical, carbon dioxide (CO2) Products of Combustion: Carbon dioxide (CO2), Carbon monoxide, Smoke, Fume, Unburned hydrocarbons Explosion Hazards: Containers, when exposed to heat from fire, may build pressure and rupture. Use water to cool closed containers. Protection of Fire-Fighters: Firefighters should wear self-contained, NIOSH-approved breathing apparatus for protection against suffocation and possible toxic decomposition products. Proper eye and skin protection should be provided. Use water spray to keep fire-exposed containers cool and to knock down vapors which may result from product decomposition. 6. Accidental Release Measures Personal Precautions: Use personal protection recommended in Section 8. Environmental Precautions: Take precautions to prevent contamination of ground and surface waters. Do not flush into sewers or storm drains. If run-off occurs, notify the proper authorities as required, that a spill has occurred. Methods for Containment & Clean-up: Eliminate all ignition sources. Dike area to contain spill. Ventilate the area with fresh air. If in confined space or limited air circulation area, clean-up workers should wear appropriate respiratory protection. Recover or absorb spilled material using an absorbent designed for chemical spills. Place used absorbents into proper waste containers. 7. Handling and Storage ? Handling Procedures: Avoid contact with eyes, skin, or clothing. Keep away from sources of ignition. Do not pressurize, cut, weld, braze, solder, drill, or grind containers. Handle with care and avoid spillage on the floor ( slippage). Ground and bond containers when transferring material. Avoid formation of aerosol. Do not breathe vapors/dust. Avoid exposure - obtain special instructions before use. Smoking, eating and drinking should be prohibited in the application area. Provide sufficient air exchange and/or exhaust in work rooms. Dispose of rinse water in accordance with local and national regulations. THE BERKEBILE OIL COMPANY, INC. PAGE 5 OF 9 PAGES B1900, B1912, B1905, B19055 Telephone: 814-443-1656 Page 5 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 Storage Prodedures: Keep away from sources of ignition. Store in a tightly closed container. Containers which are opened must be carefully re-sealed and kept upright to prevent leakage. 8. Exposure Controls / Personal Protection Exposure Guidelines: Distillates (pet), hydro-treated light OSHA TWA: 500 ppm Solvent naphtha (pet), me-dium aliph. OSHA TWA: 500 ppm 1,2,4-TRIMETHYLBENZENE ACGIH TWA: 25 ppm 1,3,5-TRIMETHYLBENZENE ACGIH TWA: 25 ppm XYLENE OSHA TWA: 100 ppm OSHA STEL: 150 ppm CUMENE OSHA PEL: 50 ppm, 245 mg/m^3 OSHA TWA: 50 ppm ACGIH TWA: 50 ppm NAPHTHALENE OSHA PEL: 10 ppm, 50 mg/m^3 OSHA TWA: 10 ppm, 50 mg/m^3 OSHA STEL: 15 ppm VINYL ACETATE OSHA TWA: 10 ppm, 30 mg/m^3 OSHA STEL: 20 ppm ETHYLBENZENE OSHA TWA: 100 ppm OSHA STEL: 125 ppm ACGIH STEL: 125 ppm Controls and Protection: Engineering Controls: All ventilation should be designed in accordance with OSHA standard (29 CFR 1910.94). Personal Protective Equip: Use of safety glassses and gloves are recommended. Eye/face Protection: For normal conditions, wear safety glasses. Where there is reasonable probability of liquid contact, wear splash-proof goggles. Skin Protection: Use protective gloves such as nitrile or natural rubber. Also, use full protective clothing if there is prolonged or repeated contact of liquid with skin. 9. Physical and Chemical Properties Appearance : liquid Colour : transparent, clear Odour : characteristic, hydrocarbon-like, solvent-like Odour Threshold : No data available THE BERKEBILE OIL COMPANY, INC. PAGE 6 OF 9 PAGES B1900, B1912, B1905, B19055 Telephone: 814-443-1656 Page 6 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 pH : not applicable Freezing Point (Melting point/range) : < -70 ?C (< -94 ?F) Boiling Point (Boiling point/boiling range) : 179 - 213.9 ?C (354 - 417.0 ?F) Flash point : 61 - 66 ?C (142 - 151 ?F) Evaporation rate : 0.04 Flammability (solid, gas) : No data available Burning rate : No data available Upper explosion limit : 6.0 - 7.0 %(V) Lower explosion limit : 0.7 - 0.8 %(V) Vapour pressure : 0.32 - 0.5 mmHg @ 20 ?C (68 ?F) Relative vapour density : > 1AIR=1 Relative density : 0.78 - 0.81Reference substance: (water = 1) Density : 0.780 - 0.803 g/cm3@15 - 15.5 ?C (59 - 59.9?F) Bulk density : No data available Auto-ignition temperature : 233 - 315 ?C Viscosity, kinematic : 1.8 mm2/s @ 20 ?C (68 ?F) 10. Stability and Reactivity Stability: Product is stable under normal conditions. Conditions to Avoid: High temperatures above 50 C (122 F) and open flame. Materials to Avoid: May burn or react violently to flourine/oxygen mixtures. 11. Toxicological Information Long-term toxicological studies have not been conducted for this product. The following information is available for components of this product: Repeated skin contact with this product may cause dermatitis or an oil acne. No component is listed as a carcinogen, mutagen, or teratogen. SKIN EFFECTS: Solvent Petroleum Naphtha, no deaths reported at 4 ml/kg (Rat). Slightly irritating (rabbit, 4 hour(s)). Vinyl Acetate Monomer, Skin absorption LD50 is 2,335 mg/kg in rabbits. ACUTE ORAL EFFECTS: Solvent Petroleum Naphtha, LD50, 10 ml/kg in rats. Oral LD 50 for Vinyl Acetate Monomer is 2,920 mg/kg in rats. ACUTE INHALATION EFFECTS: Solvent Petroleum Naphtha, no deaths at 710 ppm (v) (Rat) 4 Hour (s). Vinyl Acetate Monomer, four hour inhalation LC50 is 4,000 ppm in rats. 12. Ecological Information Avoid exposing to the environment, no specific aquatic data available THE BERKEBILE OIL COMPANY, INC. PAGE 7 OF 9 PAGES B1900, B1912, B1905, B19055 Telephone: 814-443-1656 Page 7 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 13. Disposal Considerations Dispose of in accordance with local regulations. Do not flush to surface water or drains 14. Transport Information IATA (International Air Transport Association): Not regulated as a dangerous good IMDG-Code: Not regulated as a dangerous good DOT (Department of Transportation): Special Notes: UN1268, PETROLEUM DISTILLATES, N.O.S., CBL, III The flash point for this material is greater than 100 F (38 C). Therefore, in accordance with 49 CFR 173.150(f) non- bulk containers (<450L or <119 gallon capacity) of this material may be shipped as non-regulated when transported solely by land, as long as the material is not a hazardous waste, a marine pollutant, or specifically listed as a hazardous substance. : 15. Regulatory Information OSHA Hazards : Combustible Liquid, Toxic by inhalation., Harmful by ingestion., Harmful by skin absorption., Moderate skin irritant, Aspiration hazard WHMIS Classification : B3: Combustible Liquid D2B: Toxic Material Causing Other Toxic Effects REGULATORY DISCLOSURES: New Jersey Right to Know list: 1,2,4-Trimethylbenzene, CAS #95-63-6, < 5 - 15%. 1,3,5-Trimethylbenzene, CAS # 108-67-8, < 5 %. Cumene, CAS # 98-82-8, < 0.5%. Xylene, CAS # 1330-20-7, < 0.5 %. Naphthalene, CAS# 91-20-3, < 0.5 %. Pennsylvania Right to Know List: 1,2,4-Trimethylbenzene, CAS #95-63-6, < 5 - 15%. 1,3,5-Trimethylbenzene, CAS # 108-67-8, < 5 %. Cumene, CAS # 98-82-8, < 0.5%. Xylene, CAS # 1330-20-7, < 0.5 %. Naphthalene, CAS# 91-20-3, < 0.5 %. Canadian Disclosure List 1,2,4-TRIMETHYLBENZENE (95-63-6) 1,3,5-TRIMETHYLBENZENE (108-67-8) CUMENE (98-82-8) ETHYLBENZENE (100-41-4) SARA Title III - Section 313 1,2,4-TRIMETHYLBENZENE (95-63-6) XYLENE (1330-20-7) CUMENE (98-82-8) NAPHTHALENE (91-20-3) THE BERKEBILE OIL COMPANY, INC. PAGE 8 OF 9 PAGES B1900, B1912, B1905, B19055 Telephone: 814-443-1656 Page 8 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 VINYL ACETATE (108-05-4) ETHYLBENZENE (100-41-4) CERCLA Hazardous Substances XYLENE (1330-20-7) -- RQ 1000 lb CUMENE (98-82-8) -- RQ 5000 lb NAPHTHALENE (91-20-3) -- RQ 100 lb VINYL ACETATE (108-05-4) -- RQ 5000 lb ETHYLBENZENE (100-41-4) -- RQ 1000 lb RCRA Hazardous Substances XYLENE (1330-20-7) -- RCRA Code: U239 CUMENE (98-82-8) -- RCRA Code: U055 NAPHTHALENE (91-20-3) -- RCRA Code: U165 Clean Air Act - Section 112 VINYL ACETATE (108-05-4) Title V 1,2,4-TRIMETHYLBENZENE (95-63-6) XYLENE (1330-20-7) CUMENE (98-82-8) NAPHTHALENE (91-20-3) VINYL ACETATE (108-05-4) ETHYLBENZENE (100-41-4) SC Toxic Air Pollutants List XYLENE (1330-20-7) CUMENE (98-82-8) NAPHTHALENE (91-20-3) VINYL ACETATE (108-05-4) ETHYLBENZENE (100-41-4) NFPA: HMIS III: HEALTH 2 FLAMABALITY 2 PHYSICAL HAZZARD 0 Prepared By: Kirk Sherbine Berkebile Oil #: B1900, B1912, B1905, B1955 Revision Date: 03/01/2015 Changes since last revision: All The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of Berkebile Oil?s knowledge or obtained from sources believed by Berkebile Oil to be THE BERKEBILE OIL COMPANY, INC. PAGE 9 OF 9 PAGES B1900, B1912, B1905, B19055 Telephone: 814-443-1656 Page 9 1216 Red Brant Rd., PO Box 715 Fax: 814-443-2873 Somerset, PA 15501-0715 accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this MSDS consult your supervisor, a health & safety professional, or Berkebile Oil Company.