Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Dupli-Color Products Company 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. BSP209 BSP209Product code : Product Information Telephone Number : (800) 247-3270 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 2 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 36.4% (dermal), 36.4% (inhalation) OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 1/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use explosion-proof electrical, ventilating or lighting equipment. Use non-sparking tools. Take action to prevent static discharges. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash thoroughly after handling. Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Keep cool. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Read label before use. Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified : None known. Highly flammable liquid and vapor. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May damage fertility or the unborn child. :Hazard statements Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Acetone ?25 - ?50 67-64-1 p-Chlorobenzotrifluoride ?25 - ?50 98-56-6 Ethyl 3-Ethoxypropionate ?5 763-69-9 Titanium Dioxide ?3 13463-67-7 Aluminum Oxide ?3 1344-28-1 Carbon Black ?1 1333-86-4 1-Methyl-2-Pyrrolidone ?0.3 872-50-4 Ingredient name CAS number% by weight Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 2/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 3. Composition/information on ingredients Occupational exposure limits, if available, are listed in Section 8. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 3/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. Skin contact Ingestion reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide halogenated compounds carbonyl halides metal oxide/oxides Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media : : : Flammable liquid.Remark : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 4/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 5/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 7. Handling and storage Conditions for safe storage, including any incompatibilities Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : Acetone 67-64-1 ACGIH TLV (United States, 1/2024). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. NIOSH REL (United States, 10/2020). TWA: 250 ppm 10 hours. TWA: 590 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 1000 ppm 8 hours. TWA: 2400 mg/m? 8 hours. p-Chlorobenzotrifluoride 98-56-6 None. Ethyl 3-Ethoxypropionate 763-69-9 None. Titanium Dioxide 13463-67-7 OSHA PEL (United States, 5/2018). TWA: 15 mg/m? 8 hours. Form: Total dust ACGIH TLV (United States, 1/2024). TWA: 2.5 mg/m? 8 hours. Form: respirable fraction, finescale particles Aluminum Oxide 1344-28-1 ACGIH TLV (United States, 1/2024). [Aluminum, metal and insoluble compounds] TWA: 1 mg/m? 8 hours. Form: Respirable fraction OSHA PEL (United States, 5/2018). TWA: 5 mg/m? 8 hours. Form: Respirable fraction TWA: 15 mg/m? 8 hours. Form: Total dust Carbon Black 1333-86-4 ACGIH TLV (United States, 1/2024). TWA: 3 mg/m? 8 hours. Form: Inhalable fraction NIOSH REL (United States, 10/2020). TWA: 3.5 mg/m? 10 hours. OSHA PEL (United States, 5/2018). TWA: 3.5 mg/m? 8 hours. 1-Methyl-2-Pyrrolidone 872-50-4 OARS WEEL (United States, 4/2022). Absorbed through skin. TWA: 15 ppm 8 hours. STEL: 120 mg/m? 15 minutes. STEL: 30 ppm 15 minutes. TWA: 60 mg/m? 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits (OSHA United States) Occupational exposure limits (Canada) CAS # Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 6/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection acetone 67-64-1 CA Alberta Provincial (Canada, 3/2023). OEL: 1200 mg/m? 8 hours. OEL: 1800 mg/m? 15 minutes. OEL: 500 ppm 8 hours. OEL: 750 ppm 15 minutes. CA British Columbia Provincial (Canada, 8/2023). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. CA Ontario Provincial (Canada, 6/2019). TWA: 250 ppm 8 hours. STEL: 500 ppm 15 minutes. CA Quebec Provincial (Canada, 2/2024). TWAEV: 250 ppm 8 hours. STEV: 500 ppm 15 minutes. CA Saskatchewan Provincial (Canada, 4/2021). STEL: 750 ppm 15 minutes. TWA: 500 ppm 8 hours. Carbon black 1333-86-4 CA British Columbia Provincial (Canada, 8/2023). TWA: 3 mg/m? 8 hours. Form: Inhalable CA Ontario Provincial (Canada, 6/2019). TWA: 3 mg/m? 8 hours. Form: Inhalable particulate matter. CA Quebec Provincial (Canada, 2/2024). TWAEV: 3 mg/m? 8 hours. Form: inhalable aerosol fraction CA Alberta Provincial (Canada, 3/2023). OEL: 3.5 mg/m? 8 hours. CA Saskatchewan Provincial (Canada, 4/2021). STEL: 7 mg/m? 15 minutes. TWA: 3.5 mg/m? 8 hours. N-Methyl pyrrolidone 872-50-4 CA Ontario Provincial (Canada, 6/2019). TWA: 400 mg/m? 8 hours. Ingredient name Exposure limits Acetone 67-64-1 NOM-010-STPS-2014 (Mexico, 4/2016). TWA: 500 ppm 8 hours. STEL: 750 ppm 15 minutes. Exposure limits Occupational exposure limits (Mexico) CAS # CAS # Biological exposure indices (United States) Acetone ACGIH BEI (United States, 1/2024) BEI: 25 mg/l, acetone [in urine]. Sampling time: end of shift. 1-Methyl-2-Pyrrolidone ACGIH BEI (United States, 1/2024) BEI: 100 mg/l, 5-hydroxy-N-methyl- 2-pyrrolidone [in urine]. Sampling time: end of shift. Ingredient name Exposure indices Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 7/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection : : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Environmental exposure controls : Biological exposure indices (Canada) Biological exposure indices (Mexico) No exposure indices known. Acetone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 50 mg/L [non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], acetone [in urine]. Sampling time: at the end of the work shift. 1-Methyl-2-Pyrrolidone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 100 mg/L, 5-hydroxy-n-methyl- 2-pyrrolidone [in urine]. Sampling time: at the end of the work shift. Ingredient name Exposure indices Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 8/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Respiratory protection : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Liquid. Not available. 0.99 2 [Air = 1] Not available.Odor pH Green.Color Evaporation rate 5.6 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -9?C (15.8?F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Kinematic (40?C (104?F)): <20.5 mm2/s (<20.5 cSt) Not available.Odor threshold Partition coefficient: n- octanol/water : : : : : : : : : : : : : : Appearance : 55?C (131?F) : Flammable liquid. : Lower: 0.9% Upper: 12.8% Decomposition temperature : Not available. Heat of combustion : 28.922 kJ/g Molecular weight : Not applicable. Boiling point, initial boiling point, and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 24 kPa (180 mm Hg) Solubility(ies) : Media Result cold water Not soluble Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 9/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Acetone LD50 Oral Rat 5800 mg/kg - p-Chlorobenzotrifluoride LD50 Oral Rat 13 g/kg - Ethyl 3-Ethoxypropionate LD50 Oral Rat 3200 mg/kg - Carbon Black LD50 Oral Rat >15400 mg/kg - 1-Methyl-2-Pyrrolidone LD50 Dermal Rabbit 8 g/kg - LD50 Oral Rat 3914 mg/kg - Product/ingredient name Result Species Dose Exposure Carcinogenicity Not available. Mutagenicity Not available. Irritation/Corrosion Acetone Eyes - Mild irritant Human - 186300 ppm - Eyes - Mild irritant Rabbit - 10 uL - Eyes - Moderate irritant Rabbit - 24 hours 20 mg - Eyes - Severe irritant Rabbit - 20 mg - Skin - Mild irritant Rabbit - 395 mg - Skin - Mild irritant Rabbit - 24 hours 500 mg - Ethyl 3-Ethoxypropionate Skin - Mild irritant Rabbit - 24 hours 500 mg - Titanium Dioxide Skin - Mild irritant Human - 72 hours 300 ug I - 1-Methyl-2-Pyrrolidone Eyes - Moderate irritant Rabbit - 100 mg - Product/ingredient name Result Score Exposure Observation Sensitization Not available. Species Information on toxicological effects Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 10/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 11. Toxicological information Teratogenicity Not available. Reproductive toxicity Not available. Specific target organ toxicity (single exposure) Specific target organ toxicity (repeated exposure) Acetone Category 3 - Respiratory tract irritation Category 3 Narcotic effects p-Chlorobenzotrifluoride Category 3 - Respiratory tract irritation 1-Methyl-2-Pyrrolidone Category 3 - Respiratory tract irritation Name Category Not available. Aspiration hazard Not available. Route of exposure Target organs Classification p-Chlorobenzotrifluoride - 2B - Titanium Dioxide - 2B - Carbon Black - 2B - Product/ingredient name NTPIARCOSHA Information on the likely routes of exposure Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. May cause respiratory irritation. Can cause central nervous system (CNS) depression.:Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness : Not available. Potential acute health effects Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 11/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 11. Toxicological information Not available. No known significant effects or critical hazards.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : May damage the unborn child.Teratogenicity : Developmental effects : No known significant effects or critical hazards. Fertility effects : No known significant effects or critical hazards. Skin contact Ingestion Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: irritation redness reduced fetal weight increase in fetal deaths skeletal malformations : : Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Numerical measures of toxicity Oral 85881.44 mg/kg Route ATE value Acute toxicity estimates Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. Section 12. Ecological information Toxicity Acetone Acute EC50 7200000 ?g/l Fresh water Algae - Selenastrum sp. 96 hours Acute LC50 4.42589 ml/L Marine water Crustaceans - Acartia tonsa - Copepodid 48 hours Acute LC50 7460000 ?g/l Fresh water Daphnia - Daphnia cucullata 48 hours Acute LC50 5600 ppm Fresh water Fish - Poecilia reticulata 96 hours Chronic NOEC 4.95 mg/l Marine water Algae - Ulva pertusa 96 hours Chronic NOEC 0.016 ml/L Fresh water Crustaceans - Daphniidae 21 days Chronic NOEC 0.1 ml/L Fresh water Daphnia - Daphnia magna - Neonate 21 days Product/ingredient name SpeciesResult Exposure Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 12/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 12. Ecological information Bioaccumulative potential Other adverse effects : No known significant effects or critical hazards. Not available. Product/ingredient name Aquatic half-life Photolysis Biodegradability Acetone - - Readily Chronic NOEC 5 ?g/l Marine water Fish - Gasterosteus aculeatus - Larvae 42 days Titanium Dioxide Acute LC50 >1000000 ?g/l Marine water Fish - Fundulus heteroclitus 96 hours Aluminum Oxide Acute EC50 114.357 mg/l Fresh water Daphnia - Daphnia magna - Neonate 48 hours 1-Methyl-2-Pyrrolidone Acute LC50 1.23 ppm Fresh water Daphnia - Daphnia magna 48 hours Acute LC50 832 ppm Fresh water Fish - Lepomis macrochirus 96 hours Persistence and degradability Soil/water partition coefficient (KOC) : Not available. Mobility in soil Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 PAINT. Marine pollutant (p- Chlorobenzotrifluoride) 3 UN1263 UN1263 DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) TDG Classification UN1263 PAINT 3 Mexico Classification UN1263 PAINT 3 IATA UN1263 PAINT 3 Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 13/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 14. Transport information II II - The marine pollutant mark is not required when transported in sizes of ?5 L or ?5 kg. Emergency schedules F-E, S- E Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No. Yes. Not available. : Proper shipping name : Not available. : II No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). II No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. II Yes. The environmentally hazardous substance mark is not required. The environmentally hazardous substance mark may appear if required by other transportation regulations. 128 ERG No. 128 128 ERG No. ERG No. Section 15. Regulatory information SARA 313 TSCA 5(a)2 proposed significant new use rules: 1-Methyl-2-Pyrrolidone SARA 313 (40 CFR 372.45) supplier notification can be found on the Environmental Data Sheet, where applicable. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 International regulations Montreal Protocol Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 14/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 15. Regulatory information Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International lists : Section 16. Other information 9/29/2024 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : Key to abbreviations : 9/29/2024 5/19/2024 22 Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. FLAMMABLE LIQUIDS - Category 2 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 1B Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method Procedure used to derive the classification Classification Justification ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 15/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Indicates information that has changed from previously issued version. Notice to reader N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision : 9/29/2024 Date of previous issue : 5/19/2024 Version : 22 16/16 BSP209 Dupli-Color? Paint Shop? Finish System Dark Emerald Green Metallic SHW-85-NA-GHS-US