KRYLON? OSHA Colors Safety Yellow Not available. Aerosol. US / Canada: (216) 566-2917 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Krylon Products Group 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. 1813 1813Product code : Product Information Telephone Number : US / Canada: (800) 457-9566 Mexico: Not Available Transportation Emergency Telephone Number : US / Canada: (216) 566-2917 Mexico: SETIQ 800-00-214-00 / 55-5559-1588 Available 24 hours and 365 days a year Section 2. Hazards identification AEROSOLS - Category 1 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 13.6% (oral), 13.6% (dermal), 48.6% (inhalation) OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Extremely flammable aerosol. Pressurized container: may burst if heated. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 1/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing, eye protection, face protection, or hearing protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash thoroughly after handling. Do not pierce or burn, even after use. Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN: Wash with plenty of water. If skin irritation occurs: Get medical advice or attention. Take off contaminated clothing and wash it before reuse. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Keep container tightly closed. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified : None known. Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Methyl Acetate ?25 - ?50 79-20-9 Methyl Ethyl Ketone ?10 - ?25 78-93-3 Propane ?10 - ?25 74-98-6 Butane ?10 106-97-8 2-methoxy-1-methylethyl acetate ?5 108-65-6 Xylene, mixed isomers ?5 1330-20-7 Titanium Dioxide ?3 13463-67-7 Ethylbenzene <1 100-41-4 Ingredient name Identifiers% by weight Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 2/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression.:Ingestion Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Indication of immediate medical attention and special treatment needed, if necessary Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 3/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Specific treatments : No specific treatment. See toxicological information (Section 11) Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : Flammable aerosol.Remark : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 4/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Methyl Acetate 79-20-9 ACGIH TLV (United States, 1/2024) TWA 8 hours: 200 ppm. TWA 8 hours: 606 mg/m?. STEL 15 minutes: 250 ppm. STEL 15 minutes: 757 mg/m?. NIOSH REL (United States, 10/2020) TWA 10 hours: 200 ppm. TWA 10 hours: 610 mg/m?. STEL 15 minutes: 250 ppm. STEL 15 minutes: 760 mg/m?. OSHA PEL (United States, 5/2018) TWA 8 hours: 200 ppm. TWA 8 hours: 610 mg/m?. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters CAS # Occupational exposure limits(OSHA United States) Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 5/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Methyl Ethyl Ketone 78-93-3 ACGIH TLV (United States, 1/2024) Absorbed through skin. TWA 8 hours: 75 ppm. STEL 15 minutes: 150 ppm. NIOSH REL (United States, 10/2020) TWA 10 hours: 200 ppm. TWA 10 hours: 590 mg/m?. STEL 15 minutes: 300 ppm. STEL 15 minutes: 885 mg/m?. OSHA PEL (United States, 5/2018) TWA 8 hours: 200 ppm. TWA 8 hours: 590 mg/m?. Propane 74-98-6 ACGIH TLV (United States, 1/2024) Oxygen depletion [asphyxiant] , Explosive potential. NIOSH REL (United States, 10/2020) TWA 10 hours: 1000 ppm. TWA 10 hours: 1800 mg/m?. OSHA PEL (United States, 5/2018) TWA 8 hours: 1000 ppm. TWA 8 hours: 1800 mg/m?. Butane 106-97-8 ACGIH TLV (United States, 1/2024) [Butane] Explosive potential. STEL 15 minutes: 1000 ppm. NIOSH REL (United States, 10/2020) TWA 10 hours: 800 ppm. TWA 10 hours: 1900 mg/m?. 2-methoxy-1-methylethyl acetate 108-65-6 OARS WEEL (United States, 9/2024) TWA 8 hours: 50 ppm. Xylene, mixed isomers 1330-20-7 ACGIH TLV (United States, 1/2024) [p- xylene and mixtures containing p-xylene] A4. Ototoxicant. TWA 8 hours: 20 ppm. OSHA PEL (United States, 5/2018) [Xylenes] TWA 8 hours: 100 ppm. TWA 8 hours: 435 mg/m?. Titanium Dioxide 13463-67-7 ACGIH TLV (United States, 1/2024) A3. TWA 8 hours: 2.5 mg/m?. Form: respirable fraction, finescale particles. NIOSH REL (United States, 10/2020) NIA. OSHA PEL (United States, 5/2018) TWA 8 hours: 15 mg/m?. Form: Total dust. Ethylbenzene 100-41-4 ACGIH TLV (United States, 1/2024) A3. Ototoxicant. TWA 8 hours: 20 ppm. NIOSH REL (United States, 10/2020) TWA 10 hours: 100 ppm. TWA 10 hours: 435 mg/m?. STEL 15 minutes: 125 ppm. STEL 15 minutes: 545 mg/m?. OSHA PEL (United States, 5/2018) TWA 8 hours: 100 ppm. TWA 8 hours: 435 mg/m?. Occupational exposure limits (Canada) Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 6/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Methyl acetate 79-20-9 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 250 ppm. TWA 8 hours: 200 ppm. CA British Columbia Provincial (Canada, 9/2024) TWA 8 hours: 200 ppm. STEL 15 minutes: 250 ppm. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 200 ppm. STEL 15 minutes: 250 ppm. CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 200 ppm. TWAEV 8 hours: 606 mg/m?. STEV 15 minutes: 250 ppm. STEV 15 minutes: 757 mg/m?. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 606 mg/m?. OEL 15 minutes: 757 mg/m?. OEL 15 minutes: 250 ppm. OEL 8 hours: 200 ppm. Methyl ethyl ketone 78-93-3 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 300 ppm. TWA 8 hours: 200 ppm. CA British Columbia Provincial (Canada, 9/2024) Repr. Absorbed through skin. TWA 8 hours: 50 ppm. STEL 15 minutes: 100 ppm. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 200 ppm. STEL 15 minutes: 300 ppm. CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 50 ppm. TWAEV 8 hours: 150 mg/m?. STEV 15 minutes: 100 ppm. STEV 15 minutes: 300 mg/m?. CA Alberta Provincial (Canada, 3/2023) OEL 15 minutes: 300 ppm. OEL 8 hours: 200 ppm. OEL 8 hours: 590 mg/m?. OEL 15 minutes: 885 mg/m?. Normal propane 74-98-6 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 1250 ppm. TWA 8 hours: 1000 ppm. CA British Columbia Provincial (Canada, 9/2024) Oxygen depletion [asphyxiant] , Explosive potential. CA Ontario Provincial (Canada, 6/2019) Oxygen depletion [asphyxiant] , Explosive potential. CA Quebec Provincial (Canada, 2/2024) Oxygen depletion [asphyxiant] , Explosive potential. Ingredient name Exposure limitsCAS # Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 7/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 1000 ppm. Butane 106-97-8 CA Saskatchewan Provincial (Canada, 4/2021) [Aliphatic hydrocarbon gases, Alkane [C1-C4]] STEL 15 minutes: 1250 ppm. TWA 8 hours: 1000 ppm. CA Saskatchewan Provincial (Canada, 4/2021) [Butane] STEL 15 minutes: 1250 ppm. TWA 8 hours: 1000 ppm. CA British Columbia Provincial (Canada, 9/2024) [butane, all isomers] Explosive potential. STEL 15 minutes: 1000 ppm. CA Ontario Provincial (Canada, 6/2019) [Butane, All isomers] Explosive potential. STEL 15 minutes: 1000 ppm. CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 800 ppm. TWAEV 8 hours: 1900 mg/m?. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 1000 ppm. Xylene 1330-20-7 CA Saskatchewan Provincial (Canada, 4/2021) [Xylene] STEL 15 minutes: 150 ppm. TWA 8 hours: 100 ppm. CA British Columbia Provincial (Canada, 9/2024) [xylene (o, m & p isomers)] TWA 8 hours: 100 ppm. STEL 15 minutes: 150 ppm. CA Ontario Provincial (Canada, 6/2019) [Xylene (o-, m-, p-isomers)] STEL 15 minutes: 150 ppm. TWA 8 hours: 100 ppm. CA Quebec Provincial (Canada, 2/2024) [Xylene] TWAEV 8 hours: 100 ppm. TWAEV 8 hours: 434 mg/m?. STEV 15 minutes: 150 ppm. STEV 15 minutes: 651 mg/m?. CA Alberta Provincial (Canada, 3/2023) [Dimethylbenzene] OEL 8 hours: 100 ppm. OEL 15 minutes: 651 mg/m?. OEL 15 minutes: 150 ppm. OEL 8 hours: 434 mg/m?. Ethylbenzene 100-41-4 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 125 ppm. TWA 8 hours: 100 ppm. CA British Columbia Provincial (Canada, 9/2024) Carc 2B. TWA 8 hours: 20 ppm. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 20 ppm. CA Quebec Provincial (Canada, 2/2024) Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 8/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection C3. TWAEV 8 hours: 20 ppm. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 100 ppm. OEL 8 hours: 434 mg/m?. OEL 15 minutes: 543 mg/m?. OEL 15 minutes: 125 ppm. Methyl Acetate 79-20-9 NOM-010-STPS-2014 (Mexico, 4/2016) TWA 8 hours: 200 ppm. STEL 15 minutes: 250 ppm. Methyl Ethyl Ketone 78-93-3 NOM-010-STPS-2014 (Mexico, 4/2016) TWA 8 hours: 200 ppm. STEL 15 minutes: 300 ppm. Xylene, mixed isomers 1330-20-7 NOM-010-STPS-2014 (Mexico, 4/2016) [Xileno, mezcla] A4. STEL 15 minutes: 150 ppm. TWA 8 hours: 100 ppm. Ingredient name Exposure limits Occupational exposure limits (Mexico) CAS # Biological exposure indices Methyl Ethyl Ketone ACGIH BEI (United States, 1/2024) BEI: 2 mg/l, methyl ethyl ketone [in urine]. Sampling time: end of shift. Xylene, mixed isomers ACGIH BEI (United States, 1/2024) [xylenes (technical or commercial grades)] BEI: 0.3 g/g creatinine, methylhippuric acids [in urine]. Sampling time: end of shift. Ethylbenzene ACGIH BEI (United States, 1/2024) BEI: 150 mg/g creatinine, sum of mandelic acid and phenylglyoxylic acid [in urine]. Sampling time: end of shift. Ingredient name Exposure indices Biological exposure indices (Canada) Biological exposure indices (Mexico) No exposure indices known. Methyl Ethyl Ketone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 2 mg/L, MEK [in urine]. Sampling time: at the end of the work shift. Xylene, mixed isomers Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) [xilenos Ingredient name Exposure indices (United States) Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 9/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : (grado t?cnico o comercial)] BEI: 1.5 g/g creatinine, methyl hippuric acids [in urine]. Sampling time: at the end of the work shift. Section 9. Physical and chemical properties Physical state Liquid. Not available.Odor Yellow.Color Not available.Odor threshold : : : : Appearance The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 10/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 9. Physical and chemical properties Melting point/freezing point Vapor pressure Relative density Not available. 0.81 1.55 [Air = 1] pH Evaporation rate 5.6 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29?C (-20.2?F) [Pensky-Martens Closed Cup] Not applicable. Not applicable. Viscosity Dynamic (room temperature): Not available. Kinematic (room temperature): Not available. Kinematic (40?C (104?F)): <20.5 mm2/s (<20.5 cSt) Partition coefficient: n- octanol/water : : : : : : : : : : : Not available. : Flammable aerosol. : Lower: 1% Upper: 16% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 33.704 kJ/g : Not applicable. Boiling point or initial boiling point and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density 101.3 kPa (760 mm Hg) Solubility(ies) : Media Result cold water Not soluble Density : 0.8 g/cm? Particle characteristics Median particle size : Not applicable. Aerosol product Molecular weight Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 11/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 11. Toxicological information Acute toxicity Information on toxicological effects Methyl Acetate Rat - Oral - LD50 >5 g/kg Rabbit - Dermal - LD50 >5 g/kg Methyl Ethyl Ketone Rabbit - Dermal - LD50 6480 mg/kg Rat - Oral - LD50 2737 mg/kg Butane Rat - Inhalation - LC50 Vapor 658000 mg/m? [4 hours] 2-methoxy-1-methylethyl acetate Rat - Oral - LD50 8532 mg/kg Rabbit - Dermal - LD50 >5 g/kg Xylene, mixed isomers Rat - Oral - LD50 4300 mg/kg Toxic effects: Liver - Other changes Kidney, Ureter, and Bladder - Other changes Rat - Inhalation - LC50 Gas. 6700 ppm [4 hours] Toxic effects: Behavioral - Somnolence (general depressed activity) Ethylbenzene Rat - Oral - LD50 3500 mg/kg Toxic effects: Liver - Other changes Kidney, Ureter, and Bladder - Other changes Rabbit - Dermal - LD50 >5000 mg/kg Product/ingredient name Result Conclusion/Summary [Product] : Not available. Skin corrosion/irritation Methyl Acetate Rabbit - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 500 mg Rabbit - Skin - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 20 mg Methyl Ethyl Ketone Rabbit - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 14 mg Rabbit - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 402 mg Rabbit - Skin - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 500 mg Xylene, mixed isomers Rat - Skin - Mild irritant Duration of treatment/exposure: 8 hours Amount/concentration applied: 60 uL Product/ingredient name Result Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 12/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 11. Toxicological information Rabbit - Skin - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 500 mg Rabbit - Skin - Moderate irritant Amount/concentration applied: 100 % Titanium Dioxide Human - Skin - Mild irritant Duration of treatment/exposure: 72 hours Amount/concentration applied: 300 ug I Ethylbenzene Rabbit - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 15 mg Conclusion/Summary [Product] : Not available. Not available.Conclusion/Summary [Product] Serious eye damage/eye irritation Methyl Acetate Rabbit - Eyes - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 100 mg Xylene, mixed isomers Rabbit - Eyes - Mild irritant Amount/concentration applied: 87 mg Rabbit - Eyes - Severe irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 5 mg Ethylbenzene Rabbit - Eyes - Severe irritant Amount/concentration applied: 500 mg Product/ingredient name Result : : Not available.Conclusion/Summary [Product] Respiratory corrosion/irritation Not available. Respiratory or skin sensitization Not available. Skin : Not available. Respiratory : Not available. Conclusion/Summary [Product] Conclusion/Summary [Product] Germ cell mutagenicity Not available. : Not available.Conclusion/Summary [Product] Carcinogenicity Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 13/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 11. Toxicological information Classification Xylene, mixed isomers - 3 - Titanium Dioxide - 2B - Ethylbenzene - 2B - Product/ingredient name NTPIARCOSHA Not available. : Not available.Conclusion/Summary [Product] Reproductive toxicity : Not available. Not available. Conclusion/Summary [Product] Specific target organ toxicity (single exposure) Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Skin contact : Causes skin irritation. Causes serious eye irritation.:Eye contact Potential acute health effects Specific target organ toxicity (repeated exposure) Methyl Acetate SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Methyl Ethyl Ketone SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 2-methoxy-1-methylethyl acetate SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Xylene, mixed isomers SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Respiratory tract irritation) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Ethylbenzene SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Product/ingredient name Result Product/ingredient name Result Xylene, mixed isomers SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Ethylbenzene SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Aspiration hazard Product/ingredient name Result Xylene, mixed isomers ASPIRATION HAZARD - Category 1 Ethylbenzene ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Not available. Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 14/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 11. Toxicological information Can cause central nervous system (CNS) depression.:Ingestion Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness No specific data. Adverse symptoms may include the following: irritation redness : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. May cause damage to organs through prolonged or repeated exposure.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Reproductive toxicity : Numerical measures of toxicity Acute toxicity estimates Not available. Potential chronic health effects Conclusion/Summary [Product] : Not available. Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 15/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 11. Toxicological information Product/ingredient name KRYLON? OSHA Colors 9497.1 68201.5 N/A N/A N/A Methyl Ethyl Ketone 2737 6480 N/A N/A N/A Butane N/A N/A N/A 658 N/A 2-methoxy-1-methylethyl acetate 8532 N/A N/A N/A N/A Xylene, mixed isomers 4300 2500 N/A N/A N/A Ethylbenzene 3500 N/A N/A 11 N/A Oral (mg/ kg) Dermal (mg/kg) Inhalation (gases) (ppm) Inhalation (vapors) (mg/l) Inhalation (dusts and mists) (mg/l) Section 12. Ecological information Toxicity Methyl Acetate Acute - LC50 - Fresh water Fish - Fathead minnow - Pimephales promelas Age: 28 to 32 days; Size: 17.5 mm; Weight: 0.087 g 320 mg/l [96 hours] Effect: Mortality Methyl Ethyl Ketone Acute - EC50 - Fresh water Daphnia - Water flea - Daphnia magna - Larvae Age: <24 hours 5091 mg/l [48 hours] Effect: Intoxication Acute - LC50 - Fresh water Fish - Fathead minnow - Pimephales promelas Age: 31 days; Size: 22 mm; Weight: 0.167 g 3220 mg/l [96 hours] Effect: Mortality Acute - EC50 - Marine water Algae - Diatom - Skeletonema costatum >500 mg/l [96 hours] Effect: Population Xylene, mixed isomers Acute - LC50 - Marine water Crustaceans - Daggerblade grass shrimp - Palaemon pugio 8500 ?g/l [48 hours] Effect: Mortality Acute - LC50 - Fresh water Fish - Fathead minnow - Pimephales promelas Age: 31 days; Size: 18.4 mm; Weight: 0.077 g 13.4 mg/l [96 hours] Effect: Mortality Titanium Dioxide Acute - LC50 - Marine water Fish - Mummichog - Fundulus heteroclitus >1000 mg/l [96 hours] Effect: Mortality Ethylbenzene Acute - LC50 - Fresh water Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss 4200 ?g/l [96 hours] Effect: Mortality Acute - EC50 - Fresh water Daphnia - Water flea - Daphnia magna - Neonate Age: ?24 hours 2.93 mg/l [48 hours] Product/ingredient name Result Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 16/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects No known significant effects or critical hazards. Product/ingredient name Xylene, mixed isomers - 8.1 to 25.9 Low Product/ingredient name Aquatic half-life Photolysis Biodegradability Methyl Ethyl Ketone - - Readily Xylene, mixed isomers - - Readily Ethylbenzene - - Readily Persistence and degradability Soil/Water partition coefficient : Not available. Mobility in soil Effect: Intoxication Acute - EC50 - Fresh water Algae - Green algae - Raphidocelis subcapitata 3600 ?g/l [96 hours] Effect: Population : Not available.Conclusion/Summary [Product] Not available. : Not available.Conclusion/Summary [Product] Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. :Disposal methods Section 14. Transport information AEROSOLS AEROSOLS UN1950 UN1950 DOT Classification IMDG UN number UN proper shipping name TDG Classification UN1950 AEROSOLS Mexico Classification UN1950 AEROSOLS IATA UN1950 AEROSOLS, flammable Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 17/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 14. Transport information 2.1 - 2.1 - - Emergency schedules F-D, S- U Transport hazard class(es) Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to IMO instruments No. No. Not available. : Proper shipping name : Not available. : 2.1 - No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2). 2.1 - No. - Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. 2.1 - No. - 126 ERG No. 126 126 ERG No. ERG No. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Section 15. Regulatory information U.S. Federal regulations : WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 International regulations Montreal Protocol Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 18/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 15. Regulatory information Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International lists : Section 16. Other information 6/4/2025 History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : Key to abbreviations : 6/4/2025 3/29/2025 31 Hazardous Material Information System (U.S.A.) 3 4 3 *Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. AEROSOLS - Category 1 On basis of test data SKIN CORROSION/IRRITATION - Category 2 Calculation method SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 2 Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method Procedure used to derive the classification Classification Justification ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 19/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US Section 16. Other information It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Indicates information that has changed from previously issued version. Notice to reader UN = United Nations Date of issue/Date of revision : 6/4/2025 Date of previous issue : 3/29/2025 Version : 31 20/20 1813 KRYLON? OSHA Colors Safety Yellow SHW-85-NA-GHS-US