Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Issue date: 11/29/2023 Revision date: 11/29/2023 Version: 1.0 11/29/2023 EN (English) Page 1 SECTION 1: Identification Identification Product form : Mixture Product name : ThreeBond 1217F-GM Physical state : Liquid Recommended use and restrictions on use Recommended use : Adhesives, sealants Restrictions on use : None known Supplier ThreeBond International, Inc. 6184 Schumacher Park Drive West Chester, OH 45069 T (513) 779-7300 Emergency telephone number Emergency number : CHEMTREC (Domestic North America): (800) 424-9300 (International): (703) 527-3887 SECTION 2: Hazard(s) identification Classification of the substance or mixture GHS US classification Acute toxicity (inhalation:dust,mist) Category 4 H332 Harmful if inhaled. Skin corrosion/irritation, Category 2 H315 Causes skin irritation. Serious eye damage/eye irritation, Category 1 H318 Causes serious eye damage. Skin sensitisation, Category 1 H317 May cause an allergic skin reaction. Carcinogenicity, Category 1A H350 May cause cancer. Specific target organ toxicity ? Repeated exposure, Category 2 H373 May cause damage to organs through prolonged or repeated exposure. Full text of H statements : see section 16 GHS Label elements, including precautionary statements GHS US labelling Pictograms : Signal word : Danger Hazard statements : H315 - Causes skin irritation. H317 - May cause an allergic skin reaction. H318 - Causes serious eye damage. H332 - Harmful if inhaled. H350 - May cause cancer. H373 - May cause damage to organs through prolonged or repeated exposure. Precautionary statements : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe dust/fume/gas/mist/vapours/spray. ThreeBond 1217F-GM Revision date: 06/02/2020 11/29/2023 EN (English) 2/7 P261 - Avoid breathing dust/fume/gas/mist/vapours/spray. P264 - Wash hands, forearms and face thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P272 - Contaminated work clothing must not be allowed out of the workplace. P280 - Wear protective gloves/protective clothing/eye protection/face protection. P302+P352 - If on skin: Wash with plenty of water. P304+P340 - If inhaled: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308+P313 - If exposed or concerned: Get medical advice/attention. P310 - Immediately call a poison center or doctor. P312 - Call a poison center or doctor if you feel unwell. P314 - Get medical advice/attention if you feel unwell. P321 - Specific treatment (see supplemental first aid instruction on this label). P332+P313 - If skin irritation occurs: Get medical advice/attention. P333+P313 - If skin irritation or rash occurs: Get medical advice/attention. P362+P364 - Take off contaminated clothing and wash it before reuse. P363 - Wash contaminated clothing before reuse. P405 - Store locked up. P501 - Dispose of contents/container to hazardous or special waste collection point, in accordance with local, regional, national and/or international regulation. Other hazards which do not result in classification No additional information available Unknown acute toxicity Not applicable SECTION 3: Composition/information on ingredients Name Product identifier % GHS US classification Quartz (CAS-No.) 14808-60-7 15 ? 25 Carc. 1A, H350 2-Butanone, O,O',O''-(ethenylsilylidyne)trioxime (CAS-No.) 2224-33-1 1 ? 10 Eye Dam. 1, H318 Skin Sens. 1B, H317 STOT RE 2, H373 1-Propanamine, 3-(triethoxysilyl)- (CAS-No.) 919-30-2 0.01 ? 1 Acute Tox. 4 (Oral), H302 Skin Corr. 1B, H314 Eye Dam. 1, H318 Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures Description of first aid measures First-aid measures general : Call a poison center or a doctor if you feel unwell. First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. Call a poison center or a doctor if you feel unwell. First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation or rash occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a physician immediately. First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell. Most important symptoms and effects (acute and delayed) Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Serious damage to eyes. Immediate medical attention and special treatment, if necessary Treat symptomatically. SECTION 5: Fire-fighting measures Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Water spray. Dry powder. Foam. Carbon dioxide. Unsuitable extinguishing media : Not determined. Specific hazards arising from the chemical No additional information available Special protective equipment and precautions for fire-fighters Firefighting instructions : Exercise caution when fighting any chemical fire. ThreeBond 1217F-GM Revision date: 06/02/2020 11/29/2023 EN (English) 3/7 Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures Personal precautions, protective equipment and emergency procedures General measures : Do not handle until all safety precautions have been read and understood. For non-emergency personnel Emergency procedures : Only qualified personnel equipped with suitable protective equipment may intervene. Do not breathe dust/fume/gas/mist/vapours/spray. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". Environmental precautions Avoid release to the environment. Notify authorities if product enters sewers or public waters. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Shovel or sweep up and put in a closed container for disposal. Notify authorities if product enters sewers or public waters. Other information : Dispose of materials or solid residues at an authorized site. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Take all necessary technical measures to avoid or minimize the release of the product on the workplace. Limit quantities of product at the minimum necessary for handling and limit the number of exposed workers. Provide local exhaust or general room ventilation. Wear personal protective equipment. Floors, walls and other surfaces in the hazard area must be cleaned regularly. Do not breathe dust/fume/gas/mist/vapours/spray. Avoid contact with skin and eyes. Hygiene measures : Separate working clothes from town clothes. Launder separately. Wash contaminated clothing before reuse. Contaminated work clothing should not be allowed out of the workplace. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. Conditions for safe storage, including any incompatibilities Storage conditions : Store locked up. Store in a well-ventilated place. Keep cool. SECTION 8: Exposure controls/personal protection Control parameters Limestone (1317-65-3) USA - OSHA - Occupational Exposure Limits OSHA PEL (TWA) (mg/m?) 15 mg/m? (total dust) 5 mg/m? (respirable fraction) Quartz (14808-60-7) USA - ACGIH - Occupational Exposure Limits ACGIH TWA (mg/m?) 0.025 mg/m? (respirable particulate matter) ACGIH chemical category Suspected Human Carcinogen USA - OSHA - Occupational Exposure Limits OSHA PEL (TWA) (mg/m?) 50 ?g/m? (Respirable crystalline silica) Titanium dioxide (13463-67-7) USA - ACGIH - Occupational Exposure Limits ACGIH TWA (mg/m?) 10 mg/m? ACGIH chemical category Not Classifiable as a Human Carcinogen USA - OSHA - Occupational Exposure Limits OSHA PEL (TWA) (mg/m?) 15 mg/m? (total dust) ThreeBond 1217F-GM Revision date: 06/02/2020 11/29/2023 EN (English) 4/7 Appropriate engineering controls Appropriate engineering controls : Ensure good ventilation of the work station. Environmental exposure controls : Avoid release to the environment. Individual protection measures/Personal protective equipment Hand protection: Protective gloves Eye protection: Safety glasses Skin and body protection: Wear suitable protective clothing Respiratory protection: [In case of inadequate ventilation] wear respiratory protection. SECTION 9: Physical and chemical properties Information on basic physical and chemical properties Physical state : Liquid Appearance : Paste. Colour : No data available Odour : oxime Odour threshold : No data available pH : No data available Melting point : Not applicable Freezing point : No data available Boiling point : No data available Flash point : >60?C Relative evaporation rate (butylacetate=1) : < 1 Flammability (solid, gas) : Not applicable. Vapour pressure : negligible Relative vapour density at 20 ?C : No data available Relative density : 1.49 Solubility : No data available Partition coefficient n-octanol/water (Log Pow) : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : No data available Viscosity, dynamic : 240 Pa?s Explosive limits : No data available Explosive properties : No data available Oxidising properties : No data available Other information VOC content : < 2.5 % SECTION 10: Stability and reactivity Reactivity The product is non-reactive under normal conditions of use, storage and transport. Chemical stability Stable under normal conditions. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. Conditions to avoid None under recommended storage and handling conditions (see section 7). ThreeBond 1217F-GM Revision date: 06/02/2020 11/29/2023 EN (English) 5/7 Incompatible materials Strong oxidizing agents. Hazardous decomposition products Under normal conditions of storage and use, hazardous decomposition products should not be produced. SECTION 11: Toxicological information Information on toxicological effects Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Harmful if inhaled. ATE US (dust,mist) 4.5 mg/l/4h 1-Propanamine, 3-(triethoxysilyl)- (919-30-2) LD50 oral rat 1780 mg/kg LD50 dermal rabbit 4290 mg/kg LC50 inhalation rat (mg/l) > 7.35 mg/l/4h ATE US (oral) 1780 mg/kg bodyweight ATE US (dermal) 4290 mg/kg bodyweight Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye damage. Respiratory or skin sensitisation : May cause an allergic skin reaction. Germ cell mutagenicity : Not classified Carcinogenicity : May cause cancer. Quartz (14808-60-7) IARC group 1 - Carcinogenic to humans National Toxicity Program (NTP) Status Known Human Carcinogens In OSHA Hazard Communication Carcinogen list Yes Reproductive toxicity : Not classified STOT-single exposure : Not classified STOT-repeated exposure : May cause damage to organs through prolonged or repeated exposure. 2-Butanone, O,O',O''-(ethenylsilylidyne)trioxime (2224-33-1) STOT-repeated exposure May cause damage to organs through prolonged or repeated exposure. Aspiration hazard : Not classified Viscosity, kinematic : No data available Symptoms/effects after skin contact : Irritation. May cause an allergic skin reaction. Symptoms/effects after eye contact : Serious damage to eyes. SECTION 12: Ecological information Toxicity Ecology - general : The product is not considered harmful to aquatic organisms nor to cause long-term adverse effects in the environment. 1-Propanamine, 3-(triethoxysilyl)- (919-30-2) LC50 fish 1 > 934 mg/l (Exposure time: 96 h - Species: Danio rerio [semi-static]) Persistence and degradability No additional information available Bioaccumulative potential No additional information available ThreeBond 1217F-GM Revision date: 06/02/2020 11/29/2023 EN (English) 6/7 Mobility in soil No additional information available Other adverse effects No additional information available SECTION 13: Disposal considerations Disposal methods Waste treatment methods : Dispose of contents/container in accordance with licensed collector?s sorting instructions. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Not regulated Transport by sea Not regulated Air transport Not regulated SECTION 15: Regulatory information US Federal regulations ThreeBond 1217F-GM SARA Section 311/312 Hazard Classes Health hazard - Acute toxicity (any route of exposure) Health hazard - Carcinogenicity Health hazard - Respiratory or skin sensitization Health hazard - Serious eye damage or eye irritation Health hazard - Skin corrosion or Irritation Health hazard - Specific target organ toxicity (single or repeated exposure) All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory This product or mixture is not known to contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40 CFR ?372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372. 15.2. International regulations Quartz (14808-60-7) Listed on IARC (International Agency for Research on Cancer) Listed as carcinogen on NTP (National Toxicology Program) Listed on the TCSI (Taiwan Chemical Substance Inventory) 2-Butanone, O,O',O''-(ethenylsilylidyne)trioxime (2224-33-1) Listed on the TCSI (Taiwan Chemical Substance Inventory) 1-Propanamine, 3-(triethoxysilyl)- (919-30-2) Listed on the TCSI (Taiwan Chemical Substance Inventory) US State regulations WARNING: This product can expose you to Titanium dioxide, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. ThreeBond 1217F-GM Revision date: 06/02/2020 11/29/2023 EN (English) 7/7 SECTION 16: Other information according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Revision date : 11/29/2023 Full text of H-statements: H302 Harmful if swallowed. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H332 Harmful if inhaled. H350 May cause cancer. H373 May cause damage to organs through prolonged or repeated exposure. DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This SDS was prepared and is to be used only for this product. If the product is used as a component in another product, this SDS information may not be applicable