0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 Issue date: 17/03/2022 Revision date: 26/09/2022 Supersedes version of: 14/06/2022 Version: 1.2 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 1/11 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : 0W20 dexos1 Gen 3 Product code : 16173 Type of product : ACD Product group : Blend 1.2. Relevant identified uses of the substance or mixture and uses advised against 1.2.1. Relevant identified uses Main use category : Industrial use,Professional use,Consumer use Industrial/Professional use spec : Non-dispersive use Used in closed systems Function or use category : Lubricants and additives 1.2.2. Uses advised against No additional information available 1.3. Details of the supplier of the safety data sheet 1.4. Emergency telephone number No additional information available SECTION 2: Hazards identification 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Adverse physicochemical, human health and environmental effects No additional information available 2.2. Label elements Labelling according to Regulation (EC) No. 1272/2008 [CLP] EUH-statements : EUH208 - Contains Benzenesulfonic acid, methyl-, mono-C20-24-branched alkyl derivs, calcium salts. May produce an allergic reaction. EUH210 - Safety data sheet available on request. 2.3. Other hazards Contains no PBT/vPvB substances ? 0.1% assessed in accordance with REACH Annex XIII Component Phenol, dodecyl-, branched (121158-58-5) This substance/mixture does not meet the PBT criteria of REACH regulation, annex XIII This substance/mixture does not meet the vPvB criteria of REACH regulation, annex XIII GENERAL MOTORS OVERSEAS DISTRIBUTION CORPORATION 10 Collyer Quay - 49315 #14-01 - Ocean Financial Centre Singapore acdelco@This email address is being protected from spambots. You need JavaScript enabled to view it. 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 2/11 The mixture does not contain substance(s) included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is not identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at a concentration equal to or greater than 0,1 % Component Phenol, dodecyl-, branched(121158-58-5) The substance is included in the list established in accordance with Article 59(1) of REACH for having endocrine disrupting properties, or is identified as having endocrine disrupting properties in accordance with the criteria set out in Commission Delegated Regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 SECTION 3: Composition/information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Comments : The mineral oils in the product contain < 3% DMSO extract (IP 346) Name Product identifier % Classification according to Regulation (EC) No. 1272/2008 [CLP] Zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) CAS-No.: 4259-15-8 EC-No.: 224-235-5 0.1 ? 0.99 Eye Dam. 1, H318 Aquatic Chronic 2, H411 Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl) esters, zinc salts CAS-No.: 68784-31-6 EC-No.: 272-238-5 REACH-no: 01-2119657973- 23 0.1 ? 0.99 Eye Dam. 1, H318 Aquatic Chronic 2, H411 Benzenesulfonic acid, methyl-, mono-C20-24- branched alkyl derivs., calcium salts CAS-No.: 722503-68-6 EC-No.: 682-816-2 0.1 ? 0.99 Skin Sens. 1B, H317 Phenol, dodecyl-, branched substance listed as REACH Candidate (Phenol, alkylation products (mainly in para position) with C12- rich branched alkyl chains from oligomerisation, covering any individual isomers and/ or combinations thereof (PDDP)) CAS-No.: 121158-58-5 EC-No.: 310-154-3 REACH-no: 01-2119513207- 49 0.01 ? 0.03 Skin Corr. 1C, H314 Eye Dam. 1, H318 Repr. 1A, H360F Aquatic Acute 1, H400 (M=10) Aquatic Chronic 1, H410 (M=10) Specific concentration limits: Name Product identifier Specific concentration limits Zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) CAS-No.: 4259-15-8 EC-No.: 224-235-5 ( 50 ?C < 100) Eye Dam. 1, H318 Full text of H- and EUH-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Not expected to require first aid measures. First-aid measures after skin contact : Wash skin with mild soap and water. First-aid measures after eye contact : In case of eye contact, immediately rinse with clean water for 10-15 minutes. First-aid measures after ingestion : Do not induce vomiting. Rinse mouth. Get immediate medical advice/attention. 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 3/11 4.2. Most important symptoms and effects, both acute and delayed Symptoms/effects after inhalation : Not expected to present a significant inhalation hazard under anticipated conditions of normal use. Symptoms/effects after skin contact : Not expected to present a significant skin hazard under anticipated conditions of normal use. Symptoms/effects after eye contact : Not expected to present a significant eye contact hazard under anticipated conditions of normal use. Symptoms/effects after ingestion : Not expected to present a significant ingestion hazard under anticipated conditions of normal use. 4.3. Indication of any immediate medical attention and special treatment needed No additional information available SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Water fog. Foam. Powder. Dry chemical product. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture No additional information available 5.3. Advice for firefighters Precautionary measures fire : Exercise caution when fighting any chemical fire. Firefighting instructions : Use water spray or fog for cooling exposed containers. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Wear suitable protective clothing and gloves. 6.1.2. For emergency responders Protective equipment : Wear suitable protective clothing and gloves. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if product enters sewers or public waters. 6.3. Methods and material for containment and cleaning up For containment : Impound and recover large spill by mixing it with inert granular solids. Methods for cleaning up : Detergent. Take up liquid spill into absorbent material sand, saw dust, kieselguhr. Other information : Spill area may be slippery. Use suitable disposal containers. 6.4. Reference to other sections No additional information available SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid all unnecessary exposure. Both local exhaust and general room ventilation are usually required. Handling temperature : < 40 ?C 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 4/11 Hygiene measures : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for safe storage, including any incompatibilities Storage temperature : ? 40 ?C Storage area : Store in dry, cool, well-ventilated area. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.1.1 National occupational exposure and biological limit values No additional information available 8.1.2. Recommended monitoring procedures No additional information available 8.1.3. Air contaminants formed No additional information available 8.1.4. DNEL and PNEC Additional information : 5 mg/m3 for oil mists (TWA, 8h-workday) recommended, based upon the ACGIH TLV (Analysis according to US NIOSH Method 5026, NIOSH Manual of Analytical Methods, 3rd Edition). 8.1.5. Control banding No additional information available 8.2. Exposure controls 8.2.1. Appropriate engineering controls No additional information available 8.2.2. Personal protection equipment Personal protective equipment: Safety glasses. Gloves. Personal protective equipment symbol(s): 8.2.2.1. Eye and face protection No additional information available 8.2.2.2. Skin protection Skin and body protection: No special clothing/skin protection equipment is recommended under normal conditions of use Hand protection: Permeation time: minimum >480min long term exposure; material / thickness [mm]: >0,35 mm. Nitrile rubber (NBR) / 8.2.2.3. Respiratory protection Respiratory protection: No special respiratory protection equipment is recommended under normal conditions of use with adequate ventilation. 8.2.2.4. Thermal hazards No additional information available 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 5/11 8.2.3. Environmental exposure controls No additional information available SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Colour : Yellow-brown. Appearance : Oily liquid. Odour : Characteristic. Odour threshold : Not available Melting point : Not available Freezing point : Not available Boiling point : Not available Flammability : Not available Explosive limits : Not available Lower explosion limit : Not available Upper explosion limit : Not available Flash point : > 150 ?C @ ASTM D92 Auto-ignition temperature : Not available Decomposition temperature : Not available pH : Not available Viscosity, kinematic : 36 mm?/s @ 40?C Solubility : Slightly soluble, the product remains on the water surface. Partition coefficient n-octanol/water (Log Kow) : Not available Vapour pressure : Not available Vapour pressure at 50 ?C : Not available Density : 847 kg/m? @15?C Relative density : Not available Relative vapour density at 20 ?C : Not available Particle characteristics : Not applicable 9.2. Other information 9.2.1. Information with regard to physical hazard classes No additional information available 9.2.2. Other safety characteristics No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity None under normal conditions. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions None under normal conditions. 10.4. Conditions to avoid No data available. 10.5. Incompatible materials Strong oxidizers. acids. Bases. 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 6/11 10.6. Hazardous decomposition products None under normal conditions. SECTION 11: Toxicological information 11.1. Information on hazard classes as defined in Regulation (EC) No 1272/2008 Acute toxicity (oral) : Not classified Acute toxicity (dermal) : Not classified Acute toxicity (inhalation) : Not classified Zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) (4259-15-8) LD50 oral rat 3100 mg/kg LD50 dermal rabbit > 5000 mg/kg Skin corrosion/irritation : Not classified Serious eye damage/irritation : Not classified Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified STOT-single exposure : Not classified STOT-repeated exposure : Not classified Aspiration hazard : Not classified 0W20 dexos1 Gen 3 Viscosity, kinematic 36 mm?/s @ 40?C 11.2. Information on other hazards 11.2.1. Endocrine disrupting properties Component Phenol, dodecyl-, branched(121158-58-5) The substance is identified for having endocrine disrupting properties but there is no additional data available > 11.2.2. Other information No additional information available SECTION 12: Ecological information 12.1. Toxicity Ecology - general : This product contains one or more components that have a branched alkylphenol impurity, which is very toxic for aquatic organisms (mentioned in chapter 3). The components containing this impurity, are tested and are not toxic for aquatic organisms. This is why the data from chapter 3 concerning the alkylphenol impurity cannot be used for the classification of the product regarding the aquatic toxicity. Hazardous to the aquatic environment, short?term (acute) : Not classified Hazardous to the aquatic environment, long?term (chronic) : Not classified. Zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) (4259-15-8) LC50 - Fish [1] 10 ? 35 mg/l 96h Pimephales promelas (semi static) LC50 - Fish [2] 1 ? 5 mg/l EC50 - Crustacea [1] 1 ? 1.5 mg/l 48h Daphnia magna 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 7/11 Zinc bis[O,O-bis(2-ethylhexyl)] bis(dithiophosphate) (4259-15-8) EC50 - Other aquatic organisms [1] 1 ? 5 mg/l 96h Pseudokirchneriella subcapitata 12.2. Persistence and degradability 0W20 dexos1 Gen 3 Persistence and degradability Not soluble in water, so only minimally biodegradable. Phenol, dodecyl-, branched (121158-58-5) Biodegradation 25 % Sturm-test @28d 12.3. Bioaccumulative potential Phenol, dodecyl-, branched (121158-58-5) Bioconcentration factor (BCF REACH) 2.9 @27d Partition coefficient n-octanol/water (Log Kow) 7.1 @0,1d 12.4. Mobility in soil No additional information available 12.5. Results of PBT and vPvB assessment No additional information available 12.6. Endocrine disrupting properties Component Phenol, dodecyl-, branched(121158-58-5) The substance is identified for having endocrine disrupting properties but there is no additional data available 12.7. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Additional information : Dispose in a safe manner in accordance with local/national regulations. SECTION 14: Transport information In accordance with ADR / IMDG / IATA / ADN / RID 14.1. UN number or ID number UN-No. (ADR) : Not applicable UN-No. (IMDG) : Not applicable UN-No. (IATA) : Not applicable UN-No. (ADN) : Not applicable UN-No. (RID) : Not applicable 14.2. UN proper shipping name Proper Shipping Name (ADR) : Not applicable Proper Shipping Name (IMDG) : Not applicable Proper Shipping Name (IATA) : Not applicable Proper Shipping Name (ADN) : Not applicable 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 8/11 Proper Shipping Name (RID) : Not applicable 14.3. Transport hazard class(es) ADR Transport hazard class(es) (ADR) : Not applicable IMDG Transport hazard class(es) (IMDG) : Not applicable IATA Transport hazard class(es) (IATA) : Not applicable ADN Transport hazard class(es) (ADN) : Not applicable RID Transport hazard class(es) (RID) : Not applicable 14.4. Packing group Packing group (ADR) : Not applicable Packing group (IMDG) : Not applicable Packing group (IATA) : Not applicable Packing group (ADN) : Not applicable Packing group (RID) : Not applicable 14.5. Environmental hazards Dangerous for the environment : No Marine pollutant : No Other information : No supplementary information available 14.6. Special precautions for user Overland transport Not applicable Transport by sea Not applicable Air transport Not applicable Inland waterway transport Not applicable Rail transport Not applicable 14.7. Maritime transport in bulk according to IMO instruments Not applicable SECTION 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.1.1. EU-Regulations REACH Annex XVII (Restriction List) Contains no REACH substances with Annex XVII restrictions 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 9/11 REACH Annex XIV (Authorisation List) Contains no REACH Annex XIV substances REACH Candidate List (SVHC) Contains a substance on the REACH candidate list: Phenol, alkylation products (mainly in para position) with C12-rich branched alkyl chains from oligomerisation, covering any individual isomers and/ or combinations thereof (PDDP) (EC 310-154-3, CAS 121158-58-5) PIC Regulation (Prior Informed Consent) Contains no substance subject to Regulation (EU) No 649/2012 of the European Parliament and of the Council of 4 July 2012 concerning the export and import of hazardous chemicals. POP Regulation (Persistent Organic Pollutants) Contains no substance subject to Regulation (EU) No 2019/1021 of the European Parliament and of the Council of 20 June 2019 on persistent organic pollutants Ozone Regulation (1005/2009) Contains no substance subject to REGULATION (EU) No 1005/2009 OF THE EUROPEAN PARLIAMENT AND OF THE COUNCIL of 16 September 2009 on substances that deplete the ozone layer. Explosives Precursors Regulation (2019/1148) Contains no substance subject to Regulation (EU) 2019/1148 of the European Parliament and of the Council of 20 June 2019 on the marketing and use of explosives precursors. Drug Precursors Regulation (273/2004) Contains no substance(s) listed on the Drug Precursors list (Regulation EC 273/2004 on drug precursors) 15.1.2. National regulations Germany Water hazard class (WGK) : WGK 1, Slightly hazardous to water (Classification according to AwSV, Annex 1). Hazardous Incident Ordinance (12. BImSchV) : Is not subject of the Hazardous Incident Ordinance (12. BImSchV) Netherlands SZW-lijst van kankerverwekkende stoffen : Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl) esters, zinc salts,Phenol, dodecyl-, branched are listed SZW-lijst van mutagene stoffen : Phosphorodithioic acid, mixed O,O-bis(sec-Bu and 1,3-dimethylbutyl) esters, zinc salts,Phenol, dodecyl-, branched are listed SZW-lijst van reprotoxische stoffen ? Borstvoeding : None of the components are listed SZW-lijst van reprotoxische stoffen ? Vruchtbaarheid : Phenol, dodecyl-, branched is listed SZW-lijst van reprotoxische stoffen ? Ontwikkeling : None of the components are listed Denmark Danish National Regulations : Pregnant/breastfeeding women working with the product must not be in direct contact with the product Switzerland Storage class (LK) : LK 10/12 - Liquids 15.2. Chemical safety assessment No chemical safety assessment has been carried out for the substance or the mixture by the supplier SECTION 16: Other information Indication of changes Section Changed item Change Comments Supersedes Modified Revision date Modified 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 10/11 Abbreviations and acronyms: ACGIH: American Conference of Governmental Industrial Hygienists TWA: Time Weighted Average TLV: Threshold Limit Value ASTM: American Society for Testing and Materials ADR: Accord Europ?en Relatif au Transport International des Marchandises Dangereuses par Route RID: Regulations Concerning the International Carriage of Dangerous Goods by Rail ADNR: Accord Europ?en relatif au Transport International des Marchandises Dangereuses par voie de Navigation du Rhin IMDG: International Maritime Dangerous Goods ICAO: International Civil Aviation Organization IATA: International Air Transport Association STEL: Short Term Exposure Limit LD50: median Lethal Dose for 50% of subjects ATE: acute toxicity estimate LC50: median Lethal Concentration for 50% of subjects EC50: concentration producing 50% effect Other information : The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable. Full text of H- and EUH-statements: Aquatic Acute 1 Hazardous to the aquatic environment ? Acute Hazard, Category 1 Aquatic Chronic 1 Hazardous to the aquatic environment ? Chronic Hazard, Category 1 Aquatic Chronic 2 Hazardous to the aquatic environment ? Chronic Hazard, Category 2 EUH208 Contains Benzenesulfonic acid, methyl-, mono-C20-24-branched alkyl derivs, calcium salts. May produce an allergic reaction. EUH210 Safety data sheet available on request. Eye Dam. 1 Serious eye damage/eye irritation, Category 1 H314 Causes severe skin burns and eye damage. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H360F May damage fertility. H400 Very toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Repr. 1A Reproductive toxicity, Category 1A Skin Corr. 1C Skin corrosion/irritation, Category 1, Sub-Category 1C 0W20 dexos1 Gen 3 Safety Data Sheet according to the REACH Regulation (EC) 1907/2006 amended by Regulation (EU) 2020/878 26/09/2022 (Revision date) 04/10/2022 (Printing date) EN (English) 11/11 Full text of H- and EUH-statements: Skin Sens. 1B Skin sensitisation, category 1B Safety Data Sheet (SDS), EU This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.