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DA1684
Chrome Aluminum
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DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum Not available. Aerosol. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Dupli-Color Products Company 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. DA1684 DA1684Product code : Product Information Telephone Number : (800) 247-3270 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification AEROSOLS - Category 1 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 19.9% (oral), 19.9% (dermal), 19.9% (inhalation) OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Extremely flammable aerosol. Pressurized container: may burst if heated. May be fatal if swallowed and enters airways. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May damage fertility or the unborn child. May cause damage to organs through prolonged or repeated exposure. :Hazard statements Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 1/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 2. Hazards identification Precautionary statements Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing, eye protection, face protection, or hearing protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Use only outdoors or in a well-ventilated area. Do not breathe dust or mist. Wash thoroughly after handling. Do not pierce or burn, even after use. Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF SWALLOWED: Immediately call a POISON CENTER or doctor. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage : Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Keep container tightly closed. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. General : Keep out of reach of children. If medical advice is needed, have product container or label at hand. Hazards not otherwise classified : None known. Please refer to the SDS for additional information. Keep out of reach of children. Keep upright in a cool, dry place. Do not discard empty can in trash compactor. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Section 3. Composition/information on ingredients Ethylbenzene ?25 - ?44 100-41-4 Acetone ?10 - ?25 67-64-1 Propane ?10 - ?25 74-98-6 Butane ?10 - ?25 106-97-8 Aluminum ?5 7429-90-5 Stoddard Solvent ?3 8052-41-3 Toluene ?0.3 108-88-3 Ingredient name Identifiers% by weight Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 2/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : No known significant effects or critical hazards. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 3/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments : No specific treatment. Ingestion Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide metal oxide/oxides Extremely flammable aerosol. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : Flammable aerosol.Remark : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put For non-emergency personnel Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 4/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. : on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50?C. Do not pierce or burn, even after use. Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not swallow. Avoid breathing gas. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits(OSHA United States) Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 5/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Ethylbenzene 100-41-4 ACGIH TLV (United States, 1/2024) A3. Ototoxicant. TWA 8 hours: 20 ppm. NIOSH REL (United States, 10/2020) TWA 10 hours: 100 ppm. TWA 10 hours: 435 mg/m?. STEL 15 minutes: 125 ppm. STEL 15 minutes: 545 mg/m?. OSHA PEL (United States, 5/2018) TWA 8 hours: 100 ppm. TWA 8 hours: 435 mg/m?. Acetone 67-64-1 ACGIH TLV (United States, 1/2024) A4. TWA 8 hours: 250 ppm. STEL 15 minutes: 500 ppm. NIOSH REL (United States, 10/2020) TWA 10 hours: 250 ppm. TWA 10 hours: 590 mg/m?. OSHA PEL (United States, 5/2018) TWA 8 hours: 1000 ppm. TWA 8 hours: 2400 mg/m?. Propane 74-98-6 ACGIH TLV (United States, 1/2024) Oxygen depletion [asphyxiant] , Explosive potential. NIOSH REL (United States, 10/2020) TWA 10 hours: 1000 ppm. TWA 10 hours: 1800 mg/m?. OSHA PEL (United States, 5/2018) TWA 8 hours: 1000 ppm. TWA 8 hours: 1800 mg/m?. Butane 106-97-8 ACGIH TLV (United States, 1/2024) [Butane] Explosive potential. STEL 15 minutes: 1000 ppm. NIOSH REL (United States, 10/2020) TWA 10 hours: 800 ppm. TWA 10 hours: 1900 mg/m?. Aluminum 7429-90-5 ACGIH TLV (United States, 1/2024) [Aluminum, metal and insoluble compounds] A4. TWA 8 hours: 1 mg/m?. Form: Respirable fraction. NIOSH REL (United States, 10/2020) TWA 10 hours: 10 mg/m?. Form: Total. TWA 10 hours: 5 mg/m?. Form: Respirable fraction. OSHA PEL (United States, 5/2018) TWA 8 hours: 15 mg/m? (as Al). Form: Total dust. TWA 8 hours: 5 mg/m? (as Al). Form: Respirable fraction. Stoddard Solvent 8052-41-3 ACGIH TLV (United States, 1/2024) TWA 8 hours: 100 ppm. TWA 8 hours: 525 mg/m?. NIOSH REL (United States, 10/2020) TWA 10 hours: 350 mg/m?. CEIL 15 minutes: 1800 mg/m?. OSHA PEL (United States, 5/2018) Ingredient name Exposure limitsCAS # Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 6/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA 8 hours: 500 ppm. TWA 8 hours: 2900 mg/m?. Toluene 108-88-3 ACGIH TLV (United States, 1/2024) A4. Ototoxicant. TWA 8 hours: 20 ppm. OSHA PEL Z2 (United States, 2/2013) TWA 8 hours: 200 ppm. CEIL: 300 ppm. AMP 10 minutes: 500 ppm. NIOSH REL (United States, 10/2020) TWA 10 hours: 100 ppm. TWA 10 hours: 375 mg/m?. STEL 15 minutes: 150 ppm. STEL 15 minutes: 560 mg/m?. Ethylbenzene 100-41-4 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 125 ppm. TWA 8 hours: 100 ppm. CA British Columbia Provincial (Canada, 9/2024) Carc 2B. TWA 8 hours: 20 ppm. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 20 ppm. CA Quebec Provincial (Canada, 2/2024) C3. TWAEV 8 hours: 20 ppm. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 100 ppm. OEL 8 hours: 434 mg/m?. OEL 15 minutes: 543 mg/m?. OEL 15 minutes: 125 ppm. acetone 67-64-1 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 750 ppm. TWA 8 hours: 500 ppm. CA British Columbia Provincial (Canada, 9/2024) TWA 8 hours: 250 ppm. STEL 15 minutes: 500 ppm. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 250 ppm. STEL 15 minutes: 500 ppm. CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 250 ppm. STEV 15 minutes: 500 ppm. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 1200 mg/m?. OEL 15 minutes: 1800 mg/m?. OEL 8 hours: 500 ppm. OEL 15 minutes: 750 ppm. Normal propane 74-98-6 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 1250 ppm. Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 7/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA 8 hours: 1000 ppm. CA British Columbia Provincial (Canada, 9/2024) Oxygen depletion [asphyxiant] , Explosive potential. CA Ontario Provincial (Canada, 6/2019) Oxygen depletion [asphyxiant] , Explosive potential. CA Quebec Provincial (Canada, 2/2024) Oxygen depletion [asphyxiant] , Explosive potential. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 1000 ppm. Butane 106-97-8 CA Saskatchewan Provincial (Canada, 4/2021) [Aliphatic hydrocarbon gases, Alkane [C1-C4]] STEL 15 minutes: 1250 ppm. TWA 8 hours: 1000 ppm. CA Saskatchewan Provincial (Canada, 4/2021) [Butane] STEL 15 minutes: 1250 ppm. TWA 8 hours: 1000 ppm. CA British Columbia Provincial (Canada, 9/2024) [butane, all isomers] Explosive potential. STEL 15 minutes: 1000 ppm. CA Ontario Provincial (Canada, 6/2019) [Butane, All isomers] Explosive potential. STEL 15 minutes: 1000 ppm. CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 800 ppm. TWAEV 8 hours: 1900 mg/m?. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 1000 ppm. Stoddard solvent 8052-41-3 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 125 ppm. TWA 8 hours: 100 ppm. CA British Columbia Provincial (Canada, 9/2024) TWA 8 hours: 290 mg/m?. STEL 15 minutes: 580 mg/m?. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 100 ppm. CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 100 ppm. TWAEV 8 hours: 525 mg/m?. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 572 mg/m?. OEL 8 hours: 100 ppm. toluene 108-88-3 CA Saskatchewan Provincial (Canada, 4/2021) Absorbed through skin. STEL 15 minutes: 60 ppm. TWA 8 hours: 50 ppm. CA British Columbia Provincial (Canada, 9/2024) Repr. TWA 8 hours: 20 ppm. CA Ontario Provincial (Canada, 6/2019) Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 8/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection TWA 8 hours: 20 ppm. CA Quebec Provincial (Canada, 2/2024) Ototoxicant. TWAEV 8 hours: 20 ppm. CA Alberta Provincial (Canada, 3/2023) Absorbed through skin. OEL 8 hours: 50 ppm. OEL 8 hours: 188 mg/m?. Ethylbenzene 100-41-4 NOM-010-STPS-2014 (Mexico, 4/2016) A3. TWA 8 hours: 20 ppm. Acetone 67-64-1 NOM-010-STPS-2014 (Mexico, 4/2016) A4. TWA 8 hours: 500 ppm. STEL 15 minutes: 750 ppm. Stoddard Solvent 8052-41-3 NOM-010-STPS-2014 (Mexico, 4/2016) TWA 8 hours: 100 ppm. Toluene 108-88-3 NOM-010-STPS-2014 (Mexico, 4/2016) A4. TWA 8 hours: 20 ppm. Ingredient name Exposure limits Occupational exposure limits (Mexico) CAS # Biological exposure indices Ethylbenzene ACGIH BEI (United States, 1/2024) BEI: 150 mg/g creatinine, sum of mandelic acid and phenylglyoxylic acid [in urine]. Sampling time: end of shift. Acetone ACGIH BEI (United States, 1/2024) BEI: 25 mg/l, acetone [in urine]. Sampling time: end of shift. Toluene ACGIH BEI (United States, 1/2024) BEI: 0.03 mg/l, toluene [in urine]. Sampling time: end of shift. BEI: 0.3 mg/g creatinine, o-cresol [in urine]. Sampling time: end of shift. BEI: 0.02 mg/l, toluene [in blood]. Sampling time: prior to last shift of workweek. Ingredient name Exposure indices Biological exposure indices (Canada) Biological exposure indices (Mexico) No exposure indices known. Ethylbenzene Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 0.7 g/g creatinine [non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.; semi-quantitative.The biological determinant is an indicator of chemical exposure, but the Ingredient name Exposure indices (United States) Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 9/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection quantitative interpretation of the measure is ambiguous. These biological determinants should be used as a screening test if a quantitative test is not possible.], Sum of mandelic acid and acid phenylglyoxylic [in urine]. Sampling time: at the end of the shift at the end of the work week. BEI: semi-quantitative.The biological determinant is an indicator of chemical exposure, but the quantitative interpretation of the measure is ambiguous. These biological determinants should be used as a screening test if a quantitative test is not possible., ethylbenzene [in exhaled air]. Sampling time: uncritical. Acetone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 50 mg/L [non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], acetone [in urine]. Sampling time: at the end of the work shift. Toluene Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 0.05 mg/L, toluene [in blood]. Sampling time: sample time not specified. BEI: 1.6 g/g creatinine [Basal level.The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu; non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], hippuric acid [in urine]. Sampling time: at the end of the work shift. BEI: 0.5 mg/L [Basal level.The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu], o-cresol [in urine]. Sampling time: at the end of the work shift. Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 10/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Environmental exposure controls : Section 9. Physical and chemical properties Physical state Melting point/freezing point Liquid. Not available. Not available.Odor pH Silver.Color 7 Not available.Odor threshold : : : : : : Appearance : Not available.Boiling point or initial boiling point and boiling range The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 11/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 9. Physical and chemical properties Vapor pressure Relative density 0.74 1.55 [Air = 1] Evaporation rate 5.6 (butyl acetate = 1) Auto-ignition temperature Flash point Not available. Closed cup: -29?C (-20.2?F) [Pensky-Martens Closed Cup] Not applicable. Viscosity Dynamic (room temperature): Not available. Kinematic (room temperature): Not available. Kinematic (40?C (104?F)): <20.5 mm2/s (<20.5 cSt) Partition coefficient: n- octanol/water : : : : : : : : : Flammable aerosol. : Lower: 0.8% Upper: 12.8% Decomposition temperature : Not available. Type of aerosol : Spray Heat of combustion : 28.286 kJ/g : Not applicable. Flammability Lower and upper explosion limit/flammability limit Relative vapor density 101.3 kPa (760 mm Hg) Solubility(ies) : Media Result cold water Not soluble Density : 0.74 g/cm? Particle characteristics Median particle size : Not applicable. Aerosol product Molecular weight Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 12/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 11. Toxicological information Acute toxicity Information on toxicological effects Ethylbenzene Rat - Oral - LD50 3500 mg/kg Toxic effects: Liver - Other changes Kidney, Ureter, and Bladder - Other changes Rabbit - Dermal - LD50 >5000 mg/kg Acetone Rat - Oral - LD50 5800 mg/kg Toxic effects: Behavioral - Altered sleep time (including change in righting reflex) Behavioral - Tremor Butane Rat - Inhalation - LC50 Vapor 658000 mg/m? [4 hours] Toluene Rat - Oral - LD50 636 mg/kg Rat - Inhalation - LC50 Vapor 49 g/m? [4 hours] Product/ingredient name Result Conclusion/Summary [Product] : Not available. Skin corrosion/irritation Ethylbenzene Rabbit - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 15 mg Acetone Rabbit - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 500 mg Rabbit - Skin - Mild irritant Amount/concentration applied: 395 mg Toluene Pig - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 250 uL Rabbit - Skin - Mild irritant Amount/concentration applied: 435 mg Rabbit - Skin - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 20 mg Rabbit - Skin - Moderate irritant Amount/concentration applied: 500 mg Product/ingredient name Result Conclusion/Summary [Product] : Not available. Serious eye damage/eye irritation Product/ingredient name Result Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 13/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 11. Toxicological information Not available.Conclusion/Summary [Product] Ethylbenzene Rabbit - Eyes - Severe irritant Amount/concentration applied: 500 mg Acetone Human - Eyes - Mild irritant Amount/concentration applied: 186300 ppm Rabbit - Eyes - Mild irritant Amount/concentration applied: 10 uL Rabbit - Eyes - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 20 mg Rabbit - Eyes - Severe irritant Amount/concentration applied: 20 mg Stoddard Solvent Human - Eyes - Mild irritant Amount/concentration applied: 100 ppm Rabbit - Eyes - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 500 mg Toluene Rabbit - Eyes - Mild irritant Duration of treatment/exposure: 0.5 minutes Amount/concentration applied: 100 mg Rabbit - Eyes - Mild irritant Amount/concentration applied: 870 ug Rabbit - Eyes - Severe irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 2 mg Rabbit - Eyes - Severe irritant Amount/concentration applied: 0.1 Ml : : Not available.Conclusion/Summary [Product] Respiratory corrosion/irritation Not available. Respiratory or skin sensitization Not available. Skin : Not available. Respiratory : Not available. Conclusion/Summary [Product] Conclusion/Summary [Product] Germ cell mutagenicity Not available. : Not available.Conclusion/Summary [Product] Carcinogenicity Not available. Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 14/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 11. Toxicological information Classification Ethylbenzene - 2B - Toluene - 3 - Product/ingredient name NTPIARCOSHA : Not available.Conclusion/Summary [Product] Reproductive toxicity : Not available. Not available. Conclusion/Summary [Product] Specific target organ toxicity (single exposure) Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression. May be fatal if swallowed and enters airways. :Ingestion Skin contact : No known significant effects or critical hazards. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Potential acute health effects Specific target organ toxicity (repeated exposure) Ethylbenzene SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Acetone SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Stoddard Solvent SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Toluene SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Product/ingredient name Result Product/ingredient name Result Ethylbenzene SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Toluene SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Aspiration hazard Product/ingredient name Result Ethylbenzene ASPIRATION HAZARD - Category 1 Stoddard Solvent ASPIRATION HAZARD - Category 1 Toluene ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Not available. Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 15/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 11. Toxicological information Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: nausea or vomiting reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure Potential immediate effects : Not available. Short term exposure Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. May cause damage to organs through prolonged or repeated exposure.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : May damage fertility or the unborn child.Reproductive toxicity : Numerical measures of toxicity Acute toxicity estimates Not available. Potential chronic health effects Conclusion/Summary [Product] : Not available. Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 16/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 11. Toxicological information Product/ingredient name DUPLI-COLOR? Acrylic Enamel Aerosol Paint 9332.4 N/A N/A 29.3 N/A Ethylbenzene 3500 N/A N/A 11 N/A Acetone 5800 N/A N/A N/A N/A Butane N/A N/A N/A 658 N/A Toluene N/A N/A N/A 49 N/A Oral (mg/ kg) Dermal (mg/kg) Inhalation (gases) (ppm) Inhalation (vapors) (mg/l) Inhalation (dusts and mists) (mg/l) Section 12. Ecological information Toxicity Ethylbenzene Acute - LC50 - Fresh water Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss 4200 ?g/l [96 hours] Effect: Mortality Acute - EC50 - Fresh water Daphnia - Water flea - Daphnia magna - Neonate Age: ?24 hours 2.93 mg/l [48 hours] Effect: Intoxication Acute - EC50 - Fresh water Algae - Green algae - Raphidocelis subcapitata 3600 ?g/l [96 hours] Effect: Population Acetone Acute - EC50 - Fresh water Algae - Green algae - Selenastrum sp. 7200 mg/l [96 hours] Effect: Population Chronic - NOEC - Marine water Algae - Green algae - Ulva pertusa 4.95 mg/l [96 hours] Effect: Reproduction Chronic - NOEC - Fresh water Crustaceans - Daphnia - Daphniidae 0.016 ml/l [21 days] Effect: Population Chronic - NOEC - Marine water Fish - Threespine stickleback - Gasterosteus aculeatus - Larvae Age: 7 days 5 ?g/l [42 days] Effect: Population Acute - LC50 - Marine water ISO Crustaceans - Calanoid copepod - Acartia tonsa - Copepodid 4.42589 ml/l [48 hours] Effect: Mortality Acute - LC50 - Fresh water Fish - Guppy - Poecilia reticulata Age: 4 to 12 months; Size: 2 to 10 cm; Weight: 0.5 to 14 g 5600 ppm [96 hours] Effect: Mortality Aluminum Acute - LC50 - Fresh water Product/ingredient name Result Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 17/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Product/ingredient name Toluene - 90 Low Product/ingredient name Aquatic half-life Photolysis Biodegradability Ethylbenzene - - Readily Acetone - - Readily Toluene - - Readily Persistence and degradability Soil/Water partition coefficient : Not available. Mobility in soil Fish - Rainbow trout,donaldson trout - Oncorhynchus mykiss - Embryo 120 ?g/l [96 hours] Effect: Mortality Chronic - NOEC - Fresh water Aquatic plants - Coontail - Ceratophyllum demersum Weight: 3.5 g 9 mg/l [3 days] Effect: Enzymes Acute - LC50 - Fresh water Daphnia - Water flea - Daphnia magna 38 mg/l [48 hours] Effect: Mortality Toluene Acute - LC50 - Fresh water Fish - Coho salmon,silver salmon - Oncorhynchus kisutch - Fry Weight: 1 g 5500 ?g/l [96 hours] Effect: Mortality Acute - EC50 - Fresh water Daphnia - Water flea - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 6000 ?g/l [48 hours] Effect: Intoxication Chronic - NOEC - Fresh water Daphnia - Water flea - Daphnia magna Age: ?24 hours 1 mg/l [21 days] Effect: Mortality Acute - EC50 - Fresh water Algae - Green algae - Raphidocelis subcapitata 12.5 mg/l [72 hours] Effect: Growth : Not available.Conclusion/Summary [Product] Not available. : Not available.Conclusion/Summary [Product] Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 18/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 12. Ecological information Other adverse effects No known significant effects or critical hazards. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. :Disposal methods Section 14. Transport information AEROSOLS 2.1 - AEROSOLS 2.1 - UN1950 UN1950 - Emergency schedules F-D, S- U DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. TDG Classification UN1950 AEROSOLS 2.1 - No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.13-2.17 (Class 2). Mexico Classification UN1950 AEROSOLS 2.1 - No. - IATA UN1950 AEROSOLS, flammable 2.1 - No. - 126 ERG No. 126 126 ERG No. ERG No. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Dependent upon container size, this product may ship under the Limited Quantity shipping exception. Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 19/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. : Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information U.S. Federal regulations : WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Montreal Protocol Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Section 16. Other information Hazardous Material Information System (U.S.A.) 3 4 3 *Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. Procedure used to derive the classification Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 20/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US Section 16. Other information 7/30/2025 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 7/30/2025 6/4/2025 23.01 AEROSOLS - Category 1 On basis of test data SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 1B Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Calculation method ASPIRATION HAZARD - Category 1 Calculation method Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision : 7/30/2025 Date of previous issue : 6/4/2025 Version : 23.01 21/21 DA1684 DUPLI-COLOR? Acrylic Enamel Aerosol Paint Chrome Aluminum SHW-85-NA-GHS-US
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