Dupli-Color? Paint Shop? Finish System Jet Black Not available. Liquid. (216) 566-2917 SAFETY DATA SHEET Product name Other means of identification Product type Emergency telephone number of the company Section 1. Identification : : : : Manufacturer : Dupli-Color Products Company 101 W. Prospect Avenue Cleveland, OH 44115 Relevant identified uses of the substance or mixture and uses advised against Paint or paint related material. BSP200 BSP200Product code : Product Information Telephone Number : (800) 247-3270 Transportation Emergency Telephone Number : (800) 424-9300 Section 2. Hazards identification FLAMMABLE LIQUIDS - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A CARCINOGENICITY - Category 2 TOXIC TO REPRODUCTION - Category 1B SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Classification of the substance or mixture : Signal word : Danger Hazard pictograms : Precautionary statements GHS label elements Percentage of the mixture consisting of ingredient(s) of unknown acute toxicity: 7% (dermal), 37.6% (inhalation) General : Keep out of reach of children. If medical advice is needed, have product container or label at hand. OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Highly flammable liquid and vapor. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of causing cancer. May damage fertility or the unborn child. :Hazard statements Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 1/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 2. Hazards identification Prevention : Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing and eye or face protection. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use only outdoors or in a well-ventilated area. Avoid breathing vapor. Wash thoroughly after handling. Response : IF exposed or concerned: Get medical advice or attention. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor if you feel unwell. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice or attention. Storage : Store locked up. Store in a well-ventilated place. Keep container tightly closed. Disposal Dispose of contents and container in accordance with all local, regional, national and international regulations. Hazards not otherwise classified : None known. Please refer to the SDS for additional information. Keep out of reach of children. Do not transfer contents to other containers for storage. Supplemental label elements DELAYED EFFECTS FROM LONG TERM OVEREXPOSURE. Contains solvents which can cause permanent brain and nervous system damage. Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal. WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. : Hazards identified when used : No known significant effects or critical hazards. Section 3. Composition/information on ingredients Acetone ?25 - ?50 67-64-1 Dimethyl Carbonate ?25 - ?50 616-38-6 Ethyl 3-Ethoxypropionate ?10 763-69-9 2-methoxy-1-methylethyl acetate ?3 108-65-6 Carbon Black ?3 1333-86-4 Toluene ?0.3 108-88-3 Ingredient name Identifiers% by weight Other means of identification : Not available. Substance/mixture CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified and hence require reporting in this section. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention. Section 4. First aid measures Eye contact : Description of necessary first aid measures Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 2/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 4. First aid measures Wash out mouth with water. Remove dentures if any. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 10 minutes. Get medical attention. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention. If necessary, call a poison center or physician. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Skin contact Inhalation Ingestion : : : Most important symptoms/effects, acute and delayed Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression.:Ingestion Skin contact : No known significant effects or critical hazards. Causes serious eye irritation.:Eye contact Over-exposure signs/symptoms Skin contact Ingestion Inhalation Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Potential acute health effects Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 3/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 4. First aid measures Protection of first-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours. Specific treatments : No specific treatment. See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide nitrogen oxides Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use dry chemical, CO?, water spray (fog) or foam. Extinguishing media : : : Flammable liquid.Remark : Do not use water jet. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Environmental precautions Personal precautions, protective equipment and emergency procedures : : No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). For non-emergency personnel For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 4/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 6. Accidental release measures Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations. Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Absorb with an inert material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store in a segregated and approved area. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Separate from oxidizing materials. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use appropriate containment to avoid environmental contamination. See Section 10 for incompatible materials before handling or use. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Avoid exposure - obtain special instructions before use. Avoid exposure during pregnancy. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not ingest. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Do not enter storage areas and confined spaces unless adequately ventilated. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Take precautionary measures against electrostatic discharges. Empty containers retain product residue and can be hazardous. Do not reuse container. : Precautions for safe handling Section 8. Exposure controls/personal protection Control parameters Occupational exposure limits(OSHA United States) Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 5/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Acetone 67-64-1 ACGIH TLV (United States, 1/2024) A4. TWA 8 hours: 250 ppm. STEL 15 minutes: 500 ppm. NIOSH REL (United States, 10/2020) TWA 10 hours: 250 ppm. TWA 10 hours: 590 mg/m?. OSHA PEL (United States, 5/2018) TWA 8 hours: 1000 ppm. TWA 8 hours: 2400 mg/m?. Dimethyl Carbonate 616-38-6 None. Ethyl 3-Ethoxypropionate 763-69-9 None. 2-methoxy-1-methylethyl acetate 108-65-6 OARS WEEL (United States, 9/2024) TWA 8 hours: 50 ppm. Carbon Black 1333-86-4 ACGIH TLV (United States, 1/2024) A3. TWA 8 hours: 3 mg/m?. Form: Inhalable fraction. NIOSH REL (United States, 10/2020) NIA. TWA 10 hours: 3.5 mg/m?. TWA 10 hours: 0.1 mg/m? (as cyclohexane- extractable fraction). OSHA PEL (United States, 5/2018) TWA 8 hours: 3.5 mg/m?. Toluene 108-88-3 ACGIH TLV (United States, 1/2024) A4. Ototoxicant. TWA 8 hours: 20 ppm. OSHA PEL Z2 (United States, 2/2013) TWA 8 hours: 200 ppm. CEIL: 300 ppm. AMP 10 minutes: 500 ppm. NIOSH REL (United States, 10/2020) TWA 10 hours: 100 ppm. TWA 10 hours: 375 mg/m?. STEL 15 minutes: 150 ppm. STEL 15 minutes: 560 mg/m?. Ingredient name Exposure limits acetone 67-64-1 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 750 ppm. TWA 8 hours: 500 ppm. CA British Columbia Provincial (Canada, 9/2024) TWA 8 hours: 250 ppm. STEL 15 minutes: 500 ppm. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 250 ppm. STEL 15 minutes: 500 ppm. CA Quebec Provincial (Canada, 2/2024) TWAEV 8 hours: 250 ppm. STEV 15 minutes: 500 ppm. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 1200 mg/m?. OEL 15 minutes: 1800 mg/m?. OEL 8 hours: 500 ppm. Ingredient name Exposure limits Occupational exposure limits (Canada) CAS # CAS # Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 6/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection OEL 15 minutes: 750 ppm. Carbon black 1333-86-4 CA Saskatchewan Provincial (Canada, 4/2021) STEL 15 minutes: 7 mg/m?. TWA 8 hours: 3.5 mg/m?. CA British Columbia Provincial (Canada, 9/2024) Carc 2B. TWA 8 hours: 3 mg/m?. Form: Inhalable. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 3 mg/m?. Form: Inhalable particulate matter.. CA Quebec Provincial (Canada, 2/2024) C3. TWAEV 8 hours: 3 mg/m?. Form: inhalable aerosol fraction. CA Alberta Provincial (Canada, 3/2023) OEL 8 hours: 3.5 mg/m?. toluene 108-88-3 CA Saskatchewan Provincial (Canada, 4/2021) Absorbed through skin. STEL 15 minutes: 60 ppm. TWA 8 hours: 50 ppm. CA British Columbia Provincial (Canada, 9/2024) Repr. TWA 8 hours: 20 ppm. CA Ontario Provincial (Canada, 6/2019) TWA 8 hours: 20 ppm. CA Quebec Provincial (Canada, 2/2024) Ototoxicant. TWAEV 8 hours: 20 ppm. CA Alberta Provincial (Canada, 3/2023) Absorbed through skin. OEL 8 hours: 50 ppm. OEL 8 hours: 188 mg/m?. Acetone 67-64-1 NOM-010-STPS-2014 (Mexico, 4/2016) A4. TWA 8 hours: 500 ppm. STEL 15 minutes: 750 ppm. Toluene 108-88-3 NOM-010-STPS-2014 (Mexico, 4/2016) A4. TWA 8 hours: 20 ppm. Ingredient name Exposure limits Occupational exposure limits (Mexico) CAS # Biological exposure indices Acetone ACGIH BEI (United States, 1/2024) BEI: 25 mg/l, acetone [in urine]. Sampling time: end of shift. Toluene ACGIH BEI (United States, 1/2024) BEI: 0.03 mg/l, toluene [in urine]. Sampling time: end of shift. BEI: 0.3 mg/g creatinine, o-cresol [in urine]. Sampling time: end of shift. BEI: 0.02 mg/l, toluene [in blood]. Sampling time: prior to last shift of workweek. Ingredient name Exposure indices (United States) Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 7/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Individual protection measures Environmental exposure controls : Biological exposure indices (Canada) Biological exposure indices (Mexico) No exposure indices known. Acetone Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 50 mg/L [non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], acetone [in urine]. Sampling time: at the end of the work shift. Toluene Official Mexican STANDARD NOM- 047-SSA1-2011, Environmental Health- Biological exposure indices for personnel occupationally exposed to chemical substances. (Mexico, 6/2012) BEI: 0.05 mg/L, toluene [in blood]. Sampling time: sample time not specified. BEI: 1.6 g/g creatinine [Basal level.The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu; non-specific.The determinant is nonspecific, since it can be found after exposure to other chemicals.], hippuric acid [in urine]. Sampling time: at the end of the work shift. BEI: 0.5 mg/L [Basal level.The determinant may be present in the biological sample obtained from subjects who have not been occupationally exposed, at a concentration that could affect the interpretation of the results. These background levels are included in the valu], o-cresol [in urine]. Sampling time: at the end of the work shift. Ingredient name Exposure indices Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 8/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 8. Exposure controls/personal protection Hand protection Based on the hazard and potential for exposure, select a respirator that meets the appropriate standard or certification. Respirators must be used according to a respiratory protection program to ensure proper fitting, training, and other important aspects of use. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles. Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Skin protection Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point/freezing point Vapor pressure Relative density Liquid. Not available. 0.93 2 [Air = 1] Not available.Odor pH Black.Color Evaporation rate 5.6 (butyl acetate = 1) Flash point Closed cup: -9?C (15.8?F) [Pensky-Martens Closed Cup] Not applicable. Not available.Odor threshold : : : : : : : : : : : Appearance : 55?C (131?F) : Flammable liquid. : Lower: 1.05% Upper: 13.1% Boiling point or initial boiling point and boiling range Flammability Lower and upper explosion limit/flammability limit Relative vapor density The conditions of measurement of all properties are at standard temperature and pressure unless otherwise indicated. 24 kPa (180 mm Hg) Density : 0.92 g/cm? Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 9/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 9. Physical and chemical properties Auto-ignition temperature Not available. Not applicable. Viscosity Dynamic (room temperature): Not available. Kinematic (room temperature): Not available. Kinematic (40?C (104?F)): >20.5 mm2/s (>20.5 cSt) Partition coefficient: n- octanol/water : : : Decomposition temperature : Not available. Heat of combustion : 28.595 kJ/g : Not applicable. Solubility(ies) : Media Result cold water Not soluble Particle characteristics Median particle size : Not applicable. Molecular weight Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld, braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not allow vapor to accumulate in low or confined areas. Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability Reactive or incompatible with the following materials: oxidizing materials : : : Incompatible materials : Possibility of hazardous reactions : Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity : No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Information on toxicological effects Acetone Rat - Oral - LD50 5800 mg/kg Toxic effects: Behavioral - Altered sleep time (including change in righting reflex) Behavioral - Tremor Dimethyl Carbonate Rat - Oral - LD50 13 g/kg Rabbit - Dermal - LD50 >5 g/kg Ethyl 3-Ethoxypropionate Rat - Oral - LD50 3200 mg/kg Toxic effects: Behavioral - Ataxia 2-methoxy-1-methylethyl acetate Rat - Oral - LD50 Product/ingredient name Result Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 10/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 11. Toxicological information 8532 mg/kg Rabbit - Dermal - LD50 >5 g/kg Carbon Black Rat - Oral - LD50 >15400 mg/kg Toxic effects: Behavioral - Somnolence (general depressed activity) Toluene Rat - Oral - LD50 636 mg/kg Rat - Inhalation - LC50 Vapor 49 g/m? [4 hours] Conclusion/Summary [Product] : Not available. Skin corrosion/irritation Acetone Rabbit - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 500 mg Rabbit - Skin - Mild irritant Amount/concentration applied: 395 mg Ethyl 3-Ethoxypropionate Rabbit - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 500 mg Toluene Pig - Skin - Mild irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 250 uL Rabbit - Skin - Mild irritant Amount/concentration applied: 435 mg Rabbit - Skin - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 20 mg Rabbit - Skin - Moderate irritant Amount/concentration applied: 500 mg Product/ingredient name Result Conclusion/Summary [Product] : Not available. Serious eye damage/eye irritation Acetone Human - Eyes - Mild irritant Amount/concentration applied: 186300 ppm Rabbit - Eyes - Mild irritant Amount/concentration applied: 10 uL Rabbit - Eyes - Moderate irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 20 mg Rabbit - Eyes - Severe irritant Amount/concentration applied: 20 mg Toluene Rabbit - Eyes - Mild irritant Duration of treatment/exposure: 0.5 minutes Amount/concentration applied: 100 mg Rabbit - Eyes - Mild irritant Amount/concentration applied: 870 ug Product/ingredient name Result Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 11/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 11. Toxicological information Not available.Conclusion/Summary [Product] Rabbit - Eyes - Severe irritant Duration of treatment/exposure: 24 hours Amount/concentration applied: 2 mg Rabbit - Eyes - Severe irritant Amount/concentration applied: 0.1 Ml : : Not available.Conclusion/Summary [Product] Respiratory corrosion/irritation Not available. Respiratory or skin sensitization Not available. Classification Carbon Black - 2B - Toluene - 3 - Product/ingredient name NTPIARCOSHA Skin : Not available. Respiratory : Not available. Conclusion/Summary [Product] Conclusion/Summary [Product] Germ cell mutagenicity Not available. : Not available.Conclusion/Summary [Product] Carcinogenicity Not available. : Not available.Conclusion/Summary [Product] Reproductive toxicity : Not available. Not available. Conclusion/Summary [Product] Specific target organ toxicity (single exposure) Product/ingredient name Result Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 12/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 11. Toxicological information Inhalation : Can cause central nervous system (CNS) depression. May cause drowsiness or dizziness. Can cause central nervous system (CNS) depression.:Ingestion Skin contact : No known significant effects or critical hazards. Causes serious eye irritation.:Eye contact Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: nausea or vomiting headache drowsiness/fatigue dizziness/vertigo unconsciousness reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations Adverse symptoms may include the following: reduced fetal weight increase in fetal deaths skeletal malformations : : : Eye contact : Adverse symptoms may include the following: pain or irritation watering redness Delayed and immediate effects and also chronic effects from short and long term exposure Potential acute health effects Short term exposure Specific target organ toxicity (repeated exposure) Acetone SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 2-methoxy-1-methylethyl acetate SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Toluene SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Product/ingredient name Result Toluene SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 Aspiration hazard Product/ingredient name Result Toluene ASPIRATION HAZARD - Category 1 Information on the likely routes of exposure Not available. Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 13/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 11. Toxicological information Potential immediate effects : Not available. Potential delayed effects : Not available. Potential immediate effects : Not available. Long term exposure Potential delayed effects : Not available. No known significant effects or critical hazards.General : Suspected of causing cancer. Risk of cancer depends on duration and level of exposure. Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : May damage fertility or the unborn child.Reproductive toxicity : Numerical measures of toxicity Acute toxicity estimates Product/ingredient name Dupli-Color? Paint Shop? Finish System 45742.2 N/A N/A N/A N/A Acetone 5800 N/A N/A N/A N/A Dimethyl Carbonate 13000 N/A N/A N/A N/A Ethyl 3-Ethoxypropionate 3200 N/A N/A N/A N/A 2-methoxy-1-methylethyl acetate 8532 N/A N/A N/A N/A Toluene N/A N/A N/A 49 N/A Oral (mg/ kg) Dermal (mg/kg) Inhalation (gases) (ppm) Inhalation (vapors) (mg/l) Inhalation (dusts and mists) (mg/l) Not available. Potential chronic health effects Conclusion/Summary [Product] : Not available. Section 12. Ecological information Toxicity Acetone Acute - EC50 - Fresh water Algae - Green algae - Selenastrum sp. 7200 mg/l [96 hours] Effect: Population Chronic - NOEC - Marine water Algae - Green algae - Ulva pertusa 4.95 mg/l [96 hours] Effect: Reproduction Chronic - NOEC - Fresh water Crustaceans - Daphnia - Daphniidae 0.016 ml/l [21 days] Effect: Population Chronic - NOEC - Marine water Fish - Threespine stickleback - Gasterosteus aculeatus - Larvae Age: 7 days 5 ?g/l [42 days] Product/ingredient name Result Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 14/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects Product/ingredient name Toluene - 90 Low Product/ingredient name Aquatic half-life Photolysis Biodegradability Acetone - - Readily Toluene - - Readily Persistence and degradability Soil/Water partition coefficient : Not available. Mobility in soil Effect: Population Acute - LC50 - Marine water ISO Crustaceans - Calanoid copepod - Acartia tonsa - Copepodid 4.42589 ml/l [48 hours] Effect: Mortality Acute - LC50 - Fresh water Fish - Guppy - Poecilia reticulata Age: 4 to 12 months; Size: 2 to 10 cm; Weight: 0.5 to 14 g 5600 ppm [96 hours] Effect: Mortality Toluene Acute - LC50 - Fresh water Fish - Coho salmon,silver salmon - Oncorhynchus kisutch - Fry Weight: 1 g 5500 ?g/l [96 hours] Effect: Mortality Acute - EC50 - Fresh water Daphnia - Water flea - Daphnia magna - Juvenile (Fledgling, Hatchling, Weanling) 6000 ?g/l [48 hours] Effect: Intoxication Chronic - NOEC - Fresh water Daphnia - Water flea - Daphnia magna Age: ?24 hours 1 mg/l [21 days] Effect: Mortality Acute - EC50 - Fresh water Algae - Green algae - Raphidocelis subcapitata 12.5 mg/l [72 hours] Effect: Growth : Not available.Conclusion/Summary [Product] Not available. : Not available.Conclusion/Summary [Product] Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 15/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 12. Ecological information No known significant effects or critical hazards. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly flammable or explosive atmosphere inside the container. Do not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. :Disposal methods Section 14. Transport information PAINT 3 II PAINT 3 II UN1263 UN1263 - Emergency schedules F-E, S- E DOT Classification IMDG UN number UN proper shipping name Transport hazard class(es) Packing group Additional information Environmental hazards No. No. TDG Classification UN1263 PAINT 3 II No. Product classified as per the following sections of the Transportation of Dangerous Goods Regulations: 2.18-2.19 (Class 3). Mexico Classification UN1263 PAINT 3 II No. - IATA UN1263 PAINT 3 II No. - 128 ERG No. 128 128 ERG No. ERG No. Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 16/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 14. Transport information Special precautions for user Transport in bulk according to IMO instruments Not available. : Proper shipping name : Not available. : Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (sea, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. People loading and unloading dangerous goods must be trained on all of the risks deriving from the substances and on all actions in case of emergency situations. Section 15. Regulatory information U.S. Federal regulations : WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm. California Prop. 65 Australia inventory (AIIC): Not determined. China inventory (IECSC): Not determined. Japan inventory (CSCL): Not determined. Japan inventory (ISHL): Not determined. Korea inventory (KECI): Not determined. New Zealand Inventory of Chemicals (NZIoC): Not determined. Philippines inventory (PICCS): Not determined. Taiwan Chemical Substances Inventory (TCSI): Not determined. Thailand inventory: Not determined. Turkey inventory: Not determined. Vietnam inventory: Not determined. International regulations International lists : Montreal Protocol Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Section 16. Other information Hazardous Material Information System (U.S.A.) 2 3 0 *Health Flammability Physical hazards Caution: HMIS? ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks. Although HMIS? ratings and the associated label are not required on SDSs or products leaving a facility under 29 CFR 1910.1200, the preparer may choose to provide them. HMIS? ratings are to be used with a fully implemented HMIS? program. HMIS? is a registered trademark and service mark of the American Coatings Association, Inc. The customer is responsible for determining the PPE code for this material. For more information on HMIS? Personal Protective Equipment (PPE) codes, consult the HMIS? Implementation Manual. Procedure used to derive the classification Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 17/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US Section 16. Other information 9/24/2025 History Date of printing Date of issue/Date of revision Version It is recommended that each customer or recipient of this Safety Data Sheet (SDS) study it carefully and consult resources, as necessary or appropriate, to become aware of and understand the data contained in this SDS and any hazards associated with the product. This information is provided in good faith and believed to be accurate as of the effective date herein. However, no warranty, express or implied, is given. The information presented here applies only to the product as shipped. The addition of any material can change the composition, hazards and risks of the product. Products shall not be repackaged, modified, or tinted except as specifically instructed by the manufacturer, including but not limited to the incorporation of products not specified by the manufacturer, or the use or addition of products in proportions not specified by the manufacturer. Regulatory requirements are subject to change and may differ between various locations and jurisdictions. The customer/buyer/user is responsible to ensure that his activities comply with all country, federal, state, provincial or local laws. The conditions for use of the product are not under the control of the manufacturer; the customer/buyer/user is responsible to determine the conditions necessary for the safe use of this product. The customer/buyer/user should not use the product for any purpose other than the purpose shown in the applicable section of this SDS without first referring to the supplier and obtaining written handling instructions. Due to the proliferation of sources for information such as manufacturer-specific SDS, the manufacturer cannot be responsible for SDSs obtained from any other source. Date of previous issue : : : : Indicates information that has changed from previously issued version. Key to abbreviations : 9/24/2025 7/30/2025 23 FLAMMABLE LIQUIDS - Category 2 On basis of test data SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A Calculation method CARCINOGENICITY - Category 2 Calculation method TOXIC TO REPRODUCTION - Category 1B Calculation method SPECIFIC TARGET ORGAN TOXICITY (SINGLE EXPOSURE) (Narcotic effects) - Category 3 Calculation method Classification Justification Notice to reader ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) N/A = Not available SGG = Segregation Group UN = United Nations Date of issue/Date of revision : 9/24/2025 Date of previous issue : 7/30/2025 Version : 23 18/18 BSP200 Dupli-Color? Paint Shop? Finish System Jet Black SHW-85-NA-GHS-US