1FID: 00223834 C H E M I S T R I DATE: 10/22/02 VER DATE: 1997-02-26 MATERIAL SAFETY DATA SHEET TIME: 19:01:44 PAGE: 0001 ------------------------------------------------------------------------ SECTION 01: CHEMICAL PRODUCT & COMPANY ID ------------------------------------------------------------------------ PRODUCT PRIMARY NAME: VEHICLECARE RUST PENETRANT AND INHIBITOR ALL SYNONYMS : AC DELCO RUST PENETRANT AND INHIBITOR CN8239 GENERAL PURPOSE PENETRANT/HVL (FORMER) GOODWRENCH HEAT VALVE LUBRICANT (FORMER) GOODWRENCH RUST PENETRANT AND INHIBITOR HEAT VALVE LUBRICANT LUBRICANT RUST PENETRANT AND INHIBITOR - HEAT VALVE LUBRICANT SA 4772 TPW774 VEHICLECARE RUST PENETRANT AND INHIBITOR V8-97-0013 10-6000 1052627 123123123123 1497770 2622 7005A SP CODE 88900415 SAFE USE CATEGORY AND DESCRIPTION: 04 -METAL WORKING FLUIDS AND LUBRICANTS LAST UPDATED DATE: 1998-03-27 MANUFACTURER'S ID (MID): 000539666 MANUFACTURER'S NAME: GUARDSMAN PRODUCTS INC MANUFACTURER'S EMERGENCY PHONE NUMBER/TEXT: US 231-924-3950 MANUFACTURER'S MAILING ADDRESS: ALSO SEE GMBA #556365 411 N. DARLING FREMONT MI 49412 US ------------------------------------------------------------------------ SECTION 02: COMPOSITION & INGREDIENT INFO ------------------------------------------------------------------------ CAS# FORMULATION W/V CHEMICAL NAME 000108112 < 0.0000/ 5.0000% W 2-PENTANOL, 4-METHYL- 000111762 R 10.0000/ 20.0000% W ETHANOL, 2-BUTOXY- 000544605 R 5.0000/ 15.0000% W 9-OCTADECENOIC ACID (Z)-, AMMONIUM SALT 008030306 R 40.0000/ 50.0000% W BENZIN 068476868 R 5.0000/ 15.0000% W Petroleum gases, liquefied, sweete ned 989946207 < 0.0000/ 1.0000% W NON-HAZARDOUS INGREDIENTS THRESHOLD LIMIT VALUE: ACGIH: 111762: 25 PPM; 8030306: 100 PPM; 108112: 25 PPM; 68476868: 800 PPM. PERMISSIBLE EXPOSURE LIMIT: OSHA: 111762: 25 PPM; 8030306: 100 PPM; 108112: 25 PPM; 68476868: 800 PPM. ------------------------------------------------------------------------ SECTION 03: HAZARDS IDENTIFICATION ------------------------------------------------------------------------ PRIMARY ENTRY ROUTE INDICATORS: SKIN PRIMARY ENTRY ROUTE INDICATOR = Y INHALATION PRIMARY ENTRY ROUTE INDICATOR = Y INGESTION PRIMARY ENTRY ROUTE INDICATOR = N EFFECTS OF OVEREXPOSURE - SKIN: SKIN IRRITATION OR ITCHING. EFFECTS OF OVEREXPOSURE - EYE: EYE IRRITATION, REDNESS, PAIN OR SWELLING. EFFECTS OF OVEREXPOSURE - INHALATION: INHALATION OF VAPORS MAY CAUSE HEADACHE, DIZZINESS, NAUSEA, RESPIRATORY IRRITATION, NASAL DISCOMFORT AND DISCHARGE. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NONE KNOWN ------------------------------------------------------------------------ SECTION 04: FIRST AID MEASURES ------------------------------------------------------------------------ EMERGENCY FIRST AID PROCEDURES - SKIN: REMOVE CONTAMINATED CLOTHING AND SHOES. WASH WITH MILD SOAP AND WATER, APPLY SKIN CREAM FOR IRRITATION. EMERGENCY FIRST AID PROCEDURES - EYES: FLUSH WITH RUNNING WATER FOR 15 MINUTES, HOLDING LID OPEN TO EXPOSE SURFACE. CONTACT PHYSICIAN. EMERGENCY FIRST AID PROCEDURES - INHALATION: REMOVE TO FRESH AIR AT ONCE. APPLY ARTIFICIAL RESPIRATION IF NECESSARY, CONTACT PHYSICIAN IMMEDIATELY. EMERGENCY FIRST AID PROCEDURES - INGESTION: DO NOT INDUCE VOMITING, CONTACT PHYSICIAN IMMEDIATELY. ------------------------------------------------------------------------ SECTION 05: FIRE-FIGHTING MEASURES ------------------------------------------------------------------------ FLAMMABLE LEL: ND 0.00 FLAMMABLE UEL: ND 0.00 EXTINGUISHING MEDIA: FOAM, DRY CHEMICAL, CARBON DIOXIDE. SPECIAL FIRE FIGHTING PROCEDURES: USE SCBA. WATER IS NOT SUITABLE AS AN EXTINGUISHING MEDIA, BUT MAY BE USEFUL FOR COOLING NEARBY CONTAINERS. UNUSUAL FIRE AND EXPLOSION HAZARDS: AEROSOL CONTAINERS MAY BURST WHEN EXPOSED TO TEMPERATURES IN EXCESS OF 120 F. HMIS CODES: HMIS REACTIVITY CODE = 0 HMIS HEALTH CODE = 2 HMIS FLAMMABILITY CODE = 2 NFPA CODES: NFPA FLAMMABILITY CODE = 2 NFPA HEALTH CODE = 2 NFPA REACTIVITY CODE = 0 AUTO-IGNITION TEXT: NOT DETERMINED. FLASH POINT TEMPS: = 135.00F SECTION 5 - OTHER INFORMATION: FLAME EXTENSION: > 12 // FLASHBACK: NO ------------------------------------------------------------------------ SECTION 06: ACCIDENTAL RELEASE MEASURES ------------------------------------------------------------------------ SPILL OR LEAK PROCEDURES: DANGER! LEAKING AEROSOLS ARE AN EXTREME FIRE AND EXPLOSION HAZARD! REMOVE IGNITION SOURCES, MOVE LEAKING CANS OUTDOORS AND EMPTY INTO SUITABLE CONTAINER BY DEPRESSING VALVE BUTTON. ------------------------------------------------------------------------ SECTION 07: HANDLING AND STORAGE ------------------------------------------------------------------------ PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: KEEP CONTAINERS CLOSED WHEN NOT IN USE. DO NOT USE OR STORE NEAR OPENFLAME OR STRONG OXIDIZERS. SECTION 7 - OTHER INFORMATION: AVOID BREATHING VAPORS OR MISTS; PROLONGED OR REPEATED SKIN CONTACT. ------------------------------------------------------------------------ SECTION 08: EXPOSURE CONTROLS - PROTECTION ------------------------------------------------------------------------ EYE PROTECTION: FACE SHIELD OR SAFETY GLASSES RECOMMENDED. RESPIRATORY PROTECTION: NONE REQUIRED IN NORMAL USE. VENTILATION: ADEQUATE TO MAINTAIN LEVEL BELOW ESTABLISHED STANDARDS. LOCAL EXHAUST: YES // RATE: >60 FPM // MECH (GENERAL) NO4 PERSONAL PROTECTIVE EQUIPMENT: NONE REQUIRED IN NORMAL USE. WORKPLACE/HYGIENIC PRACTICES: BASIC GOOD HOUSEKEEPING. WASH HANDS BEFORE EATING OR SMOKING. SMOKE ONLY IN DESIGNATED AREAS. PROTECTIVE GLOVES (SPECIFY TYPE): CHEMICAL RESISTANT. ------------------------------------------------------------------------ SECTION 09: PHYSICAL & CHEMICAL PROPERTIES ------------------------------------------------------------------------ BOILING POINT TEMPS: = 212.00F BOILING POINT TEXT: (INITIAL BOILING POINT) SPECIFIC GRAVITY VALUES: = 0.9200 SPECIFIC GRAVITY TEXT: TYPICAL VAPOR DENSITY TEXT: NOT DETERMINED. VAPOR PRESSURE TEXT: < 1 PERCENT VOLATILE BY WEIGHT TEXT: VOLUME: NOT DETERMINED. SOLUBILITY IN WATER TEXT: WATER SOLUBLE: NO PH OF PRODUCT AS RECEIVED (NEAT)/TEXT: NOT DETERMINED. APPEARANCE: BLACK LIQUID. ODOR: PETROLEUM ODOR. SECTION 9 - OTHER INFORMATION: WATER REACTIVE: NO. ------------------------------------------------------------------------ SECTION 10: STABILITY & REACTIVITY ------------------------------------------------------------------------ STABILITY INDICATOR: Y STABILITY - CONDITIONS TO AVOID: HEAT, SPARKS, OPEN FLAME. INCOMPATIBLE MATERIALS: STRONG OXIDIZERS LIKE CHLORINE OR CONCENTRATED OXYGEN. HAZARDOUS DECOMPOSITION PRODUCTS: VARIOUS OXIDES OF CARBON. HAZARDOUS POLYMERIZATION INDICATOR: N HAZARDOUS POLYMERIZATION - CONDITIONS TO AVOID: NONE KNOWN. ------------------------------------------------------------------------ SECTION 11: TOXICOLOGICAL INFORMATION ------------------------------------------------------------------------ CHRONIC EFFECTS: THIS PRODUCT CONTAINS 2-BUTOXYETHANOL..AVOID CONTACT. ANIMAL STUDIES INDICATE THAT EXPOSURE CAUSES RED BLOOD CELL DAMAGE, AND DAMAGE TO THEKIDNEYS AND LIVER. THESE EFFECTS HAVE NOT BEEN OBSERVED IN HUMANS, HOWEVER, AS A PRECAUTION, EXPOSURE TO LIQUIDS OR VAPORS SHOULD BE MINIMIZED. HEALTH STUDIES HAVE SHOWN THAT MANY CHEMICALS POSE HUMAN HEALTH RISKS WHICH MAY VARY FROM PERSON TO PERSON. PROLONGED OR REPEATED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS HAS BEEN LINKED TO PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. INTENTIONAL MISUSE BY DELIBERATE CONCENTRATION AND INHALATION MAY BE HARMFUL OR FATAL. CARCINOGENICITY: CARCINOGENIC LISTING : NTP: NO; IARC: NO; ACGIH: NO. ------------------------------------------------------------------------ SECTION 13: DISPOSAL CONSIDERATIONS ------------------------------------------------------------------------ WASTE DISPOSAL METHOD: COMPLY WITH ALL APPLICABLE REGULATIONS. ------------------------------------------------------------------------ SECTION 14: TRANSPORT INFORMATION ------------------------------------------------------------------------ DOT INFORMATION: DOT PRECAUTIONARY LABEL: NOT REQUIRED. // PACKING GROUP: NOT ASSIGNED. SHIPPING NAME: CONSUMER COMMODITY HAZARD CLASS: ORM-D SECTION 14 - OTHER INFORMATION: IMO ID NUMBER: UN1950 // IATA ID NUMBER: UN1950 //IMO HAZARD CLASS:2.1// IATA HAZARD CLASS: 2.1 // IMO SHIPPING NAME: AEROSOLS // IATA SHIPPING NAME: AEROSOLS, 30 // IMO PRECAUTIONARY LABEL: AEROSOLS STATEMENT. // IATA P RECAUTIONARY LABEL: FLAMMABLE GAS DIAMOND. // IMO PACKING GROUP: II // IATA PACKING GROUP: NONE ASSIGNED // IMO PAGE NUMBER: 2102 // MARINE POLLUTANT: NO. ------------------------------------------------------------------------ SECTION 15: REGULATORY INFORMATION ------------------------------------------------------------------------ SECTION 15 - OTHER INFORMATION: SARA III - SECTION 313 TOXIC CHEMICAL: 2-BUTOXYETHANOL CAS # 111762 SAFE USE CATEGORY AND DESCRIPTION : --------------------------------- 04 METAL WORKING FLUIDS AND LUBRICANTS REGULATORY IMPACTS(REG) AND ADDITIONAL HEALTH HAZARD STATEMENTS(HHS) : -------------------------------------------------------------------- CAS#: 000108112 2-PENTANOL, 4-METHYL- REG: 0001,0003,0012,0017,0039,0042,0056,0061,0063,0065 CAS#: 000111762 ETHANOL, 2-BUTOXY- REG: 0001,0003,0004,0012,0017,0019,0023,0031,0034,0038,0039,0042 0056,0061,0063,0065,0068,0069,0083,0084,0088 REG BY CATEGORY: 0020,0047,0048,0051,0066,0122 HHS: LONG-TERM OVEREXPOSURE MAY RESULT IN BLOOD DISORDERS. TOXIC EFFECTS CAN OCCUR FROM SKIN CONTACT. CAS#: 000544605 9-OCTADECENOIC ACID (Z)-, AMMONIUM SALT REG: 0012 REG BY CATEGORY: 0047,0088 CAS#: 008030306 BENZIN REG: 0001,0003,0004,0012,0014,0019,0031,0032,0034,0038,0039,0056 0061,0065,0084 REG BY CATEGORY: 0122 HHS: REFER TO THE APPROPRIATE SAFE USE INSTRUCTION FOR HEALTH HAZARD INFORMATION. CAS#: 068476868 Petroleum gases, liquefied, sweetened REG: 0012 REGULATORY KEY LIST: 0001 OSHA-PEL 0003 ACGIH-TLV 0004 GM-SPEC CHEM 0005 SUSP CARCIN 0006 EPA HW261.33 0007 EPA HW-APP 8 0008 MCMR 0009 FWPC-SEC 311 0010 EPA PRIORPOL 0011 NY SUBS CONC 0012 TSCA INV 0014 MI AIR POLLU 0015 SUP TAX CHEM 0016 MI HW-ACT 64 0017 CA HAZ SUBST 0018 NY SAN 22.8 0019 MA SUBST 0020 NJ ENV SUBST 0021 TOX ORGANICS 0022 MD CLASS I 0023 MD CLASS II 0024 EPA-ATC-I 0026 EPA-CHEMCONC 0027 WB VERY TOX 0028 WB OTHER TOX 0031 ALLGHNY CTY 0032 IL-RTK 0033 OSHA-HHCL 0034 FLT CRIT IND 0035 GM-AHC 0036 PRO EP TOX 0037 MO SPECIES 0038 MO-RTK 0039 ONT 654-86 0040 ONT DES SUB 0041 SARA312EXHAZ 0042 WI TABLE 1 0043 WI TABLE 2 0047 SARA 313 0048 CERCLASEC103 0049 P-65 CARCINO 0050 P-65 REP TOX 0051 MD CLSI .11 0052 MD CLSI .12 0053 MD CLSII .12 0054 CT 29-1 0055 CT 29-2 0056 CT 29-3 0058 EPA261.33(F) 0059 CA AIR TOX 1 0060 CA AIR TOX 2 0061 PA RTK 0063 PELS REVISED 0064 NPDES-TOXPOL 0065 NJ W&C RTK 0066 CAA HAZ POL 0067 NV HIGH HAZ. 0068 MI 307-CARC 0069 MI 307-NCARC 0070 MICH AIR 0071 CAA602 CLSI 0075 C 0076 D 0078 GREAT LAKES 0080 METALS 0082 EPA 112(R) 0083 TSCA 8(D)) 0084 GM OEG 0085 TSCA-TEST 0087 TSCA 12(B) 0088 NAT. POLL. REL 0089 NY CHEM BULK 0090 GL PERSIST 0091 LAND DISP. - II 0092 UAW/GM AUDIT 0093 TSCA - SPECIAL 0095 FIFRA REG MAT 0098 DSL - CANADA 0099 NDSL - CANADA 0102 GM 1000M 0103 CAA SEC. 112(R) 0104 CERCLA-HAZWOPER 0105 GLPPP-SPECIFIC 0106 GLPPP-SPECIFIC 0107 PET. DISTILLATE 0109 APPENDIX IX 0110 GLOBAL WARM CMP 0112 RCRA PBT -DRAFT 0113 IARC-GROUP 2B 0115 IARC-GROUP 1 0116 GMW 3059-RESTR. 0117 GMW 3059-REPORT 0118 T.W. REPORT 0121 HEX CHROME, PB, 0122 ACDM-REPORTING 0123 MDEQ PART 5 GMBA/PLANT USING THIS FID: ------------------------- GMBA: 000550678 SPO - DISTRIBUTABLE MATERIALS CISCO: 17001; STATUS :ACTIVE GMBA: 000550772 GMPTG - FLINT V-8 PLANT CISCO: 18192; STATUS :ACTIVE GMBA: 000550797 CLCD - BUICK CITY ASSEMBLY CISCO: 19400; STATUS :ACTIVE GMBA: 000550821 DELPHI E - ADMIN. BUILDING - ANDERSON CISCO: 35001; STATUS :ACTIVE GMBA: 000550897 GMPTG - WILLOW RUN PLANT CISCO: 57001; STATUS :ACTIVE GMBA: 000550957 CHEMICAL RISK MANAGEMENT CISCO: 89150; STATUS :ACTIVE GMBA: 000550960 GM DESERT PROVING GROUND CISCO: 91008; STATUS :ACTIVE GMBA: 000550964 GM TECHNICAL CENTER/ENGINEERING BUILDING CISCO: 94003; STATUS :ACTIVE GMBA: 000550966 GM PROVING GROUND - MILFORD CISCO: 94017; STATUS :ACTIVE GMBA: 000550976 GM TECHNICAL CENTER, TOTAL SITE CISCO: 96003; STATUS :ACTIVE GMBA: 000551424 SERVICE TECHNOLOGY HEADQUARTERS CISCO: 18400; STATUS :ACTIVE GMBA: 000555103 TRUCK PRODUCT CENTER VALIDATION STATUS :INACTIVE GMBA: 000556053 ADVANCED TECHNOLOGY VEHICLES STATUS :ACTIVE GMBA: 000556298 GM TECHNICAL CENTER, TOTAL SITE STATUS :ACTIVE GMBA: 000556705 ENVIRONMENTAL SYSTEMS HELPDESK CISCO: 99004; STATUS :ACTIVE GMBA: 000556732 POWERTRAIN, FLINT ENGINE SOUTH L6 STATUS :ACTIVE GMBA: 000557289 GM TECHNICAL CENTER, R & D CISCO: 99010; STATUS :ACTIVE GMBA: 000557375 SPO - CONTRACT HOUSE CISCO: 99011; STATUS :ACTIVE