ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 04/28/2014 Revision date: 04/28/2014 Version: 1.0 04/28/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : ATC - Air Tool Conditioner (Aerosol) Product code : 8-ATC-S, 16-ATC, ATC-TS 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Cleaner / Coating / Lubricant 1.3. Details of the supplier of the safety data sheet The Blaster Corporation 8500 Sweet Valley Drive 44125 Valley View, Ohio - USA T (216) 901-5800 - F (216) 901-5801 www.blasterproducts.com 1.4. Emergency telephone number Emergency number : Chemtrec (800) 424-9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Aerosol 2 Gases Under Pressure (Dissolved Gas) Skin Irritation 2 Serious eye damage 1 Skin Sensitization 1 Specific target organ toxicity (single exposure) 3 Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Flammable aerosol. Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/fume/gas/mist/vapors/spray. Wash hands thoroughly after handling. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/eye protection/face protection If on skin: Wash with plenty of water. Take off contaminated clothing and wash it before reuse. If skin irritation or rash occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/ doctor. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center/doctor if you feel unwell. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) 15 % of the mixture consists of ingredient(s) of unknown acute toxicity. ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/28/2014 EN (English) 2/7 SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Distillates, petroleum, hydrotreated heavy naphthenic (CAS No) 64742-52-5 50 - 60 Asp. Tox. 1 Petroleum distillates, hydrotreated light (CAS No) 64742-47-8 20 - 30 Flam. Liq. 3 Asp. Tox. 1 Isopropyl alcohol (CAS No) 67-63-0 10 - 20 Flam. Liq. 2 Eye Irrit. 2A STOT SE 3 Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS No) 68649-42-3 1 - 10 Skin Irrit. 2 Eye Dam. 1 Alcohols, C6-10, ethoxylated propoxylated (CAS No) 68987-81-5 1 - 3 Skin Irrit. 2 Eye Dam. 1 Carbon dioxide (CAS No) 124-38-9 1 - 5 Compressed gas N-Phenyl-1-naphthylamine (CAS No) 90-30-2 <0.5 Acute Tox. 4 (Oral) Skin Sens. 1 STOT RE 2 The specific exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. Get medical attention immediately. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Vapours may cause drowsiness and dizziness. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Carbon dioxide, dry chemical, halons, foam. Unsuitable extinguishing media : Do not use a direct stream of water. Product will float and can spread the fire. 5.2. Special hazards arising from the substance or mixture Fire hazard : Flammable aerosol. Products of combustion may include, and are not limited to: oxides of carbon and oxides of nitrogen. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.3. Advice for firefighters Firefighting instructions : Cool closed containers exposed to fire with water. Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/28/2014 EN (English) 3/7 6.1.2. For emergency responders No additional information available 6.2. Methods and material for containment and cleaning up For containment : Eliminate sources of ignition. Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Dike to collect large liquid spills. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Vacuum or sweep material and place in a disposal container. Vapours may be heavier than air and may travel along the ground to a distant ignition source and flash back. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Keep away from sources of ignition. - No smoking. Avoid contact with skin and eyes. Avoid breathing dust/fume/gas/mist/vapours/spray. Do not swallow. When using do not eat, drink or smoke. Do not spray on an open flame or other ignition source. Use only outdoors or in a well- ventilated area. Pressurized container: Do not pierce or burn, even after use. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. Contaminated work clothing should not be allowed out of the workplace. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. Storage conditions : Keep locked up and out of reach of children. Do not expose to temperatures exceeding 50 ?C/ 122 ?F. Store in a cool, dry, well ventilated place away from incompatible materials. Store away from direct sunlight or other heat sources. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? (mist) USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? (mist) Petroleum distillates, hydrotreated light (64742-47-8) USA ACGIH ACGIH TWA (mg/m?) 200 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Isopropyl alcohol (67-63-0) USA ACGIH ACGIH TWA (ppm) 200 ppm USA ACGIH ACGIH STEL (ppm) 400 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 980 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 400 ppm Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Alcohols, C6-10, ethoxylated propoxylated (68987-81-5) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Carbon dioxide (124-38-9) USA ACGIH ACGIH TWA (ppm) 5000 ppm USA ACGIH ACGIH STEL (ppm) 30000 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 9000 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm N-Phenyl-1-naphthylamine (90-30-2) USA ACGIH ACGIH TWA Not applicable. ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/28/2014 EN (English) 4/7 N-Phenyl-1-naphthylamine (90-30-2) USA OSHA OSHA PEL (TWA) Not applicable. 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Use explosion-proof ventilation equipment. Ensure that eyewash stations and safety showers are close to the workstation location. Hand protection : Wear chemically resistant protective gloves. Eye protection : Wear approved eye protection (properly fitted dust- or splash-proof chemical safety goggles) and face protection (face shield). Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas/Pressurized Liquid. Colour : Light red. Odour : No data available. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : No data available. Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable aerosol. Vapour pressure : No data available. Relative vapour density at 20 ?C : No data available. Relative density : No data available. Solubility : Negligible. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information Flame Projection = 0 cm; Heat of Combustion = 44.6 kJ/g. SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. Flammable aerosol. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Sources of ignition. 10.5. Incompatible materials Strong oxidizing agents. ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/28/2014 EN (English) 5/7 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, oxides of nitrogen. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified ATC - Air Tool Conditioner (Aerosol) LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) > 5 mg/l/4h Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat (mg/l) > 5.0 mg/l/4h Petroleum distillates, hydrotreated light (64742-47-8) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) > 5.2 mg/l/4h Isopropyl alcohol (67-63-0) LD50 oral rat 4396 mg/kg LD50 dermal rat 12800 mg/kg LD50 dermal rabbit 12870 mg/kg LC50 inhalation rat (mg/l) 72.6 mg/l/4h N-Phenyl-1-naphthylamine (90-30-2) LD50 oral rat 1625 mg/kg LD50 dermal rabbit > 5000 mg/kg Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye damage. Respiratory or skin sensitisation : May cause an allergic skin reaction. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Isopropyl alcohol (67-63-0) IARC group 3 Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : May cause drowsiness or dizziness. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : Vapours may cause drowsiness and dizziness. May cause respiratory tract irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms may include redness, edema, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : Causes serious eye damage. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. May cause burns. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology ? general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability ATC - Air Tool Conditioner (Aerosol) Persistence and degradability Not established. 12.3. Bioaccumulative potential ATC - Air Tool Conditioner (Aerosol) Bioaccumulative potential Not established. ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/28/2014 EN (English) 6/7 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Flammable vapours may accumulate in the container. Do not incinerate empty containers. Do not cut, weld, drill or grind. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No.(DOT) : UN1950 14.2. UN proper shipping name DOT Proper Shipping Name : AEROSOLS, flammable, limited quantities Hazard class (DOT) : 2.1 Packing Group (DOT) : Not applicable. Hazard labels (DOT) : 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Petroleum distillates, hydrotreated light (64742-47-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Isopropyl alcohol (67-63-0) Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on SARA Section 313 (Specific toxic chemical listings) EPA TSCA Regulatory Flag T - T - indicates a substance that is the subject of a Section 4 test rule under TSCA. SARA Section 313 - Emission Reporting 1.0 % (only if manufactured by the strong acid process, no supplier notification) Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Alcohols, C6-10, ethoxylated propoxylated (68987-81-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Carbon dioxide (124-38-9) Listed on the United States TSCA (Toxic Substances Control Act) inventory N-Phenyl-1-naphthylamine (90-30-2) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. US State regulations ATC - Air Tool Conditioner (Aerosol) State or local regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. ATC - Air Tool Conditioner (Aerosol) Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/28/2014 EN (English) 7/7 SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: IARC International Agency for Research on Cancer. 1 - Carcinogenic to humans; 2A - Probably carcinogenic to humans; 2B - Possibly carcinogenic to humans; 3 - Not classifiable; 4 - Probably not carcinogenic to humans. NTP National Toxicology Program. 1 - Evidence of Carcinogenicity; 2 - Known Human Carcinogens; 3 - Reasonably anticipated to be Human Carcinogen; 4 - Substances delisted from report on Carcinogens; 5 - Twelfth Report - Items under consideration. SECTION 16: Other information Indication of changes : None. Date of issue : 04/28/2014 Other information : None. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product