PB-50 All-Purpose Lubricant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 11/08/2013 Revision date: 11/08/2013 Version: 1.0 11/8/2013 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PB-50 All-Purpose Lubricant Product code : PB-50, PB-50-8, PB-50-3 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Multi-Purpose Lubricant. 1.3. Details of the supplier of the safety data sheet The Blaster Corporation 8500 Sweet Valley Drive Valley View, Ohio 44125 - USA T (216) 901-5800 - F (216) 901-5801 www.blasterproducts.com 1.4. Emergency telephone number Emergency number : CHEMTREC: (800) 424-9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Flammable Aerosol 2 Gases Under Pressure (Dissolved Gas) Acute Toxicity 4 (Inhalation) Aspiration Hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS02 GHS04 GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Flammable aerosol. Contains gas under pressure; may explode if heated. Harmful if inhaled. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor if you feel unwell. If swallowed: immediately call a poison center or doctor/ physician. Do NOT induce vomiting. Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Store in a well-ventilated place. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available. 2.4. Unknown acute toxicity (GHS-US) 2 % of the mixture consists of ingredient(s) of unknown acute toxicity. SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable. 3.2. Mixture Name Product identifier % GHS-US classification Petroleum distillates, hydrotreated light (CAS No) 64742-47-8 40 - 70 Flam. Liq. 3, H226 Asp. Tox. 1, H304 Distillates, petroleum, hydrotreated light naphthenic (CAS No) 64742-53-6 30 - 60 Not classified Carbon dioxide (CAS No) 124-38-9 1 - 5 Compressed gas, H280 The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. PB-50 All-Purpose Lubricant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 11/8/2013 EN (English) 2/5 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : DO NOT induce vomiting. Seek medical attention or call poison control immediately. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : Harmful if inhaled. May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. May cause stomach distress, nausea or vomiting. This product may be aspirated into the lungs and cause chemical pneumonitis. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Treat for surrounding material. Unsuitable extinguishing media : None known. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon, oxides of nitrogen. Flammable aerosol. Explosion hazard : Heat may build pressure, rupturing closed containers, spreading fire and increasing risk of burns and injuries. 5.3. Advice for firefighters Firefighting instructions : Cool closed containers exposed to fire with water. Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.1.2. For emergency responders No additional information available. 6.2. Methods and material for containment and cleaning up For containment : Eliminate sources of ignition. Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Vapours may be heavier than air and may travel along the ground to a distant ignition source and flash back. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with skin and eyes. Do not swallow. Do not breathe gas, fumes, vapour or spray. When using do not eat, drink or smoke. Do not spray on an open flame or other ignition source. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Use only outdoors or in a well-ventilated area. Keep away from sources of ignition - No smoking. Pressurized container: Do not pierce or burn, even after use. Hygiene measures : Wash hands before eating, drinking, or smoking. Launder contaminated clothing before reuse. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Proper grounding procedures to avoid static electricity should be followed. PB-50 All-Purpose Lubricant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 11/8/2013 EN (English) 3/5 Storage conditions : Keep locked up and out of reach of children. Do not expose to temperatures exceeding 50?C/ 122?F. Store away from direct sunlight or other heat sources. Storage area : Store in a well-ventilated place. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Petroleum distillates, hydrotreated light (64742-47-8) USA ACGIH ACGIH TWA (mg/m?) 200 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 100 ppm Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? (mist) USA OSHA OSHA PEL (TWA) (ppm) 5 mg/m? (mist) Carbon dioxide (124-38-9) USA ACGIH ACGIH TWA (ppm) 5000 ppm USA ACGIH ACGIH STEL (ppm) 30000 ppm USA OSHA OSHA PEL (TWA) (mg/m?) 9000 mg/m? USA OSHA OSHA PEL (TWA) (ppm) 5000 ppm 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : A NIOSH approved respirator is recommended in poorly ventilated areas or when permissible exposure limits may be exceeded. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Gas/Pressurized Liquid. Appearance : Clear. Colour : White. Odour : Mild aliphatic. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : >1(NBA=1) Melting point : No data available. Freezing point : No data available. Boiling point : 193 ?C/380 ?F Flash point : 64 ?C/148 ?F (TCC) Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Flammable Aerosol. Vapour pressure : No data available. Relative vapour density at 20 ?C : >1(Air=1) Relative density : 8.2 Solubility : Partial. Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. PB-50 All-Purpose Lubricant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 11/8/2013 EN (English) 4/5 Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information Flame Projection 65 cm (25.6 inches); Heat of Combustion 45.9 kJ/g. SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. Flammable aerosol. Contents under pressure. Container may explode if heated. Do not puncture. Do not burn. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Sources of ignition. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon, oxides of nitrogen. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Harmful if inhaled. Petroleum distillates, hydrotreated light (64742-47-8) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/L) > 5.2 mg/L 4h PB-50 All-Purpose Lubricant ATE (oral) >2000 mg/kg, rat ATE (dermal) >2000 mg/kg, rabbit ATE (inhalation) 3.34 mg/L, rat Skin corrosion/irritation : Based on available data, the classification criteria are not met. Serious eye damage/irritation : Based on available data, the classification criteria are not met. Respiratory or skin sensitisation : Based on available data, the classification criteria are not met. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Reproductive toxicity : Based on available data, the classification criteria are not met. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. Symptoms/injuries after inhalation : Harmful if inhaled. May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. Symptoms/injuries after eye contact : May cause eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. May cause stomach distress, nausea or vomiting. This product may be aspirated into the lungs and cause chemical pneumonitis. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. PB-50 All-Purpose Lubricant Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 11/8/2013 EN (English) 5/5 12.2. Persistence and degradability PB-50 All-Purpose Lubricant Persistence and degradability Not established. 12.3. Bioaccumulative potential PB-50 All-Purpose Lubricant Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available. 12.5. Other adverse effects No additional information available. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. Additional information : Flammable vapours may accumulate in the container. Do not incinerate empty containers. SECTION 14: Transport information In accordance with DOT 14.1. UN number UN-No.(DOT) : UN1950 14.2. UN proper shipping name DOT Proper Shipping Name : AEROSOLS, flammable, limited quantities Hazard class (DOT) 2.1 Packing Group (DOT) Not applicable. Hazard labels (DOT) : 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations Petroleum distillates, hydrotreated light (64742-47-8) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Carbon dioxide (124-38-9) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. US State regulations PB-50 All-Purpose Lubricant State or local regulations This product does not contain a chemical known to the State of California to cause cancer, birth defects or other reproductive harm. SECTION 16: Other information Indication of changes : None. Other information : None. This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product