SAFETY DATA SHEET 1. Identification Product identifier Mass Air Flow Sensor Cleaner Other means of identification Product code 05110, 05610 Recommended use Mass air flow sensor cleaner Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Category 1Flammable aerosolsPhysical hazards Compressed gasGases under pressure Category 2Reproductive toxicity (fertility)Health hazards Category 2Specific target organ toxicity, repeated exposure Category 1Aspiration hazard Category 2Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. May be fatal if swallowed and enters airways. Suspected of damaging fertility. May cause damage to organs (eyes, central nervous system, liver, kidney) through prolonged or repeated exposure. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. 1 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not spray on an open flame or other ignition source. Do not apply while equipment is energized. Pressurized container: Do not pierce or burn, even after use. Extinguish all flames, pilot lights and heaters. Vapors will accumulate readily and may ignite. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not breathe gas. Do not breathe mist or vapor. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Response If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. If exposed or concerned: Get medical attention. Collect spillage. Storage Store in a well-ventilated place. Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50?C/122?F. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information 92.18% of the mixture consists of component(s) of unknown acute hazards to the aquatic environment. 91.98% of the mixture consists of component(s) of unknown long-term hazards to the aquatic environment. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 64742-49-0Naphtha (petroleum), hydrotreated light 80 - 90 124-38-9Carbon dioxide 5 - 10 540-84-12,2,4-Trimethylpentane 3 - 5 110-54-3n-Hexane 3 - 5 67-56-1Methanol < 1 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation If symptoms develop move victim to fresh air. Get medical attention if symptoms persist. Skin contact Rinse skin with water/shower. Get medical attention if irritation develops and persists. Eye contact Rinse with water. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Aspiration may cause pulmonary edema and pneumonitis. Most important symptoms/effects, acute and delayed Prolonged exposure may cause chronic effects. Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. 2 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US Specific hazards arising from the chemical Contents under pressure. Pressurized container may explode when exposed to heat or flame. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. Special protective equipment and precautions for firefighters Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA. Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. General fire hazards Extremely flammable aerosol. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Remove all possible sources of ignition in the surrounding area. Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not breathe gas. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. Stop the flow of material, if this is without risk. Collect spillage. Prevent entry into waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Contact local authorities in case of spillage to drain/aquatic environment. Prevent further leakage or spillage if safe to do so. Do not contaminate water. Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not breathe mist or vapor. Do not breathe gas. Avoid prolonged exposure. Use only in well-ventilated areas. Should be handled in closed systems, if possible. Pregnant or breastfeeding women must not handle this product. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Observe good industrial hygiene practices. Avoid release to the environment. Do not empty into drains. For product usage instructions, please see the product label. Conditions for safe storage, including any incompatibilities Level 3 Aerosol. Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50?C/122 ?F. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. This material can accumulate static charge which may cause spark and become an ignition source. Avoid spark promoters. These alone may be insufficient to remove static electricity. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 2350 mg/m32,2,4-Trimethylpentane (CAS 540-84-1) 500 ppm PEL 9000 mg/m3Carbon dioxide (CAS 124-38-9) 3 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type 5000 ppm PEL 260 mg/m3Methanol (CAS 67-56-1) 200 ppm PEL 1800 mg/m3n-Hexane (CAS 110-54-3) 500 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 30000 ppmCarbon dioxide (CAS 124-38-9) TWA 5000 ppm STEL 250 ppmMethanol (CAS 67-56-1) TWA 200 ppm TWA 50 ppmn-Hexane (CAS 110-54-3) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type Ceiling 1800 mg/m32,2,4-Trimethylpentane (CAS 540-84-1) 385 ppm TWA 350 mg/m3 75 ppm STEL 54000 mg/m3Carbon dioxide (CAS 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm STEL 325 mg/m3Methanol (CAS 67-56-1) 250 ppm TWA 260 mg/m3 200 ppm TWA 180 mg/m3n-Hexane (CAS 110-54-3) 50 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 15 mg/l Methanol Urine *Methanol (CAS 67-56-1) 0.4 mg/l 2,5-Hexanedio n, without hydrolysis Urine *n-Hexane (CAS 110-54-3) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Methanol (CAS 67-56-1) Skin designation applies. US - Tennesse OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. 4 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US Appropriate engineering controls Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Nitrile. Polyvinyl chloride (PVC). Viton?. Other Wear appropriate chemical resistant clothing. Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Aerosol. Color Clear. Colorless. Odor Not available. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling range 123 ?F (50.6 ?C) estimated Flash point < 0 ?F (< -17.8 ?C) Tag Closed Cup Evaporation rate Very fast. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) 0.9 % estimated Flammability limit - upper (%) 36 % estimated Vapor pressure 3201.5 hPa estimated Vapor density > 1 (air = 1) Relative density 0.7 estimated Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 489.2 ?F (254 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 95 % estimated 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Heat, flames and sparks. Contact with incompatible materials. 5 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US Incompatible materials Strong oxidizing agents. Hazardous decomposition products Carbon oxides. 11. Toxicological information Information on likely routes of exposure Ingestion May be fatal if swallowed and enters airways. Inhalation Prolonged inhalation may be harmful. May cause damage to organs through prolonged or repeated exposure by inhalation. Skin contact Prolonged skin contact may cause temporary irritation. Eye contact Direct contact with eyes may cause temporary irritation. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Test ResultsProduct Species Mass Air Flow Sensor Cleaner LD50 Rabbit Dermal Acute 2037.8894 mg/kg estimated LC50 Rat Inhalation 1527.8224 mg/l, 4 Hours estimated LD50 Rat 68313.3516 mg/m3, 4 hours estimated LD50 Human Oral 6193.4844 mg/kg estimated Rat 16418.0957 mg/kg estimated LDL0 Human 37160.9063 mg/kg estimated * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye irritation Direct contact with eyes may cause temporary irritation. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. Reproductive toxicity Suspected of damaging fertility. Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure May cause damage to organs (eyes, central nervous system, liver, kidney) through prolonged or repeated exposure. Aspiration hazard May be fatal if swallowed and enters airways. Chronic effects Prolonged inhalation may be harmful. May cause damage to organs through prolonged or repeated exposure. 12. Ecological information Ecotoxicity Toxic to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected. Product Test ResultsSpecies Mass Air Flow Sensor Cleaner Aquatic LC50Fish 1329.3086 mg/l, 96 hours estimatedFish 6 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US Components Test ResultsSpecies Methanol (CAS 67-56-1) Aquatic LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Acute EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) * Estimates for product may be based on additional component data not shown. n-Hexane (CAS 110-54-3) Aquatic LC50Fish 2.101 - 2.981 mg/l, 96 hoursFathead minnow (Pimephales promelas) Persistence and degradability Not available. Bioaccumulative potential Not available. Partition coefficient n-octanol / water (log Kow) 2,2,4-Trimethylpentane 5.18 Methanol -0.77 n-Hexane 3.9 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from residues / unused products If discarded, this product is considered a RCRA ignitable waste, D001. Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code D001: Waste Flammable material with a flash point <140 F Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk 2.1Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user N82Special provisions 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, flammable, Limited QuantityUN proper shipping name 2.1Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Environmental hazards 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 7 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only IMDG UN1950UN number AEROSOLS, LIMITED QUANTITY, MARINE POLLUTANTUN proper shipping name 2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group YesMarine pollutant Environmental hazards F-D, S-UEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user General information IMDG Regulated Marine Pollutant. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Methanol (CAS 67-56-1) n-Hexane (CAS 110-54-3) CERCLA Hazardous Substance List (40 CFR 302.4) 2,2,4-Trimethylpentane (CAS 540-84-1) Methanol (CAS 67-56-1) n-Hexane (CAS 110-54-3) CERCLA Hazardous Substances: Reportable quantity 2,2,4-Trimethylpentane (CAS 540-84-1) 1000 LBS Methanol (CAS 67-56-1) 5000 LBS n-Hexane (CAS 110-54-3) 5000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List 2,2,4-Trimethylpentane (CAS 540-84-1) n-Hexane (CAS 110-54-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act (SDWA) Not regulated. Food and Drug Administration (FDA) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - Yes Reactivity Hazard - No SARA 302 Extremely hazardous substance No 8 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US US state regulations US. New Jersey Worker and Community Right-to-Know Act 2,2,4-Trimethylpentane (CAS 540-84-1) Carbon dioxide (CAS 124-38-9) Methanol (CAS 67-56-1) n-Hexane (CAS 110-54-3) US. Massachusetts RTK - Substance List 2,2,4-Trimethylpentane (CAS 540-84-1) Carbon dioxide (CAS 124-38-9) n-Hexane (CAS 110-54-3) US. Pennsylvania Worker and Community Right-to-Know Law Methanol (CAS 67-56-1) 2,2,4-Trimethylpentane (CAS 540-84-1) Carbon dioxide (CAS 124-38-9) n-Hexane (CAS 110-54-3) US. Rhode Island RTK 2,2,4-Trimethylpentane (CAS 540-84-1) Methanol (CAS 67-56-1) n-Hexane (CAS 110-54-3) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Developmental toxin Methanol (CAS 67-56-1) Listed: March 16, 2012 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 95 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products Not regulated VOC content (CA) 95 % VOC content (OTC) 95 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 06-30-2014 Prepared by Allison Cho Version # 01 9 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US Further information CRC # 599C HMIS? ratings Health: 2* Flammability: 4 Physical hazard: 0 Personal protection: B NFPA ratings Health: 2 Flammability: 4 Instability: 0 NFPA ratings 02 4 Disclaimer The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. 10 / 10 Material name: Mass Air Flow Sensor Cleaner 1827 Version #: 01 Issue date: 06-30-2014 SDS US