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SAFETY DATA SHEET 1. Identification Product identifier Brakleen? Brake Parts Cleaner - Non-Chlorinated Other means of identification Product code 05085, 05087, 05186 Recommended use Brake parts cleaner Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Category 2Flammable liquidsPhysical hazards Category 3Acute toxicity, oralHealth hazards Category 2Skin corrosion/irritation Category 2ASerious eye damage/eye irritation Category 2Reproductive toxicity (fertility, the unborn child) Category 1Specific target organ toxicity, single exposure Category 3 narcotic effectsSpecific target organ toxicity, single exposure Category 2Specific target organ toxicity, repeated exposure Category 1Aspiration hazard Category 3Hazardous to the aquatic environment, acute hazard Environmental hazards Category 2Hazardous to the aquatic environment, long-term hazard Not classified.OSHA defined hazards Label elements Signal word Danger Hazard statement Highly flammable liquid and vapor. Toxic if swallowed. May be fatal if swallowed and enters airways. Causes skin irritation. Causes serious eye irritation. May cause drowsiness or dizziness. Suspected of damaging fertility. Suspected of damaging the unborn child. Causes damage to organs (eyes). May cause damage to organs (liver, kidneys, lungs, brain) through prolonged or repeated exposure. Harmful to aquatic life. Toxic to aquatic life with long lasting effects. 1 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Use only with adequate ventilation; maintain ventilation during use and until all vapors are gone. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. If you experience any symptoms listed on this label, increase ventilation or leave the area. Do not breathe mist or vapor. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Avoid release to the environment. Response If swallowed: Immediately call a poison center/doctor. Rinse mouth. Do NOT induce vomiting. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical attention. Take off contaminated clothing and wash before reuse. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention. Call a POISON CENTER or doctor/physician if you feel unwell. If exposed or concerned: Get medical attention. In case of fire: Do not use water jet as an extinguisher, as this will spread the fire. Collect spillage. Storage Keep cool. Store in a well-ventilated place. Keep container tightly closed. Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) Static accumulating flammable liquid can become electrostatically charged even in bonded and grounded equipment. Sparks may ignite liquid and vapor. May cause flash fire or explosion. Supplemental information When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as formaldehyde. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 67-56-1Methanol 40 - 50 67-64-1Acetone 10 - 20 108-88-3Toluene 10 - 20 589-34-43-Methylhexane 5 - 10 142-82-5n-Heptane 5 - 10 108-87-2Methylcyclohexane 3 - 5 110-82-7Cyclohexane 1 - 3 100-41-4Ethylbenzene < 0.2 110-54-3n-Hexane < 0.2 Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Call a physician or poison control center immediately. Rinse mouth. Do not induce vomiting. If vomiting occurs, keep head low so that stomach content doesn't get into the lungs. Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Most important symptoms/effects, acute and delayed May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Upper respiratory tract irritation. Skin irritation. May cause redness and pain. Prolonged exposure may cause chronic effects. 2 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US Indication of immediate medical attention and special treatment needed Provide general supportive measures and treat symptomatically. Thermal burns: Flush with water immediately. While flushing, remove clothes which do not adhere to affected area. Call an ambulance. Continue flushing during transport to hospital. Keep victim warm. Keep victim under observation. Symptoms may be delayed. General information IF exposed or concerned: Get medical advice/attention. Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Show this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Alcohol resistant foam. Water fog. Carbon dioxide (CO2). Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. Unsuitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire. Specific hazards arising from the chemical Vapors may form explosive mixtures with air. Vapors may travel considerable distance to a source of ignition and flash back. This product is a poor conductor of electricity and can become electrostatically charged. If sufficient charge is accumulated, ignition of flammable mixtures can occur. To reduce potential for static discharge, use proper bonding and grounding procedures. This liquid may accumulate static electricity when filling properly grounded containers. Static electricity accumulation may be significantly increased by the presence of small quantities of water or other contaminants. Material will float and may ignite on surface of water. During fire, gases hazardous to health may be formed. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as formaldehyde. Special protective equipment and precautions for firefighters Self-contained breathing apparatus and full protective clothing must be worn in case of fire. Fire-fighting equipment/instructions In case of fire and/or explosion do not breathe fumes. Move containers from fire area if you can do so without risk. General fire hazards Highly flammable liquid and vapor. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Wear appropriate protective equipment and clothing during clean-up. Do not breathe mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Use appropriate containment to avoid environmental contamination. Transfer by mechanical means such as vacuum truck to a salvage tank or other suitable container for recovery or safe disposal. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Methods and materials for containment and cleaning up Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Take precautionary measures against static discharge. Use only non-sparking tools. Keep combustibles (wood, paper, oil, etc.) away from spilled material. This material is classified as a water pollutant under the Clean Water Act and should be prevented from contaminating soil or from entering sewage and drainage systems which lead to waterways. Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Cover with plastic sheet to prevent spreading. Use a non-combustible material like vermiculite, sand or earth to soak up the product and place into a container for later disposal. Following product recovery, flush area with water. Small Spills: Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid release to the environment. Prevent further leakage or spillage if safe to do so. Avoid discharge into drains, water courses or onto the ground. Inform appropriate managerial or supervisory personnel of all environmental releases. Use appropriate containment to avoid environmental contamination. 3 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not handle, store or open near an open flame, sources of heat or sources of ignition. Protect material from direct sunlight. Explosion-proof general and local exhaust ventilation. Minimize fire risks from flammable and combustible materials (including combustible dust and static accumulating liquids) or dangerous reactions with incompatible materials. Handling operations that can promote accumulation of static charges include but are not limited to: mixing, filtering, pumping at high flow rates, splash filling, creating mists or sprays, tank and container filling, tank cleaning, sampling, gauging, switch loading, vacuum truck operations. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Use non-sparking tools and explosion-proof equipment. Do not breathe mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Do not taste or swallow. When using, do not eat, drink or smoke. Pregnant or breastfeeding women must not handle this product. Should be handled in closed systems, if possible. Wear appropriate personal protective equipment. Wash hands thoroughly after handling. Avoid release to the environment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Conditions for safe storage, including any incompatibilities Keep away from heat, sparks and open flame. Prevent electrostatic charge build-up by using common bonding and grounding techniques. Eliminate sources of ignition. Avoid spark promoters. Ground/bond container and equipment. These alone may be insufficient to remove static electricity. Store in a cool, dry place out of direct sunlight. Store in original tightly closed container. Store in a well-ventilated place. Keep in an area equipped with sprinklers. Store away from incompatible materials (see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 2400 mg/m3Acetone (CAS 67-64-1) 1000 ppm PEL 1050 mg/m3Cyclohexane (CAS 110-82-7) 300 ppm PEL 435 mg/m3Ethylbenzene (CAS 100-41-4) 100 ppm PEL 260 mg/m3Methanol (CAS 67-56-1) 200 ppm PEL 2000 mg/m3Methylcyclohexane (CAS 108-87-2) 500 ppm PEL 2000 mg/m3n-Heptane (CAS 142-82-5) 500 ppm PEL 1800 mg/m3n-Hexane (CAS 110-54-3) 500 ppm US. OSHA Table Z-2 (29 CFR 1910.1000) ValueComponents Type Ceiling 300 ppmToluene (CAS 108-88-3) TWA 200 ppm US. ACGIH Threshold Limit Values ValueComponents Type STEL 500 ppm3-Methylhexane (CAS 589-34-4) TWA 400 ppm STEL 750 ppmAcetone (CAS 67-64-1) TWA 500 ppm TWA 100 ppmCyclohexane (CAS 110-82-7) TWA 20 ppmEthylbenzene (CAS 100-41-4) STEL 250 ppmMethanol (CAS 67-56-1) 4 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US US. ACGIH Threshold Limit Values ValueComponents Type TWA 200 ppm STEL 500 ppmMethylcyclohexane (CAS 108-87-2) TWA 400 ppm STEL 500 ppmn-Heptane (CAS 142-82-5) TWA 400 ppm TWA 50 ppmn-Hexane (CAS 110-54-3) TWA 20 ppmToluene (CAS 108-88-3) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 590 mg/m3Acetone (CAS 67-64-1) 250 ppm TWA 1050 mg/m3Cyclohexane (CAS 110-82-7) 300 ppm STEL 545 mg/m3Ethylbenzene (CAS 100-41-4) 125 ppm TWA 435 mg/m3 100 ppm STEL 325 mg/m3Methanol (CAS 67-56-1) 250 ppm TWA 260 mg/m3 200 ppm TWA 1600 mg/m3Methylcyclohexane (CAS 108-87-2) 400 ppm Ceiling 1800 mg/m3n-Heptane (CAS 142-82-5) 440 ppm TWA 350 mg/m3 85 ppm TWA 180 mg/m3n-Hexane (CAS 110-54-3) 50 ppm STEL 560 mg/m3Toluene (CAS 108-88-3) 150 ppm TWA 375 mg/m3 100 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 50 mg/l Acetone Urine *Acetone (CAS 67-64-1) 0.15 g/g Sum of mandelic acid and phenylglyoxylic acid Creatinine in urine *Ethylbenzene (CAS 100-41-4) 15 mg/l Methanol Urine *Methanol (CAS 67-56-1) 0.4 mg/l 2,5-Hexanedio n, without hydrolysis Urine *n-Hexane (CAS 110-54-3) 0.3 mg/g o-Cresol, with hydrolysis Creatinine in urine *Toluene (CAS 108-88-3) 0.03 mg/l Toluene Urine * 0.02 mg/l Toluene Blood * * - For sampling details, please see the source document. 5 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US Exposure guidelines US - California OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin. Toluene (CAS 108-88-3) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Methanol (CAS 67-56-1) Skin designation applies. Toluene (CAS 108-88-3) Skin designation applies. US - Tennessee OELs: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. US ACGIH Threshold Limit Values: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. n-Hexane (CAS 110-54-3) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation Methanol (CAS 67-56-1) Can be absorbed through the skin. Appropriate engineering controls Explosion-proof general and local exhaust ventilation. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear protective gloves such as: Nitrile. Polyvinyl alcohol (PVA). Neoprene. Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Respiratory protection If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Thermal hazards Wear appropriate thermal protective clothing, when necessary. General hygiene considerations When using, do not eat, drink or smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Liquid. Form Liquid. Color Clear. Odor Solvent. Odor threshold Not available. pH Not available. Melting point/freezing point -195.9 ?F (-126.6 ?C) estimated Initial boiling point and boiling range 132.9 ?F (56.1 ?C) estimated Flash point -0.00004 ?F (-17.8 ?C) Tag Closed Cup Evaporation rate Not available. Flammability (solid, gas) Not available. Upper/lower flammability or explosive limits Flammability limit - lower (%) 1 % estimated Flammability limit - upper (%) 36 % estimated Vapor pressure 107.9 hPa estimated Vapor density Not available. 6 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US Relative density 0.78 Solubility (water) Not available. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 539.6 ?F (282 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 100 % 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. When exposed to extreme heat or hot surfaces, vapors may decompose to harmful or fatal corrosive gases such as formaldehyde. Contact with incompatible materials. Incompatible materials Acids. Alkalies. Reducing agents. Strong oxidizing agents. Hypochlorites. Peroxides. Aluminum. Magnesium. Sodium. Zinc. Hazardous decomposition products Carbon oxides. Formaldehyde. 11. Toxicological information Information on likely routes of exposure Ingestion Toxic if swallowed. May be fatal or cause blindness if swallowed. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. Inhalation May cause damage to organs by inhalation. May cause damage to organs through prolonged or repeated exposure by inhalation. May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Symptoms related to the physical, chemical and toxicological characteristics May cause drowsiness and dizziness. Headache. Nausea, vomiting. Irritation of nose and throat. Aspiration may cause pulmonary edema and pneumonitis. Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Upper respiratory tract irritation. Skin irritation. May cause redness and pain. Information on toxicological effects Acute toxicity May be fatal if swallowed and enters airways. Narcotic effects. Test ResultsProduct Species Brakleen? Brake Parts Cleaner - Non-Chlorinated LD50 Rabbit Dermal Acute 4356.5029 mg/kg estimated LC50 Rat Inhalation 37.3684 mg/l, 4 Hours estimated LD50 Human Oral 102.2495 mg/kg estimated Rat 4161.1147 mg/kg estimated * Estimates for product may be based on additional component data not shown. Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye irritation. Respiratory sensitization Not available. Skin sensitization This product is not expected to cause skin sensitization. 7 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Carcinogenicity Based on available data, the classification criteria are not met. This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity Ethylbenzene (CAS 100-41-4) 2B Possibly carcinogenic to humans. Toluene (CAS 108-88-3) 3 Not classifiable as to carcinogenicity to humans. Reproductive toxicity Suspected of damaging the unborn child. Suspected of damaging fertility. Specific target organ toxicity - single exposure Causes damage to organs. Even small amounts (30-250 ml methanol) may be fatal. Symptoms are stomach ache, nausea, vomiting, dullness, visual disorder and blindness. May cause drowsiness and dizziness. Specific target organ toxicity - repeated exposure May cause damage to organs (liver, kidneys, lungs, brain) through prolonged or repeated exposure. Aspiration hazard May be fatal if swallowed and enters airways. If aspirated into lungs during swallowing or vomiting, may cause chemical pneumonia, pulmonary injury or death. Chronic effects Prolonged inhalation may be harmful. May cause damage to organs through prolonged or repeated exposure. 12. Ecological information Ecotoxicity Toxic to aquatic life with long lasting effects. Product Test ResultsSpecies Brakleen? Brake Parts Cleaner - Non-Chlorinated Aquatic EC50Crustacea 48.6123 mg/l, 48 hours estimatedDaphnia Acute LC50Fish 34.3781 mg/l, 96 hours estimatedFish Components Test ResultsSpecies Acetone (CAS 67-64-1) Aquatic EC50Crustacea 21.6 - 23.9 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 4740 - 6330 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Cyclohexane (CAS 110-82-7) Aquatic LC50Fish 23.03 - 42.07 mg/l, 96 hoursFathead minnow (Pimephales promelas) Ethylbenzene (CAS 100-41-4) Aquatic Acute EC50Crustacea 2.1 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 12.1 mg/l, 96 hoursFathead minnow (Pimephales promelas) Methanol (CAS 67-56-1) Aquatic LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Acute EC50Crustacea > 10000 mg/l, 48 hoursWater flea (Daphnia magna) LC50Fish 18000 - 20000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) Methylcyclohexane (CAS 108-87-2) Aquatic LC50Fish 5.8 mg/l, 96 hoursStriped bass (Morone saxatilis) 8 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US Components Test ResultsSpecies n-Heptane (CAS 142-82-5) Aquatic Acute LC50Fish 2.1 - 2.98 mg/l, 96 hoursFathead minnow (Pimephales promelas) n-Hexane (CAS 110-54-3) Aquatic LC50Fish 2.101 - 2.981 mg/l, 96 hoursFathead minnow (Pimephales promelas) Toluene (CAS 108-88-3) Aquatic EC50Crustacea 5.46 - 9.83 mg/l, 48 hoursWater flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50Fish 8.11 mg/l, 96 hoursCoho salmon,silver salmon (Oncorhynchus kisutch) Persistence and degradability No data is available on the degradability of this product. Bioaccumulative potential No data available. Partition coefficient n-octanol / water (log Kow) Acetone -0.24 Cyclohexane 3.44 Ethylbenzene 3.15 Methanol -0.77 Methylcyclohexane 3.61 n-Heptane 4.66 n-Hexane 3.9 Toluene 2.73 Mobility in soil No data available. Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 13. Disposal considerations Disposal of waste from residues / unused products If discarded, this product is considered a RCRA ignitable waste, D001. Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose in accordance with all applicable regulations. Hazardous waste code D001: Waste Flammable material with a flash point <140 F Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. 14. Transport information DOT UN1992UN number Flammable liquids, toxic, n.o.s. (Methanol RQ = 10225 LBS, Toluene RQ = 5348 LBS)UN proper shipping name 3Class Transport hazard class(es) 6.1Subsidiary risk 3, 6.1Label(s) IIPacking group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user IB2, T7, TP2, TP13Special provisions 150Packaging exceptions 202Packaging non bulk 243Packaging bulk IATA UN1992UN number Flammable liquid, toxic, n.o.s. (Methanol, Toluene)UN proper shipping name 9 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US 3Class Transport hazard class(es) 6.1Subsidiary risk IIPacking group No.Environmental hazards 3HPERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed.Passenger and cargo aircraft Other information Allowed.Cargo aircraft only IMDG UN1992UN number FLAMMABLE LIQUID, TOXIC, N.O.S. (Methanol, Toluene), MARINE POLLUTANTUN proper shipping name 3Class Transport hazard class(es) 6.1Subsidiary risk IIPacking group YesMarine pollutant Environmental hazards F-E, S-DEmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user General information IMDG Regulated Marine Pollutant. 15. Regulatory information US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. All components are on the U.S. EPA TSCA Inventory List. TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. SARA 304 Emergency release notification Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance Cyclohexane (CAS 110-82-7) Ethylbenzene (CAS 100-41-4) Methanol (CAS 67-56-1) Toluene (CAS 108-88-3) CERCLA Hazardous Substance List (40 CFR 302.4) Acetone (CAS 67-64-1) Cyclohexane (CAS 110-82-7) Ethylbenzene (CAS 100-41-4) Methanol (CAS 67-56-1) Toluene (CAS 108-88-3) CERCLA Hazardous Substances: Reportable quantity Acetone (CAS 67-64-1) 5000 LBS Cyclohexane (CAS 110-82-7) 1000 LBS Ethylbenzene (CAS 100-41-4) 1000 LBS Methanol (CAS 67-56-1) 5000 LBS Toluene (CAS 108-88-3) 1000 LBS Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Methanol (CAS 67-56-1) Toluene (CAS 108-88-3) Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. 10 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US Safe Drinking Water Act (SDWA) Not regulated. Drug Enforcement Administration (DEA). List 2, Essential Chemicals (21 CFR 1310.02(b) and 1310.04(f)(2) and Chemical Code Number Acetone (CAS 67-64-1) 6532 Toluene (CAS 108-88-3) 6594 Drug Enforcement Administration (DEA). List 1 & 2 Exempt Chemical Mixtures (21 CFR 1310.12(c)) Acetone (CAS 67-64-1) 35 %WV Toluene (CAS 108-88-3) 35 %WV DEA Exempt Chemical Mixtures Code Number Acetone (CAS 67-64-1) 6532 Toluene (CAS 108-88-3) 594 Food and Drug Administration (FDA) Not regulated. Superfund Amendments and Reauthorization Act of 1986 (SARA) Section 311/312 Hazard categories Immediate Hazard - Yes Delayed Hazard - Yes Fire Hazard - Yes Pressure Hazard - No Reactivity Hazard - No SARA 302 Extremely hazardous substance No US state regulations US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. New Jersey Worker and Community Right-to-Know Act 3-Methylhexane (CAS 589-34-4) Acetone (CAS 67-64-1) Methylcyclohexane (CAS 108-87-2) n-Heptane (CAS 142-82-5) Cyclohexane (CAS 110-82-7) Ethylbenzene (CAS 100-41-4) Methanol (CAS 67-56-1) n-Hexane (CAS 110-54-3) Toluene (CAS 108-88-3) US. Massachusetts RTK - Substance List 3-Methylhexane (CAS 589-34-4) Acetone (CAS 67-64-1) Cyclohexane (CAS 110-82-7) Methanol (CAS 67-56-1) Methylcyclohexane (CAS 108-87-2) n-Heptane (CAS 142-82-5) Toluene (CAS 108-88-3) US. Pennsylvania Worker and Community Right-to-Know Law Acetone (CAS 67-64-1) Cyclohexane (CAS 110-82-7) Ethylbenzene (CAS 100-41-4) Methanol (CAS 67-56-1) Toluene (CAS 108-88-3) 3-Methylhexane (CAS 589-34-4) Methylcyclohexane (CAS 108-87-2) n-Heptane (CAS 142-82-5) n-Hexane (CAS 110-54-3) US. Rhode Island RTK Acetone (CAS 67-64-1) Cyclohexane (CAS 110-82-7) Ethylbenzene (CAS 100-41-4) Methanol (CAS 67-56-1) n-Hexane (CAS 110-54-3) Toluene (CAS 108-88-3) 11 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance Benzene (CAS 71-43-2) Listed: February 27, 1987 Cumene (CAS 98-82-8) Listed: April 6, 2010 Ethanal (CAS 75-07-0) Listed: April 1, 1988 Ethylbenzene (CAS 100-41-4) Listed: June 11, 2004 US - California Proposition 65 - CRT: Listed date/Developmental toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Methanol (CAS 67-56-1) Listed: March 16, 2012 Toluene (CAS 108-88-3) Listed: January 1, 1991 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin Toluene (CAS 108-88-3) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin Benzene (CAS 71-43-2) Listed: December 26, 1997 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 90 % Consumer products (40 CFR 59, Subpt. C) Not regulated State Consumer products This product is regulated as a Brake Cleaner. This product is not compliant to be sold for use in California, Connecticut, Delaware, the District of Columbia, Illinois, Indiana, Maine, Maryland, Massachusetts, Michigan, New Hampshire, New Jersey, New York, Ohio, Pennsylvania, Rhode Island and parts of Utah and Virginia. This product is compliant in all other states. VOC content (CA) 90 % VOC content (OTC) 90 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustralia Australian Inventory of Chemical Substances (AICS) NoCanada Domestic Substances List (DSL) YesCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) YesEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 08-14-2014 Revision date 08-27-2014 Prepared by Allison Cho Version # 02 Further information CRC # 483A 12 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US HMIS? ratings Health: 3* Flammability: 3 Physical hazard: 0 Personal protection: B NFPA ratings Health: 3 Flammability: 3 Instability: 0 NFPA ratings 03 3 Disclaimer CRC cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user?s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. 13 / 13 Material name: Brakleen? Brake Parts Cleaner - Non-Chlorinated 05085, 05087, 05186 Version #: 02 Revision date: 08-27-2014 Issue date: 08-14-2014 SDS US