SAFETY DATA SHEET 1. Identification Battery Cleaner with Acid IndicatorProduct identifier Other means of identification 05023Product code Battery cleanerRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufactured or sold by: Company name CRC Industries, Inc. Address 885 Louis Dr. Warminster, PA 18974 US Telephone General Information 215-674-4300 Technical Assistance 800-521-3168 Customer Service 800-272-4620 24-Hour Emergency 800-424-9300 (US) (CHEMTREC) 703-527-3887 (International) Website www.crcindustries.com 2. Hazard(s) identification Liquefied gasGases under pressurePhysical hazards Not classified.Health hazards Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Warning Hazard statement Contains gas under pressure; may explode if heated. Precautionary statement Prevention Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 49?C/120?F. Use with adequate ventilation. Open doors and windows or use other means to ensure a fresh air supply during use and while product is drying. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Exposure to high temperature may cause can to burst. Disposal Dispose of contents/container in accordance with local/regional/national regulations. Hazard(s) not otherwise classified (HNOC) None known. 3. Composition/information on ingredients Mixtures CAS number %Common name and synonymsChemical name 7732-18-5 80 - 90water 68476-86-8 5 - 10liquefied petroleum gas 1 / 8 Material name: Battery Cleaner with Acid Indicator 05023 Version #: 02 Revision date: 03-08-2016 Issue date: 07-24-2015 SDS US CAS number %Common name and synonymsChemical name 111-76-2 1 - 32-butoxyethanol Specific chemical identity and/or percentage of composition has been withheld as a trade secret. 4. First-aid measures Move to fresh air. Call a physician if symptoms develop or persist.Inhalation Rinse skin with water/shower. Get medical attention if irritation develops and persists.Skin contact Rinse with water. Get medical attention if irritation develops and persists.Eye contact Call a POISON CENTER or doctor/physician.Ingestion Direct contact with eyes may cause temporary irritation.Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically.Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media During fire, gases hazardous to health may be formed.Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters Fire-fighting equipment/instructions In case of fire: Stop leak if safe to do so. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. Contents under pressure. Pressurized container may rupture when exposed to heat or flame.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of low areas. Many gases are heavier than air and will spread along ground and collect in low or confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.) away from spilled material. This product is miscible in water. Stop the flow of material, if this is without risk. Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground.Environmental precautions 7. Handling and storage Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Use caution around energized equipment. The metal container will conduct electricity if it contacts a live source. This may result in injury to the user from electrical shock and/or flash fire. Do not get in eyes, on skin, or on clothing. Use only in well-ventilated areas. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. For product usage instructions, please see the product label. Precautions for safe handling Level 1 Aerosol. Contents under pressure. Do not expose to heat or store at temperatures above 120?F/49?C as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 2 / 8 Material name: Battery Cleaner with Acid Indicator 05023 Version #: 02 Revision date: 03-08-2016 Issue date: 07-24-2015 SDS US 8. Exposure controls/personal protection Occupational exposure limits US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 240 mg/m32-butoxyethanol (CAS 111-76-2) 50 ppm US. ACGIH Threshold Limit Values ValueComponents Type TWA 20 ppm2-butoxyethanol (CAS 111-76-2) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 24 mg/m32-butoxyethanol (CAS 111-76-2) 5 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine *2-butoxyethanol (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies 2-butoxyethanol (CAS 111-76-2) Skin designation applies. US - Tennessee OELs: Skin designation 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 2-butoxyethanol (CAS 111-76-2) Can be absorbed through the skin. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear protective gloves such as: Nitrile.Hand protection Wear suitable protective clothing.Other If engineering controls are not feasible or if exposure exceeds the applicable exposure limits, use a NIOSH-approved cartridge respirator with an organic vapor cartridge. Use a self-contained breathing apparatus in confined spaces and for emergencies. Air monitoring is needed to determine actual employee exposure levels. Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards When using do not smoke. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state 3 / 8 Material name: Battery Cleaner with Acid Indicator 05023 Version #: 02 Revision date: 03-08-2016 Issue date: 07-24-2015 SDS US Aerosol.Form Clear.Color Odorless.Odor Odor threshold Not available. pH 8.5 Melting point/freezing point -103 ?F (-75 ?C) estimated Initial boiling point and boiling range 212 ?F (100 ?C) estimated Flash point None (Tag Closed Cup) Evaporation rate Slow. Not available.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) 1.3 % estimated Flammability limit - upper (%) 10.6 % estimated Vapor pressure 265.9 hPa estimated Vapor density > 1 (air = 1) Relative density 1.01 Solubility (water) Soluble. Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature 446 ?F (230 ?C) estimated Decomposition temperature Not available. Viscosity (kinematic) Not available. Percent volatile 94.3 % estimated 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Heat, flames and sparks. Contact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials Carbon oxides.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion May cause discomfort if swallowed. Symptoms related to the physical, chemical and toxicological characteristics Direct contact with eyes may cause temporary irritation. Information on toxicological effects Acute toxicity Not classified. 4 / 8 Material name: Battery Cleaner with Acid Indicator 05023 Version #: 02 Revision date: 03-08-2016 Issue date: 07-24-2015 SDS US Test ResultsProduct Species Battery Cleaner with Acid Indicator Dermal Acute LD50 Rabbit 15187 mg/kg estimated Inhalation LC50 Rat 83 mg/l, 4 hours estimated Oral * Estimates for product may be based on additional component data not shown. LD50 Rat 21294 mg/kg estimated Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Direct contact with eyes may cause temporary irritation.Serious eye damage/eye irritation Respiratory sensitization Not a respiratory sensitizer. This product is not expected to cause skin sensitization.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA. IARC Monographs. Overall Evaluation of Carcinogenicity 2-butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. US. National Toxicology Program (NTP) Report on Carcinogens Not available. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects May be harmful if absorbed through skin. 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and prolonged. These effects have not been observed in humans. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test ResultsSpecies 2-butoxyethanol (CAS 111-76-2) Aquatic Acute EC50Crustacea 1550 mg/l, 48 hoursWater flea (Daphnia magna) * Estimates for product may be based on additional component data not shown. LC50Fish >= 1000 mg/l, 96 hoursRainbow trout,donaldson trout (Oncorhynchus mykiss) No data is available on the degradability of this product. Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol / water (log Kow) 2-butoxyethanol 0.81, log Pow No data available.Mobility in soil Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component. 5 / 8 Material name: Battery Cleaner with Acid Indicator 05023 Version #: 02 Revision date: 03-08-2016 Issue date: 07-24-2015 SDS US 13. Disposal considerations The dispensed liquid product is not a RCRA hazardous waste (See 40 CFR Part 261.20 - 261.33). Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush. Do not allow this material to drain into sewers/water supplies. Do not contaminate ponds, waterways or ditches with chemical or used container. Dispose of contents/container in accordance with local/regional/national regulations. Disposal of waste from residues / unused products Not regulated.Hazardous waste code Empty containers should be taken to an approved waste handling site for recycling or disposal. Since emptied containers may retain product residue, follow label warnings even after container is emptied. Do not re-use empty containers. Contaminated packaging 14. Transport information DOT UN1950UN number Aerosols, non-flammable, limited quantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk 2.2Label(s) Not applicable.Packing group Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 306Packaging exceptions NonePackaging non bulk NonePackaging bulk IATA UN1950UN number Aerosols, non-flammable, limited quantityUN proper shipping name 2.2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group 10LERG Code Read safety instructions, SDS and emergency procedures before handling.Special precautions for user Allowed with restrictions.Passenger and cargo aircraft Other information Allowed with restrictions.Cargo aircraft only IMDG UN1950UN number AEROSOLS, LIMITED QUANTITYUN proper shipping name 2Class Transport hazard class(es) -Subsidiary risk Not applicable.Packing group No.Environmental hazards Not available.EmS Read safety instructions, SDS and emergency procedures before handling.Special precautions for user 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not listed. SARA 304 Emergency release notification Not regulated. US EPCRA (SARA Title III) Section 313 - Toxic Chemical: Listed substance 2-butoxyethanol (CAS 111-76-2) 6 / 8 Material name: Battery Cleaner with Acid Indicator 05023 Version #: 02 Revision date: 03-08-2016 Issue date: 07-24-2015 SDS US CERCLA Hazardous Substance List (40 CFR 302.4) 2-butoxyethanol (CAS 111-76-2) CERCLA Hazardous Substances: Reportable quantity Not listed. Spills or releases resulting in the loss of any ingredient at or above its RQ require immediate notification to the National Response Center (800-424-8802) and to your Local Emergency Planning Committee. Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) Not regulated.Food and Drug Administration (FDA) Superfund Amendments and Reauthorization Act of 1986 (SARA) Immediate Hazard - No Delayed Hazard - No Fire Hazard - No Pressure Hazard - Yes Reactivity Hazard - No Section 311/312 Hazard categories NoSARA 302 Extremely hazardous substance US state regulations US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) 2-butoxyethanol (CAS 111-76-2) liquefied petroleum gas (CAS 68476-86-8) US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100) Not listed. US. Massachusetts RTK - Substance List 2-butoxyethanol (CAS 111-76-2) US. Rhode Island RTK 2-butoxyethanol (CAS 111-76-2) US. New Jersey Worker and Community Right-to-Know Act 2-butoxyethanol (CAS 111-76-2) US. Pennsylvania Worker and Community Right-to-Know Law 2-butoxyethanol (CAS 111-76-2) US. California Proposition 65 WARNING: This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US - California Proposition 65 - CRT: Listed date/Carcinogenic substance 1,4-dioxane (CAS 123-91-1) Listed: January 1, 1988 ethylene oxide (CAS 75-21-8) Listed: July 1, 1987 US - California Proposition 65 - CRT: Listed date/Developmental toxin ethylene oxide (CAS 75-21-8) Listed: August 7, 2009 US - California Proposition 65 - CRT: Listed date/Female reproductive toxin ethylene oxide (CAS 75-21-8) Listed: February 27, 1987 US - California Proposition 65 - CRT: Listed date/Male reproductive toxin ethylene oxide (CAS 75-21-8) Listed: August 7, 2009 Volatile organic compounds (VOC) regulations EPA VOC content (40 CFR 51.100(s)) 7.9 % Not regulatedConsumer products (40 CFR 59, Subpt. C) State Not regulatedConsumer products 7 / 8 Material name: Battery Cleaner with Acid Indicator 05023 Version #: 02 Revision date: 03-08-2016 Issue date: 07-24-2015 SDS US VOC content (CA) 7.9 % VOC content (OTC) 7.9 % International Inventories Country(s) or region Inventory name On inventory (yes/no)* YesAustralia Australian Inventory of Chemical Substances (AICS) YesCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) YesChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) YesKorea Existing Chemicals List (ECL) YesNew Zealand New Zealand Inventory YesPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 07-24-2015Issue date 03-08-2016Revision date Allison ChoPrepared by Version # 02 CRC # 530CFurther information Health: 1 Flammability: 0 Physical hazard: 0 Personal protection: B HMIS? ratings Health: 1 Flammability: 0 Instability: 0 NFPA ratings NFPA ratings 01 0 The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. This information is accurate to the best of CRC Industries' knowledge or obtained from sources believed by CRC to be accurate. Before using any product, read all warnings and directions on the label. For further clarification of any information contained on this (M)SDS consult your supervisor, a health & safety professional, or CRC Industries. Disclaimer 8 / 8 Material name: Battery Cleaner with Acid Indicator 05023 Version #: 02 Revision date: 03-08-2016 Issue date: 07-24-2015 SDS US