1. IDENTIFICATION Product identifier Product Name SURFACE PREP 4.5OZ AE Other means of identification Product Code 24163 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Surface active agent Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Specific target organ toxicity (single exposure) Category 3 Aspiration toxicity Category 1 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 9 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Danger Flammable aerosols Causes skin irritation May cause drowsiness or dizziness May be fatal if swallowed and enters airways Category 1 Extremely flammable aerosol Pressurized container: May burst if heated Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 17-Mar-2015 SAFETY DATA SHEET Version 1 _____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Wear protective gloves Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep container tightly closed Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % w/w 1,3-butadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases (2-)9-16 (Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3 Toxic to aquatic life with long lasting effects Unknown acute toxicity 5% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% Trade Secret HEPTANE 142-82-5 40 - 70 * PROPANE 74-98-6 10 - 30 * ISOBUTANE 75-28-5 10 - 30 * ETHANOL 64-17-5 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. _____________________________________________________________________________________________ Page 2 / 9 24163 - SURFACE PREP 4.5OZ AE Revision Date 17-Mar-2015 Physical state Liquid Odor SolventAppearance Green _____________________________________________________________________________________________ 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. Will be easily ignited by heat, sparks or flames. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. _____________________________________________________________________________________________ Page 3 / 9 24163 - SURFACE PREP 4.5OZ AE Revision Date 17-Mar-2015 _____________________________________________________________________________________________ Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Take precautionary measures against static discharges. Use spark-proof tools and explosion-proof equipment. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Incompatible materials Strong acids, Bases, Acids 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH HEPTANE 142-82-5 STEL: 500 ppm TWA: 400 ppm TWA: 500 ppm TWA: 2000 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1600 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 2000 mg/m3 IDLH: 750 ppm Ceiling: 440 ppm 15 min Ceiling: 1800 mg/m3 15 min TWA: 85 ppm TWA: 350 mg/m3 PROPANE 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 ISOBUTANE 75-28-5 STEL: 1000 ppm - TWA: 800 ppm TWA: 1900 mg/m3 ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. _____________________________________________________________________________________________ Page 4 / 9 24163 - SURFACE PREP 4.5OZ AE Revision Date 17-Mar-2015 _____________________________________________________________________________________________ General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Green Odor Solvent Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 97.6% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Take precautionary measures against static discharges. Incompatible materials Strong acids, Bases, Acids _____________________________________________________________________________________________ Page 5 / 9 Gives a flame projection at full valve opening or flashback at any degree of valve opening pH Partition coefficient No information available No information available Evaporation rate <1 Autoignition temperature No information available 24163 - SURFACE PREP 4.5OZ AE Decomposition temperature No information available Ether = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: 9.5% Values Lower flammability limit: 1.0% Revision Date 17-Mar-2015 Vapor pressure 71 psig Boiling point / boiling range Not determined No data available Vapor density >1 Remarks ? Method Air = 1 Relative density 0.66 Flash point Water solubility Negligible < 0 ?C / < 32 ?F Solubility in other solvents No information available _____________________________________________________________________________________________ Hazardous Decomposition Products Carbon oxides, Phosphorus, Copper compounds 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Potential for aspiration if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 HEPTANE 142-82-5 - = 3000 mg/kg ( Rabbit ) = 103 g/m3 ( Rat ) 4 h PROPANE 74-98-6 - - = 658 mg/L ( Rat ) 4 h ISOBUTANE 75-28-5 - - = 658 mg/L ( Rat ) 4 h ETHANOL 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA ETHANOL 64-17-5 A3 Group 1 Known X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Target Organ Effects Central nervous system, Respiratory system, Eyes, Skin, blood, liver. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 353000 mg/kg ATEmix (dermal) 4615 mg/kg ATEmix (inhalation-gas) 1124303 mg/l ATEmix (inhalation-dust/mist) 155 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 33% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea _____________________________________________________________________________________________ Page 6 / 9 24163 - SURFACE PREP 4.5OZ AE Revision Date 17-Mar-2015 _____________________________________________________________________________________________ HEPTANE 142-82-5 - 375.0: 96 h Cichlid fish mg/L LC50 10: 24 h Daphnia magna mg/L EC50 ETHANOL 64-17-5 - 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient HEPTANE 142-82-5 4.66 PROPANE 74-98-6 2.3 ISOBUTANE 75-28-5 2.88 ETHANOL 64-17-5 -0.32 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status HEPTANE 142-82-5 Toxic Ignitable ETHANOL 64-17-5 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 Emergency Response Guide Number 126 IATA _____________________________________________________________________________________________ Page 7 / 9 24163 - SURFACE PREP 4.5OZ AE Revision Date 17-Mar-2015 _____________________________________________________________________________________________ UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Does not comply Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 _____________________________________________________________________________________________ Page 8 / 9 24163 - SURFACE PREP 4.5OZ AE Revision Date 17-Mar-2015 _____________________________________________________________________________________________ ETHANOL - 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania HEPTANE 142-82-5 X X X PROPANE 74-98-6 X X X ISOBUTANE 75-28-5 X X X ETHANOL 64-17-5 X X X ORGANO-COPPER COMPOUND 68084-48-0 X - X ORGANO-COPPER COMPOUND 22221-10-9 X - X ORGANO-COPPER COMPOUND 85737-14-0 X - X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 17-Mar-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 9 / 9 - 24163 - SURFACE PREP 4.5OZ AE HMIS NFPA Health hazards 2 Flammability 3 Revision Date 17-Mar-2015 Physical hazards 0 Personal protection B Health hazards 2 Flammability 3 Instability 0