1. IDENTIFICATION Product identifier Product Name 1AR FORM A GASKET #1 SEALANT 1.5 OZ. Other means of identification Product Code 80007 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 3 Skin sensitization Category 1 Carcinogenicity Category 2 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 10 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 27-Apr-2015 Toxic if swallowed May cause an allergic skin reaction Suspected of causing cancer SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Danger _____________________________________________________________________________________________ Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF ON SKIN: Wash with plenty of soap and water If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Harmful to aquatic life with long lasting effects. Unknown acute toxicity 58.78% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret KAOLIN 1332-58-7 30 - 60 * ROSIN 8050-09-7 10 - 30 * ETHANOL 64-17-5 7 - 13 * 2-PROPANOL 67-63-0 1 - 5 * TITANIUM DIOXIDE 13463-67-7 0.1 - 1 * CRYSTALLINE SILICA 14808-60-7 0.1 - 1 * METHANOL 67-56-1 0.1 - 1 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES _____________________________________________________________________________________________ Page 2 / 10 80007 - 1AR FORM A GASKET #1 SEALANT 1.5 OZ. Revision Date 27-Apr-2015 Appearance Reddish golden brown Physical state Paste Odor Alcohol _____________________________________________________________________________________________ Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash with soap and water. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Rinse mouth. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. _____________________________________________________________________________________________ Page 3 / 10 Revision Date 27-Apr-201580007 - 1AR FORM A GASKET #1 SEALANT 1.5 OZ. _____________________________________________________________________________________________ Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Store locked up. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH KAOLIN 1332-58-7 TWA: 2 mg/m3 particulate matter containing no asbestos and <1% crystalline silica, respirable fraction TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 10 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction TWA: 10 mg/m3 total dust TWA: 5 mg/m3 respirable dust ROSIN 8050-09-7 - (vacated) TWA: 0.1 mg/m3 Formaldehyde TWA: 0.1 mg/m3 Formaldehyde ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 2-PROPANOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 TITANIUM DIOXIDE 13463-67-7 TWA: 10 mg/m3 TWA: 15 mg/m3 total dust (vacated) TWA: 10 mg/m3 total dust IDLH: 5000 mg/m3 CRYSTALLINE SILICA 14808-60-7 TWA: 0.025 mg/m3 respirable fraction (vacated) TWA: 0.1 mg/m3 respirable dust : (30)/(%SiO2 + 2) mg/m3 TWA total dust : (250)/(%SiO2 + 5) mppcf TWA respirable fraction : (10)/(%SiO2 + 2) mg/m3 TWA respirable fraction IDLH: 50 mg/m3 respirable dust TWA: 0.05 mg/m3 respirable dust METHANOL 67-56-1 STEL: 250 ppm TWA: 200 ppm S* TWA: 200 ppm TWA: 260 mg/m3 (vacated) TWA: 200 ppm (vacated) TWA: 260 mg/m3 (vacated) STEL: 250 ppm (vacated) STEL: 325 mg/m3 (vacated) S* IDLH: 6000 ppm TWA: 200 ppm TWA: 260 mg/m3STEL: 250 ppm STEL: 325 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). _____________________________________________________________________________________________ Page 4 / 10 80007 - 1AR FORM A GASKET #1 SEALANT 1.5 OZ. Revision Date 27-Apr-2015 _____________________________________________________________________________________________ Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance Reddish golden brown Odor Alcohol Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 13.5% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY _____________________________________________________________________________________________ Page 5 / 10 Remarks ? Method Air = 1 Relative density 1.44 Flash point Water solubility Partially soluble Does not apply 80007 - 1AR FORM A GASKET #1 SEALANT 1.5 OZ. Solubility in other solvents No information available ASTM D 4359 pH Partition coefficient No information available No information available Evaporation rate 7.7 Autoignition temperature No information available Decomposition temperature No information available Butyl acetate = 1 Revision Date 27-Apr-2015 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Vapor pressure 33 mmHg @ 68?F Boiling point / boiling range 82 ?C / 180 ?F Vapor density >1 _____________________________________________________________________________________________ Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides Aldehydes Carboxylic acids 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Toxic if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ROSIN 8050-09-7 = 3 mg/kg ( Rat ) = 7600 mg/kg ( Rat ) > 2500 mg/kg ( Rabbit ) = 1.5 mg/L ( Rat ) 4 h ETHANOL 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h 2-PROPANOL 67-63-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h TITANIUM DIOXIDE 13463-67-7 > 10000 mg/kg ( Rat ) - - CRYSTALLINE SILICA 14808-60-7 = 500 mg/kg ( Rat ) - - METHANOL 67-56-1 = 6200 mg/kg ( Rat ) = 15800 mg/kg ( Rabbit ) = 22500 ppm ( Rat ) 8 h = 64000 ppm ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA ETHANOL 64-17-5 A3 Group 1 Known X 2-PROPANOL 67-63-0 - Group 1 - X TITANIUM DIOXIDE 13463-67-7 - Group 2B - X CRYSTALLINE SILICA 14808-60-7 A2 Group 1 Known X _____________________________________________________________________________________________ Page 6 / 10 80007 - 1AR FORM A GASKET #1 SEALANT 1.5 OZ. Revision Date 27-Apr-2015 No data available _____________________________________________________________________________________________ ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. Target Organ Effects Blood, Central nervous system, Eyes, Liver, Reproductive System, Respiratory system, Skin, Thyroid. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 5 mg/kg ATEmix (dermal) 3403 mg/kg ATEmix (inhalation-dust/mist) 31 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 60.82% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea ROSIN 8050-09-7 400: 72 h Desmodesmus subspicatus mg/L EC50 - 3.8 - 5.4: 48 h Daphnia magna mg/L EC50 ETHANOL 64-17-5 - 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 2-PROPANOL 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 11130: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 1400000: 96 h Lepomis macrochirus ?g/L LC50 13299: 48 h Daphnia magna mg/L EC50 METHANOL 67-56-1 - 28200: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static 19500 - 20700: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 13500 - 17600: 96 h Lepomis macrochirus mg/L LC50 flow-through 18 - 20: 96 h Oncorhynchus mykiss mL/L LC50 static - Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ETHANOL 64-17-5 -0.32 2-PROPANOL 67-63-0 0.05 _____________________________________________________________________________________________ Page 7 / 10 80007 - 1AR FORM A GASKET #1 SEALANT 1.5 OZ. Revision Date 27-Apr-2015 _____________________________________________________________________________________________ METHANOL 67-56-1 -0.77 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes METHANOL 67-56-1 - Included in waste stream: F039 - U154 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ETHANOL 64-17-5 Toxic Ignitable 2-PROPANOL 67-63-0 Toxic Ignitable METHANOL 67-56-1 Toxic Ignitable 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances _____________________________________________________________________________________________ Page 8 / 10 Revision Date 27-Apr-201580007 - 1AR FORM A GASKET #1 SEALANT 1.5 OZ. _____________________________________________________________________________________________ KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2-PROPANOL - 67-63-0 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) METHANOL 67-56-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental TITANIUM DIOXIDE - 13463-67-7 Carcinogen CRYSTALLINE SILICA - 14808-60-7 Carcinogen METHANOL - 67-56-1 Developmental METHYL ISOBUTYL KETONE - 108-10-1 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania KAOLIN 1332-58-7 X X X ETHANOL 64-17-5 X X X 2-PROPANOL 67-63-0 X X X TITANIUM DIOXIDE 13463-67-7 X X X CRYSTALLINE SILICA 14808-60-7 X X X METHANOL 67-56-1 X X X IRON OXIDE 1309-37-1 X X X METHYL ISOBUTYL KETONE 108-10-1 X X X U.S. EPA Label Information _____________________________________________________________________________________________ Page 9 / 10 80007 - 1AR FORM A GASKET #1 SEALANT 1.5 OZ. Revision Date 27-Apr-2015 _____________________________________________________________________________________________ EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 27-Apr-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 10 / 10 - HMIS NFPA Health hazards 2 80007 - 1AR FORM A GASKET #1 SEALANT 1.5 OZ. Flammability 1 Physical hazards 0 Personal protection B Health hazards 2 Revision Date 27-Apr-2015 Flammability 1 Instability 0