1. IDENTIFICATION Product identifier Product Name 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT Other means of identification Product Code 80019 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 3 Skin sensitization Category 1 Carcinogenicity Category 1A Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 10 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Danger Flammable liquids Toxic if swallowed May cause an allergic skin reaction May cause cancer Category 2 Highly flammable liquid and vapor Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 26-Jan-2015 SAFETY DATA SHEET Version 1 _____________________________________________________________________________________________ Precautionary Statements - Prevention Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product Avoid breathing dust/fume/gas/mist/vapors/spray Contaminated work clothing should not be allowed out of the workplace Wear protective gloves Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ventilating/lighting/equipment Use only non-sparking tools Take precautionary measures against static discharge Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) If skin irritation or rash occurs: Get medical advice/attention Wash contaminated clothing before reuse IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Rinse mouth In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Harmful to aquatic life with long lasting effects Unknown acute toxicity 54.89515% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% Trade Secret VEGETABLE OIL 68187-84-8 15 - 40 * ROSIN 8050-09-7 10 - 30 * TALC 14807-96-6 10 - 30 * _____________________________________________________________________________________________ Page 2 / 10 80019 - 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT Revision Date 26-Jan-2015 Appearance Dark brown Physical state Liquid Odor Alcohol _____________________________________________________________________________________________ ETHANOL 64-17-5 10 - 30 * 2-PROPANOL 67-63-0 1 - 5 * METHYL ISOBUTYL KETONE 108-10-1 0.1 - 1 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation or rash occurs:. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Highly flammable. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Remove all sources of ignition. Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. _____________________________________________________________________________________________ Page 3 / 10 Revision Date 26-Jan-201580019 - 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT _____________________________________________________________________________________________ Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH ROSIN 8050-09-7 - (vacated) TWA: 0.1 mg/m3 Formaldehyde TWA: 0.1 mg/m3 Formaldehyde TALC 14807-96-6 TWA: 2 mg/m3 particulate matter containing no asbestos and <1% crystalline silica, respirable fraction (vacated) TWA: 2 mg/m3 respirable dust <1% Crystalline silica, containing no Asbestos TWA: 20 mppcf if 1% Quartz or more, use Quartz limit IDLH: 1000 mg/m3 TWA: 2 mg/m3 containing no Asbestos and <1% Quartz respirable dust ETHANOL 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 2-PROPANOL 67-63-0 STEL: 400 ppm TWA: 200 ppm TWA: 400 ppm TWA: 980 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 980 mg/m3 (vacated) STEL: 500 ppm (vacated) STEL: 1225 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 980 mg/m3 STEL: 500 ppm STEL: 1225 mg/m3 METHYL ISOBUTYL KETONE 108-10-1 STEL: 75 ppm TWA: 20 ppm TWA: 100 ppm TWA: 410 mg/m3 (vacated) TWA: 50 ppm (vacated) TWA: 205 mg/m3 (vacated) STEL: 75 ppm (vacated) STEL: 300 mg/m3 IDLH: 500 ppm TWA: 50 ppm TWA: 205 mg/m3 STEL: 75 ppm STEL: 300 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). _____________________________________________________________________________________________ Page 4 / 10 Revision Date 26-Jan-201580019 - 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT _____________________________________________________________________________________________ Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Dark brown Odor Alcohol Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 19.4% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY _____________________________________________________________________________________________ Page 5 / 10 Remarks ? Method Air = 1 Relative density 1.090-1.114 Flash point Water solubility Partially soluble 16 ?C / 61 ?F 80019 - 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT Solubility in other solvents No information available pH Partition coefficient No information available No information available Evaporation rate 7.7 Autoignition temperature No information available Decomposition temperature No information available Ether = 1 Revision Date 26-Jan-2015 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: 12% Values Lower flammability limit: 2.0 Vapor pressure 33 mm Hg Boiling point / boiling range 82 ?C / 180 ?F Vapor density 2.07 _____________________________________________________________________________________________ Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides, Aldehydes, Carboxylic acids 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. May cause sensitization by skin contact. Ingestion Toxic if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 ROSIN 8050-09-7 = 3 mg/kg ( Rat ) = 7600 mg/kg ( Rat ) > 2500 mg/kg ( Rabbit ) = 1.5 mg/L ( Rat ) 4 h ETHANOL 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h 2-PROPANOL 67-63-0 = 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h METHYL ISOBUTYL KETONE 108-10-1 = 2080 mg/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 8.2 mg/L ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA TALC 14807-96-6 - Group 3 - - ETHANOL 64-17-5 A3 Group 1 Known X 2-PROPANOL 67-63-0 - Group 1 - X METHYL ISOBUTYL KETONE 108-10-1 A3 Group 2B - X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen _____________________________________________________________________________________________ Page 6 / 10 80019 - 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT Revision Date 26-Jan-2015 No data available _____________________________________________________________________________________________ IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Contains a known or suspected reproductive toxin. Target Organ Effects Blood, Central nervous system, Central Vascular System (CVS), Eyes, Liver, Reproductive System, Respiratory system, Skin, Thyroid. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 6 mg/kg ATEmix (dermal) 3537 mg/kg ATEmix (inhalation-dust/mist) 23.6 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 37.08865% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea ROSIN 8050-09-7 400: 72 h Desmodesmus subspicatus mg/L EC50 - 3.8 - 5.4: 48 h Daphnia magna mg/L EC50 TALC 14807-96-6 - 100: 96 h Brachydanio rerio g/L LC50 semi-static - ETHANOL 64-17-5 - 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 100: 96 h Pimephales promelas mg/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 2-PROPANOL 67-63-0 1000: 96 h Desmodesmus subspicatus mg/L EC50 1000: 72 h Desmodesmus subspicatus mg/L EC50 11130: 96 h Pimephales promelas mg/L LC50 static 9640: 96 h Pimephales promelas mg/L LC50 flow-through 1400000: 96 h Lepomis macrochirus ?g/L LC50 13299: 48 h Daphnia magna mg/L EC50 METHYL ISOBUTYL KETONE 108-10-1 400: 96 h Pseudokirchneriella subcapitata mg/L EC50 496 - 514: 96 h Pimephales promelas mg/L LC50 flow-through 170: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ETHANOL 64-17-5 -0.32 2-PROPANOL 67-63-0 0.05 METHYL ISOBUTYL KETONE 108-10-1 1.19 Other adverse effects No information available _____________________________________________________________________________________________ Page 7 / 10 80019 - 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT Revision Date 26-Jan-2015 _____________________________________________________________________________________________ 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes METHYL ISOBUTYL KETONE 108-10-1 - Included in waste stream: F039 - U161 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status ETHANOL 64-17-5 Toxic Ignitable 2-PROPANOL 67-63-0 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no 1866 Proper shipping name: Resin, solution, Limited Quantity (LQ) Hazard Class 3 Packing Group II Emergency Response Guide Number 127 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1866 Proper shipping name: Resin, solution, Limited Quantity (LQ) Hazard Class 3 Packing Group II EmS-No F-E, S-E 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Does not comply IECSC Complies KECL Complies PICCS Complies AICS Complies _____________________________________________________________________________________________ Page 8 / 10 Revision Date 26-Jan-201580019 - 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT _____________________________________________________________________________________________ Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2-PROPANOL - 67-63-0 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) METHYL ISOBUTYL KETONE 108-10-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHANOL - 64-17-5 Carcinogen Developmental METHANOL - 67-56-1 Developmental METHYL ISOBUTYL KETONE - 108-10-1 Carcinogen Developmental U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania TALC 14807-96-6 X X X ETHANOL 64-17-5 X X X WATER 7732-18-5 - - X 2-PROPANOL 67-63-0 X X X METHANOL 67-56-1 X X X METHYL ISOBUTYL KETONE 108-10-1 X X X _____________________________________________________________________________________________ Page 9 / 10 80019 - 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT Revision Date 26-Jan-2015 _____________________________________________________________________________________________ U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 26-Jan-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 10 / 10 - Revision Date 26-Jan-2015 HMIS NFPA Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B Health hazards 2 Flammability 3 80019 - 3H AVIATION FORM-A-GASKET #3 SEALANT .25PT Instability 0