1. IDENTIFICATION Product identifier Product Name 34B VALVE GRINDING COMPOUND 3OZ Other means of identification Product Code 80037 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Grinding compound Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 4 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 8 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Harmful if swallowed Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 14-May-2015 SAFETY DATA SHEET Warning Version 1 _____________________________________________________________________________________________ Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell Rinse mouth Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Not applicable. Unknown acute toxicity 43.602% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS substance(s) Chemical Name CAS No Weight-% Trade Secret WATER 7732-18-5 30 - 60 * SILICON CARBIDE 409-21-2 15 - 40 * ETHYLENE GLYCOL 107-21-1 10 - 30 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. _____________________________________________________________________________________________ Page 2 / 8 80037 - 34B VALVE GRINDING COMPOUND 3OZ Revision Date 14-May-2015 Appearance Gray Physical state Paste Odor Slight _____________________________________________________________________________________________ Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical None in particular. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed in a dry and well-ventilated place. Keep from freezing. Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION _____________________________________________________________________________________________ Page 3 / 8 Revision Date 14-May-201580037 - 34B VALVE GRINDING COMPOUND 3OZ _____________________________________________________________________________________________ Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH SILICON CARBIDE 409-21-2 TWA: 10 mg/m3 nonfibrous, inhalable fraction, particulate matter containing no asbestos and <1% crystalline silica TWA: 3 mg/m3 nonfibrous, respirable fraction, particulate matter containing no asbestos and <1% crystalline silica TWA: 0.1 fiber/cm3 respirable fibers, including whiskers, length >5 ?m, aspect ratio >=3:1 as determined by the membrane filter method at 400-450X magnification (4-mm objective), using phase-contrast illumination. TWA: 15 mg/m3 total dust TWA: 5 mg/m3 respirable fraction (vacated) TWA: 10 mg/m3 total dust (vacated) TWA: 5 mg/m3 respirable fraction TWA: 10 mg/m3 total dust TWA: 5 mg/m3 respirable dust ETHYLENE GLYCOL 107-21-1 Ceiling: 100 mg/m3 aerosol only (vacated) Ceiling: 50 ppm (vacated) Ceiling: 125 mg/m3 - NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Paste Appearance Gray Odor Slight Odor threshold No information available _____________________________________________________________________________________________ Page 4 / 8 Revision Date 14-May-2015 Flash point None pH No information available Evaporation rate <1 Butyl acetate = 1 Flammability (solid, gas) No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values 80037 - 34B VALVE GRINDING COMPOUND 3OZ Boiling point / boiling range > 100 ?C / >212 ?F Remarks ? Method _____________________________________________________________________________________________ Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 0 Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Excessive heat. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Harmful if swallowed. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 WATER 7732-18-5 > 90 mL/kg ( Rat ) - - ETHYLENE GLYCOL 107-21-1 4000 - 10200 mg/kg ( Rat ) = 10600 mg/kg ( Rat ) = 9530 ?L/kg ( Rabbit ) - Information on toxicological effects _____________________________________________________________________________________________ Page 5 / 8 Relative density 1.36 Revision Date 14-May-2015 Water solubility Soluble in water Solubility in other solvents No information available Vapor pressure No information available Partition coefficient No information available 80037 - 34B VALVE GRINDING COMPOUND 3OZ Autoignition temperature No information available No data available Vapor density Decomposition temperature No information available >1 Lower flammability limit: No information available Kinematic viscosity No information available Air = 1 Dynamic viscosity No information available _____________________________________________________________________________________________ Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA SILICON CARBIDE 409-21-2 A2 - - - ACGIH (American Conference of Governmental Industrial Hygienists) A2 - Suspected Human Carcinogen IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 1938 mg/kg ATEmix (dermal) 41087 mg/kg 12. ECOLOGICAL INFORMATION Ecotoxicity 43.602% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea ETHYLENE GLYCOL 107-21-1 6500 - 13000: 96 h Pseudokirchneriella subcapitata mg/L EC50 41000: 96 h Oncorhynchus mykiss mg/L LC50 14 - 18: 96 h Oncorhynchus mykiss mL/L LC50 static 27540: 96 h Lepomis macrochirus mg/L LC50 static 40761: 96 h Oncorhynchus mykiss mg/L LC50 static 40000 - 60000: 96 h Pimephales promelas mg/L LC50 static 16000: 96 h Poecilia reticulata mg/L LC50 static 46300: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient ETHYLENE GLYCOL 107-21-1 -1.93 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable _____________________________________________________________________________________________ Page 6 / 8 80037 - 34B VALVE GRINDING COMPOUND 3OZ Revision Date 14-May-2015 _____________________________________________________________________________________________ 14. TRANSPORT INFORMATION DOT Proper shipping name: Not regulated IATA Proper shipping name: Not regulated IMDG Proper shipping name: Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed. IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % ETHYLENE GLYCOL - 107-21-1 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) _____________________________________________________________________________________________ Page 7 / 8 80037 - 34B VALVE GRINDING COMPOUND 3OZ Revision Date 14-May-2015 _____________________________________________________________________________________________ ETHYLENE GLYCOL 107-21-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania SILICON CARBIDE 409-21-2 X X X ETHYLENE GLYCOL 107-21-1 X X X TRIETHANOLAMINE 102-71-6 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 14-May-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 8 / 8 Revision Date 14-May-2015 - HMIS NFPA Health hazards 1 Flammability 0 Physical hazards 0 Personal protection B Health hazards 1 80037 - 34B VALVE GRINDING COMPOUND 3OZ Flammability 0 Instability 0