1. IDENTIFICATION Product identifier Product Name HIGH TACK SPRAY-A-GASKET SEALANT 4 OZ Other means of identification Product Code 80064 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Aerosol Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Reproductive toxicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 Aspiration toxicity Category 1 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 9 Danger Flammable aerosols Revision Date 27-Feb-2015 Causes skin irritation Suspected of damaging fertility or the unborn child May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways Category 1 Extremely flammable aerosol SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 _____________________________________________________________________________________________ Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Keep container tightly closed Ground/bond container and receiving equipment Use only non-sparking tools Take precautionary measures against static discharge Keep cool Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention If skin irritation occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting In case of fire: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0,1 % w/w benzene (EINECS No 200-753-7). The classification as a carcinogen or mutagen need not apply if it can be shown that the substance contains less than 0.1 % w/w 1,3-butadiene (EINECS No. 203-450-8). If the substance is not classified as a carcinogen or mutagen, at least the S-phrases (2-)9-16 (Table 3.2) should apply. This note applies only to certain complex oil-derived substances in Part 3 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% Trade Secret PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 30 - 60 * _____________________________________________________________________________________________ Page 2 / 9 80064 - HIGH TACK SPRAY-A-GASKET SEALANT 4 OZ Revision Date 27-Feb-2015 Odor SolventAppearance Red Physical state Liquid _____________________________________________________________________________________________ SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 64742-89-8 10 - 30 * N-HEXANE 110-54-3 10 - 30 * ETHYL ACETATE 141-78-6 1 - 5 * ACETONE 67-64-1 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. Heating causes rise in pressure with risk of bursting. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures _____________________________________________________________________________________________ Page 3 / 9 80064 - HIGH TACK SPRAY-A-GASKET SEALANT 4 OZ Revision Date 27-Feb-2015 _____________________________________________________________________________________________ Personal precautions Remove all sources of ignition. Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions Do not flush into surface water or sanitary sewer system. See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Keep away from heat/sparks/open flames/hot surfaces. ? No smoking. Take precautionary measures against static discharges. Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH N-HEXANE 110-54-3 TWA: 50 ppm S* TWA: 500 ppm TWA: 1800 mg/m3 (vacated) TWA: 50 ppm (vacated) TWA: 180 mg/m3 IDLH: 1100 ppm TWA: 50 ppm TWA: 180 mg/m3 ETHYL ACETATE 141-78-6 TWA: 400 ppm TWA: 400 ppm TWA: 1400 mg/m3 (vacated) TWA: 400 ppm (vacated) TWA: 1400 mg/m3 IDLH: 2000 ppm TWA: 400 ppm TWA: 1400 mg/m3 ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). _____________________________________________________________________________________________ Page 4 / 9 80064 - HIGH TACK SPRAY-A-GASKET SEALANT 4 OZ Revision Date 27-Feb-2015 _____________________________________________________________________________________________ Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Red Odor Solvent Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 44.5% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY _____________________________________________________________________________________________ Page 5 / 9 Remarks ? Method Air = 1 Relative density 0.90-0.99 Flash point Water solubility Negligible < -18 ?C / < 0 ?F 80064 - HIGH TACK SPRAY-A-GASKET SEALANT 4 OZ Solubility in other solvents No information available Gives a flame projection at full valve opening or flashback at any degree of valve opening pH Partition coefficient No information available Does not apply Evaporation rate >1 Autoignition temperature No information available Decomposition temperature No information available Ether = 1 Revision Date 27-Feb-2015 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available Vapor pressure Not determined Boiling point / boiling range > 38 ?C / 100 ?F Vapor density >1 _____________________________________________________________________________________________ Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Incompatible materials Strong oxidizing agents Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May be harmful by inhalation. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 64742-89-8 - = 3000 mg/kg ( Rabbit ) - N-HEXANE 110-54-3 = 25 g/kg ( Rat ) = 3000 mg/kg ( Rabbit ) = 48000 ppm ( Rat ) 4 h ETHYL ACETATE 141-78-6 = 5620 mg/kg ( Rat ) > 18000 mg/kg ( Rabbit ) > 20 mL/kg ( Rabbit ) - ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity No information available. Reproductive toxicity Product is or contains a chemical which is a known or suspected reproductive hazard. Target Organ Effects Central nervous system, Eyes, Peripheral Nervous System (PNS), Respiratory system, Skin. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 53308 mg/kg ATEmix (dermal) 5950 mg/kg ATEmix (inhalation-dust/mist) 4008 mg/l ATEmix (inhalation-vapor) 192000 mg/l _____________________________________________________________________________________________ Page 6 / 9 No data available 80064 - HIGH TACK SPRAY-A-GASKET SEALANT 4 OZ Revision Date 27-Feb-2015 _____________________________________________________________________________________________ 12. ECOLOGICAL INFORMATION Ecotoxicity None known 45% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea SOLVENT NAPHTHA (PETROLEUM), LIGHT ALIPH. 64742-89-8 4700: 72 h Pseudokirchneriella subcapitata mg/L EC50 - - N-HEXANE 110-54-3 - 2.1 - 2.98: 96 h Pimephales promelas mg/L LC50 flow-through 1000: 24 h Daphnia magna mg/L EC50 ETHYL ACETATE 141-78-6 3300: 48 h Desmodesmus subspicatus mg/L EC50 352 - 500: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 220 - 250: 96 h Pimephales promelas mg/L LC50 flow-through 484: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 560: 48 h Daphnia magna mg/L EC50 Static ACETONE 67-64-1 - 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient PETROLEUM GASES, LIQUEFIED, SWEETENED 68476-86-8 <=2.8 ETHYL ACETATE 141-78-6 0.6 ACETONE 67-64-1 -0.24 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes ETHYL ACETATE 141-78-6 - Included in waste stream: F039 - U112 ACETONE 67-64-1 - Included in waste stream: F039 - U002 This product contains one or more substances that are listed with the State of California as a hazardous waste. _____________________________________________________________________________________________ Page 7 / 9 80064 - HIGH TACK SPRAY-A-GASKET SEALANT 4 OZ Revision Date 27-Feb-2015 _____________________________________________________________________________________________ Chemical Name California Hazardous Waste Status N-HEXANE 110-54-3 Toxic Ignitable ETHYL ACETATE 141-78-6 Toxic Ignitable ACETONE 67-64-1 Ignitable 14. TRANSPORT INFORMATION DOT UN/ID no UN 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 IMDG UN/ID no UN 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Does not comply IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % N-HEXANE - 110-54-3 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes _____________________________________________________________________________________________ Page 8 / 9 80064 - HIGH TACK SPRAY-A-GASKET SEALANT 4 OZ Revision Date 27-Feb-2015 _____________________________________________________________________________________________ Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) N-HEXANE 110-54-3 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ ETHYL ACETATE 141-78-6 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania N-HEXANE 110-54-3 X X X ACETONE 67-64-1 X X X ETHYL ACETATE 141-78-6 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 27-Feb-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 9 / 9 Revision Date 27-Feb-2015 - HMIS NFPA Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B Health hazards 2 80064 - HIGH TACK SPRAY-A-GASKET SEALANT 4 OZ Flammability 3 Instability 0