1. IDENTIFICATION Product identifier Product Name SA-8 BATTERY CLEANER 5 OZ AE Other means of identification Product Code 80369 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Battery Cleaning Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label elements Emergency Overview Hazards not otherwise classified (HNOC) Not applicable Other Information _____________________________________________________________________________________________ Page 1 / 8 SAFETY DATA SHEET Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Warning Aerosol Pressurized container: May burst if heated Category 3 Revision Date 20-Mar-2015 Odor MildAppearance White Physical state Liquid _____________________________________________________________________________________________ Causes mild skin irritation Unknown acute toxicity 4.4% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Chemical Name CAS No Weight-% Trade Secret WATER 7732-18-5 60 - 100 * SODIUIM BICARBONATE 144-55-8 5 - 10 * PROPANE 74-98-6 3 - 7 * 2-BUTOXYETHANOL 111-76-2 1 - 5 * TRIETHANOLAMINE 102-71-6 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Call a physician. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Heating causes rise in pressure with risk of bursting. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. _____________________________________________________________________________________________ Page 2 / 8 Revision Date 20-Mar-201580369 - SA-8 BATTERY CLEANER 5 OZ AE _____________________________________________________________________________________________ Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Use personal protective equipment as required. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Avoid contact with skin and eyes. Do not eat, drink or smoke when using this product. Contents under pressure. Do not puncture or incinerate cans. Conditions for safe storage, including any incompatibilities Storage Conditions Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F. Keep from freezing. Incompatible materials Strong oxidizing agents, Strong bases, Strong acids, Alkali, Aluminum 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH PROPANE 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 2-BUTOXYETHANOL 111-76-2 TWA: 20 ppm TWA: 50 ppm TWA: 240 mg/m3 (vacated) TWA: 25 ppm (vacated) TWA: 120 mg/m3 (vacated) S* S* IDLH: 700 ppm TWA: 5 ppm TWA: 24 mg/m3 TRIETHANOLAMINE 102-71-6 TWA: 5 mg/m3 - - NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls _____________________________________________________________________________________________ Page 3 / 8 Revision Date 20-Mar-201580369 - SA-8 BATTERY CLEANER 5 OZ AE _____________________________________________________________________________________________ Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance White Odor Mild Odor threshold No information available Explosive properties No information available Oxidizing properties No information available Other Information Softening point No information available Molecular weight No information available VOC Content (%) 8.4% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity _____________________________________________________________________________________________ Page 4 / 8 Revision Date 20-Mar-2015 Flash point Water solubility Soluble in water No information available Solubility in other solvents No information available Aerosol Category 3 pH Partition coefficient No information available 7.95-8.05 Evaporation rate <1 Autoignition temperature No information available Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available Values Lower flammability limit: No information available 80369 - SA-8 BATTERY CLEANER 5 OZ AE Vapor pressure Not determined Boiling point / boiling range > 93 ?C / 199 ?F No data available Vapor density >1 Remarks ? Method Air = 1 Relative density 1.035-1.045 _____________________________________________________________________________________________ Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Heat, flames and sparks. Keep from freezing. Incompatible materials Strong oxidizing agents, Strong bases, Strong acids, Alkali, Aluminum Hazardous Decomposition Products Carbon oxides Aldehydes Ketones and their derivatives 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May cause irritation of respiratory tract. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Ingestion may cause irritation to mucous membranes. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 WATER 7732-18-5 > 90 mL/kg ( Rat ) - - SODIUIM BICARBONATE 144-55-8 = 4220 mg/kg ( Rat ) - - PROPANE 74-98-6 - - = 658 mg/L ( Rat ) 4 h 2-BUTOXYETHANOL 111-76-2 = 470 mg/kg ( Rat ) = 99 mg/kg ( Rabbit ) = 450 ppm ( Rat ) 4 h TRIETHANOLAMINE 102-71-6 = 4190 mg/kg ( Rat ) > 16 mL/kg ( Rat ) > 20 mL/kg ( Rabbit ) - Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA 2-BUTOXYETHANOL 111-76-2 A3 Group 3 - - TRIETHANOLAMINE 102-71-6 - Group 3 - - ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Not classifiable as a human carcinogen Chronic toxicity May cause adverse effects on the bone marrow and blood-forming system. May cause adverse liver effects. Target Organ Effects Blood, Central nervous system, Eyes, Hematopoietic System, kidney, Liver, Respiratory system, Skin. _____________________________________________________________________________________________ Page 5 / 8 80369 - SA-8 BATTERY CLEANER 5 OZ AE Revision Date 20-Mar-2015 _____________________________________________________________________________________________ The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 9187 mg/kg ATEmix (dermal) 26488 mg/kg ATEmix (inhalation-gas) 5613727 mg/l ATEmix (inhalation-dust/mist) 37.5 mg/l ATEmix (inhalation-vapor) 11250 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 11% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea SODIUIM BICARBONATE 144-55-8 650: 120 h Nitzschia linearis mg/L EC50 8250 - 9000: 96 h Lepomis macrochirus mg/L LC50 static 2350: 48 h Daphnia magna mg/L EC50 2-BUTOXYETHANOL 111-76-2 - 1490: 96 h Lepomis macrochirus mg/L LC50 static 2950: 96 h Lepomis macrochirus mg/L LC50 1000: 48 h Daphnia magna mg/L EC50 1698 - 1940: 24 h Daphnia magna mg/L EC50 TRIETHANOLAMINE 102-71-6 216: 72 h Desmodesmus subspicatus mg/L EC50 169: 96 h Desmodesmus subspicatus mg/L EC50 10600 - 13000: 96 h Pimephales promelas mg/L LC50 flow-through 1000: 96 h Pimephales promelas mg/L LC50 static 450 - 1000: 96 h Lepomis macrochirus mg/L LC50 static 1386: 24 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient PROPANE 74-98-6 2.3 2-BUTOXYETHANOL 111-76-2 0.81 TRIETHANOLAMINE 102-71-6 -2.53 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated packaging Do not reuse container. US EPA Waste Number Not applicable 14. TRANSPORT INFORMATION DOT _____________________________________________________________________________________________ Page 6 / 8 Revision Date 20-Mar-201580369 - SA-8 BATTERY CLEANER 5 OZ AE _____________________________________________________________________________________________ UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.2 Emergency Response Guide Number 126 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.2 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Not Listed IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % 2-BUTOXYETHANOL - 111-76-2 1.0 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard No Fire hazard No Sudden release of pressure hazard No Reactive Hazard No CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) _____________________________________________________________________________________________ Page 7 / 8 Revision Date 20-Mar-201580369 - SA-8 BATTERY CLEANER 5 OZ AE _____________________________________________________________________________________________ CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania PROPANE 74-98-6 X X X 2-BUTOXYETHANOL 111-76-2 X X X TRIETHANOLAMINE 102-71-6 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 20-Mar-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 8 / 8 Revision Date 20-Mar-2015 - HMIS NFPA Health hazards 1 Flammability 1 Physical hazards 0 Personal protection B Health hazards 1 80369 - SA-8 BATTERY CLEANER 5 OZ AE Flammability 1 Instability 0