1. IDENTIFICATION Product identifier Product Name SA9 BATTERY PROTECTOR & SEALER 5 OZ AE Other means of identification Product Code 80370 Synonyms None Recommended use of the chemical and restrictions on use Recommended Use Battery Sealant Uses advised against No information available Details of the supplier of the safety data sheet Company Phone Number 1-87-Permatex (877) 376-2839 24 Hour Emergency Phone Number Chem-Tel: 800-255-3924 International Emergency: 00+1+ 813-248-0585 Contract Number: MIS0003453 E-mail address This email address is being protected from spambots. You need JavaScript enabled to view it. 2. HAZARDS IDENTIFICATION Classification OSHA Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2 Carcinogenicity Category 2 Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2 Aspiration toxicity Category 1 Label elements Emergency Overview _____________________________________________________________________________________________ Page 1 / 10 Version 1 Manufacturer Address ITW Permatex 10 Columbus Blvd. Hartford, CT 06106 USA Danger Flammable aerosols Category 1 Distributor ITW Permatex Canada 35 Brownridge Road, Unit 1 Halton Hills, ON Canada L7G 0C6 Telephone: (800) 924-6994 Revision Date 14-May-2015 SAFETY DATA SHEET _____________________________________________________________________________________________ Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Do not breathe dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. ? No smoking Do not spray on an open flame or other ignition source Pressurized container: Do not pierce or burn, even after use Precautionary Statements - Response IF exposed or concerned: Get medical advice/attention Specific treatment (see supplemental first aid instructions on this label) IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention If skin irritation occurs: Get medical advice/attention IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Do NOT induce vomiting Precautionary Statements - Storage Store locked up Protect from sunlight. Do not expose to temperatures exceeding 50 ?C/122 ?F Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Hazards not otherwise classified (HNOC) Not applicable Other Information Toxic to aquatic life with long lasting effects. Unknown acute toxicity 7.5% of the mixture consists of ingredient(s) of unknown toxicity 3. COMPOSITION/INFORMATION ON INGREDIENTS _____________________________________________________________________________________________ Page 2 / 10 80370 - SA9 BATTERY PROTECTOR & SEALER 5 OZ AE Causes skin irritation Causes serious eye irritation Suspected of causing cancer May cause drowsiness or dizziness May cause damage to organs through prolonged or repeated exposure May be fatal if swallowed and enters airways Revision Date 14-May-2015 Extremely flammable aerosol Odor SolventAppearance Purple Physical state Liquid _____________________________________________________________________________________________ substance(s) Chemical Name CAS No Weight-% Trade Secret XYLENE 1330-20-7 10 - 30 * PROPANE 74-98-6 10 - 30 * ACETONE 67-64-1 10 - 30 * MINERAL OIL 8042-47-5 5 - 10 * DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 5 - 10 * ETHYL BENZENE 100-41-4 1 - 5 * *The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES Description of first aid measures General advice Get medical advice/attention if you feel unwell. Eye contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin contact IF ON SKIN:. Wash skin with soap and water. If skin irritation persists, call a physician. Wash contaminated clothing before reuse. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. If symptoms persist, call a physician. Ingestion IF SWALLOWED:. Call a physician or poison control center immediately. Do NOT induce vomiting. Self-protection of the first aider Use personal protective equipment as required. Avoid contact with skin, eyes or clothing. Most important symptoms and effects, both acute and delayed Symptoms See section 2 for more information. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Carbon dioxide (CO2), Dry chemical, Foam Unsuitable extinguishing media None. Specific hazards arising from the chemical Extremely flammable. Keep product and empty container away from heat and sources of ignition. Vapors may travel to source of ignition and flash back. Explosion data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. _____________________________________________________________________________________________ Page 3 / 10 Revision Date 14-May-201580370 - SA9 BATTERY PROTECTOR & SEALER 5 OZ AE _____________________________________________________________________________________________ 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Use personal protective equipment as required. Remove all sources of ignition. Ensure adequate ventilation, especially in confined areas. Avoid contact with eyes and skin. Environmental precautions Environmental precautions See Section 12 for additional ecological information. Do not flush into surface water or sanitary sewer system. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Eliminate all ignition sources if safe to do so. Ensure adequate ventilation. Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid breathing vapors or mists. Avoid contact with skin, eyes or clothing. Wash thoroughly after handling. Wash contaminated clothing before reuse. Use personal protective equipment as required. Conditions for safe storage, including any incompatibilities Storage Conditions Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Incompatible materials Strong oxidizing agents, Acids 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines . Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH XYLENE 1330-20-7 STEL: 150 ppm TWA: 100 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 655 mg/m3 - PROPANE 74-98-6 TWA: 1000 ppm TWA: 1000 ppm TWA: 1800 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1800 mg/m3 IDLH: 2100 ppm TWA: 1000 ppm TWA: 1800 mg/m3 ACETONE 67-64-1 STEL: 750 ppm TWA: 500 ppm TWA: 1000 ppm TWA: 2400 mg/m3 (vacated) TWA: 750 ppm (vacated) TWA: 1800 mg/m3 (vacated) STEL: 2400 mg/m3 The acetone STEL does not apply to the cellulose acetate fiber industry. It is in effect for all other sectors (vacated) STEL: 1000 ppm IDLH: 2500 ppm TWA: 250 ppm TWA: 590 mg/m3 _____________________________________________________________________________________________ Page 4 / 10 80370 - SA9 BATTERY PROTECTOR & SEALER 5 OZ AE Revision Date 14-May-2015 _____________________________________________________________________________________________ ETHYL BENZENE 100-41-4 TWA: 20 ppm TWA: 100 ppm TWA: 435 mg/m3 (vacated) TWA: 100 ppm (vacated) TWA: 435 mg/m3 (vacated) STEL: 125 ppm (vacated) STEL: 545 mg/m3 IDLH: 800 ppm TWA: 100 ppm TWA: 435 mg/m3 STEL: 125 ppm STEL: 545 mg/m3 NIOSH IDLH Immediately Dangerous to Life or Health Other Information Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). Appropriate engineering controls Engineering Controls Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin and body protection Wear protective gloves and protective clothing. Respiratory protection Use NIOSH-approved air-purifying respirator with organic vapor cartridge or canister, as appropriate. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Regular cleaning of equipment, work area and clothing is recommended. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Purple Odor Solvent Odor threshold No information available Explosive properties No information available Oxidizing properties No information available _____________________________________________________________________________________________ Page 5 / 10 Values Lower flammability limit: No information available Vapor pressure Not determined Boiling point / boiling range > 38 ?C / 100 ?F Vapor density >1 Remarks ? Method Air = 1 Relative density 0.85 80370 - SA9 BATTERY PROTECTOR & SEALER 5 OZ AE Flash point Water solubility No information available < -18 ?C / < 0 ?F Solubility in other solvents No information available Gives a flame projection at full valve opening or flashback at any degree of valve opening pH Partition coefficient No information available No information available Evaporation rate > 1 Autoignition temperature No information available Revision Date 14-May-2015 Decomposition temperature No information available Butyl acetate = 1 Kinematic viscosity No information available Flammability (solid, gas) No information available Dynamic viscosity No information available Property Flammability Limit in Air Melting point / freezing point No information available Upper flammability limit: No information available _____________________________________________________________________________________________ Other Information Softening point No information available Molecular weight No information available VOC Content (%) 45% Density No information available Bulk density No information available 10. STABILITY AND REACTIVITY Reactivity Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid Keep away from all heat sources, open flames and other sources of ignition. Incompatible materials Strong oxidizing agents, Acids Hazardous Decomposition Products Carbon oxides 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Inhalation May be harmful by inhalation. May cause drowsiness or dizziness. Eye contact Contact with eyes may cause irritation. May cause redness and tearing of the eyes. Skin contact May cause skin irritation and/or dermatitis. Ingestion Harmful if swallowed. Potential for aspiration if swallowed. Aspiration may cause pulmonary edema and pneumonitis. Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 XYLENE 1330-20-7 = 3500 mg/kg ( Rat ) > 1700 mg/kg ( Rabbit ) > 4350 mg/kg ( Rabbit ) = 29.08 mg/L ( Rat ) 4 h = 5000 ppm ( Rat ) 4 h PROPANE 74-98-6 - - = 658 mg/L ( Rat ) 4 h ACETONE 67-64-1 = 5800 mg/kg ( Rat ) - = 50100 mg/m3 ( Rat ) 8 h MINERAL OIL 8042-47-5 > 5000 mg/kg ( Rat ) - - DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 > 5000 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 5.2 mg/L ( Rat ) 4 h ETHYL BENZENE 100-41-4 = 3500 mg/kg ( Rat ) = 15400 mg/kg ( Rabbit ) = 17.2 mg/L ( Rat ) 4 h Information on toxicological effects Symptoms No information available. Delayed and immediate effects as well as chronic effects from short and long-term exposure _____________________________________________________________________________________________ Page 6 / 10 Revision Date 14-May-2015 No data available 80370 - SA9 BATTERY PROTECTOR & SEALER 5 OZ AE _____________________________________________________________________________________________ Sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA XYLENE 1330-20-7 - Group 3 - - ETHYL BENZENE 100-41-4 A3 Group 2B - X ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 2B - Possibly Carcinogenic to Humans Not classifiable as a human carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Target Organ Effects Central nervous system, Eyes, Respiratory system, Skin. The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 6594 mg/kg ATEmix (dermal) 5376 mg/kg ATEmix (inhalation-gas) 1459569 mg/l ATEmix (inhalation-dust/mist) 5.4 mg/l 12. ECOLOGICAL INFORMATION Ecotoxicity 32.5% of the mixture consists of components(s) of unknown hazards to the aquatic environment Chemical Name Algae/aquatic plants Fish Crustacea XYLENE 1330-20-7 - 13.4: 96 h Pimephales promelas mg/L LC50 flow-through 2.661 - 4.093: 96 h Oncorhynchus mykiss mg/L LC50 static 13.5 - 17.3: 96 h Oncorhynchus mykiss mg/L LC50 13.1 - 16.5: 96 h Lepomis macrochirus mg/L LC50 flow-through 19: 96 h Lepomis macrochirus mg/L LC50 7.711 - 9.591: 96 h Lepomis macrochirus mg/L LC50 static 23.53 - 29.97: 96 h Pimephales promelas mg/L LC50 static 780: 96 h Cyprinus carpio mg/L LC50 semi-static 780: 96 h Cyprinus carpio mg/L LC50 30.26 - 40.75: 96 h Poecilia reticulata mg/L LC50 static 3.82: 48 h water flea mg/L EC50 0.6: 48 h Gammarus lacustris mg/L LC50 ACETONE 67-64-1 - 4.74 - 6.33: 96 h Oncorhynchus mykiss mL/L LC50 6210 - 8120: 96 h Pimephales promelas mg/L LC50 static 8300: 96 h Lepomis macrochirus mg/L LC50 10294 - 17704: 48 h Daphnia magna mg/L EC50 Static 12600 - 12700: 48 h Daphnia magna mg/L EC50 MINERAL OIL 8042-47-5 - 10000: 96 h Lepomis macrochirus mg/L LC50 - DISTILLATES (PETROLEUM), HYDROTREATED LIGHT 64742-47-8 - 45: 96 h Pimephales promelas mg/L LC50 flow-through 2.2: 96 h Lepomis macrochirus mg/L LC50 static 2.4: 96 h Oncorhynchus mykiss mg/L LC50 static 4720: 96 h Den-dronereides heteropoda mg/L LC50 _____________________________________________________________________________________________ Page 7 / 10 80370 - SA9 BATTERY PROTECTOR & SEALER 5 OZ AE Revision Date 14-May-2015 _____________________________________________________________________________________________ ETHYL BENZENE 100-41-4 4.6: 72 h Pseudokirchneriella subcapitata mg/L EC50 438: 96 h Pseudokirchneriella subcapitata mg/L EC50 2.6 - 11.3: 72 h Pseudokirchneriella subcapitata mg/L EC50 static 1.7 - 7.6: 96 h Pseudokirchneriella subcapitata mg/L EC50 static 11.0 - 18.0: 96 h Oncorhynchus mykiss mg/L LC50 static 9.6: 96 h Poecilia reticulata mg/L LC50 static 4.2: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 7.55 - 11: 96 h Pimephales promelas mg/L LC50 flow-through 32: 96 h Lepomis macrochirus mg/L LC50 static 9.1 - 15.6: 96 h Pimephales promelas mg/L LC50 static 1.8 - 2.4: 48 h Daphnia magna mg/L EC50 Persistence and degradability No information available. Bioaccumulation No information available. Mobility No information available. Chemical Name Partition coefficient XYLENE 1330-20-7 2.77 - 3.15 PROPANE 74-98-6 2.3 ACETONE 67-64-1 -0.24 MINERAL OIL 8042-47-5 >6 ETHYL BENZENE 100-41-4 3.118 Other adverse effects No information available 13. DISPOSAL CONSIDERATIONS Waste treatment methods Disposal of wastes This material, as supplied, is a hazardous waste according to federal regulations (40 CFR 261). Contaminated packaging Do not reuse container. US EPA Waste Number D001 Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes XYLENE 1330-20-7 - Included in waste stream: F039 - U239 ACETONE 67-64-1 - Included in waste stream: F039 - U002 ETHYL BENZENE 100-41-4 - Included in waste stream: F039 - - This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical Name California Hazardous Waste Status XYLENE 1330-20-7 Toxic Ignitable ACETONE 67-64-1 Ignitable ETHYL BENZENE 100-41-4 Toxic Ignitable_____________________________________________________________________________________________ Page 8 / 10 Revision Date 14-May-201580370 - SA9 BATTERY PROTECTOR & SEALER 5 OZ AE _____________________________________________________________________________________________ 14. TRANSPORT INFORMATION DOT UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 Emergency Response Guide Number 126 IATA UN/ID no ID 8000 Proper shipping name: Consumer commodity Hazard Class 9 ERG Code 9L IMDG UN/ID no 1950 Proper shipping name: Aerosols, Limited Quantity (LQ) Hazard Class 2.1 EmS-No F-D, S-U 15. REGULATORY INFORMATION International Inventories TSCA Complies DSL/NDSL Complies EINECS/ELINCS Complies ENCS Complies IECSC Complies KECL Complies PICCS Complies AICS Complies Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 Chemical Name SARA 313 - Threshold Values % XYLENE - 1330-20-7 1.0 ETHYL BENZENE - 100-41-4 0.1 SARA 311/312 Hazard Categories Acute health hazard Yes Chronic Health Hazard Yes Fire hazard Yes Sudden release of pressure hazard No Reactive Hazard No _____________________________________________________________________________________________ Page 9 / 10 80370 - SA9 BATTERY PROTECTOR & SEALER 5 OZ AE Revision Date 14-May-2015 _____________________________________________________________________________________________ CWA (Clean Water Act) This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances XYLENE 1330-20-7 100 lb - - X ETHYL BENZENE 100-41-4 1000 lb X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) XYLENE 1330-20-7 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ ACETONE 67-64-1 5000 lb - RQ 5000 lb final RQ RQ 2270 kg final RQ ETHYL BENZENE 100-41-4 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals Chemical Name California Proposition 65 ETHYL BENZENE - 100-41-4 Carcinogen U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania XYLENE 1330-20-7 X X X ACETONE 67-64-1 X X X PROPANE 74-98-6 X X X ETHYL BENZENE 100-41-4 X X X U.S. EPA Label Information EPA Pesticide Registration Number Not applicable NFPA (National Fire Protection Association) HMIS (Hazardous Material Information System) Revision Date 14-May-2015 Disclaimer The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet _____________________________________________________________________________________________ Page 10 / 10 - Revision Date 14-May-2015 HMIS NFPA Health hazards 2 Flammability 3 Physical hazards 0 Personal protection B Health hazards 2 Flammability 3 80370 - SA9 BATTERY PROTECTOR & SEALER 5 OZ AE Instability 0