PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. Date of issue: 04/30/2014 Revision date: 04/30/2014 Version: 1.0 04/30/2014 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name : PENRAY ENGINE OIL TREATMENT Product code : 3112 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Engine oil treatment. 1.3. Details of the supplier of the safety data sheet The Penray Companies, Inc. 440 Denniston Ct. 60090 Wheeling, IL T (800) 373-6729 1.4. Emergency telephone number Emergency number : (800) 373-6729 CHEMTREC (800) 424-9300 CHEMTREC International +1 (703) 527-3887 24 hr SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Eye irritation 2A Skin sensitization 1 Reproductive toxicity 1B Aspiration hazard 1 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : Causes serious eye irritation. May cause an allergic skin reaction. May damage fertility or the unborn child. May be fatal if swallowed and enters airways. Precautionary statements (GHS-US) : Wash hands thoroughly after handling. Avoid breathing gas/mist/vapors/spray. Contaminated work clothing must not be allowed out of the workplace. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves/protective clothing/eye protection/face protection. If exposed or concerned: Get medical advice/attention. If on skin: Wash with plenty of water. Wash contaminated clothing before reuse. If skin irritation or rash occurs: Get medical advice/attention. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. If swallowed: Immediately call a poison center/doctor. Do NOT induce vomiting. Store locked up. Dispose of contents and container in accordance with all local, regional, national and international regulations. 2.3. Other hazards No additional information available SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable 3.2. Mixture Name Product identifier % GHS-US classification Distillates, petroleum, solvent-refined heavy paraffinic (CAS No) 64741-88-4 30 - 60 Not classified Distillates, petroleum, hydrotreated light naphthenic (CAS No) 64742-53-6 15 - 40 Not classified Distillates, petroleum, hydrotreated heavy naphthenic (CAS No) 64742-52-5 10 - 30 Asp. Tox. 1 Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (CAS No) 68649-42-3 1 - 5 Skin Irrit. 2 Eye Dam. 1 Phenol, (tetrapropenyl) derivatives (CAS No) 74499-35-7 0.1 - 1 Skin Irrit. 2 Eye Irrit. 2A Repr. 2 Phenol, (tetrapropenyl) derivatives, calcium salts (CAS No) 132752-19-3 0.1 - 1 Repr. 1B PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 2/6 Name Product identifier % GHS-US classification The exact percentage (concentration) of composition has been withheld as a trade secret in accordance with paragraph (i) of ?1910.1200. SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : If inhaled and if breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical advice/attention if you feel unwell. First-aid measures after skin contact : In case of contact, immediately flush skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician if irritation develops and persists. First-aid measures after eye contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. If easy to do, remove contact lenses, if worn. If irritation persists, get medical attention. First-aid measures after ingestion : If swallowed, do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. May cause sensitization by skin contact. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. 4.3. Indication of any immediate medical attention and special treatment needed Symptoms may not appear immediately. In case of accident or if you feel unwell, seek medical advice immediately (show the label or SDS where possible). SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Powder, water spray, foam, carbon dioxide. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Products of combustion may include, and are not limited to: oxides of carbon. 5.3. Advice for firefighters Protection during firefighting : Keep upwind of fire. Wear full fire fighting turn-out gear (full Bunker gear) and respiratory protection (SCBA). Use water spray to keep fire-exposed containers cool. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use personal protection recommended in Section 8. Isolate the hazard area and deny entry to unnecessary and unprotected personnel. 6.2. Methods and material for containment and cleaning up For containment : Contain and/or absorb spill with inert material (e.g. sand, vermiculite), then place in a suitable container. Do not flush to sewer or allow to enter waterways. Use appropriate Personal Protective Equipment (PPE). Methods for cleaning up : Scoop up material and place in a disposal container. Provide ventilation. 6.3. Reference to other sections See section 8 for further information on protective clothing and equipment and section 13 for advice on waste disposal. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Avoid contact with skin and eyes. Avoid breathing gas/mist/vapors/spray. Do not swallow. Handle and open container with care. When using do not eat, drink or smoke. Hygiene measures : Launder contaminated clothing before reuse. Wash hands before eating, drinking, or smoking. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep out of the reach of children. Keep container tightly closed. Store locked up. 7.3. Specific end use(s) Not available. SECTION 8: Exposure controls/personal protection 8.1. Control parameters PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 3/6 Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) USA ACGIH ACGIH TWA (mg/m?) 5 mg/m? USA OSHA OSHA PEL (TWA) (mg/m?) 5 mg/m? Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Phenol, (tetrapropenyl) derivatives (74499-35-7) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. Phenol, (tetrapropenyl) derivatives, calcium salts (132752-19-3) USA ACGIH ACGIH TWA Not applicable. USA OSHA OSHA PEL (TWA) Not applicable. 8.2. Exposure controls Appropriate engineering controls : Use ventilation adequate to keep exposures (airborne levels of dust, fume, vapor, etc.) below recommended exposure limits. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear chemically resistant protective gloves. Eye protection : Safety glasses or goggles are recommended when using product. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Environmental exposure controls : Maintain levels below Community environmental protection thresholds. Other information : Do not eat, smoke or drink where material is handled, processed or stored. Wash hands carefully before eating or smoking. Handle according to established industrial hygiene and safety practices. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid. Appearance : Clear. Colour : Amber. Odour : Petroleum odor. Odour threshold : No data available. pH : No data available. Relative evaporation rate (butylacetate=1) : No data available. Melting point : No data available. Freezing point : No data available. Boiling point : No data available. Flash point : > 100 ?C (> 212 ?F) Self ignition temperature : No data available. Decomposition temperature : No data available. Flammability (solid, gas) : Not flammable. Vapour pressure : No data available. Relative vapour density at 20 ?C : No data available. Relative density : 0.876 - 0.886 Solubility : No data available. PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 4/6 Log Pow : No data available. Log Kow : No data available. Viscosity, kinematic : No data available. Viscosity, dynamic : No data available. Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity No dangerous reaction known under conditions of normal use. 10.2. Chemical stability Stable under normal storage conditions. 10.3. Possibility of hazardous reactions No dangerous reaction known under conditions of normal use. 10.4. Conditions to avoid Heat. Incompatible materials. Direct sunlight. 10.5. Incompatible materials Strong oxidizing agents. 10.6. Hazardous decomposition products May include, and are not limited to: oxides of carbon. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified 3112 LD50 oral rat > 2000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) No data available. Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) 2.18 mg/l/4h Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 2000 mg/kg LC50 inhalation rat (mg/l) 2.18 mg/l/4h Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) LD50 oral rat > 5000 mg/kg LD50 dermal rabbit > 5000 mg/kg LC50 inhalation rat (mg/l) > 5 mg/l/4h Methyl alcohol (67-56-1) LD50 oral rat 5628 mg/kg LD50 dermal rabbit 15800 mg/kg LC50 inhalation rat (mg/l) 83.2 mg/l/4h Skin corrosion/irritation : Based on available data, the classification criteria are not met. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : May cause an allergic skin reaction. Germ cell mutagenicity : Based on available data, the classification criteria are not met. Carcinogenicity : Based on available data, the classification criteria are not met. Reproductive toxicity : May damage fertility or the unborn child. Specific target organ toxicity (single exposure) : Based on available data, the classification criteria are not met. Specific target organ toxicity (repeated exposure) : Based on available data, the classification criteria are not met. Aspiration hazard : May be fatal if swallowed and enters airways. PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 5/6 Symptoms/injuries after inhalation : May cause respiratory tract irritation. Symptoms/injuries after skin contact : May cause skin irritation. Symptoms may include redness, drying, defatting and cracking of the skin. May cause sensitisation by skin contact. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms may include discomfort or pain, excess blinking and tear production, with marked redness and swelling of the conjunctiva. Symptoms/injuries after ingestion : May be fatal if swallowed and enters airways. This product may be aspirated into the lungs and cause chemical pneumonitis. May cause stomach distress, nausea or vomiting. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : May cause long-term adverse effects in the aquatic environment. 12.2. Persistence and degradability 3112 Persistence and degradability Not established. 12.3. Bioaccumulative potential 3112 Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects No additional information available SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : This material must be disposed of in accordance with all local, state, provincial, and federal regulations. The generation of waste should be avoided or minimized wherever possible. SECTION 14: Transport information In accordance with DOT 14.1. UN number Not applicable 14.2. UN proper shipping name Not applicable 14.3. Additional information Other information : No supplementary information available. Special transport precautions : Do not handle until all safety precautions have been read and understood. SECTION 15: Regulatory information 15.1. US Federal regulations Distillates, petroleum, solvent-refined heavy paraffinic (64741-88-4) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, hydrotreated light naphthenic (64742-53-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory Distillates, petroleum, hydrotreated heavy naphthenic (64742-52-5) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phosphorodithioic acid, O,O-di-C1-14-alkyl esters, zinc salts (68649-42-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phenol, (tetrapropenyl) derivatives (74499-35-7) Listed on the United States TSCA (Toxic Substances Control Act) inventory Phenol, (tetrapropenyl) derivatives, calcium salts (132752-19-3) Listed on the United States TSCA (Toxic Substances Control Act) inventory 15.2. US State regulations 3112 State or local regulations This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. PENRAY ENGINE OIL TREATMENT Safety Data Sheet according to the Hazard Communication Standard (CFR29 1910.1200) HazCom 2012. 04/30/2014 EN (English) 6/6 SOURCE AGENCY CARCINOGEN CLASSIFICATIONS: IARC International Agency for Research on Cancer. 1 - Carcinogenic to humans; 2A - Probably carcinogenic to humans; 2B - Possibly carcinogenic to humans; 3 - Not classifiable; 4 - Probably not carcinogenic to humans. NTP National Toxicology Program. 1 - Evidence of Carcinogenicity; 2 - Known Human Carcinogens; 3 - Reasonably anticipated to be Human Carcinogen; 4 - Substances delisted from report on Carcinogens; 5 - Twelfth Report - Items under consideration. SECTION 16: Other information Indication of changes : None. Date of issue : 04/30/2014 Other information : None. NFPA health hazard : 2 NFPA fire hazard : 1 NFPA reactivity : 0 This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product